Magnetic and microstructural properties of some lodestones

An iron ore which behaves as a permanent magnet is lodestone. The intrinsic magnetic properties and the microstructual characteristics which are responsible for the permanent-magnet properties of the lodestone have never been described or explained. Iron ores capable of being charged sufficiently strongly to behave as permanent magnets are defined here as proto-lodestones and fall into two categories — Class I which contains Fe as the only significant cation, and Class II which contains considerable Ti, Mg and Al as well. Proto-Lodestones are magnetically hardened by oxidation and precipitation processes which produce the microstructure responsible for the permanent-magnet properties. Lodestones are charged proto-lodestone iron ores. Lodestones have R_H values (ratio of remanent coercive force, H_R, to coercive force, H_C) between 2.0 and 2.5; R_I values (ratio of saturation remanence, I_SR, to saturation magnetization, I_S) >0.1–0.25 and the ratio of NRM/SIRM (natural remanence to saturation remanence) is 0.15–0.7. The intrinsic magnetic properties and microstructural characteristics of proto-lodestones and other iron ores are described and explained. The mechanism of charging the proto-lodestone appears to be either transient magnetic fields associated with lightning-discharge currents or presently obscure aspects of magnetization intensity enhancement associated with maghemitization of massive iron ores.     

443 Eros: Problems with the meteorite magnetism record in attempting an asteroid match

Abstract— The magnetometer experiment (MAG) onboard the Near‐Earth Asteroid Rendezvous (NEAR)‐Shoemaker spacecraft detected no global scale magnetization and established a maximum magnetization of 2.1 times 10^?6 Am² kg^?1 for asteroid 433 Eros. This is in sharp contrast with the estimated magnetization of other S‐class asteroids (Gaspra, ?2.4 times 10^?2 Am² kg^?1; Braille, ?2.8 times 10^?2 Am² kg^?1) and is below published values for all types of ordinary chondrites. This includes the L/LL types considered to most closely match 433 Eros based on preliminary interpretations of NEAR remote geochemical experiments. The ordinary chondrite meteorite magnetization intensity data was reviewed in order to assess the reasonableness of an asteroid‐meteorite match based on magnetic property measurements. Natural remanent magnetization (NRM) intensities for the ordinary chondrite meteorites show at least a 2 order of magnitude range within each of the H, L, and LL groups, all well above the 2.1 times 10^?6 Am² kg^?1 level for 433 Eros. The REM values (ratio of the NRM to the SIRM (saturation remanent magnetization)) range over 3 orders of magnitude for all chondrite groups indicating no clear relationship between NRM and the amount of magnetic material. Levels of magnetic noise in chondrite meteorites can be as much as 70% or more of the NRM. Consequently, published values of the NRM should be considered suspect unless careful evaluation of the noise sources is done. NASA Goddard SFC studies of per unit mass intensities in large (>10 000 g) and small (down to <1 g) samples from the same meteorite demonstrate magnetic intensity decreases as size increases. This would appear to be explained by demagnetization due to magnetic vector randomness at unknown scale sizes in the larger samples. This would then argue for some level of demagnetization of large objects such as an asteroid. The possibility that 433 Eros is an LL chondrite cannot be discounted.     

The magnetic characteristics of returned lunar samples and 5heir implications for regolith processes

Magnetic observations yield information about the amount and nature of the magnetic phases present in a sample. They reveal that the predominant magnetic phase in the lunar samples is metallic iron which is sometimes alloyed with nickel and cobalt. In the mare basalts less than 0.1% of metallic iron is present, whereas in the non-mare crystalline rocks several percent of iron has been found in some samples. The soils have approximately 0.5% of iron, which is fine grain, rather pure iron occurring in impact glass. In the recrystallized breccias and the igneous rocks the iron is coarser. Systematic minor variations in metallic iron content in the soils reveal soil maturity trends. Mixing between highland and mare soils can be traced with the Fe²⁺ content. Mare soils differ from highland soils in having a higher value of reduced remanence. The magnetic characteristics of the Apollo 14 breccias are not consistent with the progressive metamorphism of a common starting material. Shock welding in the range of tens of kbs can account for the characteristics of some of the ‘unmetamorphosed’ breccias. Greater shock accompanied by recovery can account for the magnetic characteristics of the ‘recrystallized’ breccias.     

