On the survivability of an enantiomeric excess of amino acids in comet nuclei during the decay of26Al and other radionuclides

We present a computer model calculation for the racemization of a possible excess of amino acids in the icy fraction of comet nuclei bring about by ionizing radiation released during the decay of²⁶Al,⁴⁰K,²³⁵U,²³⁸U and²³²Th. The model takes into account a total of 110 chemical reactions, of which 91 are needed to explain the radiation chemical processing of the major constituents of comet nuclei (Navarro-Gonzálezet al., 1992) and 19 are necessary to simulate the radiolysis of glycine/alanine mixtures in aqueous solutions (Navarro-Gonzálezet al., 1994 and 1996). It is predicted that an enantiomeric excess of alanine would not be destroyed by radioracemization during the decay of embedded radionuclides. Nevertheless, this enantiomeric excess could be attenuated by the formation of racemic amino acids in the interior of comet nuclei as a result of the radiation-induced polymerization of HCN.     

Partial Melting and Counterclockwise P T Path of Subducted Oceanic Crust (Sierra del Convento Melange, Cuba)

Partial melting of subducted oceanic crust has been identifiedin the Sierra del Convento mélange (Cuba). This serpentinite-matrixmélange contains blocks of mid-ocean ridge basalt (MORB)-derivedplagioclase-lacking epidote ± garnet amphibolite intimatelyassociated with peraluminous trondhjemitic–tonalitic rocks.Field relations, major element bulk-rock compositions, mineralassemblages, peak metamorphic conditions (c. 750°C, 14–16kbar), experimental evidence, and theoretical phase relationssupport formation of the trondhjemitic–tonalitic rocksby wet melting of subducted amphibolites. Phase relations andmass-balance calculations indicate eutectic- and peritectic-likemelting reactions characterized by large stoichiometric coefficientsof reactant plagioclase and suggest that this phase was completelyconsumed upon melting. The magmatic assemblages of the trondhjemitic–tonaliticmelts, consisting of plagioclase, quartz, epidote, ±paragonite, ± pargasite, and ± kyanite, crystallizedat depth (14–15 kbar). The peraluminous composition ofthe melts is consistent with experimental evidence, explainsthe presence of magmatic paragonite and (relict) kyanite, andplaces important constraints on the interpretation of slab-derivedmagmatic rocks. Calculated P–T conditions indicate counterclockwiseP–T paths during exhumation, when retrograde blueschist-faciesoverprints, composed of combinations of omphacite, glaucophane,actinolite, tremolite, paragonite, lawsonite, albite, (clino)zoisite,chlorite, pumpellyite and phengite, were formed in the amphibolitesand trondhjemites. Partial melting of subducted oceanic crustin eastern Cuba is unique in the Caribbean realm and has importantconsequences for the plate-tectonic interpretation of the region,as it supports a scenario of onset of subduction of a youngoceanic lithosphere during the early Cretaceous (c. 120 Ma).The counterclockwise P–T paths were caused by ensuingexhumation during continued subduction. KEY WORDS: amphibolite; Cuba; exhumation; partial melting; trondhjemite; subduction     

Coastal Upwelling Activity on the Pacific Shelf of the Baja California Peninsula

High primary productivity on the Pacific coast of the Baja California Peninsula is usually related to coastal upwelling activity that injects nutrients into the euphotic zone in response to prevailing longshore winds (from the northwest to north). The upwelling process has maximum intensity from April to June, with the coastal upwelling index varying from 50 to 300 m³/s per 100 m of coastline. Along the entire coast of the peninsula, the upwelling intensity changes in accordance with local wind conditions and bottom topography. Spatial variability can also be modulated by the influence of mesoscale meanders of the California Current. We have identified the seasonal and synoptic variability of upwelling signatures on the Baja California shelf, using averaged monthly and weekly sea surface temperature (SST) distributions obtained from remote sensing imagery from the Advanced Very High Resolution Radiometer in the period from 1996 to 2001. Analysis of SST distribution and direct experimental data on temperature and nutrient concentration shows that the areas with the coldest SST anomalies were closely related to the bottom slope, shelf width, and coastline orientation relating to wind direction. We also assume that the nutrient transport into the coastal lagoons may be forced by the coupling of coastal upwelling and tidal pumping of surface waters into the lagoon system. This revised version was published online in August 2006 with corrections to the Cover Date.     

Influence of Rhodolith-Forming Species and Growth-Form on Associated Fauna of Rhodolith Beds in the Central-West Gulf of California, México

Abstract.  Rhodoliths provide a stable and three-dimensional habitat to which other seaweeds and invertebrates can attach. Although ecological factors affecting rhodolith beds have been studied, little is known about the effect of rhodolith species and growth-form on associated fauna. Experiments were conducted at three rhodolith beds in the central-west Gulf of California. Faunal abundance differed significantly in relation to rhodolith-forming species, but no significant differences were observed between different growth-forms. Rhodolith structure differs between the species Lithophyllum margaritae and Neogoniolithon trichotomum , and the combination of structure differences and rhodolith abundances may be responsible of the significant differences in faunal abundance and richness. Crustaceans, polychaetes and molluscs were the most important taxa in all three rhodolith beds. The amphipod species Pontogeneia nasa and the cnidarian Aiptasia sp. were dominant in both rhodolith beds, El Requesón and Isla Coyote, in Bahía Concepción. The Isla Coronados rhodolith bed was dominated by an unidentified harpacticoid copepod (Copepoda sp.1). Rhodolith species is more important than growth-form in determining abundance and richness of the associated fauna. Nevertheless, factors such as wave motion, depth, bioturbation and others should be considered when studying organisms associated with rhodolith beds.     

