Nutrient transports in a Swedish estuary

Himmerfjärd is a Swedish estuary bordering on the Baltic. The estuary lacks astronomical tides and its circulation is driven by winds and freshwater runoff. Because of a tertiary sewage treatment plant located at its inner end, the estuary is becoming increasingly eutrophic. A field study was carried out for a 78-day period in late summer and early fall of 1977 to determine rates of nutrient transport and to construct nutrient budgets. Since physical parameters (current velocity, temperature, salinity, winds and water level changes) were measured more frequently than nutrients (phosphate, nitrate, nitrite and ammonium) it was necessary to develop a suitable method to calculate nutrient flux time series and net nutrient fluxes. Over the study period, Himmerfjärd imported phosphorus and exported nitrogen. Direction of nutrient fluxes and changes in flux direction were consistent with the structure of the baroclinic currents.     

Ice‐cover variability on shallow lakes at high latitudes: model simulations and observations

A one‐dimensional thermodynamic model for simulating lake‐ice phenology is presented and evaluated. The model can be driven with observed daily or hourly atmospheric forcing of air temperature, relative humidity, wind speed, cloud amount and snowfall. In addition to computing the energy balance components, key model output includes the temperature profile at an arbitrary number of levels within the ice/snow (or the water temperature if there is no ice) and ice thickness (clear ice and snow‐ice) on a daily basis, as well as freeze‐up and break‐up dates. The lake‐ice model is used to simulate ice‐growth processes on shallow lakes in arctic, sub‐arctic, and high‐boreal forest environments. Model output is compared with field and remote sensing observations gathered over several ice seasons. Simulated ice thickness, including snow‐ice formation, compares favourably with field measurements. Ice‐on and ice‐off dates are also well simulated when compared with field and satellite observations, with a mean absolute difference of 2 days. Model simulations and observations illustrate the key role that snow cover plays on the seasonal evolution of ice thickness and the timing of spring break‐up. It is also shown that lake morphometry, depth in particular, is a determinant of ice‐off dates for shallow lakes at high latitudes. Copyright © 2003 John Wiley & Sons, Ltd.     

Retrograde fluid infiltration in the high-grade Modum Complex South Norway: evidence for age,source and REE mobility

The high-grade metamorphic basement of the Modum Complex, South Norway,exhibits retrogradation and alteration due to late stage fluid infiltration.Extensive alteration zones of albite-and calcite-rich veining occur especiallywithin and around numerous metagabbros. The gabbros, intruded at 1224±15Ma, are now partly altered to amphibolites due to the subsequent high-grade metamorphism.Two generations of albite-rich rocks have been recognized: (1) a fine-grained, foliated type;(2) a coarse-grained, crosscutting type. Both types show a typical greenschist facies mineralassemblage; albite ± actinolite ± chlorite ± talc. The calcite veins/dykesrepresent a younger generation of veins than both albite-rich types. U–Pb data for spheneof type (1) yielded an age of 1080±3 Ma, determining a point on the retrogradeP-T-t path of the Modum Complex. Increasing albitisation of themetagabbros leads to a decrease in(¹⁴³ND/¹⁴⁴Nd)_oand an increase in (⁸⁷Sr/⁸⁶)_o.Albite- and calcite-rich samples show negative _Nd and positive _Sr, suggesting that fluids which interacted with the metagabbros originated from a crustal reservoir. The Nd and Sr isotopic data show disequilibrium at the microscale as well as at the macroscale. Negative Sm–Nd model ages of the albite-rich rocks demonstrate that rare-earth elements (REEs) were mobile and fractionated during albitisation.     

Serpentinization of abyssal peridotites from the MARK area, Mid-Atlantic Ridge: sulfur geochemistry and reaction modeling

The opaque mineralogy and the contents and isotope compositions of sulfur in serpentinized peridotites from the MARK (Mid-Atlantic Ridge, Kane Fracture Zone) area were examined to understand the conditions of serpentinization and evaluate this process as a sink for seawater sulfur. The serpentinites contain a sulfur-rich secondary mineral assemblage and have high sulfur contents (up to 1 wt.%) and elevated δ³⁴S_sulfide (3.7 to 12.7‰). Geochemical reaction modeling indicates that seawater-peridotite interaction at 300 to 400°C alone cannot account for both the high sulfur contents and high δ³⁴S_sulfide. These require a multistage reaction with leaching of sulfide from subjacent gabbro during higher temperature (∼400°C) reactions with seawater and subsequent deposition of sulfide during serpentinization of peridotite at ∼300°C. Serpentinization produces highly reducing conditions and significant amounts of H₂ and results in the partial reduction of seawater carbonate to methane. The latter is documented by formation of carbonate veins enriched in ¹³C (up to 4.5‰) at temperatures above 250°C. Although different processes produce variable sulfur isotope effects in other oceanic serpentinites, sulfur is consistently added to abyssal peridotites during serpentinization. Data for serpentinites drilled and dredged from oceanic crust and from ophiolites indicate that oceanic peridotites are a sink for up to 0.4 to 6.0 × 10¹² g seawater S yr⁻¹. This is comparable to sulfur exchange that occurs in hydrothermal systems in mafic oceanic crust at midocean ridges and on ridge flanks and amounts to 2 to 30% of the riverine sulfate source and sedimentary sulfide sink in the oceans. The high concentrations and modified isotope compositions of sulfur in serpentinites could be important for mantle metasomatism during subduction of crust generated at slow spreading rates.     

