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21.
Maggie Cusack Yannicke Dauphin Jean-Pierre Cuif Murielle Salom Andy Freer Huabing Yin 《Chemical Geology》2008,253(3-4):172-179
Biominerals are natural composite materials comprising organic and inorganic components. Detailed knowledge of the nature and distribution of both components is a crucial requirement in order to advance our understanding of biomineral formation, their material properties and preservation potential as well as the interpretation of environmental data. Detailed chemical data are essential for our understanding of the nature and distribution of such components. Micro-XANES mapping at the sulphur K-edge reveals that, in the brachiopod Terebratulina retusa, the sulphate concentration is higher in the outer (primary) layer than in the calcite fibres of the secondary layer. This is co-incident with a higher magnesium concentration. In contrast, the sheaths surrounding the calcite fibres contain sulphur as thiol, confirming the presence of protein while, the sulphur within the fibres themselves, occurs as sulphate. Micro-XANES analysis of the insoluble organic extract from T. retusa indicates the presence of organic sulphate while Micro-Raman spectroscopy confirms that structurally substituted sulphate (SSS) is also present although semi-quantitative Raman spectroscopy carried out in this spectral region (wavenumbers 900–1200) indicates that the sulphate present is at the threshold of detection by Raman spectroscopy. The distribution of phosphorus in the shell of T. retusa correlates well with that of protein indicating the presence of phosphorylated proteins in the periostracum, the sheaths surrounding the calcite fibres and the interface between the primary and secondary layer. 相似文献
22.
Controlling of landsides safely and economically is a great challenge to mine operators because landslides are major geological
problems especially in open-pit mines. In this paper, a case history at Panluo open-pit mine is presented in detail to share
the experiences and lessons with mine operators. Panluo open-pit mine is located in the southwestern Fujian province of China.
It is the largest open-pit iron mine in the Fujian province and was planned in 1965 and is in full operation from 1978. In
July 1990, an earthquake of magnitude 5.3 in Taiwan Strait and big rainstorms impacted the mine slope, causing tension cracks
and rather large-scale failures, and forming a U-shaped landslide. Total potential volume was estimated to be up to 1.0 × 106 m3. This directly threatened the mine production. In order to protect the mine production and the dwellers’ safety around, a
dynamic comprehensive method was implemented including geotechnical investigations, in-situ testing and monitoring, stability
analysis, and many mitigation and preventive measures. These measures slowed down the development and further occurrence of
the landslide. The results showed that the landslides were still active, it was slowed with the control measures and moved
rapidly with rainfall and mining down. However, no catastrophic accidents occurred and the pit mining was continued till it
was closed at the elevation of 887 m in 2000. As a successful case of landslide control at an open-pit mine for 10 years,
this paper reports the controlling measures in details. These experiences of landslide control may be beneficial to other
similar mines for landslide control. 相似文献
23.
采于墨西哥湾GC238海底天然气渗漏区浅表层的冷泉碳酸盐岩呈结核状产出,由方解石微晶和胶结物及少量的黄铁矿构成。胶结物由直径为0.1~0.5 m的方解石化的球体、卵形体、棒状体组成,充填于方解石晶体之间。冷泉碳酸盐岩结核下表面发育有由方解石化的球体、卵形体、棒状体组成的薄层,其中的一些球状集合体(约5 m)断面显示发育有核和外壳的层圈结构。黄铁矿呈草莓状,也具有相似的层圈结构。这种层状结构与活体古细菌被硫酸盐还原细菌包裹的层圈结构相似。样品中所保存的球体、卵形体、棒状体及其所组成的层圈结构可能是石化的甲烷氧化古细菌和硫酸盐还原细菌。 相似文献
24.
地下水库特征水位与特征库容的划分及确定研究 总被引:2,自引:0,他引:2
参考地表水库调控指标的划分方法,将地下水库的特征水位与特征库容划分为死水位与死库容、正常蓄水位与调蓄库容、腾空库容和已占库容以及总库容,并提出了特征水位确定的一般原则以及承压地下水库的库容计算原理与方法。以大庆市西部地下水位降落漏斗区地下水库为实例,确定地下水库水量调蓄的死水位为115m,正常蓄水位为132m,结合现状地下水位,计算得出相应的死库容为1161.58×108m3,调蓄库容为1.75×108m3,腾空库容为1.57×108m3,总库容为1163.33×108m3。 相似文献
25.
26.
冲绳海槽有孔虫壳体的微量元素Sr,Nd同位素地球化学 总被引:6,自引:1,他引:6
钙质生物壳的微量元素组合和Sr,Nd同位素组成是识别海底混合源沉积物中生物源物质相对贡献的重要参数.冲绳海槽有孔虫壳体强烈富集Sr,P,Mn和Ba,富集Li,U,Th,Sc,Co,Pb,Zn,Cr,Rb,Y,Sb和轻稀土元素,弱富集V,Ga,Zr,Nb,Cd和中稀土元素,相对贫Ge,Mo,In,Sn,Cs,Hf,Ta,W,Tl,Bi和重稀土元素,海水中微量元素的背景含量和生物活动对微量元素的选择性吸收是有孔虫壳体中微量元素发生富集和贫化的主要机制,冲绳海槽有孔虫壳体的稀土元素配分模式与海水和太平洋有孔虫的有明显差异,表现出中稀土元素相对富集,并具有微弱的负Ce异常.有孔虫壳体的Sr,Nd同位素比值也与大洋海水不同,分别为0.709769和0.512162,前者略高于大洋海水,后者略低于大洋海水,表明冲绳海槽海水明显受大陆河水影响. 相似文献
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