西秦岭党川地区花岗岩的成因及其构造意义

对西秦岭造山带党川地区的党川花岗岩和石门花岗岩进行了LA-ICP-MS锆石U-Pb定年、元素地球化学和Sr-Nd-Pb同位素组成的研究.结果表明, 党川花岗岩和石门花岗岩的岩浆结晶年龄分别为438±3Ma和220±2Ma.在岩石地球化学特征上, 党川花岗岩类似于C-型埃达克质岩石, 岩浆产生于增厚地壳物质的部分熔融, 而石门花岗岩类似于普通的地壳深熔型花岗岩.党川花岗岩的I_Sr=0.70660~0.70929, ε_Nd (t) =-2.24~-4.48;石门花岗岩的I_Sr=0.70581~0.70804, ε_Nd (t) =-3.73~-4.72.Sr-Nd同位素组成进一步指示它们的岩浆派生于地壳物质.然而, 在Pb同位素组成上, 党川花岗岩和石门花岗岩存在着明显的差异.党川花岗岩以相对富放射成因Pb同位素组成为特征, 初始Pb同位素比值为: 206Pb/204Pb=18.288~18.484, 207Pb/204Pb=15.677~15.693, 208Pb/204Pb=38.182~38.283;而石门花岗岩以相对低的放射成因Pb同位素组成为特征, 初始Pb同位素比值为: 206Pb/204Pb=17.989~18.189, 207Pb/204Pb=15.560~15.567, 208Pb/204Pb=37.982~38.000.这表明党川花岗岩和石门花岗岩的岩浆来自于不同地壳物质的部分熔融.区域分析表明, 西秦岭党川地区中古生代和早中生代的岩浆事件、岩石成因机制及岩浆源区均可与东秦岭地区北秦岭构造单元相对比, 由此说明西秦岭党川地区是东秦岭地区北秦岭构造单元的西延, 并且东秦岭地区早中生代南秦岭块体向北秦岭块体的大陆俯冲作用向西一直延至到西秦岭地区.      

桐柏-大别造山带高压变质单元面理化(含榴)花岗岩地球化学及其对岩石成因的限制

桐柏-大别造山带中,面理化(含榴)花岗岩作为榴辉岩的重要围岩之一,仅分布在高压变质单元和超高压变质单元中.对高压变质单元中面理化(含榴)花岗岩进行了元素地球化学研究,结果显示,这类岩石 SiO2 71.96%～ 77.99%, K2O Na2O 7.59%～8.66%, Al2O3 11.15%～14.50%, CaO 0.10%～0.91%, MgO0.04%～0.73%,Sr 27.3～269 μ g/g,A/CNK 0.97～1.10.相对于 S型和 I型花岗岩,面理化(含榴)花岗岩具有某些 A型花岗岩的地球化学特征,如岩石明显富硅、富碱质和富高场强元素(如 Zr、Hf、Nb、Ta、Y等),贫 Ca、Mg、Al、Sr等元素,高 Ga/Al比值;在稀土元素特征方面,大部分样品具有明显的 Eu负异常(Eu/Eu0.06～0.60),(La/Yb)N 2.34～7.87.在岩石成因类型元素判别图解上,面理化(含榴)花岗岩主要落于 A型花岗岩区;构造判别图解和构造学、岩石学特征表明该类花岗岩形成于碰撞后的构造环境.因此,高压变质单元面理化(含榴)花岗岩总体地球化学特征表明它们属于 A型花岗岩类,形成于岩石圈伸展的碰撞后构造环境,与大别山超高压 /高压变质岩的折返过程存在密切联系.     