The role of nickel content and the magnetic remanence in iron-nickel alloys of lunar composition

Lunar samples are magnetic primarily due to the body centered cubic (BBC) iron and ironnickel alloys they contain. Presented for the first time are results which demonstrate that the magnitude of the martensitic thermal remanence (MTRM) induced on quenching iron-nickel alloy in the geomagnetic field depends on the nickel content of the alloy. High magnetic stability is due to the increasing dislocation density and increasingly complex microstructures associated with increasing nickel content in the alloys. The results agree with the mechanical and structural properties of the alloys. The characteristic quench martensite microstructure observed on metallographic examination provides a recognition criterion for the MTRM mechanism. These results are important for lunar and meteoritic research intending to ascertain the paleofield responsible for the observed remanent magnetization.     

Possible magnetic effects due to fine particle metal and intergrown phases in lunar samples

Electron microscopy has confirmed the existence of both body centered cubic (BBC)-α metal and face centered cubic (FCC)-γ metal in lunar fines and breccia samples. Under appropriate conditions of composition, size, and other constraints iron-nickel alloys can exist as FCC phases over the entire range from 0 to 100% nickel. Lunar rock magnetism research has not generally considered the implications of structures, mechanisms, crystallography, and possible interaction effects in fine particle metal. FCC metal is antiferromagnetic (? 30 wt % nickel) and would be measured in the paramagnetic component, showing a cryogenic temperature Neel point; only BCC metal would figure in the estimation of the free iron content based on saturation magnetization measurements. Evidence is presented for changes in saturation magnetization, magnetic remanence, and coercivity, and for the introduction of magnetic anisotropy when FCC metal transforms to BCC metal. From the results in the published metallurgical literature it is inferred that the induced magnetic anisotropy observed during plastic deformation of fine FCC iron precipitates in a copper matrix is associated with uniaxial development of BCC plates in the FCC precipitate. Directional impulse or any uniaxial deformation may produce magnetic anisotropy if FCC metal is made to transform to BCC metal (theγ→α _M transformation), and there will be an angular dependence for remanence acquisition, because of shape, which must be considered in paleointensity determinations. It should be noted that the transformation can be activated at any temperature below the Curie point of the BCC metal High field rotational hysteresis (Wr) has been measured in lunar fines and rocks, indicating that exchange anisotropy and/or ferromagnetic minerals with large uniaxial anisotropy exist in the lunar samples. The following are possible sources of the hysteresis:

1. Fine intergrowths of spinels or other nonequilibrium phase intergrowths developed during subsolidus reduction;
2. Fine particle intergrowths of iron and iron sulfide;
3. Iron and wustite or magnetite due to fine particle oxidation;
4. Ferromagnetic (BCC) and antiferromagnetic (FCC) metallic intergrowths.

     

Magnetic study of serpentinized harzburgites from the Islas Orcadas Fracture Zone

Magnetic properties and bulk densities of 27 serpentinized harzburgite samples from the Islas Orcadas Fracture Zone, located in the vicinity of the Bouvet Triple Junction, have been measured and analyzed. Polished sections were examined using reflected light and scanning electron microscopy to characterize the size and geometric arrangement of opaque minerals. The relationship between the saturation magnetization (I_S) and remanent coercive force (H_R) is considered in terms of the amount of ferrimagnetic material and maghemitization. A suite of continental serpentinites from Canada is offered as contrast, to consider the role of weathering and maghemitization. Magnetite in the Islas Orcadas serpentinites is variably maghemitized, whereas continental serpentinites do not appear to contain maghemitized oxides. We verify this with optical microscopy, thermomagnetic analyses and cryogenic temperature cycling of saturation remanence. Maghemitization serves to reduce initial magnetic susceptibility, and introduce error in the use of I_S to evaluate the magnetic mode of magnetite. The presence of maghemite and the existence of a three dimensional vein network for magnetite geometry would suggest that magnetic hysteresis parameters can not reliably indicate grain size. Magnetic hysteresis ratios fall in a restricted range regardless of coercivity. The apparent grain size configured in a three dimensional vein network plus maghemitization might be responsible for this observation. Maghemitization does not affect thermal magnetic stability and enhances the geophysical importance of remanence in serpentinites. Paleomagnetic data suggest that important information about the geologic circumstances for oceanic rock serpentinization is embodied in the paleomagnetic records. This observation may be very important for generation of long wavelength aeromagnetic and possibly even satellite magnetic anomalies.     

