Transfer and early diagenesis of biogenic silica oxygen isotope signals during settling and sedimentation of diatoms in a temperate freshwater lake (Lake Holzmaar, Germany)

We have investigated the transfer of oxygen isotope signals of diatomaceous silica (δ¹⁸O_diatom) from the epilimnion (0-7 m) through the hypolimnion to the lake bottom (∼20 m) in freshwater Lake Holzmaar, Germany. Sediment-traps were deployed in 2001 at depths of 7 and 16 m to harvest fresh diatoms every 28 days. The 7 m trap collected diatoms from the epilimnion being the main zone of primary production, while the 16 m trap collected material already settled through the hypolimnion. Also a bottom sediment sample was taken containing diatom frustules from approximately the last 25 years. The δ¹⁸O_diatom values of the 7 m trap varied from 29.4‰ in spring/autumn to 26.2‰ in summer according to the temperature dependence of oxygen isotope fractionation and represent the initial isotope signal in this study. Remarkably, despite the short settling distance δ¹⁸O_diatom values of the 7 and the 16 m trap were identical only during spring and autumn seasons while from April to September δ¹⁸O_diatom values of the 16 m trap were roughly ∼1.5‰ enriched in ¹⁸O compared to those of the 7 m trap. Isotopic exchange with the isotopically lighter water of the hypolimnion would shift the δ¹⁸O_diatom value to lower values during settling from 7 to 16 m excluding this process as a cause for the deviation. Dissolution of opal during settling with intact organic coatings of the diatom cells and near neutral pH of the water should only cause a minor enrichment of the 16 m values. Nevertheless, opal from the bottom sediment was found to be 2.5‰ enriched in ¹⁸O compared to the weighted average of the opal from the 7 m trap. Thus, resuspension of bottom material must have contributed to the intermediate δ¹⁸O_diatom signal of the 16 m trap during summer. Dissolution experiments allowed further investigation of the cause for the remarkably enriched δ¹⁸O_diatom value of the bottom sediment. Experiments with different fresh diatomaceous materials show an increase of opaline ¹⁸O at high pH values which is remarkably reduced when organic coatings of the cells still exist or at near neutral pH. In contrast, high pH conditions do not affect the δ¹⁸O_diatom values of sub-fossil and even fossil opal. IR analyses show that the ¹⁸O enrichment of the sedimentary silica is associated with a decrease in Si-OH groups and the formation of Si-O-Si linkages. This indicates a silica dehydroxylation process as cause for the isotopic enrichment of the bottom sediment. Silica dissolution and dehydroxylation clearly induce a maturation process of the diatom oxygen isotope signal presumably following an exponential behaviour with a rapid initial phase of signal alteration. The dynamics of this process is of particular importance for the quantitative interpretation of sedimentary δ¹⁸O_diatom values in terms of palaeothermometry.     

Palaeoenvironmental change recorded in the palaeodunefields of the western Murray Basin,South Australia – New data from single grain OSL-dating

This study is concerned with the reconstruction of the palaeoenvironmental history of southeastern Australia for the last ～300 ka by establishing a luminescence chronology of dune sand deposition in the western Murray Basin (South Australia). In the study area, vast fields of palaeodunes, stabilised by vegetation, provide evidence of past environmental change. In total 98 samples were collected from dune sand layers at 13 different dune sections. The time of their deposition was determined using optically stimulated luminescence dating of single quartz grains, accounting for the impact of post-depositional mixing by the use of a finite mixture model. The oldest depositional phase demonstrates that dune sand layers of great antiquity are preserved in the western Murray Basin, ranging up to at least 380 ka. Phases of substantial dune sand deposition were identified for the periods 18–38 ka and 63–72 ka. Older depositional phases also exist, but are poorly resolved due to relatively large errors of the luminescence ages. Aeolian deposition during the last termination and the Holocene is relatively limited, with a slight clustering of ages at the time of the Antarctic Cold Reversal and from 5–8 ka. Two modern ages give evidence of very recent dune sand deposition. Comparison with other palaeoclimate records from the region suggests that phases with high aeolian sedimentation coincide with more arid conditions and breaks in the dune record with more humid phases. Thus, although dune records are often discontinuous and their interpretation in palaeoclimatic terms is not always straightforward, the palaeodunes of the western Murray Basin show a good preservation of phases of aeolian activity and provide useful information for palaeoenvironmental reconstruction.     