安庆早白垩世洪镇花岗岩成因及其对基底构造格局的启示

花岗岩可以有效示踪大陆基底物质,并区分具有不同地壳结构和演化历史的构造块体。洪镇花岗岩位于长江中下游地区江北A型花岗岩带的西延位置,距离郯庐断裂带约30 km。锆石SIMS定年表明,安庆怀宁县洪镇花岗岩形成于126. 2±2. 0 Ma,与长江中下游A型花岗岩以及大别造山带I型花岗岩的形成时代一致。洪镇花岗岩高硅、富钾,属于高钾钙碱性系列I型花岗岩。其富集轻稀土元素和大离子亲石元素,相对亏损中稀土元素和高场强元素,经历了角闪石为主的结晶分异。洪镇花岗岩具有较为富集的Sr—Nd—Hf同位素,和低放射性成因Pb同位素组成,其n(87Sr)/n(86Sr)(t)为0. 7065~0. 7066,εNd(t)值为-10. 9~-12. 0,锆石εHf(t)为-6. 7~-13. 2,n(206Pb)/n(204Pb)(t)、n(207Pb)/n(204Pb)(t)和n(208Pb)/n(204Pb)(t)分别在17. 063~17. 109、15. 568~15. 572和37. 351~37. 373之间。综合研究表明,洪镇花岗岩起源于古—中元古代中低成熟度沉积岩的水致部分熔融,为幔源岩浆底侵导致。从物质来源上,洪镇花岗岩岩浆源区类似于大别造山带经历过俯冲、折返后的中上地壳,而显著不同于长江中下游同时代A型花岗岩源区,表明洪镇地区具有上下地壳分属长江中下游和大别造山带的构造属性。在早白垩世早期郯庐断裂带南段西盘向南的强烈挤压下,大别造山带下地壳发生不规则流动,越过郯庐断裂带进入到洪镇地区下地壳成为洪镇花岗岩的源区。     

从Pb同位素组成看东秦岭官坡超高压变质岩片的走势

通过研究表明,东秦岭官坡超高压变质岩片具有较高的放射性成因铅同位素组成：^206Pb／^204Pb=18．089～18．772,^207Pb／^204Pb=15．571～15．631,^208Pb／^204Pb=38．299～38．829。其铅同位素组成与秦岭岩群及二郎岩坪群一致,而与大别超高压变质带有明显的区别。结合构造分析可以判断,东秦岭超高压变质带与大别超高压变质带是两个不同的构造带,中央造山带内可能至少发育有两条超高压变质带。     

桐柏高压变质地体:对桐柏-大别-苏鲁高压/超高压变质带构造框架和俯冲/折返机制的制约

桐柏造山带位于秦岭造山带和大别-苏鲁造山带之间,是揭示秦岭-桐柏-大别-苏鲁巨型造山带中各地质体之间构造关系及地质演化差异的关键地区。桐柏高压变质地体主要由两个高压岩片(I和II)及其北侧的构造混杂岩带和南侧的蓝片岩-绿片岩带构成。高压岩片I以北、南两条榴辉岩带为代表,构成桐柏山背形构造的两翼,其峰期变质条件分别为530~610℃、1.7~2.0GPa和460~560℃、1.3~1.9GPa。高压岩片II以桐柏杂岩中的变质岩包体为代表,其峰期变质条件推测在<700℃、>1.2GPa的榴辉岩相范围内,而退变质条件为660~700℃、0.80~1.03GPa。U-Pb、Lu-Hf、Rb-Sr和Ar-Ar同位素年代学研究表明,高压岩片I的峰期变质时代为255Ma,冷却至白云母封闭温度的时代为238Ma;而高压岩片II的主期变质作用发生在232~220Ma,作为桐柏杂岩主体的片麻状花岗岩则侵位于140Ma。这说明,高压岩片I和II分属于两个时代不同的俯冲/折返岩片,当高压岩片II被俯冲到地壳深处并经受高压变质时,其上覆的高压岩片I已经折返到中上地壳的水平。这一结果验证了在西大别、东大别和苏鲁地区提出的高压/超高压岩石的穿时(或差异)俯冲/折返模型,同时说明华南大陆地壳最早的俯冲发生在晚二叠世,这也代表华北与华南陆块之间从洋壳俯冲转化为陆壳俯冲的时间。基于桐柏杂岩与北大别杂岩的可比性,认为桐柏高压变质地体相对低温低压的变质环境以及超高压岩石的缺乏缘于华南陆块的俯冲深度向西逐渐变浅,而早白垩世的构造挤出造成了桐柏-大别高压/超高压变质带东宽西窄的构造格局。     

