A triple porosity scheme for fluid/solid substitution: theory and experiment

Quantifying the effects of pore-filling materials on elastic properties of porous rocks is of considerable interest in geophysical practice. For rocks saturated with fluids, the Gassmann equation is proved effective in estimating the exact change in seismic velocity or rock moduli upon the changes in properties of pore infill. For solid substance or viscoelastic materials, however, the Gassmann theory is not applicable as the rigidity of the pore fill (either elastic or viscoelastic) prevents pressure communication in the pore space, which is a key assumption of the Gassmann equation. In this paper, we explored the elastic properties of a sandstone sample saturated with fluid and solid substance under different confining pressures. This sandstone sample is saturated with octadecane, which is a hydrocarbon with a melting point of 28°C, making it convenient to use in the lab in both solid and fluid forms. Ultrasonically measured velocities of the dry rock exhibit strong pressure dependency, which is largely reduced for the filling of solid octadecane. Predictions by the Gassmann theory for the elastic moduli of the sandstone saturated with liquid octadecane are consistent with ultrasonic measurements, but underestimate the elastic moduli of the sandstone saturated with solid octadecane. Our analysis shows that the difference between the elastic moduli of the dry and solid-octadecane-saturated sandstone is controlled by the squirt flow between stiff, compliant, and the so-called intermediate pores (with an aspect ratio larger than that of compliant pore but much less than that of stiff pores). Therefore, we developed a triple porosity model to quantify the combined squirt flow effects of compliant and intermediate pores saturated with solid or viscoelastic infill. Full saturation of remaining stiff pores with solid or viscoelastic materials is then considered by the lower embedded bound theory. The proposed model gave a reasonable fit to the ultrasonic measurements of the elastic moduli of the sandstone saturated with liquid or solid octadecane. Comparison of the predictions by the new model to other solid substitution schemes implied that accounting for the combined effects of compliant and intermediate pores is necessary to explain the solid squirt effects.     

A concerted research effort to advance the hydrological understanding of tropical páramos

Páramos, a neotropical alpine grassland-peatland biome of the northern Andes and Central America, play an essential role in regional and global cycles of water, carbon, and nutrients. They act as water towers, delivering water and ecosystem services from the high mountains down to the Pacific, Caribbean, and Amazon regions. Páramos are also widely recognized as a biodiversity and climate change hot spots, yet they are threatened by anthropogenic activities and environmental changes. Despite their importance for water security and carbon storage, and their vulnerability to human activities, only three decades ago, páramos were severely understudied. Increasing awareness of the need for hydrological evidence to guide sustainable management of páramos prompted action for generating data and for filling long-standing knowledge gaps. This has led to a remarkably successful increase in scientific knowledge, induced by a strong interaction between the scientific, policy, and (local) management communities. A combination of well-established and innovative approaches has been applied to data collection, processing, and analysis. In this review, we provide a short overview of the historical development of research and state of knowledge of the hydrometeorology, flux dynamics, anthropogenic impacts, and the influence of extreme events in páramos. We then present emerging technologies for hydrology and water resources research and management applied to páramos. We discuss how converging science and policy efforts have leveraged traditional and new observational techniques to generate an evidence base that can support the sustainable management of páramos. We conclude that this co-evolution of science and policy was able to successfully cover different spatial and temporal scales. Lastly, we outline future research directions to showcase how sustainable long-term data collection can foster the responsible conservation of páramos water towers.     

All-sky ultraviolet surveys: the needs and the means

This is a crucial time in the history of astronomy with major all-sky surveying work being carried out in all spectral bands, as well as in astrometry. The results of this activity are advancing all fields of astrophysical research, from the investigation of exo-planetary systems to the study of the chemical evolution of the Universe. Full sky surveys are available from the radio domain to X-ray wavelengths but not in the ultraviolet range (UV). While large UV missions are currently under discussion within the astrophysical community and at the major Space Agencies, the efficient use of resources requires preparatory work that can fill the UV surveying gap. This article summarizes the research and on-going activities in this field.     

Asteroid impact effects on Snowball Earth

Several Snowball Earth periods, in which the Earth has been (almost) totally glaciated, are known from Earth history. Neither the trigger for the initiation, nor the reason for the ending of such phases, are well understood. Here we discuss some mechanical effects of the impact of asteroids 5–10 km in diameter on the Snowball Earth environment. An impact of this scale is the largest impact that is statistically predictable for 10–60 Myr time periods. The impact cratering itself (shock waves, impact crater formation) is not powerful enough to change the natural climate evolution path on Earth. However, the products of impact (mainly—water vapor) can be quickly distributed over a substantial part of the globe, influencing the global circulation (e.g., facilitating cloud formation). It is a question for future studies to confirm if such an event (which is possible statistically during this interval) may or may not have influenced the global climate of the Snowball Earth, and/or contributed to deglaciation.     

