Green Lake Landslide and other giant and very large postglacial landslides in Fiordland,New Zealand

Green Lake Landslide is an ancient giant rock slide in gneiss and granodiorite located in the deeply glaciated Fiordland region of New Zealand. The landslide covers an area of 45 km² and has a volume of about 27 km³. It is believed to be New Zealand's largest landslide, and possibly the largest landslide of its type on Earth. It is one of 39 known very large (10⁶–10⁷ m³) and giant (≥10⁸ m³) postglacial landslides in Fiordland discussed in the paper. Green Lake Landslide resulted in the collapse of a 9 km segment of the southern Hunter Mountains. Slide debris moved up to 2.5 km laterally and 700 m vertically, and formed a landslide dam about 800 m high, impounding a lake about 11 km long that was eventually infilled with sediments. Geomorphic evidence supported by radiocarbon dating indicates that Green Lake Landslide probably occurred 12 000–13 000 years ago, near the end of the last (Otira) glaciation. The landslide is described, and its geomorphic significance, age, failure mechanism, cause, and relevance in the region are discussed, in relation to other large landslides and recent earthquake-induced landslides in Fiordland. The slope failure occurred on a low-angle fault zone undercut by glacial erosion, and was probably triggered by strong shaking (MM IX–X) associated with a large (≥ M 7.5–8) earthquake, on the Alpine Fault c. 80 km to the northwest. Geology was a major factor that controlled the style and size of Green Lake landslide, and in that respect it is significantly different from most other gigantic landslides. Future large earthquakes on the Alpine Fault in Fiordland are likely to trigger more very large and giant landslides across the region, causing ground damage and devastation on a scale that has not occurred during the last 160 years, with potentially disastrous effects on towns, tourist centres, roads, and infrastructure. The probability of such an event occurring within the next 50 years may be as high as 45%.     

Integral field spectroscopy with the GEMINI multiobject spectrographs

We describe the integral field unit (IFU) which converts the Gemini Multiobject Spectrograph (GMOS) installed on the Gemini-North telescope to an integral field spectrograph,which produces spectra over a contiguous field of view of 7 × 5 arcsec with spatial sampling of 0.2 arcsecover the wavelength range 0.4-1.0 μm.GMOS is converted to this mode by the remote insertion of the IFU into thebeam in place of the masks used for the multiobject mode. A separate fieldof half the area of the main field, but otherwise identical, is alsoprovided to improve background subtraction. The IFU contains 1500lenslet-coupled fibres and was the first facility of any type for integralfield spectroscopy employed on an 8/10 m telescope.We describe the design, construction and testing of the GMOS IFU and present measurements of the throughput both in the laboratory and at the telescope. We compare these with a theoretical prediction made before construction started. All are in good agreement with each other, with the on-telescope throughput exceeding 60% (averaged over wavelength). Finallywe show an example of data obtained during commissioning to illustrate the power of the device.     

The second order characteristic condition for plastic flow

In this paper the second order characteristic (discontinuous bifurcation) condition is derived for the granular flow (fully plastic) equations. This second order bifurcation equation is shown to be formally identical to the first order localization requirement during steady elastoplastic deformation provided the elastic compliance tensor is substituted for the product of the plastic multiplier with the flow Hessian. For isotropic yield and flow functions the invariant form of the characteristic condition is given in detail, as well as an alternative expression in adapted co‐ordinates. The characteristic condition can be regarded as defining a hardening function which is maximized to identify the critical angles. When the method is applied to 3D Coulomb flow, Mohr's 3D fracture plane conditions are obtained uniquely. Copyright © 2003 John Wiley & Sons, Ltd.     

Shear-wave polarizations on a curved wavefront at an isotropic free surface

Summary. We present polarization diagrams of the particle motions at the free surface of an isotropic half-space generated by incident shear waves from a local buried point source. The reflectivity technique is used to calculate synthetic seismograms from which the particle motions are plotted. The particle motions are examined over a range of epicentral distances in a uniform isotropic half-space for different source frequencies and polarization angles, and for different Poisson's ratios. The particle motions due to a curved wavefront possess different characteristics from those generated by plane wavefronts at corresponding incidence angles. A curved wavefront generates a local SP -phase: a P -headwave which propagates along the free surface, and arrives shortly before the direct S -wave. These two arrivals give rise to cruciform particle motions in the sagittal and horizontal planes, which could be misinterpreted as anisotropy-induced shear-wave splitting. An examination of the particle motion in the transverse plane, mutually orthogonal to the sagittal and horizontal planes, can be used to discriminate between isotropic and anisotropic interpretations. The amplitude of the SP -phase is enhanced when it propagates in a low-velocity surface layer overlying the source layer, and may then become the dominant phase on radial-component seismograms. The presence of even a single surface layer may introduce considerable complexity into the seismogram, and we examine the effects of layer thickness, velocity contrast, and source depth on the corresponding polarization diagrams. Reliable information on the source and propagation path characteristics of shear waves from a buried local point source can only be obtained from free-surface records if they are recorded within a very limited epicentral distance range.     