大别造山带早白垩世基性岩的同位素特征及下地壳物质对岩浆源区的贡献

大别造山带中生代岩浆岩的物质来源和成因机制,是大陆碰撞造山带研究的热点和前沿问题之一.本文通过对北大别椒子岩和沙村岩体的早白垩世基性岩进行全岩的主量、微量元素特别是Pb-Sr-Nd同位素研究,探讨了北大别基性岩的岩浆源区性质及下地壳的贡献.椒子岩基性岩的(87Sr/86Sr);的范围为0.7072～0.7075,εNd(t)范围为-10.4～11.9;椒子岩和沙村基性岩的(206Pb/204Pb)i为16.464～17.394,(207Pb/204Pb)i为15.349～15.453,(208Pb/204Pb)i为37.338～37.976.这样的同位素组成显示岩浆源区中下地壳物质的贡献显著;尤其Pb同位素特征表明下地壳贡献来自大别造山带自身的下地壳.下地壳物质的参与可能与拆沉有关.     

桐柏山高压变质带及其区域构造型式

桐柏山是秦岭－大别山造山带的重要组成部分。新近的构造学和岩石学详细研究表明，该区广泛分布有大量的、大小不一的榴辉岩及退变质榴辉岩块体，构成一个延展长约200km和宽约40km的高压变质带。由榴辉岩或退变质榴辉岩、遭受过高压变质作用的沉积和火山岩、由榴辉岩退变质而成的片麻岩和片岩，以及面理化的含榴或不含榴的花岗岩组成的高压变质单位（HP），在组成及变质演化特征方面，均与大别－苏鲁地区的高压单位类似。构造上，显示一典型的西北美型变质核杂岩。分隔开由桐柏杂岩组成的核部杂岩单位（CC）及上覆的高压单位的km尺度的伸展拆离带，具有下和中伸展拆离带的复合性质，是在高压变质作用期后伸展体制下形成的。桐柏山高压变质带是与大别山地区的高压变质带相联接的，据其岩石学、构造学及相关的主要构造边界展布特征，推测该高压变质带穿过南襄盆地有继续向东秦岭延伸的趋势。桐柏山高压变质带是东秦岭造山带与大别－苏鲁超高压和高压变质带间的构造纽带。     

大别山超高压变质岩形成深度的同位素限制

大别山超高压变质岩形成深度是各国地质学家十分关心的问题。它不仅影响对碰撞造山带形成机制和演化过程的认识,而且影响对地球深部状况及地球动力学的研究。该文对大别山超高压变质岩已有同位素资料进行了分析与讨论。大别山榴辉岩的ε_Nd为-6.2~-17,ε_Sr为18~42,且显示明显的Nd同位素的不平衡现象。大别山榴辉岩的氧同位素组成研究表明,这些榴辉岩的原岩在超高压变质前,不同程度地与贫18O的大气降水(或海水)发生过氧同位素交换,且在超高压变质过程中依然保留了这些痕迹。除一个样品外,大别-苏鲁地区的榴辉岩的3He/4He比值都落在0.79×10-7~9.35×10-7范围内,显示陆壳岩石来源He的重要贡献。所有Sr-Nd、O和He同位素研究均表明:超高压变质岩保存着表壳岩石原岩的同位素特征,而未显示变质时受到地幔物质的明显影响。对于超高压变质岩的上述同位素特征,有人认为是由于大别山造山带俯冲和折返的速度太快造成的。由于造山带俯冲和折返的速度太快,表壳岩石原岩变质时来不及与地幔物质发生交换,故没有留下地幔物质参与的痕迹。该研究认为这种解释有些勉强,因为大别造山带俯冲和折返时间至少需要15Ma.在如此长的时间内,在100多公里地幔深处高于700℃的高温下发生超高压变质作用,表壳岩石原岩不可能不与地幔物质发生同位素交换。相反,如果认为大别山超高压变质岩就在地壳内形成,则大别山超高压变质岩同位素的所有特征就很好解释了。      