Sedimentology of early Pliocene sandstones in the south-western Taiwan foreland: Implications for basin physiography in the early stages of collision

This work presents sedimentological observations and interpretations on three detailed sections of the Pliocene Yutengping/Ailiaochiao formations, deposited in the early stages of collision in Taiwan. Seven facies associations record paleoenvironments of deposition ranging from nearshore to lower offshore with a strong influence of tidal reworking, even in shelfal sub-tidal environments, and a pro-delta setting characterized by mass-flows. The association of shallow facies of the upper offshore to lower shoreface with pro-delta turbidite facies sourced in the orogen to the east suggests a peculiar setting in which turbidite deposition occurred below wave base but on the shelf, in water depths of probably less than 100 m. This adds to the examples of “shallow turbidites” increasingly commonly found in foreland basins and challenges the classical view of a “deep” early underfilled foreland basin. Time series analysis on tidal rhythmites allow us to identify a yearly signal in the form of periodic changes of sand-supply, energy and bioturbation that suggests a marked seasonality possibly affecting precipitation and sediment delivery as well as temperature. The Taiwan foreland basin may also present a potentially high-resolution record in shallow sediments of the early installation of monsoonal circulation patterns in east Asia. We confirm partly the paleogeography during the early stages of collision in Taiwan: the Chinese margin displayed a pronounced non-cylindrical geometry with a large basement promontory to the west in place of the modern Taiwan mountain range. Collision in Taiwan may have happened at once along the whole length of the modern mountain range, instead of progressively from north to south as classically considered.     

Distribution and expression of gas seeps in a gas hydrate province of the northeastern Sakhalin continental slope, Sea of Okhotsk

Multidisciplinary surveys were conducted to investigate gas seepage and gas hydrate accumulation on the northeastern Sakhalin continental slope (NESS), Sea of Okhotsk, during joint Korean–Russian–Japanese expeditions conducted from 2003 to 2007 (CHAOS and SSGH projects). One hundred sixty-one gas seeps were detected in a 2000 km² area of the NESS (between 53°45′N and 54°45′N). Active gas seeps in a gas hydrate province on the NESS were evident from features in the water column, on the seafloor, and in the subsurface: well-defined hydroacoustic anomalies (gas flares), side-scan sonar structures with high backscatter intensity (seepage structures), bathymetric structures (pockmarks and mounds), gas- and gas-hydrate-related seismic features (bottom-simulating reflectors, gas chimneys, high-amplitude reflectors, and acoustic blanking), high methane concentrations in seawater, and gas hydrates in sediment near the seafloor. These expressions were generally spatially related; a gas flare would be associated with a seepage structure (mound), below which a gas chimney was present. The spatial distribution of gas seeps on the NESS is controlled by four types of geological structures: faults, the shelf break, seafloor canyons, and submarine slides. Gas chimneys that produced enhanced reflection on high-resolution seismic profiles are interpreted as active pathways for upward gas migration to the seafloor. The chimneys and gas flares are good indicators of active seepage.     

The significance of isotope specific diffusion coefficients for reaction-transport models of sulfate reduction in marine sediments

Modeling isotopic signatures in systems affected by diffusion, advection, and a reaction which modifies the isotopic abundance of a given species, is a discipline in its infancy. Traditionally, much emphasis has been placed on kinetic isotope effects during biochemical reactions, while isotope effects caused by isotope specific diffusion coefficients have been neglected. A recent study by Donahue et al. (2008) suggested that transport related isotope effects may be of similar magnitude as microbially mediated isotope effects. Although it was later shown that the assumed differences in the isotope specific diffusion coefficients were probably overstated by one or two orders of magnitude (Bourg, 2008), this study raises several important issues: (1) Is it possible to directly calculate isotopic enrichment factors from measured concentration data without modeling the respective system? (2) Do changes in porosity and advection velocity modulate the influence of isotope specific diffusion coefficients on the fractionation factor α? (3) If one has no a priori knowledge whether diffusion coefficients are isotope specific or not, what is the nature and magnitude of the error introduced by either assumption? Here we argue (A) That the direct substitution of measured data into a differential equation is problematic and cannot be used as a replacement for a reaction-transport model; (B) That the transport related fractionation scales linearly with the difference between the respective diffusion coefficients of a given isotope system, but depends in a complex non-linear way on the interplay between advection velocity, and downcore changes of temperature and porosity. Last but not least, we argue that the influence of isotope specific diffusion coefficients on microbially mediated sulfate reduction in typical marine sediments is considerably smaller than the error associated with the determination of the fractionation factor.     

Spatial variation in fluid flow and geochemical fluxes across the sediment-seawater interface at the Carlos Ribeiro mud volcano (Gulf of Cadiz)

Submarine mud volcanism is an important pathway for transfer of deep-sourced fluids enriched in hydrocarbons and other elements into the ocean. Numerous mud volcanoes (MVs) have been discovered along oceanic plate margins, and integrated elemental fluxes are potentially significant for oceanic chemical budgets. Here, we present the first detailed study of the spatial variation in fluid and chemical fluxes at the Carlos Ribeiro MV in the Gulf of Cadiz. To this end, we combine analyses of the chemical composition of pore fluids with a 1-D transport-reaction model to quantify fluid fluxes, and fluxes of boron, lithium and methane, across the sediment-seawater interface. The pore fluids are significantly depleted in chloride, but enriched in lithium, boron and hydrocarbons, relative to seawater. Pore water profiles of sulphate, hydrogen sulphide and total alkalinity indicate that anaerobic oxidation of methane occurs at 34-180 cm depth below seafloor. Clay mineral dehydration, and in particular the transformation of smectite to illite, produces pore fluids that are depleted in chloride and potassium. Profiles of boron, lithium and potassium are closely related, which suggests that lithium and boron are released from the sediments during this transformation. Pore fluids are expelled into the water column by advection; fluid flow velocities are 4 cm yr⁻¹ at the apex of the MV but they rapidly decrease to 0.4 cm yr⁻¹ at the periphery. The associated fluxes of boron, lithium and methane vary between 7-301, 0.5-6 and 0-806 mmol m⁻² yr⁻¹, respectively. We demonstrate that fluxes of Li and B due to mud volcanism may be important on a global scale, however, release of methane into the overlying water column is suppressed by microbial methanotrophy.