Hydrogen fluence in Genesis collectors: Implications for acceleration of solar wind and for solar metallicity

NASA's Genesis mission was flown to capture samples of the solar wind and return them to the Earth for measurement. The purpose of the mission was to determine the chemical and isotopic composition of the Sun with significantly better precision than known before. Abundance data are now available for noble gases, magnesium, sodium, calcium, potassium, aluminum, chromium, iron, and other elements. Here, we report abundance data for hydrogen in four solar wind regimes collected by the Genesis mission (bulk solar wind, interstream low‐energy wind, coronal hole high‐energy wind, and coronal mass ejections). The mission was not designed to collect hydrogen, and in order to measure it, we had to overcome a variety of technical problems, as described herein. The relative hydrogen fluences among the four regimes should be accurate to better than ±5–6%, and the absolute fluences should be accurate to ±10%. We use the data to investigate elemental fractionations due to the first ionization potential during acceleration of the solar wind. We also use our data, combined with regime data for neon and argon, to estimate the solar neon and argon abundances, elements that cannot be measured spectroscopically in the solar photosphere.     

Upper mantle anisotropy of southeast Arabia passive margin [Gulf of Aden northern conjugate margin], Oman

In this study, we used data recorded by two consecutive passive broadband deployments on the Gulf of Aden northern margin, Dhofar region, Sultanate of Oman. The objective of these deployments is to map the young eastern Gulf of Aden passive continental margin crust and upper mantle structure and rheology. In this study, we use shear-wave splitting analysis to map lateral variations of upper mantle anisotropy beneath the study area. In this study, we found splitting magnitudes to vary between 0.33 and 1.0 s delay times, averaging about 0.6 s for a total of 17 stations from both deployment periods. Results show distinct abrupt lateral anisotropy variation along the study area. Three anisotropy zones are identified: a western zone dominated by NW–SE anisotropy orientations, an eastern zone dominated with NE–SW anisotropy orientations, and central zone with mixed anisotropy orientations similar to the east and west zones. We interpret these shorter wavelength anisotropy zones to possibly represent fossil lithospheric mantle anisotropy. We postulate that the central anisotropy zone may be representing a Proterozoic suture zone that separates two terranes to the east and west of it. The anisotropy zones west and east were being used indicative of different terranes with different upper mantle anisotropy signatures.     

Evolution of deep-water stratigraphic architecture, Magallanes Basin, Chile

The ˜4000 m thick and ∼20 Myr deep-water sedimentary fill of the Upper Cretaceous Magallanes Basin was deposited in three major phases, each with contrasting stratigraphic architecture: (1) the oldest deep-water formation (Punta Barrosa Formation) comprises tabular to slightly lenticular packages of interbedded sandy turbidites, slurry-flow deposits, and siltstone that are interpreted to record lobe deposition in an unconfined to weakly ponded setting; (2) the overlying, 2500 m thick and shale-dominated Cerro Toro Formation includes a succession of stacked conglomeratic and sandstone channel-fill deposits with associated finer-grained overbank deposits interpreted to record deposition in a foredeep-axial channel-levee system; (3) the final phase of deep-water sedimentation is characterized by sandstone-rich successions of highly variable thickness and cross-sectional geometry and mudstone-rich mass transport deposits (MTDs) that are interpreted to record deposition at the base-of-slope and lower slope segments of a prograding delta-fed slope system. The deep-water formations are capped by shallow-marine and deltaic deposits of the Dorotea Formation.These architectural changes are associated with the combined influences of tectonically driven changes and intrinsic evolution, including: (1) the variability of amount and type of source material, (2) variations in basin shape through time, and (3) evolution of the fill as a function of prograding systems filling the deep-water accommodation. While the expression of these controls in the stratigraphic architecture of other deep-water successions might differ in detail, the controls themselves are common to all deep-water basins. Information about source material and basin shape is contained within the detrital record and, when integrated and analyzed within the context of stratigraphic patterns, attains a more robust linkage of processes to products than stratigraphic characterization alone.     