In Situ Measurement of Pinna nobilis Shells for Age and Growth Studies: A New Device

Abstract. Pinna nobilis Linnaeus 1758 is an endemic bivalve mollusc in the Mediterranean Sea, where it inhabits seagrass meadows, especially Posidonia oceanica (L.) Delile. It is the largest bivalve in the Mediterranean, reaching lengths up to 120 cm. In its natural habitat, P. nobilis lives with the anterior part of the valve buried in the seabed, attached to Posidonia rhizomes by byssus threads.
This habit makes it impossible to measure its total length directly in situ. As the only way to determine the individual age is the relationship between age and total length, several equations have been proposed to estimate total length by relating it to the unburied parts of the shell. Such measurements are essential to ecological studies that consider age, growth, and population dynamics, and that evaluate the environmental factors that affect this species.
Accurately estimating total length depends on the accuracy and precision of the method employed to measure the unburied shell parts. In this paper, we point out the lack of precision of the instruments and methods used until now; we also demonstrate the reason for this imprecision. A new device to measure unburied parts of Pinna nobilis with a precision comparable to that obtained when measuring extracted valves is described. This device is unaffected by substratum type and reduces measurement time. The latter is a very important feature, because these procedures are usually performed whilst SCUBA diving. Finally, a growth equation has been fitted to the measurements obtained with the new device from a population located in Moraira (Alicante, western Mediterranean).     

Multiple scattering ofSH waves in 2-D media with many cavities

The full waveform synthetic seismogram of multiple scatteredSH waves by many cylindrical cavities in two-dimensional homogeneous elastic media is computed. We used the so-called single-layer potential integral representation of the scattered field and a discretization scheme with line source distribution for each cavity. The total field is the sum of the incident wave plus the field radiated from all sources, each multiplied by an unknown complex constant representing its strength. These constants are determined by imposing the appropriate boundary conditions in the least-squares sense. Here we solve scattering problems involving one, two, four, twelve and fifty cavities regularly distributed in a half-space. The seismograms computed along the free-surface show regions where the incident wave is strongly attenuated, as well as the arrivals of all multiple scattered phases. The accuray of the method is estimated from the degree of agreement of our solution for one cavity with the corresponding analytical solution, and also from the magnitude of the residual tractions along the boundaries of two cavities separated at various distances. Finally we apply the method to compute the case of fifty cylindrical cavities, each of radiusa, randomly distributed in a region 80a wide by 30a deep in a half-space. The value of scattering loss is obtained from the amplitude decay of the primary wave with distance for wavelengths in the range from 1.7a to 13.3a, using the synthetic seismogram calculated for the same distribution of 50 cavities as above, but in full-space.     

Surface temperature differences between minerals in crystalline rocks: Implications for granular disaggregation of granites through thermal fatigue

Thermal expansion differences between minerals within rocks under insolation have previously been assumed to drive breakdown by means of granular disaggregation. However, there have been no definitive demonstrations of the efficacy of this weathering mechanism. Different surface temperatures between minerals should magnify thermal expansion differences, and thus subject adjacent minerals to repeated stresses that might cause breakdown through fatigue failure. This work confirms the existence of surface temperature differences between minerals in granitic rocks under simulated short-term temperature fluctuations so as to discriminate their potential for initiating granular disaggregation. The influence of colour, as a surrogate for albedo, and crystal size, as a function of thermal mass are specifically identified because of their ease of quantification. Four rock types with a range of these properties were examined, and subjected to repeated short-term temperature cycles by radiative heating and cooling under laboratory conditions. Results show that while albedo is the main control for overall and individual maximum temperatures, crystal size is the main factor controlling higher temperature differences between minerals. Thus, stones with large differences of mineral sizes can undergo magnified stresses due to thermal expansion differences.     

Building Web-Based Spatial Information Solutions around Open Specifications and Open Source Software

Geographic Information Systems (GIS) are moving from isolated, standalone, monolithic, proprietary systems working in a client‐server architecture to smaller web‐based applications and components offering specific geo‐processing functionality and transparently exchanging data among them. Interoperability is at the core of this new web services model. Compliance with Open Specifications (OS) enables interoperability. Web‐GIS software's high costs, complexity and special requirements have prevented many organizations from deploying their data and geo‐processing capabilities over the World Wide Web. There are no‐cost Open Source Software (OSS) alternatives to proprietary software for operating systems, web servers, and Relational Database Management Systems. We tested the potential of the combined use of OS and OSS to create web‐based spatial information solutions. We present in detail the steps taken in creating a prototype system to support land use planning in Mexico with web‐based geo‐processing capabilities currently not present in commercial web‐GIS products. We show that the process is straightforward and accessible to a broad audience of geographic information scientists and developers. We conclude that OS and OSS allow the development of web‐based spatial information solutions that are low‐cost, simple to implement, compatible with existing information technology infrastructure, and have the potential of interoperating with other systems and applications in the future.     

Assessing land use/cover changes: a nationwide multidate spatial database for Mexico

A nationwide multidate GIS database was generated in order to carry out the quantification and spatial characterization of land use/cover changes (LUCC) in Mexico. Existing cartography on land use/cover at a 1:250,000 scale was revised to select compatible inputs regarding the scale, the classification scheme and the mapping method. Digital maps from three different dates (the late 1970s, 1993 and 2000) were revised, evaluated, corrected and integrated into a GIS database. In order to improve the reliability of the database, an attempt was made to assess the accuracy of the digitalisation procedure and to detect and correct unlikely changes due to thematic errors in the maps. Digital maps were overlaid in order to generate LUCC maps, transition matrices and to calculate rates of conversion. Based upon this database, rates of deforestation between 1976 and 2000 were evaluated as 0.25 and 0.76% per year for temperate and tropical forests, respectively.