试论桐柏造山带与西大别造山带的对比

根据已有资料探讨了桐柏造山带与西大别造山带的对比。桐柏造山带由6个构造单元组成,西大别造山带可划分为10个构造单元。两个造山带北部的5个构造单元可以完全对比,并可恢复为华北板块南缘的古生代活动性大陆边缘,表明桐柏与西大别曾共同经历扬子板块古生代的俯冲。再向南,熊店—浒湾韧性剪切带中的熊店榴辉岩意味着古生代高压变质作用的存在,但不能划定明确的分布范围和构造单元。而其他中生代高压—超高压岩石以带状和穹窿状分布,在桐柏和西大别地区占据中生代造山带的主体部分,构成可以对比的线状和穹窿状构造单元。桐柏与西大别造山带的结构都是由北部古生代弧陆碰撞造山带和南部中生代高压—超高压折返形成的造山带拼合而成,因此两者都具有古生代和中生代多期造山带的特点。从构造单元和演化阶段方面分析,两个造山带是可以对比的。     

长江中下游中生代花岗岩类源区的壳—壳混源性质

长江中下游地区中生代花岗岩类形成于大别造山带碰撞后岩石圈物质的调整演化过程。Ｓｒ、Ｎｄ、Ｐｂ同位素组成数据表明，早、晚阶段花岗岩类具有相似的壳－壳混合源区性质，其主要源岩端员可能分别相当于以大别杂岩为代表的深变质岩系和中、新元古界底侵（ｕｎｄｅｒｐｌａｔｉｎｇ）基性物质与部分古元古界沉积－火山－侵入岩系组成的扬子陆块下地壳岩石。这两种成分不同的下地壳物质在这里呈指状穿插体结构。长江中下游地区下地壳在碰撞造山过程中曾是大别地块与扬子地块之间的深部构造混杂带。本文主要根据各类已有的Ｓｒ、Ｎｄ、Ｐｂ同位素组成资料讨论花岗岩类的源区性质问题     

Geochemical Characteristics of Pb Isotope of High-Pressure Metamorphic Rocks and Foliated Granites from HP Unit of Tongbai-Dabie Orogenic Belt

Whole-rock Pb isotopic compositions of the high-pressure (HP) metamorphic rocks, consisting of two-mica albite gneisses and eclogites, and foliated granites from the HP metamorphic unit of the Tongbai-Dabie orogenic belt are firstly reported in this paper. The results show that the tip metamorphic rocks in different parts of this orogenic belt have similar Pb isotopic compositions. The twomica albite gneisses have ^206 pb/^204 Pb=17. 657 -18. 168, ^207pb/^204 Pb=15. 318-15. 573,^ 208Pb/^204ob=38.315-38. 990, and the eclogites have ^206Pb/^204 Pb=17. 599 -18. 310, ^207Pb/^204 Pb=15. 465 -15. 615,^208Pb/^204Pb=37. 968-39. 143. The HP metamorphic rocks are characterized by upper crustal Pb isotopic composition. Although the Pb isotopic composition of the HP metamorphic rocks partly overlaps that of the ultrahigh-pressure (UHP) metamorphic rocks, as a whole, the former is higher than the latter. The high radiogenic Pb isotopic composition for the HP metamorphic rocks confirms that the subducted Yangtze continental crust in the Tongbai-Dabie orogenic belt has the chemical structure of increasing radiogenic Pb isotopic composition from lower crust to upper crust. The foliated granites, intruded in the HP metamorphic rocks post the HP/UHP metamorphism, have ^206Pb/^204 Pb=17. 128- 17. 434,^207Pb/^204pb=15. 313-15. 422 and ^208Pb/^204Pb=37. 631-38. 122, which are obviously different from the Pb isotopic compositions of the HP metamorphic rocks but similar to those of the UHP metamorphic rocks and the foliated garnet-bearing granites in the UHP unit. This shows that the foliated granites from the HP and UHP units have common magma source. Combined with the foliated granites having the geochemical characteristics of A-type granites, it is suggested that the magma for the foliated granites in the UHP and HP unit would be derived from the partial melting of the retrometamorphosed UHP metamorphic rocks exhumed into middle to lower crust, and partial magmas were intruded into the HP unit.     