Interannual variability in vertical export in the Ross Sea: Magnitude, composition, and environmental correlates

The vertical flux of particulate matter from the surface of the Ross Sea, Antarctica, has been suggested as being large, with substantial seasonal and spatial variations. We conducted a study in which vertical flux was quantified using sediment traps deployed at 200 m and compared to estimates calculated from one-dimensional budgets of nutrients (nitrogen and silicon). Estimates of flux were collected at two locations in the southern Ross Sea from late December to early February during four years: 2001-2002, 2003-2004, 2004-2005, and 2005-2006. Phytoplankton biomass and vertical flux varied substantially seasonally and spatially between the two sites, and among years. The greatest flux was observed in 2001-2002, with a short-term maximum organic carbon flux of 3.13 mmol m⁻² d⁻¹, and the summer mean organic carbon flux equal to 0.93 mmol m⁻² d⁻¹. In contrast, the mean carbon flux at the same site in 2003-2004 was over an order of magnitude less, averaging 0.19 mmol m⁻² d⁻¹, despite the fact that productivity in that year was substantially greater. In 2005-206 the contribution of fecal pellets to flux was smallest among all years, and the pellet contribution ranged from <1 to more than 50% of organic flux. As the moorings also had surface layer fluorometers, the relationship between surface biomass and sediment trap flux was compared. Temporal lags between surface fluorescence and flux at 200 m maxima in 2003-2004 and 2004-2005 ranged from two to six days; however, in 2005-2006 the temporal offset between biomass and flux was much longer, ranging from 11 to 27 days, suggesting that fecal pellet production appeared to increase the coupling between flux and surface production. Estimates of export from the upper 200 m based on one-dimensional nutrient budgets were greater than those recorded by the sediment traps. Nutrient budgets also indicated that siliceous production averaged ca. 40% of the total annual production. The variations observed in the flux of biogenic matter to depth in the Ross Sea are large, appear to reflect different forcing among years, and at present are not adequately understood. However, such variability needs to be both understood and represented in biogeochemical models to accurately assess and predict the effects of climate change on biogeochemical cycles.     

Marine renewable energy: The ecological implications of altering the hydrodynamics of the marine environment

Many countries now recognise the need for mitigation of climate change induced by human activities and have incorporated renewable energy resources within their energy policy. There are extensive resources of renewable energy within the marine environment and increasing interest in extracting energy from locations with either large tidal range, rapid flow with and without wave interaction, or large wave resources. However, the ecological implications of altering the hydrodynamics of the marine environment are poorly understood. Ecological data for areas targeted for marine renewable developments are often limited, not least because of the considerable challenges to sampling in high energy environments. In order to predict the scale and nature of ecological implications there is a need for greater understanding of the distribution and extent of the renewable energy resource and in turn, of how marine renewable energy installations (MREIs) may alter energy in the environment. Regional ecological implications of a MREI need to be considered against the greater and global ecological threat of climate change. Finally, it is recommended that the identification of species and biotopes susceptible to the removal of hydrokinetic energy could be a suitable strategy for understanding how a MREI may alter flow conditions.     

Submarine hydrothermal activity and gold-rich mineralization at Brothers Volcano, Kermadec Arc, New Zealand

