南极菲尔德斯半岛湖泊沉积物的稀土地球化学

本文研究了燕鸥湖、西湖和基太湖湖泊沉积物的稀土地球化学。这些湖泊沉积物的稀土分布模式与菲尔德斯半岛第三纪火山岩非常相似，它们的物质来源是菲尔德斯半岛岛弧火山岩。湖泊沉积相与冰碛层稀土模式的差异，反映了它们经历的化学风化程度不同、粘土含量不同。Ｃｅ异常意味着每个湖泊沉积旋回结束的阶段气候是比较干燥的。湖泊沉积物的稀土含量和分布模式变化小，也意味着在中晚更新世时气候是比较干燥的。     

中国东部上地幔岩石组构与稀土配分之间的关系

本文通过对中国东部新生代玄武岩中二辉橄榄岩包体的研究认为,上地幔岩石变形结构和组构类型在不同大地构造单元中的分布是不同的,据此,可划分为华北—东北上地幔弱变形域和东南沿海上地幔强变形域。与变形特征对应的东南沿海地区包体稀土元素配分型式为LREE富集型,华北—东北地区包体稀土元素配分型式则为平坦型和轻微LREE富集型,这表明上地幔流变剪切作用强度与稀土元素富集作用呈正相关,同时反映出上地幔流变状态的差异。根据包体变形特征,我们提出华北—东北地区与东南沿海地区中新生代具有截然不同的大地构造演化特征。     

山东碳酸岩磷灰石的特征及其研究意义

鲁中隆起的北缘分布着100多个燕山期的碳酸岩体。本文详细研究了岩体中磷灰石的一些重要特征,包括晶体形态、物理性质、光学常数、晶胞参数、化学成分、包裹体及钕锶同位素组成等。并据所得资料对岩体的成因,成岩物质来源等问题进行探讨。     

姑婆山主体花岗岩中富钇钍石的发现

本文论述一种据X射线粉晶分析属钍石类矿物结构,但成分上富含高量重稀土(HRE_2O_3达11.51%),且以钇(Y_2O_3达8.69%)为主的钍石矿物。文中在阐述其产状、共生组合及物性的基础上,对其生成条件进行了初步探讨,认为该矿物的生成是两次替代作用的结果。铀在其中起了媒介作用;重稀土(特别是钇)在姑婆山主体花岗岩边部相岩石中的明显富集是其生成的物质条件。     

云南双沟变质橄榄岩中蛇纹石的稀土元素空间分布

本文探讨变质橄榄岩的ＬＲＥＥ富集型及Ｕ型分布的ＲＥＥ球粒陨石模型，是橄榄石固有的还是后期蚀变形成的。并寻求复原蚀变前橄榄石的ＲＥＥ丰度及型式。我们用蛇纹石颗粒代表蚀变后的橄榄石，用分选法和化学分层剥离法对样品进行予处理。用中子活化分析（ＮＡＡ）手段进行了测试。结果表明：分选法确定了ＬＲＥＥ的主要赋存载体是蛇纹石。分层剥离最后内核的ＲＥＥ丰度及模型，可近似地作为原来（未蚀变前）橄榄石的ＲＥＥ丰度及模型。     

743阳离子交换快速分离——ICPS-PGS2单道扫描直读光谱仪测定地质样品中15个微量稀土元素

本文采用过氧化钠(Na_2O_2)熔样,743阳离子交换树脂快速分离,0.4mol/L柠檬酸25ml洗脱稀土,无需浓缩,即可用lCPS-PGS2单道扫描直读光谱仪直接测定15个微量稀土元素。在选择的最佳测量条件下,本法测定下限为0.005~g/ml(Eu)-0.50μg/ml(Ce),标准加入回收在88％—110％之间,样品分析精度为3.3％—17％,样品分析结果与参考值相符。本法适用于一般地质样品中微量稀土元素的例行分析。     

Rare-earth element mobility during ore-forming hydrothermal alteration: A case study of Dongping gold deposit Hebei Province,China