Pb Isotope Mapping in the Tongbai-Dabie Orogenic Belt, Central China

Tongbai-Dabie orogenic belt in Central China is a part of the collisional belt between the Yangtze and North China cratons. It represents one of the most extensive ultrahigh-pressure （UHP） and high-pressure （HP） metamorphic rocks in the world. The Pb isotope mapping in this area is a significant method to constrain the crustal structure and tectonic evolution and to identify the tectonic boundaries within the vertical tectonic stack. Based on the Pb isotope compositions of the Dabie complex （DBC）, the Tongbai complex （TBC）, UHP and HP metamorphic rocks and associated foliated granites, the lower metamorphosed rocks from North Huaiyang （NHY） tectonic belt, and Cretaceous granites in the Tongbai-Dabie orogenic belt, we determined the Pb isotope geochemical map of the Tongbai-Dabie orogenic belt. The Pb isotope map shows that the Pb isotope compositions are similar within each geological body or lithotectonic unit, but the Pb isotope compositions of different lithotectonic units show systematic variations in the Tongbai-Dabie orogenic belt. The NHY tectonic belt contrasts strongly with the Tongbai-Dabie UHP.HP metamorphic belt in Pb isotope compositions. It is suggested that the line along the Xiaotian-Mozitan fault, the north limit of the Tongbai-Dabie UHP and HP metamorphic rocks, represents an important tectonic boundary. Within the Tongbai-Dabie HP -UHP metamorphic belt, to the south of Xiaotian-Mozitan fault, the vertical variations of Pb isotope compositions in different lithotectonic units and the spatial relationship among different major lithotectonic units have been constrained.     

Pb and Nd isotopic composition of the Jigongshan granite: constraints on crustal structure of Tongbaishan in the middle part of the Qinling–Tongbai–Dabie orogenic belt, Central China

The Qinling–Dabie–Sulu belt is the world's largest ultrahigh pressure (UHP) metamorphic belt. The UHP metamorphism is well dated at 220–245 Ma in the Dabie–Sulu belt but at 507 Ma in the Qinling belt. The Tongbaishan is located between the Qinling orogenic belt to the west and the Dabie–Sulu UHP metamorphic belt to the east. It is the key area for studying the tectonic relation between the Qinling and Dabie–Sulu belts and the diachronous UHP metamorphism. The Jigongshan granitic pluton (t=128 Ma) with a total area of 1200 km², composed of monzogranite, was mostly emplaced into the Tongbai complex, an exposed basement in the Tongbaishan. The Jigongshan granites have SiO₂=69.85–72.35%, K₂O/Na₂O=0.87–1.13, A/CNK=0.91–1.03, Rb/Sr=0.14–0.25 and Th/U=3.3–12. Their REE compositions show strongly fractionated patterns with (La/Yb)_N=14–58 and Eu*/Eu=0.79–1.05. The granites are characterized by low radiogenic Pb isotopic composition. The present-day whole-rock Pb isotopic ratios are ²⁰⁶Pb/²⁰⁴Pb=16.707–17.055, ²⁰⁷Pb/²⁰⁴Pb=15.239–15.326 and ²⁰⁸Pb/²⁰⁴Pb=37.587–37.853, which are similar to that of the continental lower crust. Their _Nd(t) values range from −16 to −20, and depleted-mantle Nd model ages (T_DM) from 1.8 to 2.2 Ga. The above evidence indicates that the magma of the Jigongshan granites was derived from the partial melting of the continental crust. The Pb and Nd isotopic compositions of the Jigongshan granites resemble those of the Dabie core complex in the Dabieshan but are distinct from those of the Tongbai complex in the Tongbaishan. Thus, the Dabie core complex would be the magma source of the Jigongshan granites. The result implies that the Dabie core complex is extended to the west and constitutes the unexposed basement underlaying the Tongbai complex in the Tongbaishan.     

大别超高压变质地体四道河地区岩石学研究

对四道河地区超高压变质岩剖面的研究分析显示,该剖面有3种岩石类型:榴辉岩类、片麻岩和面理化含榴花岗岩。榴辉岩具不同程度的退变质现象,呈透镜体状产出于斜长角闪岩、片麻岩和面理化含榴花岗岩中,原生矿物组合为石榴石、绿辉石、柯石英和金红石。榴辉岩退变为斜长角闪岩近于等化学系列;片麻岩在主量成分上与榴辉岩及其退变产物(斜长角闪岩)存在突变关系,但微量元素与榴辉岩有一定的相似性;面理化含榴花岗岩主量元素和微量元素地球化学特点为:富SiO2 、K2 O Na2 O和高价阳离子Ga、Y以及REE ,K2 O/Na2 O值低,贫Al、Ca、Mg、Ti、P ,结合构造环境、同位素及年代学资料分析,其应属于后碰撞造山A型花岗岩。基于以上认识推断:大陆板片俯冲至上地幔经历了超高压变质作用,表壳岩变质形成榴辉岩;当超高压变质岩石折返至中下地壳时发生了强烈的减压退变质作用形成斜长角闪岩,随后,与片麻岩及面理化含榴花岗岩一道从中下地壳向地表进一步折返,并一同经历了后期的变质变形作用。     

