钨—水杨基荧光酮络合物的极谱催化波研究

在HCl、KCl介质中,W(Ⅵ)-水杨基荧光酮络合物有一灵敏的催化波,峰电位为-1.22V(υs.SCE),W(Ⅵ)浓度在4.4×10~(-11)—4.4 ×10~(-8)mol/L范围内与峰电流呈线性关系,检测限2.2×10~(-11)mol/L。实验表明该波为氢催化波,可用于痕量或超痕量W的测定。     

Ti—PAR—KBrO3体系络合吸附催化波的研究

在HAc-NaAc(pH为6.2)存在下,Ti(Ⅳ)—PAR—KBrO_3体系形成一灵敏的催化波,峰电位为-1.08V(vs.SCE),Ti(Ⅳ)浓度在1.0×10~(-8)～8.0×10~(-7)mol/L范围与峰电流成线性关系,络合物的络合比为Ti(Ⅳ):PAR=1:1,实验证明该波为络合吸附催化波。可用于痕量Ti(Ⅳ)的测定。     

钨—桑色素络合物极谱催化波的研究

在H2SO4，NaCl介质中，钨—桑色素络合物能产生一灵敏的催化波．峰电位为-1．16V(vs．SCE)，W(Ⅵ)浓度在1．7×10^-10～3．4×10^-7mol/L范围内与峰电流呈线性关系。检测限8．5×10^-11mol/L。电化学实验结果表明该波为氢催化波。可用于痕量钨的测定．     

一滴汞脉冲极谱法测定矿石中痕量铀

本文报道了在pH5.5的PMBP-醋酸-醋酸钠复合支持电解质中,铀酰离子于E_p=-0.57V(S.C.E.)处产生一灵敏的极谱催化波。本文对铀在此体系中的极谱催化波进行了初步探讨,选择了极谱催化波的底液条件,研究了影响催化电流的因素和波的性质,并用该法测定了矿石中痕量铀。     

钴—锌试剂配合物吸附波的研究

本文提出极谱法测定痕量Co的Co(Ⅱ)-锌试剂新体系。在8.0 ×10~(-5)mol/L锌试剂、0.5mol/L KCl溶液中,Co(Ⅱ)-锌试剂配合物在单扫描示波极谱上有一灵敏的配合物吸附波。峰电位为-1.10V(υs.SCE),Co浓度在0.001—1μg/ml范围内与导数波高呈良好的线性关系。制定的方法应用于化探样品中痕量Co的测定,结果满意。     

极谱催化波法测定化探样品中的钨钼

试样经高温焙烧、碱熔分解,铁、铜、锰、钴、镍、钛、铋、镁等元素呈氢氧化物沉淀与钨、钼分离。在硫酸—二苯乙醇酸—二苯胍—氯酸钾底液中,钼、钨分别于约-0.26V(相对饱和甘汞电极钼峰电位)、-0.76V(钨峰电位)产生灵敏的平行催化波,根据测定区间内极限扩散电流的大小(选定区间内峰谷间的垂直距离)同时测定这两种元素。方法适用于化探样品、水系沉积物、土壤及岩石等样品中ω(Mo或W)1.0~100.0ng/mL的测定。     

极谱催化波法测定化探样品中的钨钼

试样经高温焙烧、碱熔分解,铁、铜、锰、钴、镍、钛、铋、镁等元素呈氢氧化物沉淀与钨、钼分离。在硫酸—二苯乙醇酸—二苯胍—氯酸钾底液中,钼、钨分别于约-0.26V(相对饱和甘汞电极钼峰电位)、-0.76V(钨峰电位)产生灵敏的平行催化波,根据测定区间内极限扩散电流的大小(选定区间内峰谷间的垂直距离)同时测定这两种元素。方法适用于化探样品、水系沉积物、土壤及岩石等样品中ω(Mo或W)1.0¹00.0ng/mL的测定。     

