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通过浸渍法(IM)和沉积-沉淀(DP)法制备了一系列Pt/TiO2P25)催化剂,并分别用甲醛溶液和氢气还原处理催化剂.利用原位红外监测催化剂表面吸附物种在反应过程中的变化,探究了催化剂制备和还原条件及Pt负载量对催化剂结构和催化氧化甲醛活性的影响.结果显示,用DP法制备并用甲醛还原的Pt/P25催化剂中Pt颗粒分散均匀,并具有合适的粒径和高浓度的表面活性氧,显示出良好的甲醛氧化活性.在空速30 000 ml/(g·h)、反应温度30°C和甲醛初始浓度50 mg/m的条件下,0.4%Pt/P25(DP-HCHO)上的甲醛转化率达到98%,并能稳定运行100 h以上.相比之下,Pt/P25(DP-H2)由于表面活性氧较少,不利于甲酸盐氧化,活性较低.Pt/P25(IM-H2)虽然具有高浓度的表面活性氧,却同时具有最大的Pt颗粒粒径,在甲醛转化为甲酸盐和甲酸盐氧化两步反应中的活性均较差,因而甲醛氧化活性最差. 相似文献
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基于GIS的攀西地区铂族元素成矿地质条件初步分析 总被引:2,自引:1,他引:2
攀西地区以良好的铂族元素(PGE)成矿地质背景,而成为我国铂族元素找矿热点地区之一。本文在建立攀西地区铂族元素矿床地质概念模型的基础上,用地理信息系统(GIS)分析了该地区的铂族元素成矿地质条件,包括地质构造、峨眉山玄武岩、基性一超基性岩和铂族元素地球化学异常特征。指出研究区的深大断裂对铂族元素的富集表现出很好的控制作用,峨眉山玄武岩为铂族元素的矿源层之一,岩浆岩为铂族元素的富集提供了成矿物质及成矿能量。 相似文献
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Basin-fill sequences of Mesozoic typical basins in the Yanshan area, North China may be divided into four phases, reflecting lithosphere tectonic evolution from flexure (T3), flexure with weak rifting (J1+2), tectonic transition (J3), and rifting (K). Except the first phase, the other three phases all start with lava and volcaniclastic rocks, and end with thick coarse clastic rocks and/or conglomerates, showing cyclic basin development rather than simple cyclic rift mechanism and disciplinary basin-stress change from extension to compression in each phase. Prototype basin analysis, based on basin-fill sequences, paleocurrent distribution and depositional systems, shows that single basin-strike and structural-line direction controlling basin development had evidently changed from east-west to northeast in Late Jurassic in the Yanshan area, although basin group still occurred in east-west zonal distribution. Till Early Cretaceous, main structural-line strike controlling basins just turned to northeast by north in the studied area. 相似文献
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ZHAGN Yijun DONG Wansheng ZHAO Yang ZHANG Guangshu Zhang Hongfa CHEN Chengpin ZHANG Tong 《中国科学D辑(英文版)》2004,47(Z1)
The comprehensive observations on lightning discharges were conducted in Naqu area of Qinghai-Tibet Plateau in summer of 2002. The electric structures of thunderstorms and the characteristics of lightning discharges at initial stage were analyzed by using the observation data. The results show that most of intracloud (IC) lightning flashes were polarities inverted in thunderstorms with tripole electric charge structure and occurred between negative charge region located in the middle of the thunderstorm and positive charge region located at the bottom of the thunderstorm. The radiation characteristics of discharge processes in cloud with longer lasting time involved in Cloud-to-Ground (CG) lightning flashes were similar to that of IC discharges.A lot of radiation pulses were produced in these discharge processes. Because the IC discharges took place at the bottom of thundercloud and were near the ground, they may produce more serious damage to equipment on the ground therefore should not be neglected in lightning protection. 相似文献
17.
The superimposed basin must have undergone the changes of regional stress field. Study on the nature and switch of regional stress field of superimposed basin is very useful to understanding its stress state and tectonic events during its formation and evolution. As sensitive markers of small stress changes, joint and shear fracture, characterized by consistency of orientation over wide area, can be used to reconstruct paleostress state and its evolution. Detailed observations and analysis on the orientations, geometrical patterns, sequences of joints and shear fractures and their chronological relation to faults and folds show that, the NEE-SWW systematic joints and NNW-SSE systematic joints developed in the Mesozoic and Cenozoic strata are much more prominent than NW-SE systematic joints and shear fractures with different orientations. And the NWW-SEE and NW-SE systematic joints formed later than NEE-SWW systematic joints but earlier than shear fractures with different orientations. According to the relationships between joint and shear fractures and stress, the NEE-SWW systematic joints are inferred to result from lateral weak extension caused by the late Cretaceous regional uplift, while the NNW-SSE and NW-SE systematic joints are interpreted as syn-tectonic deformation relating to strong N-S compression in the Neogene. But some conjugate shear fractures occur probably due to sinistral strike-slip faulting in the Kuqa depression. At the beginning of the Neogene, the stress field changed and the maximal principal stress σ1 switched from vertical to horizontal. 相似文献
18.
Problem on development control of marine source bed hold in Chinese petroleum industry progression. The Hongshuizhuang Formation,Tieling Formation and Xiamaling Formation in the Middle and Upper Proterozoic are important hydrocarbon source beds in northern North China, and investigation of their sedimentary environments and the controls has great significance for petroleum exploration in North China. Based on sedimentology (sequence stratigraphy), palaeoecology, sedimentary geochemistry, and sedimentary palaeogeography, their development pattern is discussed. All these studies indicate that the development controls of the hydrocarbon source beds include a favorite palaeogeographic location, exceeding propagation of biomes in low and middle latitudes, anoxic environments, enrichment of phosphorus element and the adsorption of clay minerals during the preservation of organic matter in the marine carbonates. 相似文献
19.
遥感影像三维可视化研究 总被引:1,自引:0,他引:1
利用DEM高程资料实现遥感影像的三维显示可大大提高遥感监测产品的使用价值,而商用软件成本高操作繁琐普及困难。利用计算机图形学知识和Delphi编程语言,开发了一套遥感影像三维可视化软件。对在开发过程中遇到的有关DEM数据的裁剪与拼接、图像配准、地表模拟、透视变换、消隐处理、光照和阴影效果以及颜色变换等问题的解决方案和实现方法作了简要的介绍。 相似文献
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