Comparison of llama fiber obtained from two production regions of Argentina

The Puna is an arid region running along the Andes mountains, more than 3600 m above sea level. Overgrazing has severely degraded much of this ecosystem, and this has dramatically reduced agricultural production and resulted in poverty for human inhabitants. Llamas are native to the Puna and are well suited to live there. Their grazing habits and digestive system make efficient use of native forages, and their padded feet keep soil disturbance to a minimum, thereby reducing erosion. Uncontrolled llama breeding over the last 500 years has degraded the quality of the fiber they produce, so today it is generally of low quality. Analysis of llama fibers obtained from two production regions of Argentina showed that some llamas possess sufficiently fine mean fiber diameters (less than 23 μm if guard hairs are excluded) to allow their fleeces to be sold at a premium. A higher price would make llamas more attractive to raise than the goats and sheep commonly found in the Puna today. Switching to llama production would increase grower income and sustainability of agriculture in the region.     

Boundary-layer depth and entrainment zone characterization with a boundary-layer profiler

A technique for determining the height of the convective atmospheric boundary layer (CBL) with a 915 MHz boundary-layer profiler is discussed. The results are compared with CBL heights determined from radiosonde measurements. The profiler provides continuous CBL height measurements with very good time resolution (30 minutes or less), allowing for detailed understanding of the growth and fluctuations of the CBL. In addition, the profiler provides information about the degree of definition of the CBL top and the thickness of the entrainment zone. The measurements discussed were taken during the Rural Oxidants in the Southern Environment II (ROSE II) experiment.     

Zeolite and prehnite-pumpellyite facies in south central Puerto Rico

The intermediate lavas and pyroclastic rocks of south central Puerto Rico have been subjected to about four kilometers of burial. Despite shallow burial the mineralogy of these rocks has systematically readjusted. The degree of metamorphism is proportional to permeability; secondary phases appear in greater quantities in porous pyroclastics. In lavas, plagioclase and olivine phenoerysts contain a progressive sequence of alteration phases reflecting temperature and pressure conditions during alteration. The generalized sequence of appearance of secondary phases from low to high rank is as follows: 1. analcime, celadonite, chlorite, and sericite; 2. laumontite and albite; 3. prehnite; 4. pumpellyite; 5. epidote; 6. actinolite. Assemblages containing analcime, heulandite, celadonite, and laumontite belong to the zeolite facies. Remaining assemblages belong to the prehnite-pumpellyite facies.During alteration two major thresholds were crossed. First, calcium-aluminum silicates formed from materials released by decomposition of calcium feldspar. Second, clinopyroxene was decomposed in a process that added considerable mafic material to the reacting system, and made bulk rock compositions approximately equivalent to the composition of the reacting system. Comparison with other regions of similar metamorphic rank and composition indicates that zonation of such sequences on the basis of individual mineral occurrences, especially epidote, is justified only for local regions where the behavior of volatiles was uniform.Based on part of a dissertation (Jolly, 1969) presented to the faculty of the Department of Geology, State University of New York at Binghamton.     

An ion-association model for PbO-SiO2 melts: interpretation of thermochemical,conductivity, and density data

We propose that within PbO-SiO₂ melts the component species PbO(1) and SiO₂(1) associate to form a lead orthosilicate complex [Pb₂SiO₄(1)] according to $\text{2PbO(1) + SiO}{}_2\text{(1)}\text{a}\text{?}\text{f Pb}{}_2\text{SiO}{}_4\text{(1)}$ The association constant (K) for the above reaction is near 30 at 900 and 1000°C On the premises that the enthalpy of the above reaction is the only contributor to the enthalpy of mixing and that three melt species [PbO(1), SiO₂(1), Pb₂SiO₄(1)] mix ideally (Raoult's Law obeyed), the partial molar properties and the integral mixing properties of the melt have been calculated and have been found to accurately reproduce the measured thermochemical data.The conductivity data and density data for PbO-SiO₂ melts have been calculated using the association model. The calculated data again are remarkably consistent with the experimental data.Other silicate-melt models have been reinterpreted and that of Toop and Samis is compatible with the proposed model. In fact the Toop and Samis model implicitly assumes the formation of orthosilicate species rather than condensed polymeric species.     

Assessing Nitrogen Dynamics Throughout the Estuarine Landscape

Assessing nitrogen dynamics in the estuarine landscape is challenging given the unique effects of individual habitats on nitrogen dynamics. We measured net N₂ fluxes, sediment oxygen demand, and fluxes of ammonium and nitrate seasonally from five major estuarine habitats: salt marshes, seagrass beds (SAV), oyster reefs, and intertidal and subtidal flats. Net N₂ fluxes ranged from 332?±?116 μmol?N-N₂?m^?2?h^?1 from oyster reef sediments in the summer to ?67?±?4 μmol?N-N₂?m^?2?h^?1 from SAV in the winter. Oyster reef sediments had the highest rate of N₂ production of all habitats. Dissimilatory nitrate reduction to ammonium (DNRA) was measured during the summer and winter. DNRA was low during the winter and ranged from 4.5?±?3.0 in subtidal flats to 104?±?34 μmol?¹⁵NH ₄ ⁺ ?m^?2?h^?1 in oyster reefs during the summer. Annual denitrification, accounting for seasonal differences in inundation and light, ranged from 161.1?±?19.2 mmol?N-N₂?m^?2?year^?1 for marsh sediments to 509.9?±?122.7 mmol?N-N₂?m^?2?year^?1 for SAV sediments. Given the current habitat distribution in our study system, an estimated 28.3?×?10⁶?mol of N are removed per year or 76 % of estimated watershed nitrogen load. These results indicate that changes in the area and distribution of habitats in the estuarine landscape will impact ecosystem function and services.