Ion microprobe analysis of oxygen isotope ratios in granulite facies magnetites: diffusive exchange as a guide to cooling history

Ion microprobe analysis of magnetites from the Adirondack Mountains, NY, yields oxygen isotope ratios with spatial resolution of 2–8 m and precision in the range of 1 (1 sigma). These analyses represent 11 orders of magnitude reduction in sample size compared to conventional analyses on this material and they are the first report of routinely reproducible precision in the 1 per mil range for analysis of ¹⁸O at this scale. High precision micro-analyses of this sort will permit wide-ranging new applications in stable isotope geochemistry. The analyzed magnetites form nearly spherical grains in a calcite matrix with diopside and monticellite. Textures are characteristic of granulite facies marbles and show no evidence for retrograde recrystallization of magnetite. Magnetites are near to Fe₃O₄ in composition, and optically and chemically homogeneous. A combination of ion probe plus conventional BrF₅ analysis shows that individual grains are homogeneous with ¹⁸O=8.9±1 SMOW from the core to near the rim of 0.1–1.2 mm diameter grains. Depth profiling into crystal growth faces of magnetites shows that rims are 9 depleted in ¹⁸O. These low ¹⁸O values increase in smooth gradients across the outer 10 m of magnetite rims in contact with calcite. These are the sharpest intracrystalline gradients measured to date in geological materials. This discovery is confirmed by bulk analysis of 150–350 m diameter magnetites which average 1.2 lower in ¹⁸O than coarse magnetites due to low ¹⁸O rims. Conventional analysis of coexisting calcite yields °¹⁸O=18.19, suggesting that bulk ¹⁸O (Cc-Mt)=9.3 and yielding an apparent equilibration temperature of 525° C, over 200° C below the temperature of regional metamorphism. Consideration of experimental diffusion data and grain size distribution for magnetite and calcite suggests two contrasting cooling histories. The data for oxygen in calcite under hydrothermal conditions at high P(H₂O) indicates that diffusion is faster in magnetite and modelling of the low ¹⁸O rims on magnetite would suggest that the Adirondacks experienced slow cooling after Grenville metamorphism, followed by a brief period of rapid cooling, possibly related to uplift. Conversely, the data for calcite at low P(H₂O) show slower oxygen diffusion than in magnetite. Modelling based on these data is consistent with geochronology that shows slow cooling through the blocking temperature of both minerals, suggesting that the low ¹⁸O rims form by exchange with late, low temperature fluids similar to those that infiltrated the rock to serpentinize monticellite and which infiltrated adjacent anorthosite to form late calcite veinlets. In either case, the ion microprobe results indicate that two distinct events are recorded in the post-metamorphic exchange history of these magnetites. Recognition of these events is only possible through microanalysis and has important implications for geothermometry.     

Decomposition of Hudson estuary macrophytes: Photosynthetic pigment transformations and decay constants

Plant pigment decay constants were determined for four macrophytes collected from the Hudson Estuary.Typha angustifolia andScirpus fluviatilis were used as representatives of emergent aquatic vegetation (EAV), andPotamogeton sp. andVallisneria americana were used to represent submerged aquatic vegetation (SAV). Litter bags were maintained in an environmental chamber in the dark for 104 d. The fastest rate of total mass loss was in the SAVV. americana and slowest in the EAVT. angustifolia. Changes in carotenoid and chloropigment concentration resulting from microbial and meiofaunal heterotrophy in each of the macrophytes were quantified using reverse-phase, high-performance liquid chromatography (RP-HPLC) techniques. Chlorophyllc and the carotenoid, fucoxanthin, provided useful biomarkers in determining the presence of epiphytic diatom growth, which only occurred on the SAV. The highest concentrations of phaeophorbidea, commonly used as an indication of metazoan grazing, were found in the SAVV. americana. Low concentrations of phaeophorbidea in the SAVPotamogeton sp. indicate inefficient use of this SAV by meiofaunal grazers. Lutein decayed slower than all other carotenoids in both EAV and SAV. Microcosm studies such as this are necessary to further understand the mechanisms and kinetics of photosynthetic pigment transformations in natural systems.     