The formation of foliated (garnet-bearing) granites in the Tongbai-Dabie orogenic belt: partial melting of subducted continental crust during exhumation

Foliated (garnet-bearing) (FGB) granites are associated closely with and are usually the major wall rocks of the high-pressure (HP) and ultrahigh-pressure (UHP) metamorphic rocks in the Tongbai-Dabie region, the mid segment of the Qinling-Dabie-Sulu orogenic belt in central China. These granites appear either as small plutons or as veins, which commonly intrude into or surround the HP and UHP metamorphic eclogites or gneisses. The veins of FGB granites usually penetrate into the retrograded eclogites or gneisses along the foliations. Condensation rims can occasionally be found along the margins of granite veins. These granites are rich in Si and alkali with high Ga/Al ratios, and depleted in Ca, Mg, Al, Ti, Sc, V, Ni, Co, Cr and Sr, which are similar to A-type granites. In a chondrite normalized diagram, the samples are light rare earth elements enriched with different extent of negative Eu anomaly. Moreover, Rb, Nb, Ta, Sr, P and Ti show different degrees of negative anomalies, whereas Ba, K, La, Zr and Hf show positive anomalies in the primitive mantle normalized diagram. Negative anomalies of Eu and Sr indicate strong influence of plagioclase. In conventional discrimination diagrams, these FGB granites belong to the A-type granite, with geochemical characteristics affinitive to post-collisional granites. The εNd (230 Ma) values (−15.80 to −2.52) and T _DM values (1.02–2.07 Ga) suggest that magma for the FGB granites were derived from a heterogeneous crustal source. Therefore, the FGB granites may provide clues for deciphering the formation of post-collisional granites. It is proposed that the magma of the FGB granites both in the HP and UHP units was formed in an extensional tectonic setting slightly post-dating the HP and UHP metamorphism, most likely as a result of decompressional partial melting of UHP retrograded eclogites during exhumation.     

Major Constituents of the Dabie Collisional Orogenic Belt and Partial Melting in the Ultrahigh-Pressure Unit

The present constitution and architecture of the Dabieshan orogenic belt is the combined result of Triassic subduction collision, extensional tectonics postdating the HP and UHP metamorphism, and thermo-tectonic evolution in Mesozoic-Cenozoic time. In addition to Yanshanian and post-Yan-shanian magmatic intrusion, volcanic eruption, and basin deposition, lithotectonic constituents of the Dabie orogenic belt consist mainly of a core complex (CC) unit, an UHP unit, an HP unit, an epidote-blueschist (EBS) unit, and a sedimentary cover (SC) unit. Minor mafic-ultramafic plutons were intruded into or preserved within the CC, UHP, HP, or EBS units. Slices of UHP, HP, and EBS units are progressively sandwiched between the underlying core complex and the overlying sedimentary cover. The distribution of lithotectonic units is controlled by an extensional tectonic framework, which postdates the collisional event. The tectonic pattern of the Dabieshan orogenic belt as a whole is characterized by a general doming, with the development of multi-layered detachment zones.

The study of partial melting associated with decompressive retrogression in the UHP unit during exhumation of the eclogites provides us with a better understanding of the relationship between eclogites and the surrounding country rock (socalled UHP gneisses), and the foliated garnet-bearing granites (the non-HP country rocks). It supports the “in situ” interpretation. Anatexis occurred under conditions of amphibolite-facies metamorphism at lower to middle crustal levels. This partial melting associated with decompression is one of the most important physico-chemical processes that postdate the collisional event in the Dabieshan. It signaled the evolution of the deformation regime from compression to extension, and reflected thinning of the continental crust and rapid uplift of UHP metamorphic rocks to middle to lower crustal levels by regional-scale extension.     

