Wetting Induced Deformation of Soils Triggering Landslides in Pakistan

Geotechnical and Geological Engineering - Shallow and deep seated landslides in natural slopes are often induced by rainfall. The cause of the failure is usually considered to be due to the...     

Retention studies of chromium (VI) from aqueous solution on the surface of a novel carbonaceous material

In the present study, the retention capacity of carbonaceous material obtained from the diesel engine exhaust mufflers for Cr(VI) removal has been investigated. The physicochemical properties such as density, pH of aqueous slurry, pH at point of zero charge, ash content, moisture content, volatile matter, surface area, scanning electron microscopy and electron dispersive spectroscopy of the carbonaceous material were determined. The capacity of adsorbent for removal of Cr(VI) from aqueous solution was observed under different experimental condition like contact time, initial concentration of metal ions, pH and temperatures on the adsorption capacity of the adsorbent. Maximum adsorption of Cr(VI) ions was found at low pH. The adsorption process was found to follow second-order kinetics. The rate constant was evaluated at different temperatures along with other thermodynamic parameters like activation energy, Gibbs free energy change, enthalpy change and entropy change. Both Langmuir and Freundlich isotherms were used to describe the adsorption equilibrium of carbonaceous material at different temperatures. Langmuir isotherm shows better fit than Freundlich isotherm at given conditions. The result shows that low-cost carbonaceous material from diesel engine exhaust mufflers can be efficiently used for wastewater treatment containing Cr(VI) ions.     

Guidelines for EIA of fish and shrimp hatcheries in a semi-enclosed water body

Natural fisheries in most parts of the world are under pressure due to heavy fishing activities and pollution threats. The establishment of fish and shrimp hatcheries using native species provides an opportunity for replenishment of fish and shrimp stocks in an environmentally responsible manner. This paper provides guidelines for conducting an EIA of fish and shrimp hatcheries in a semi-enclosed water body, such as the Arabian Gulf and Red Sea. The purpose of the guidelines is to outline issues that may be relevant to the design and construction of hatcheries and to identify important factors for consideration in an EIA study. Effective consultations and technical discussions during the design stage with project proponent and relevant government agencies are recommended. Early evaluation of alternative sites and consideration of environmental factors in ascertaining the suitability of intended project site can help minimize potential impacts. Aspects to be considered in depth include impacts on water quality, sediment and habitat loss. The paper also provides suggested mitigation measures for minimizing potential impacts along with key elements to be considered in the development of an adequate Environmental Management and Monitoring Plan.     

Opening and closure of a marginal Southern California lagoon inlet

Over the past 50 yr, direct observations of the inlet status (open or closed) of San Dieguito Lagoon, a typical southern California lagoon located in Del Mar, California, have shown that river flooding is the major natural determinant of inlet conditions on time scales longer than a few years. River flooding is strongly dependent on rainfall in the San Dieguito River watershed and on the influences of two water storage reservoirs in the area. Rainfall fluctuates on yearly and longer time scales and undergoes cycles of wet and dry periods. Over short time periods, ranging from a few months to several years, inlet status is primarily determined by the available tidal prism and littoral sand transport. Recognition of these factors is crucial in order to correctly evaluate the probability that a small lagoon will remain open naturally. A probability approach is essential because the variables controlling inlet conditions are random in nature. The results of our study show that the inlet will remain open naturally 34% of the time. The tendency to remain open is vastly smaller during years of dry weather (12%) versus times of above-average rainfall (66%).     

Ionic Liquid Modified Resin for the Adsorptive Removal of Dibutyl Phthalate: Equilibrium,Kinetic, and Thermodynamic Studies

This study evaluated the adsorptive properties of dibutyl phthalate (DBP) on room temperature ionic liquid (RTIL) modified XAD‐4 resin. The modified RTIL‐XAD 4 sorbent was characterized by FTIR. Effect of varying experimental conditions such as pH, contact time, temperature, shaking speed, concentrations, and interfering species were investigated by batch adsorption experiments. Adsorption was found to be most favorable at pH 6 within 30 min. Experimental data were evaluated in terms of kinetic, equilibrium, and thermodynamic modeling. Kinetics of the sorption was found to follow pseudo second order rate equation whereas Freundlich and D–R isotherms were the most suitable models to explain sorption phenomenon. Thermodynamically sorption was endothermic, irreversible, and spontaneous in nature.     

Hindcasting of tropical cyclone winds and waves

Ocean Dynamics - This paper describes a series of hindcast simulations of 17 tropical cyclones over the northwest shelf region of Australia. Tropical cyclone track and vortex details were obtained...