钼—AAAQ体系吸附波的极谱法研究

在pH4.1-4.5的HAc-NaAc底液中,Mo(Ⅵ)与5-(4-安替比林偶氮)-8-氨基喹啉(AAAQ)形成1:1的离子缔合物。该缔合物吸附于滴汞电极上于-1.32V(υs.SCE)处产生一灵敏的极谱峰,峰电流与Mo(Ⅵ)浓度在8 ×10~(-4)-8×10~(-2)μg/ml范围内呈线性关系。研究了极谱波性质、缔合物的结构及电极反应过程和机理。应用本法测定了铜钼矿中Mo。     

催化极谱法同时测定化探样品中的钨、钼

样品经碱熔分解,热水浸取,干扰元素铁、锰、钴、镍等形成氢氧化物沉淀与钨、钼分离。分取清液,在硫酸-苦杏仁酸-氯酸钠-辛可宁底液中,钨和钼均能产生灵敏的极谱催化波,峰电位分别为-0.76V和-0.25V(对饱和甘汞电极而言),固定试液体积,混合底液用针管一次加入,节省了稀释、定容、混匀的步骤,在JP4000型示波极谱仪上一次扫描同时测定钨和钼的峰电流,以峰高为纵坐标、含量为横坐标绘制工作曲线,直接计算出样品中钨、钼的含量,方法检出限(以三倍标准偏差计算)钨0.21μg/g,钼0.17μg/g,测定体系中,钨、钼分别在0.02~10.0μg范围内成良好的线性关系。     

应用极谱平行催化波同时测定样品中的钨钼

试样经高温焙烧、碱熔分解,铁、铜、锰、钴、镍、钛、铋、镁等元素呈氢氧化物沉淀而与钨、钼分离;在0.25mol/L硫酸—0.04g/L二苯乙醇酸—0.10g/L二苯胍—20g/L氯酸钠底液中,钼、钨分别于约-0.25V(对饱和甘汞电极钼峰电位)、-0.85V(钨峰电位)产生灵敏的平行催化波,根据极限扩散电流的相对大小(选定区间内峰谷间的垂直距离)同时测定这两种元素。方法样品的测定下限:W(X0+3S)=0.086×10-6,Mo(X0+3S)=0.099×10-6;准确度(RE)≤±10.53%,精密度(RSD)≤7.72%。此方法适用于水系沉积物、土壤及岩石等样品中ω(Mo或W)/10-6=(0.10～500)×10-6的测定。     

西安市街道灰尘中铬、镉、铅赋存状态及环境效应

本文通过对街道灰尘中铬、镉、铅三种元素赋存状态研究、铬、铅在街道灰尘中以残渣态为主，镉以有机质结合态为主。虽然铬、铅、镉存在形式稍有差异，但其在街道灰尘中主要以矿物质的形态存在，说明其比较稳定，不易迁移转化，对环境的危害比较持久。在治理措施上应有早遏止微量元素向环境中排放，以免其与灰尘发生相互作用对环境造成长期的危害。     

长江口南槽季节性冲淤变化及其对河流入海水沙响应关系的初步研究

本文利用长江口南槽1989年12个月的实测地形图和大通站相应的水沙资料,采用GIS技术和数理统计技术分析了南槽的地形变化及其与河流来水来沙的关系.结果表明南槽水深与大通站各月平均流量、输沙率和含沙量之间有明显的相关性,说明河口冲淤对流域水沙变化有敏感响应;河槽的响应具有1～1.5月的滞后性.     

岩石破坏的机理再认识

岩石的各种强度准则一直是解释岩石或岩体破坏机理的主要理论。此外,从流变现象出发,通过数值模拟、实验对照、理论分析、进一步对岩石破坏机理的解释进行了探讨,认为受力岩石或岩体内差异流动变形也是导致岩石破坏的原因。     

国际工程中设计方的责任

建筑工程中的“设计方”一般是指从事工程设计的专业人士,如建筑师和工程师,但也可能包括除施工或供货以外还承担某些工程设计工作的承包商、分包商及供应商。 “设计”并不限于制作建筑及工程图纸或进行结构方面的运算。设计范围极广,甚至包括了某种材料的选用以及为达到某个目的所应采用的工艺。设计的实质就是选择,选择足以满足工程要求     

