Influence of soft clays on the response spectra for structures in eastern Canada

The 1990 edition of the National Building Code of Canada (Associate Committee of the National Building Code, National Research Council, Ottawa, 1990) makes a clear distinction between eastern and western Canada in terms of seismic acceleration and velocity zones. While it is well established that ground motions can be amplified significantly through loose clay deposits, no results are available that take into consideration the typical high frequency content of ground motions in eastern Canada. This paper develops ground amplification curves for clays having depths between 10 and 70 m excited by typical eastern Canadian ground motions scaled to two different values of peak horizontal accelerations. Simplified free-field spectral design curves, which could be used by structural designers, are proposed. The curves show that maximum spectral accelerations occur for structural periods between 0.2 and 0.5 s. In addition, soil depth does not appear to be an important parameter controlling the response of typical clay deposits in eastern Canada.     

A stepwise method for determining the number of component distributions in a mixture

This paper considers the problem of estimatingm, the number of components in a finite mixture of distributions from a parametric family. A step-up procedure using the bootstrap method is proposed. Some properties of the procedure are illustrated with simulation studies. An example of the method, applied to orientation of beach clasts, is given.     

Speciation of trace metals in sediments of a tropical estuary

Axial surveys were performed in the two river tributaries of the Cochin estuary, SW India during November 1988. Surficial sediments were subjected to sequential chemical extractions to delineate five metal fractions, namely, exchangeable, carbonate bound, easily reducible, organic/sulfide bound, and residual. The results indicated selective accumulation of Mn and Ni in carbonate bound and organic/sulfide forms, along with marginal amounts of Co in the exchangeable fraction. Large portions of Fe and Cr occurred in the residual fraction, whereas composite fractionation of Zn species was noticed. The exchangeable fractions of Fe and Cr as well as of easily reducible cobalt were below detection limits. The levels of Cr and Zn indicate anthropogenic inputs in this estuary, whereas Co and Ni show regional contamination exceeding natural levels. The analytical speciation procedure helps to deduce the sedimental diagenetic processes in the estuarine environment.     

Cokriging nonstationary data

Universal cokriging is used to obtain predictions when dealing with multivariate random functions. An important type of nonstationarity is defined in terms of multivariate random functions with increments which are stationary of orderk. The covariance between increments of different variables is modeled by means of the pseudo-cross-covariance function. Criteria are formulated to which the parameters of pseudo-cross-covariance functions must comply so as to ensure positive-definiteness. Cokriging equations and the induced cokriging equations are given. The study is illustrated by an example from soil science.     

Recharge and salinization in the Madrid Basin

The purpose of this work was to reinvestigate the existing hydrogeological conceptual model of the basin of Madrid, Spain. A cumulative chemical isotopic diagram which enabled the distinction between different groups of water as well as calculation of the mode of their blending was used for this investigation. It was found that the groups of discharge were lighter in their isotopic composition than that of recharge. The previous explanation of this fact, backed by carbon-14 dating, was the long residence time due to flow lines going down to depths of more than 1000 m. This flow model assumes homogenous conditions to these depths. This assumption can not be supported by evidence from deep wells. Thus a modified model is suggested which maintains homogenous conditions only to about 300 m and a deep confined aquifer below containing paleowater. The higher degree of depletion of this water has been explained by a colder climate on top of an altitude effect. Another interesting observation was the correlation between the isotopic composition of the rains, the month of the rain event and the composition of the recharge group groundwater. It could be seen that the winter rains resemble the groundwater composition, which shows that practically all the spring and summer rains were evapotranspirated.     

Discrimination of sedimentary facies by association analysis

The ability of association analysis to discriminate sedimentary facies was tested on Purdy's modal analyses of modern sediments of the Great Bahama Bank. Purdy's data set has served in the past as a standard reference for evaluating various multivariate classification algorithms. In order to adapt Purdy's data to association analysis, the percent abundance of the 12 constituents was converted to binary form by dichotomizing each variable on its mean value. The results obtained by association analysis are virtually identical to those obtained by Purdy and other authors. The same four main sedimentary facies were discriminated; 86% of the samples were identically classified (97% when misclassified borderline cases are counted as matches); the total partition variance of the classification is only negligibly greater (4%); and the grouping of the variables yielded the same four groups. The rank order of the three division-attributes responsible for the sample classification is fines, oolites, and corals. Association analysis has been employed by other authors to differentiate meaningful facies groups in studies of ancient reef carbonates, modern reef sediments, and heavy minerals in stream sediments. In all these studies, the results were found to be compatible with those obtained by using the continuous quantitative measurements, indicating that qualitative binary data may often be sufficient for the purpose of facies discrimination in many branches of geology and that association analysis is an effective method for this purpose.     

雾化进样石墨炉原子吸收光谱法的研究 Ⅰ.直接雾化进样装置及其性能

介绍一种自行设计和加工的直接雾化石墨炉进样装置的结构、工作原理和操作方法。该装置由微机控制与石墨炉加热程序同步工作,可以实现自动控制和自动测量。对雾化进样石墨炉分析的仪器参数和实验条件进行了研究和选择。结果表明,该装置与石墨炉结合具有自动化程度高、重现性好、样品利用率高和分析速度快等特点。