Dating of lower terrace sediments from the Middle Rhine area, Germany

Modern and known-age Pleistocene fluvial sediments were investigated by optical dating of quartz to test the suitability of the approach for dating deposits from the deeply incised Middle Rhine Valley. Samples from modern flood sediments revealed skewed distributions indicating different residual levels of equivalent dose (D_e) within the different aliquots. Nevertheless, a substantial number of aliquots from the modern deposits reflect D_e values close to zero. For the Pleistocene samples, optical ages are in general consistent with age control given by the presence of the Laacher See Tephra and radiocarbon dating. However, some samples overestimate the known age by a few thousand years when using the arithmetic mean. This is apparently explained by including aliquots in the determination of mean D_e where the optical signal was incompletely bleached at deposition. The most difficult issue in this context is identifying a suitable approach that can distinguish between the variability of D_e due to partial bleaching and microdosimetry. However, even when considering these limitations it appears that optical dating will by a quite suitable method to date Pleistocene sediments from such a complex fluvial environment, especially when focusing on a precision scale beyond a few thousand years.     

Earthquakes,catastrophic sediment additions and the response of urban stream communities

Disturbance events can regularly impact stream ecosystems; however, large-scale catastrophic disturbances are rare. From September 2010 to September 2011 Christchurch City experienced over 8500 earthquakes including a magnitude 7.1. One consequence was catastrophic additions of silt and sand into waterways throughout the city. Of 161 km of permanent waterways, 102 km (63%) were affected by earthquake siltation. Benthic invertebrates and fish communities were compared across 16 streams with differing siltation. Invertebrate taxonomic richness decreased significantly (mean 17 taxa reduced to 10 taxa) and EPT taxa (Ephemeroptera, Plecoptera and Trichoptera) were removed entirely from streams receiving heavy siltation. Fish richness and density decreased significantly, with fish absent from some heavily silted streams. Many of these urban streams are sourced from springs and their stable flows and low gradient limit their ability to flush sediment. We predict that without human intervention there will be a long-term sediment legacy and it may take many years for these streams to recover from this catastrophic disturbance.     

A Comparison of In Situ Analytical Methods for Trace Element Measurement in Gold Samples from Various South African Gold Deposits

Trace element concentrations in gold grains from various geological units in South Africa were measured in situ by field emission‐electron probe microanalysis (FE‐EPMA), laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) and synchrotron micro X‐ray fluorescence spectroscopy (SR‐μ‐XRF). This study assesses the accuracy, precision and detection limits of these mostly non‐destructive analytical methods using certified reference materials and discusses their application in natural sample measurement. FE‐EPMA point analyses yielded reproducible and discernible concentrations for Au and trace concentrations of S, Cu, Ti, Hg, Fe and Ni, with detection limits well below the actual concentrations in the gold. LA‐ICP‐MS analyses required larger gold particles (> 60 μm) to avoid contamination during measurement. Elements that measured above detection limits included Ag, Cu, Ti, Fe, Pt, Pd, Mn, Cr, Ni, Sn, Hg, Pb, As and Te, which can be used for geochemical characterisation and gold fingerprinting. Although LA‐ICP‐MS measurements had lower detection limits, precision was lower than FE‐EPMA and SR‐μ‐XRF. The higher variability in absolute values measured by LA‐ICP‐MS, possibly due to micro‐inclusions, had to be critically assessed. Non‐destructive point analyses of gold alloys by SR‐μ‐XRF revealed Ag, Fe, Cu, Ni, Pb, Ti, Sb, U, Cr, Co, As, Y and Zr in the various gold samples. Detection limits were mostly lower than those for elements measured by FE‐EPMA, but higher than those for elements measured by LA‐ICP‐MS.     