Lead Isotopic Composition and Lead Source in the Bainiuchang Ag-polymetailic Deposit,Yunnan Province,China

The Bainiuchang deposit in Yunnan Province,China,is located geographically between the Gejiu ore field and the Dulong ore field.In addition to the>7000 t Ag reserves,the deposit also boasts of large-scale Pb,Zn and Sn reserves with a lot of dispersed elements(In,Cd,Ge,Ga,etc.).We have determined systematically the Pb isotope composition of the deposit.The Pb isotope ratios of the ores that are of sea-floor exhalative sedimentary origin in the northwest of the mining district,are ~(206)Pb/~(204)Pb=17.758-18.537,~(207)pb/~(204)pb=15.175-15.862 and ~(208)pb/~(204)pb=37.289-39.424,while those of ores that are of magmatic hydrothermal superimposition origin in the southeast of the mining district, are ~(206)Pb/~(204)Pb=17.264-18.359,~(207)Pb/~(204)Pb=14.843-15.683 and ~(208)Pb/~(204)Pb=36.481-38.838, respectively.In terms of the Pb isotope composition of feldspar in magmatic rocks or magmatic whole- rock samples from the mining district,we have determined the Pb isotope composition and acquired the Pb isotope ratios as:~(206)Pb/~(204)Pb=18.224-18.700,~(207)Tpb/~(204)Pb=15.595-15.797 and ~(208)Pb/~(204)Pb= 38.193-39.608.Then,in the light of the Pb isotope composition of metamorphic rock samples from the Proterozoic basement exposed in the Dulong ore field,we have determined the Pb isotope composition and obtained the isotope ratios as:~(206)Pb/~(204)Pb=18.434-19.119,~(207)Pb/~(204)Pb=15.644-15.693,and ~(208)Pb/~(204)Pb=38.514-38.832.And the Pb isotope ratios of Cambrian sedimentary rocks,which are exposed in the Bainiuchang mining district,are ~(206)Pb/~(204)Pb=18.307-19.206,~(207)Pb/~(204)Pb= 15.622-15.809,and ~(206)Pb/~(204)Pb=38.436-39.932.By comparing the two types of ores with respect to their Pb isotope compositions,it is indicated that lead in the Bainiuchang deposit was derived largely from the lower-crust granulite which is earlier than Neoproterozoic in age,but the Yanshanian magmatic hydrothermal fluids probably provided a part of ore-forming elements such as Sn for the ore blocks in the south of the mining district.     

Extensional Tectonic Framework of Post High and Ultrahigh Pressure Metamorphism in Dabieshan, China

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超高压变质作用过程中的流体——来自苏鲁超高压变质岩岩石学、氧同位素和流体包裹体研究的限定

苏鲁造山带超高压变质岩岩石学、氧同位素、流体包裹体和名义上无水矿物的研究表明，流体-岩石相互作用在大陆地壳的俯冲与折返过程中起到多重的重要作用，并形成了复杂的流体演化过程：（1）大陆表壳岩通过与高纬度大气降水的交换作用被广泛水化，并获得了异常低的氧同位素成分；（2）在水化陆壳物质的俯冲过程中发生了一系列的进变质脱水反应，所释放的流体主要结合进了高压、超高压含水矿物和名义上无水超高压矿物；（3）在超高压变质过程中，以水为主的变质流体通过选择性的吸收使其盐度逐渐升高，并在峰期出现高密度、高盐度的H2O或CO2-H2O流体。有机质的分解反应在局部形成了以CO2、N2、CH4或它们的混合物为主要成分的变质流体；（4）名义上无水超高压矿物的结构水出溶是早期退变质流体的主要来源，并在局部富集形成了高压变质脉体；（5）透入性的中、低盐度水流体活动使超高压变质岩通过一系列的水化反应转变成角闪岩相变质岩；（6）沿韧性剪切带和脆性破碎带的强烈水流体活动为绿片岩相退变质作用和低压石英脉的形成提供了变质流体；（7）可变盐度的H2O或CO2-H2O流体是整个超高压变质岩形成与折返过程中的主要流体，但局部的流体．岩石相互作用形成了非极性的变质流体。