Brothers volcano, of the Kermadec intraoceanic arc, is host to a hydrothermal system unique among seafloor hydrothermal systems known anywhere in the world. It has two distinct vent fields, known as the NW Caldera and Cone sites, whose geology, permeability, vent fluid compositions, mineralogy, and ore-forming conditions are in stark contrast to each other. The NW Caldera site strikes for ??600?m in a SW?CNE direction with chimneys occurring over a ??145-m depth interval, between ??1,690 and 1,545?m. At least 100 dead and active sulfide chimney spires occur in this field and are typically 2?C3?m in height, with some reaching 6?C7?m. Their ages (at time of sampling) fall broadly into three groups: <4, 23, and 35?years old. The chimneys typically occur near the base of individual fault-controlled benches on the caldera wall, striking in lines orthogonal to the slopes. Rarer are massive sulfide crusts 2?C3?m thick. Two main types of chimney predominate: Cu-rich (up to 28.5?wt.% Cu) and, more commonly, Zn-rich (up to 43.8?wt.% Zn). Geochemical results show that Mo, Bi, Co, Se, Sn, and Au (up to 91?ppm) are correlated with the Cu mineralization, whereas Cd, Hg, Sb, Ag, and As are associated with the dominant Zn-rich mineralization. The Cone site comprises the Upper Cone site atop the summit of the recent (main) dacite cone and the Lower Cone site that straddles the summit of an older, smaller, more degraded dacite cone on the NE flank of the main cone. Huge volumes of diffuse venting are seen at the Lower Cone site, in contrast to venting at both the Upper Cone and NW Caldera sites. Individual vents are marked by low-relief (??0.5?m) mounds comprising predominately native sulfur with bacterial mats. Vent fluids of the NW Caldera field are focused, hot (??300°C), acidic (pH????2.8), metal-rich, and gas-poor. Calculated end-member fluids from NW Caldera vents indicate that phase separation has occurred, with Cl values ranging from 93% to 137% of seawater values. By contrast, vent fluids at the Cone site are diffuse, noticeably cooler (??122°C), more acidic (pH?1.9), metal-poor, and gas-rich. Higher-than-seawater values of SO₄ and Mg in the Cone vent fluids show that these ions are being added to the hydrothermal fluid and are not being depleted via normal water/rock interactions. Iron oxide crusts 3?years in age cover the main cone summit and appear to have formed from Fe-rich brines. Evidence for magmatic contributions to the hydrothermal system at Brothers includes: high concentrations of dissolved CO₂ (e.g., 206?mM/kg at the Cone site); high CO₂/³He; negative ??D and ??¹⁸O_H2O for vent fluids; negative ??³⁴S for sulfides (to ?4.6??), sulfur (to ?10.2??), and ??¹⁵N₂ (to ?3.5??); vent fluid pH values to 1.9; and mineral assemblages common to high-sulfidation systems. Changing physicochemical conditions at the Brothers hydrothermal system, and especially the Cone site, occur over periods of months to hundreds of years, as shown by interlayered Cu?+?Au- and Zn-rich zones in chimneys, variable fluid and isotopic compositions, similar shifts in ³He/⁴He values for both Cone and NW Caldera sites, and overprinting of ??magmatic?? mineral assemblages by water/rock-dominated assemblages. Metals, especially Cu and possibly Au, may be entering the hydrothermal system via the dissolution of metal-rich glasses. They are then transported rapidly up into the system via magmatic volatiles utilizing vertical (??2.5?km long), narrow (??300-m diameter) ??pipes,?? consistent with evidence of vent fluids forming at relatively shallow depths. The NW Caldera and Cone sites are considered to represent stages along a continuum between water/rock- and magmatic/hydrothermal-dominated end-members.     

The effect of methanogenesis on the geochemistry of low temperature water–Fe0–basalt reactions

Hydrogen gas produced in the subsurface from the hydration of mafic rocks is known to be a major energy source for chemolithotrophic life in extreme environments such as hydrothermal vents. The possibility that in situ anaerobic microorganisms present in the deep subsurface are sustained by low temperature H₂-generating water–rock reactions taking place around them is being investigated. Whether the growth and activity of H₂-utilizing microbes directly influences aqueous geochemistry, rates of mineral dissolution, and the chemical composition of the alteration products is also being quantitatively evaluated.To explore how microorganisms are affected by water–rock reactions, and how their activity may in turn affect reaction progress, laboratory experiments have been conducted to monitor the growth of a methanogenic Archaea in the presence of H_2(g) produced from low temperature water–Fe⁰–basalt reactions. In these systems, the conversion of Fe(II) to Fe(III) and subsequent hydrolysis of water is responsible for the production of H_2(g). To characterize key components of the geochemical system, time series measurements of H₂ and CH₄ gas concentrations, Fe and Si aqueous concentrations, and spatially resolved synchrotron-based analyses of microscale Fe distribution and speciation were conducted. Culture experiments were compared with an abiotic control to document changes in the geochemistry both in the presence and absence of the methanogen.In the control abiotic batch experiment, H₂ was continuously produced, until the headspace became saturated, while in the biotic experiments, microbial consumption of H₂ for methanogenesis draws H₂ down and produces CH₄. Purging the headspace gas reinitiates H₂ and CH₄ production in abiotic and culture experiments, respectively. Mass balance analysis of the amount of CH₄ produced suggests that the total H₂ production in microbial experiments does not exceed the abiotic experiment. Soluble Si concentrations, while buffered to relatively constant values, were higher in culture experiments than the abiotic control.Iron_(aq) concentrations appear to respond to perturbations of H₂ and CH₄ gas concentrations in both culture experiments and the abiotic control. A pulse of Fe preceded the rise in either H₂ or CH₄ production, and as the gas concentrations increased the Fe_(aq) decreased. Iron-bearing mineral assemblages change with increasing reaction time and mineral assemblages vary between culture experiments and the abiotic control. These geochemical trends suggest that there are different reaction paths between the culture experiments and the abiotic control.The hydration of mafic rocks is a common geologic reaction and one that has taken place on Earth for the majority of its history and is postulated to occur on Mars. These reactions are important because of their effect on the rheology and geochemistry of the ocean crust. While most often studied at temperatures of ～250 °C, this work suggests that at lower temperatures microorganisms may have a profound effect on what has long been thought to be solely an abiotic reaction, and may produce diagnostic mineral assemblages that will be preserved in the geological record.     

