Application of an improved self-starter to geoacoustic inversion

The self-starter is improved using the operator of the split-step Pade solution. In addition to providing greater stability and being applicable closer to the source, the improved self-starter is an efficient forward model for geoacoustic inversion. It is necessary to solve only O(10) tridiagonal systems of equations to obtain the acoustic field on a vertical array located O(10) wavelengths from a source. This experimental configuration is effective for geoacoustic inverse problems involving unknown parameters deep in the ocean bottom. For problems involving depth-dependent acoustic parameters, the improved self-starter can be used to solve nonlinear inverse problems involving O(10) unknown sediment parameters in less than a minute on the current generation of workstations     

Isobaric cooling and anti-clockwise P–T paths in the Variscan Odenwald Crystalline Complex, Germany

Mineral assemblages in Al₂O₃‐rich, SiO₂‐ and K₂O‐poor metapelitic rocks from the western Odenwald Crystalline Complex (Variscan Mid‐German Crystalline Rise, southern Germany) include corundum, spinel, cordierite, sillimanite, garnet and staurolite. Quartz is absent from almost all samples. Therefore, the applicability of conventional geothermobarometry is very limited or even impossible. Detailed petrographic investigation on selected samples permits inference of the sequence of appearance and disappearance of several mineral assemblages. The recognition of such partial re‐equilibration stages and their associated mineral assemblages, together with mineral stabilities predicted from KFMASH pseudosections, enables the determination of the pressure‐temperature (P–T) trajectories experienced by these rocks during the Variscan metamorphism. The rocks were metamorphosed under low‐P/high‐T conditions and underwent an anti‐clockwise P–T evolution. A pressure increase from about 2 kbar to 4 ± 0.5 kbar was accompanied by heating. Peak metamorphic conditions were reached at pressures of 4 ± 0.5 kbar and temperatures of at least 640 °C, probably even higher. The retrograde evolution is characterised by near‐isobaric cooling from ≥ 640 °C to approximately 550 °C. The rocks underwent the anti‐clockwise evolution in a subduction‐related magmatic arc setting. The close spatial association of the low‐P/high‐T rocks with recently discovered metabasic eclogites in the eastern part of the Odenwald Crystalline Complex may indicate a fossil paired metamorphic belt in the Central European Variscides.     

Ice‐cover variability on shallow lakes at high latitudes: model simulations and observations

A one‐dimensional thermodynamic model for simulating lake‐ice phenology is presented and evaluated. The model can be driven with observed daily or hourly atmospheric forcing of air temperature, relative humidity, wind speed, cloud amount and snowfall. In addition to computing the energy balance components, key model output includes the temperature profile at an arbitrary number of levels within the ice/snow (or the water temperature if there is no ice) and ice thickness (clear ice and snow‐ice) on a daily basis, as well as freeze‐up and break‐up dates. The lake‐ice model is used to simulate ice‐growth processes on shallow lakes in arctic, sub‐arctic, and high‐boreal forest environments. Model output is compared with field and remote sensing observations gathered over several ice seasons. Simulated ice thickness, including snow‐ice formation, compares favourably with field measurements. Ice‐on and ice‐off dates are also well simulated when compared with field and satellite observations, with a mean absolute difference of 2 days. Model simulations and observations illustrate the key role that snow cover plays on the seasonal evolution of ice thickness and the timing of spring break‐up. It is also shown that lake morphometry, depth in particular, is a determinant of ice‐off dates for shallow lakes at high latitudes. Copyright © 2003 John Wiley & Sons, Ltd.     

North European last glacial–interglacial transition (LGIT; 15–9 ka) tephrochronology: extended limits and new events

High‐precision correlation of palaeoclimatic and palaeoenvironmental records is crucial for testing hypotheses of synchronous change. Although radiocarbon is the traditional method for dating late Quaternary sedimentary sequences, particularly during the last glacial–interglacial transition (LGIT; 15–9 ka), there are inherent problems with the method, particularly during periods of climate change which are often accompanied by major perturbations in atmospheric radiocarbon content. An alternative method is the use of tephras that act as time‐parallel marker horizons. Within Europe, numerous volcanic centres are known to have erupted during the LGIT, providing considerable potential for high‐precision correlation independent of past radiocarbon fluctuations. Here we report the first identification of the Vedde Ash and Askja Tephra in Ireland, significantly extending the known provenance of these events. We have also identified two new horizons (the Roddans Port Tephras A and B) and tentatively recognise an additional horizon from Vallensgård Mose (Denmark) that provide crucial additional chronological control for the LGIT. Two phases of the Laacher See Tephra (LST) are reported, the lower Laacher See Tephra (LLST) and probably the C2 phase of the Middle Laacher See Tephra (MLST‐C2) indicating a more northeasterly distribution of this fan than reported previously. Copyright © 2006 John Wiley & Sons, Ltd.     

Composition of brines in halite‐hosted fluid inclusions in the Upper Ordovician,Canning Basin,Western Australia: new data on seawater chemistry

Analyses of primary and early diagenetic fluid inclusions in the halite from the Late Ordovician Mallowa Salt, Canning Basin, Western Australia indicate a Ca‐rich composition and high concentration of parent brines in the basin which were close to sylvite and carnallite precipitation. The salt‐bearing series in the sampled interval was overheated up to 62 °C. The recorded differences in gas compositions result from the input of several gas sources including dispersed organic matter in the salt series and hydrocarbon deposits in the underlying rocks. The high concentration of the brines in fluid inclusions does not allow quantitative reconstruction of the chemical composition of Late Ordovician parent seawater. Using the information from Early Cambrian and Late Silurian basins as a proxy, however, the new data indicate that Late Ordovician seawater was undoubtedly Ca‐rich and, in comparison with modern seawater, had a similar K content, considerably lower Mg content (c. 30%), approximately three times the Ca content and one‐third the SO₄ content.     

A technique for calibration of monostatic echosounder systems

A calibration technique has been adapted to render complete system calibrations of high-frequency acoustical instrumentation. This is based on standard targets; specifically, precisely manufactured spheres composed of tungsten carbide with 6% cobalt binder. The use of multiple sphere sizes was found to be advantageous, both as an independent check of the calibrations, and so that resonances in the sphere responses at certain frequencies could be avoided. Complete system gains and beam patterns, which include effects of bandpass filters and finite-pulse lengths, were determined by moving the spheres individually in the transducer far-fields. Use of this procedure ensures control over the acoustical characteristics of transducers, which may change from the time of manufacture and first testing due, for example, to platform mounting. It also provides a direct means of measuring the sampling volume at relatively high and constant signal-to-noise ratios. Implementation of this technique is discussed using a multifrequency sonar system as an example     

Dissolved organic carbon dynamics in two streams draining forested catchments at loch ard,Scotland

Dissolved organic carbon (DOC) was measured at four or eight hour intervals between mid-1989 and mid-1991 in two catchments in west central Scotland. The experimental catchment had been recently clear-felled and the control remained under forest. The amount of DOC varied during individual storm events following the stream hydro-graph. Maximum variations were found in the summer half-year and in the clear-felled catchment. There was also evidence of the exhaustion of DOC in the later events of a sequence. Differences between the catchments were related to catchment characteristics and to land-use change. The reduced magnitude of variation in DOC with discharge in the control stream was due to the influence of a wetland area through which the stream flowed. The mean DOC concentrations were similar in the two streams and annual exports were 15 g m^?2 from the control and 16g m^?2 from the felled catchment. The stream draining the clear-felled catchment had greater high flow DOC concentrations in the summer half-year, probably due to the effect of greater mean summer temperatures on DOC release and of the greater supply of organic debris in the stream channel.