Species composition,abundance and biomass of microphytoplankton in the KwaZulu-Natal Bight on the east coast of South Africa

Nearshore marine environments are influenced by an array of variables that can either be land-derived or of marine origin, and nearshore phytoplankton communities may differ in their taxonomic composition and biomass in response to such variables. The KwaZulu-Natal Bight (hereafter referred to as ‘the bight’) is an oligo-mesotrophic, nearshore oceanic environment, that is influenced by both terrestrial run-off and upwelling. A microphytoplankton survey of the bight conducted over several stations and depths and two seasons was conducted in order to ascertain species composition, abundance and biomass. Microphytoplankton abundance was generally low (a maximum of 180 000 cells l–1 was recorded) but differed considerably between sites and seasons. A total of 99 taxa of mainly Bacillariophyceae and some Dinophyceae, Prymnesiophyceae and Cyanophyceae were identified in the present study. In the central bight, higher abundance and biomass were measured in February (wet season), which may be a possible consequence of terrestrial nutrient inputs. In the northern and southern bight we measured higher abundance and biomass in August (dry season). Upwelling was not detected during the study, but an influence of terrestrial nutrient sources was detected at the coastal stations. Turbid conditions were specific to the site near the Thukela River mouth and possibly influenced abundance, biomass and species composition at this site. Historic data on microphytoplankton composition are scarce, but comparisons with surveys from the 1960s reveal that around 60% of the common diatoms recorded then also occurred in the present study. Small taxa [20–200 µm] dominated the microphytoplankton community. Community composition was fairly uniform throughout the bight in both seasons, dominated in general by Chaetoceros species, and on occasion co-dominated by Thalassionema nitzschioides and Dactyliosolen fragilissimus.     

Quaternary coral-reef terraces from Kish and Qeshm Islands, Persian Gulf: new radiometric ages and tectonic implications

A survey of raised coral reef terraces in locations along the southern coast of Iran was carried out with the aim of assessing regional Late Quaternary tectonic uplift rates influenced by salt doming. Two islands were studied: Kish, where no previous data were available, and Qeshm, where a previous survey had already attributed the lowest step in two sequences of raised marine terraces to the Last Interglacial.Twenty-five ESR and seven Th/U ages were obtained from Kish Island. The results show that this flat, about 32 m high, gently domed island was totally submerged during the last two interglacial periods. Corals ascribed to MIS 5 and MIS 7 have been dated at the same elevations, near the present sea level, and in the uppermost, inner part of the island, giving evidence of a polycyclic origin for the island surface deposits. Following a discussion on the possible position of eustatic peaks during MIS 7, a maximal average uplift rate of 0.20±0.02 mm/yr has been deduced from the above data.Furthermore, the survey obtained some new results from Qeshm, where seven ESR ages confirmed the MIS 5 age of the lowest raised marine terrace (that also corresponds to an uplift rate of about 0.2 mm/yr), failing, however, to date older steps, due to significant coral-sample re-crystallisation. In the western part of Qeshm, five new radiocarbon ages of elevated beach material demonstrated the variability of uplift rates even along short distances around an active salt dome.     

Treatment of broad palaeodose distributions in OSL dating of dune sands from the western Murray Basin, South Australia

Preliminary results of an optically stimulated luminescence dating study in the western Murray Basin in semi-arid south-eastern Australia are presented. The ultimate objective of the dating study is a reconstruction of dune formation indicative of palaeoclimatic changes in this region. So far, one site has been dated using the single-aliquot regenerative (SAR) dose protocol for quartz. A high scatter in individual palaeodoses was observed, which is unexpected in supposedly well bleached aeolian deposits. Therefore other sources of variability such as microdosimetry and bioturbation have to be taken into account. Nevertheless, the resulting ages are in chronostratigraphic order and document a long aeolian record from 180 to 9 ka.