Particle Filter-based assimilation algorithms for improved estimation of root-zone soil moisture under dynamic vegetation conditions

In this study, we implement Particle Filter (PF)-based assimilation algorithms to improve root-zone soil moisture (RZSM) estimates from a coupled SVAT-vegetation model during a growing season of sweet corn in North Central Florida. The results from four different PF algorithms were compared with those from the Ensemble Kalman Filter (EnKF) when near-surface soil moisture was assimilated every 3 days using both synthetic and field observations. In the synthetic case, the PF algorithm with the best performance used residual resampling of the states and obtained resampled parameters from a uniform distribution and provided reductions of 76% in root mean square error (RMSE) over the openloop estimates. The EnKF provided the RZSM and parameter estimates that were closer to the truth than the PF with an 84% reduction in RMSE. When field observations were assimilated, the PF algorithm that maintained maximum parameter diversity offered the largest reduction of 16% in root mean square difference (RMSD) over the openloop estimates. Minimal differences were observed in the overall performance of the EnKF and PF using field observations since errors in model physics affected both the filters in a similar manner, with maximum reductions in RMSD compared to the openloop during the mid and reproductive stages.     

A revised evolutionary history of armadillos (Dasypus) in North America based on ancient mitochondrial DNA

The large, beautiful armadillo, Dasypus bellus, first appeared in North America about 2.5 million years ago, and was extinct across its southeastern US range by 11 thousand years ago (ka). Within the last 150 years, the much smaller nine‐banded armadillo, D. novemcinctus, has expanded rapidly out of Mexico and colonized much of the former range of the beautiful armadillo. The high degree of morphological similarity between these two species has led to speculation that they might be a single, highly adaptable species with phenotypical responses and geographical range fluctuations resulting from environmental changes. If this is correct, then the biology and tolerance limits for D. novemcinctus could be directly applied to the Pleistocene species, D. bellus. To investigate this, we isolated ancient mitochondrial DNA from late Pleistocene‐age specimens of Dasypus from Missouri and Florida. We identified two genetically distinct mitochondrial lineages, which most likely correspond to D. bellus (Missouri) and D. novemcinctus (Florida). Surprisingly, both lineages were isolated from large specimens that were identified previously as D. bellus. Our results suggest that D. novemcinctus, which is currently classified as an invasive species, was already present in central Florida around 10 ka, significantly earlier than previously believed.     

Multi‐year water balance assessment of a newly constructed wetland,Fort McMurray,Alberta

Oil sands mining in Alberta transforms the boreal landscape of forests and wetlands into open pits, tailings ponds and overburden piles. Whereas reclamation efforts have primarily focused on upland forests, rebuilding wetland systems has recently become a motivation for research. Wetland creation and sustainability in this region is complicated by the sub‐humid climate and salinity of underlying mining material. In 2012, Syncrude Canada Ltd. completed the construction of the Sandhill Fen Watershed (SFW), a 52‐ha upland‐wetland system to evaluate wetland reclamation strategies on soft tailings. SFW includes an active pumping system, upland hummocks, a fen wetland and underdrains. To evaluate the influence of management practices on the hydrology of the system, this study reports the water balance from January 2013 to December 2014, the first 2 years after commissioning. A semi‐distributed approach was taken to examine the fluxes and stores of water in uplands and lowlands. Natural and artificial inputs and outputs were measured using a series of precipitation gauges and pumps, and evapotranspiration was quantified using three eddy covariance towers. A series of near surface wells recorded water table position. Both 2013 and 2014 were normal rainfall years, with 2013 having more and 2014 less snow than normal. In 2013, inflow/outflow from pumping was the predominant hydrological fluxes, resulting in considerable variability in water table position and storage changes throughout the summer. In 2014, the artificial addition of water was negligible, yet the water table remained near the surface in lowland locations, suggesting that wetland conditions could be maintained under current conditions. Evapotranspiration rates between uplands and lowlands were similar between years and sites, ranging from 2.2 ± 1.8 to 2.5 ± 1.2 mm/day and were largely controlled by climate. These rates were less than nearby older upland systems, suggesting that water balance partitioning will change as vegetation develops. Comparison between years and with natural systems provides insight on how management practices influence hydrologic dynamics and the overall water balance of the SFW. Copyright © 2016 John Wiley & Sons, Ltd.