REE mobility during hydrothermal ore-forming processes has been extensively investigated in recent years and the potential of REE to provide information about ore forming processes has commonly been recognized.The Dongping gold deposit,which is located in northwestern Hebei Province,China,occurring in the inner contact zone of the Shuiquangou syenite complex,is spatially,and probably genetically,related to the syenite,the deposit was formed under the moderate to high temperature(220℃ to 320℃),weakly acidic to weakly alkaline,rather high fo2(lgfo2=-30～-34)environment.The REE study of the host rocks,altered wall rocks,ores and gangue minerals from the deposit suggests that the REEs have been mobilized and differentiated during K-feldspathization and silicification.The extremely altered syenite enveloping auriferous quartz vein shows positive Ce anomaly and larger LREE/HREE ratio than that of the unaltered syenite.The REE concentrations and patterns of the ores are determined by the ore types and mineral assemblages,LREE/HREE ratios in the gangue quartz and hydrothermal Kfeldspars are relatively low.The most significant observation is that the gangue quartz shows significant positive Eu anomaly,whereas the hydrothermal K-feldspars show less significant or no positive Eu anomaly at all relative to the primary feldspar in the unaltered syenite. It is evident that the REEs are mobile during K-feldspathization and silicification in the ore forming process.Weak to moderate K-feldspathization caused REE mobility without apparent differentiation with the exception of extreme K-feldspathization and silicification which resulted in significant depletion of HREE and Eu and relative enrichment of Ce.The REE,Y,U,Th and Au contents of the syenite decrease as the degrees of K-feldspathization and silicification of the rocks increase towards the auriferous quartz veins.As the ores were deposited under a rather oxidized environment,Ce^4 predominated over Ce^3 .The precipitation of the former in the form of CeO2 or absorpted onto the secondary mineral assemblage resulted in the inconsistent removal of the REE and the relative Ce enrichment in the strongly altered rocks.in contrast,Eu was present mainly in a low valence state (Eu^2 ).The geochemical differences from the other REE^3 and much less sites in the secondary minerals to accommodate the Eu released form the original minerals resulted in the enrichment of Eu in the fluids.The mobility and differentiation of REE and the coherent mobilities of Y,U,Th and Au also support the argument that the syenite is one of the source rocks for gold mineralization.The REE contents and patterns of the altered rocks enveloping the auriferous quartz vein could be used as a guide for locating ore veins in mineral exploration.     

姑婆山复式岩体的基本特征及其与成矿作用的关系

姑婆山复式岩体由晚侏罗世里松岩体、姑婆山岩体及早白垩世新路岩体组成。复式岩体为壳幔混合源成因。据岩石地球化学判断和分析,姑婆山岩体和新路岩体为含锡岩体;整个姑婆山复式岩体为含钨岩体,里松岩体和姑婆山岩体为含稀有、稀土岩体。上述矿产的形成与岩石中挥发份F、B及放射性U、T h等元素的高含量有关。     

相山、下庄铀矿田稀土元素特征对比

为了从大的区域上探讨铀矿的成矿作用,本文分别采集了相山、下庄两个铀矿田的围岩和矿石样品并用ICP-M S方法进行测定。结果发现两个铀矿田的围岩REE特征均为LREE富集型,具有明显的负铕异常。相山矿田的矿石富集REE特别是HREE,并且与铀含量呈正相关关系,矿石和围岩的负铕异常相同;下庄矿田的矿石亏损REE尤其是LREE,具有比围岩更强烈的负铕异常。认为两矿田的围岩都是由沉积岩为源岩的地壳物质部分熔融形成的,ΣCO2是两个铀矿田的主要矿化剂,也是铀和REE运移的主要载体,造成两矿石REE特征不同的主要原因是相山矿田围岩蚀变以酸性为主而下庄铀矿田围岩蚀变以碱性为主。     

冕宁-德昌稀土成矿带碳酸岩流体研究

通过对四川冕宁-德昌稀土矿带主要矿物中包裹体岩相学、显微测温分析与包裹体成分分析,指出由岩浆碳酸岩分异出的成矿流体为富含高密度CO2、K、Na、SO42-和多种成矿元素的超临界流体,流体以高温、高压、超高盐度、富CO2为特征,从早期到晚期流体中CO2含量增加。结合前人对碳酸岩流体、稀土矿带周边新生代盆地中无机成因CO2气藏、富钾卤水、稳定同位素和隋性气体同位素研究成果,从碳酸岩流体的性质、流体体系、碳、氦同位素组成,初步探讨了碳酸岩流体与周边新生代盆地中CO2气藏、富钾卤水的成因联系。