The significance of observed rotational magnetic hysteresis in lunar samples

Rotational Magnetic hysteresis (W _R ) curves for lunar soils 10084, 12070, 14259, and rock 14053, have been published. There is no adequate explanation to date for the observed largeW _R at high fields. Lunar rock magnetism researchers consider fine particle iron to be the primary source of stable magnetic remanence in lunar samples. Iron has cubic anisotropy with added shape anisotropy for extreme particle shapes. The observed high fieldW _R must have its source in uniaxial or unidirectional anisotropy. This implies the existence of minerals with uniaxial anisotropy or exchange coupled spin states. Therefore, the source of this observed high fieldW _R must be identified and understood before serious paleointensity studies are made. It is probable that the exchange coupled spin states and/or the source of uniaxial anisotropy responsible for the high fieldW _R might be influenced by the lunar surface diurnal temperature cycling. The possible sources of high fieldW _R in lunar samples are presented and considered.     

Shock remagnetization associated with meteorite impact at planetary surfaces

Shock remagnetization is a significant mode of alteration of the intensity and direction of magnetization in planetary crustal rocks subjected to the dynamic and thermochemical effects associated with meteorite impact. Shock remagnetization will take place almost instantaneously during and following the transient shock episode, and over longer times depending on residual temperature effects associated with shock heating and the production of impact melt. Remagnetization will follow certain demagnetization effects. The following transitions and residual effects will result in remagnetization of planetary crustal material:

1. First order reversible crystallographic transitions in bodycentered cubic iron-nickel alloys.
2. Second order Curie temperature transitions in face-centered cubic iron-nickel alloys.
3. Shock induced uniaxial anisotropy due to magnetoelasstic coupling of magnetic vectors to the shock wave.
4. Shock melting of iron containing silicates.
5. Subsolidus reduction and FeO decomposition.
6. Partial ther moremanence due to post-shock temperature.
7. Total thermoremanence due to post-shock temperature.
8. Production of a superparamagnetic distribution of iron which is sensitive to surface temperature fluctuation.
9. Thermal effects in metal and alloy phases.

Lunar breccia and soil samples are generally more reduced than crystalline rocks and some of th's reduction is subsolidus probably associated with the transient thermal effects due to meteorite impact in teh porous reglith.     

Crustal magnetization and temperature at depth beneath the Yilgarn block, Western Australia inferred from Magsat data

Variations in crustal magnetization along a seismic section across the Archean Yilgarn block of Western Australia inferred from Magsat data are interpreted as a subtle thermal effect arising from variations in depth to the Curie isotherm. The isotherm lies deep within the mantle of the eastern part of the province, but transects the crust-mantle transition and rises well into the crust on the western side. The model is consistent with heat flow variations along the section line. The mean crustal magnetization implied by the model is approximately 2 A/m. The temperature variation implied by the model is consistent with the hypothesis that the crust-mantle transition seen seismically corresponds to the mafic granulite-eclogite phase transition within a zone of igneous crustal underplating.     

Satellite and surface geophysical expression of anomalous crustal structure in Kentucky and Tennessee

An equivalent layer magnetization model obtained from inversion of long-wavelength satellite magnetic anomaly data indicates a very magnetic source region centered in south central Kentucky. The magnetization maximum nearly coincides with a gravity high elongated north-south and extending into Tennessee. Previous refraction profiles suggest that the source of the gravity anomaly is a large mass of rock occupying much of the crustal thickness. The outline of the source delineated by gravity contours is also discernible in aeromagnetic anomaly patterns. Taken together, the geophysical data suggest a large, localized mass of intracrustal rock which is both dense and very magnetic. A simple magnetization/density model is given which accounts for the gravity and long-wavelength aeromagnetic anomalies due to the body. We interpret it as a mafic plutonic complex, and several lines of evidence are consistent with a rift association. The body is, however, clearly related to the inferred position of the Grenville Front. It is bounded on the north by the fault zones of the 38th Parallel Lineament. The inferred mean magnetization (4 A/m) of the body is large, but not inconsistent with values reported by others for deep crustal bodies associated with long-wavelength magnetic anomalies. Such magnetization levels can be achieved with magnetic mineralogies produced by normal oxidation and metamorphic processes and enhanced by viscous build-up, especially in mafic rocks of alkaline character.