Supercritical gas sorption on moist coals

The effect of moisture on the CO₂ and CH₄ sorption capacity of three bituminous coals from Australia and China was investigated at 55 °C and at pressures up to 20 MPa. A gravimetric apparatus was used to measure the gas adsorption isotherms of coal with moisture contents ranging from 0 to about 8%. A modified Dubinin–Radushkevich (DR) adsorption model was found to fit the experimental data under all conditions. Moisture adsorption isotherms of these coals were measured at 21 °C. The Guggenheim–Anderson–de Boer (GAB) model was capable of accurately representing the moisture isotherms over the full range of relative pressures.Moist coal had a significantly lower maximum sorption capacity for both CO₂ and CH₄ than dry coal. However, the extent to which the capacity was reduced was dependent upon the rank of the coal. Higher rank coals were less affected by the presence of moisture than low rank coals. All coals exhibited a certain moisture content beyond which further moisture did not affect the sorption capacity. This limiting moisture content was dependent on the rank of the coal and the sorbate gas and, for these coals, corresponded approximately to the equilibrium moisture content that would be attained by exposing the coal to about 40–80% relative humidity. The experimental results indicate that the loss of sorption capacity by the coal in the presence of water can be simply explained by volumetric displacement of the CO₂ and CH₄ by the water. Below the limiting moisture content, the CO₂ sorption capacity reduced by about 7.3 kg t^− 1 for each 1% increase in moisture. For CH₄, sorption capacity was reduced by about 1.8 kg t^− 1 for each 1% increase in moisture.The heat of sorption calculated from the DR model decreased slightly on addition of moisture. One explanation is that water is preferentially attracted to high energy adsorption sites (that have high energy by virtue of their electrostatic nature), expelling CO₂ and CH₄ molecules.     

Advances in our understanding of the gem corundum deposits of the West Pacific continental margins intraplate basaltic fields

Recent discoveries over the last decade of new gemfields, exploitation of new and existing deposits, and application of relatively new techniques have greatly increased our knowledge of the basalt-derived gem sapphire–ruby–zircon deposits. In this paper we focus on the Late Mesozoic to Cenozoic intraplate basaltic fields of the West Pacific continental margins. We review advances made in understanding the genesis of these deposits, based on the application of newer techniques. We also critically review existing data on the gem corundum deposits, in order to further refine a model for their origin.In some of the intraplate basaltic fields, corundum-bearing xenoliths have been found showing a range of PT formation conditions from 790 °C at 0.85 GPa to as much as 1100 to 1200 °C at 1.0 to 2.5 GPa. Although most magmatic sapphires contain syngenetic inclusions of columbite-group phases, zircon, spinel and rutile, some contain additional nepheline and K-feldspar, suggesting crystallization from more undersaturated alkaline magma while the Weldborough field of NE Tasmania also contains molybdenite and beryl, suggesting at least some interaction with more fractionated ‘granitic-type’ magmas. There is a large range in PT conditions calculated for the metamorphic rubies (from 780 to 940 °C, through 800 to 1150 °C up to 1000 to 1300 °C). Fluid/melt inclusion studies on magmatic corundums generally suggest that they formed in a CO₂-rich environment from a ‘syenitic’ melt under a range of T conditions from 720 to 880 °C up to 1000 to 1200 °C. Oxygen isotope studies reveal that typical magmatic corundums have values of + 4.4 to 6.9‰, whereas metamorphic corundums from the same basaltic host have lower values of + 1.3 to 4.2‰.Geochronological studies have shown that some fields produced a simple eruptive and zircon/corundum crystallization event while others had multiple eruptive events but only one or two zircon crystallization events. For a few fields, some corundums/zircons crystallized in storage regions and then remained relatively inert for periods of 200 to 400 Ma without significant change before transport to the surface in the Cenozoic. Tectonic studies of the Australian region suggest that many of the corundums crystallized from magmas related to episodic basaltic volcanism in a tectonic regime of extension, associated with the opening of the Tasman and Coral Seas. For the Asian region, the magmatic–polygenetic corundums within the basaltic fields largely crystallized in a tectonic regime of distributed E–W extension, whereas the metamorphic-metasomatic corundums crystallised in a transpressional regime associated with the collision of the Indian Plate with the Eurasian Plate (e.g., [Garnier, V., Giuliani, G., Maluski, H., Ohnenstetter, D., Deloule, E., 2003. Ar–Ar and U–Pb ages of marble-hosted ruby deposits from Central and South-east Asia. Geophysical Research Abstracts 5, 03751; Garnier, V., Giuliani, G., Ohnenstetter, D., and Schwarz, D., 2004. Les gisements de corindon: classification et genese. Les placers a corindon gemme. Le Regne Mineral 55, 7-47; Garnier, V., Ohnenstetter, D., Giuliani, G., Maluski, H., Deloule, E., Phan Trong, T., Pham Van, L., Hoang Quang, V., 2005a. Age and significance of ruby-bearing marble from the Red River Shear Zone, Northern Vietnam. Canadian Mineralogist 43, 1315–1329]).