树根桩在基础加固工程中的应用

树根桩对于已建建筑物的地基加固纠偏具有到之处，效果显著。通过工程实例分析，对树根桩的设计原理、施工方法和其承载力作用了阐述。     

The Cambrian metamorphic history of Tasmania: The Metapelites

The metamorphic complexes of Tasmania formed during the Cambrian (ca 510 Ma) as a result of rapid compression in a subduction zone setting followed by rapid exhumation, which brought various fault-bounded metamorphic complexes back to the surface in less than 5 Ma. The two highest grade complexes, the Franklin Metamorphic Complex, and the Port Davey Metamorphic Complex, experienced initial growth of metamorphic garnets at ～560°C, ～0.56 GPa. However, their subsequent metamorphic histories diverge, with the FMC displaying a marked increase in pressure (to 1.4 GPa at peak P/T), while the PDMC shows only a slight increase in pressure (to ～0.7 GPa). Both complexes show only a minor increase in temperature (～100°C) between initial garnet growth and peak metamorphic conditions. Rapid exhumation of these complexes can be accounted for by a slab-breakoff model. However, the difference in peak pressure between these complexes requires either continued subduction of the FMC while the PDMC had already begun its return towards the surface or that the subduction zone geometry resulted in significantly different pressures occurring contemporaneously within portions of the channel, which are not far removed from one another.     

小尺度的碳酸盐岩层序地层学分析——塔里木盆地桑塔木断垒带奥陶系层序地层学研究

层序地层学理论现已日臻完善，位人们往往被局限在大范围、大尺度的研究领域中，包括整个盆地或整个陆架的粗线条描述。那么，小尺度（小范围和次级层序）内的层序格式和沉积样式又是如何的呢？本文将作一阐述。在地层学、沉积学的研究基础上，在区域层序地层学的框架下，将桑塔木断垒带这样一个盆地内的三级局部构造的奥陶系进行层序地层学解剖。由于地震资料分辨率的限制，采用大量的钻井录井资料（岩心、电测等），通过岩性、古生物等特征标志建立相对水深变化曲线，以此来对比划分层序。得出，奥陶系内存在一个Ⅰ类层序界面，并将其划分为两个四级层序及相应的五级层序。其中，高水位体系域为最佳储层带。其研究方法和结论在对其他局部构造的研究中可起到类比作用     

The Archaean Nucleus of Singhbhum: The Present State of Knowledge

The supracrustal rocks of the Older Metamorphic Group (OMG), consisting of metasediments and ortho-amphibolite, constitute the oldest unit in the Archaean nucleus of Singhbhum. However, there are indications that still older (3.4–3.8 Ga) crust of both sialic and mafic composition existed in this region. The OMG ortho-amphibolites were formed by partial melting of mantle with near chondritic composition ca. 3.3 Ga ago, probably as a result of plume activity. Shortly afterwards, partial melting of the underplated mafic material produced a tonalitic melt (Older Metamorphic Tonalitic Gneiss — OMTG), which intruded the OMG supracrustals and the entire suite was deformed and metamorphosed to upper amphibolite facies. Subsequent to this, melting of the OMG ortho-amphibolites and the lower crustal material of probable andesitic composition produced melts varying in composition from tonalite to granite and these intruded in different phases to produce plutons of Singhbhum Granite, Bonai Granite and Kaptipada Granite, which together form volumetrically the major part of the Archaean nucleus. The older OMG and OMTG occur as enclaves within these younger granitoids. The time difference between the emplacements of the OMTG and the early phases of younger granitic intrusion was of the order of 100–200 Ma. Thus, serial additions of juvenile material led to the formation of a stable microcontinent by 3.2 Ga. Thermally triggered stretching in this microcontinent produced basins peripheral to the present day Singhbhum Granite pluton, and in these basins the younger supracrustal rocks of the Iron Ore Group (IOG), consisting of BIF, associated argillaceous and subordinate arenaceous rocks, and mafic lavas were laid down. There is inadequate field or geochronological evidence to resolve the issue of whether the different iron ore basins were coeval or not. Meagre geochronological data suggest that some of the BIFs are older than ca. 3.1 Ga. Post-IOG activity is confined to the intrusion of mafic dyke swarms and formation of intracratonic basins, the ages of both being uncertain.