青海省格尔木市哈西亚图地区铁多金属矿床的发现及意义

通过钻探工程验证高精度磁测异常,2010年青海省核工业地质局发现了格尔木市哈西亚图地区矽卡岩型铁多金属矿,初步估算铁资源量规模已达中型。赋矿地层为古元古界金水口岩群下岩组,华力西期灰色石英闪长岩与成矿密切相关。这一突破性发现对环柴达木盆地古元古界金水口岩群分布区的铁多金属矿找矿具有重要指导意义。     

Fluid Inclusions and Hydrogen,Oxygen, Sulfur Isotopes of Nuri Cu‐W‐Mo Deposit in the Southern Gangdese,Tibet

The Nuri Cu‐W‐Mo deposit is located in the southern subzone of the Cenozoic Gangdese Cu‐Mo metallogenic belt. The intrusive rocks exposed in the Nuri ore district consist of quartz diorite, granodiorite, monzogranite, granite porphyry, quartz diorite porphyrite and granodiorite porphyry, all of which intrude in the Cretaceous strata of the Bima Group. Owing to the intense metasomatism and hydrothermal alteration, carbonate rocks of the Bima Group form stratiform skarn and hornfels. The mineralization at the Nuri deposit is dominated by skarn, quartz vein and porphyry type. Ore minerals are chalcopyrite, pyrite, molybdenite, scheelite, bornite and tetrahedrite, etc. The oxidized orebodies contain malachite and covellite on the surface. The mineralization of the Nuri deposit is divided into skarn stage, retrograde stage, oxide stage, quartz‐polymetallic sulfide stage and quartz‐carbonate stage. Detailed petrographic observation on the fluid inclusions in garnet, scheelite and quartz from the different stages shows that there are four types of primary fluid inclusions: two‐phase aqueous inclusions, daughter mineral‐bearing multiphase inclusions, CO₂‐rich inclusions and single‐phase inclusions. The homogenization temperature of the fluid inclusions are 280°C–386°C (skarn stage), 200°C–340°C (oxide stage), 140°C–375°C (quartz‐polymetallic sulfide stage) and 160°C–280°C (quartz‐carbonate stage), showing a temperature decreasing trend from the skarn stage to the quartz‐carbonate stage. The salinity of the corresponding stages are 2.9%–49.7 wt% (NaCl) equiv., 2.1%–7.2 wt% (NaCl) equiv._, 2.6%–55.8 wt% (NaCl) equiv. and 1.2%–15.3 wt% (NaCl) equiv., respectively. The analyses of CO₂‐rich inclusions suggest that the ore‐forming pressures are 22.1 M Pa–50.4 M Pa, corresponding to the depth of 0.9 km–2.2 km. The Laser Raman spectrum of the inclusions shows the fluid compositions are dominated in H₂O, with some CO₂ and very little CH₄, N₂, etc. δD values of garnet are between ?114.4‰ and ?108.7‰ and δ¹⁸O_H2O between 5.9‰ and 6.7‰; δD of scheelite range from ?103.2‰ to ?101.29‰ and δ¹⁸O_H2O values between 2.17‰ and 4.09‰; δD of quartz between ?110.2‰ and ?92.5‰ and δ¹⁸O_H2O between ?3.5‰ and 4.3‰. The results indicate that the fluid came from a deep magmatic hydrothermal system, and the proportion of meteoric water increased during the migration of original fluid. The δ³⁴S values of sulfides, concentrated in a rage between ?0.32‰ to 2.5‰, show that the sulfur has a homogeneous source with characteristics of magmatic sulfur. The characters of fluid inclusions, combined with hydrogen‐oxygen and sulfur isotopes data, show that the ore‐forming fluids of the Nuri deposit formed by a relatively high temperature, high salinity fluid originated from magma, which mixed with low temperature, low salinity meteoric water during the evolution. The fluid flow through wall carbonate rocks resulted in the formation of layered skarn and generated CO₂ or other gases. During the reaction, the ore‐forming fluid boiled and produced fractures when the pressure exceeded the overburden pressure. Themeteoric water mixed with the ore‐forming fluid along the fractures. The boiling changed the pressure and temperature, oxygen fugacity, physical and chemical conditions of the whole mineralization system. The escape of CO₂ from the fluid by boiling resulted in scheelite precipitation. The fluid mixing and boiling reduced the solubility of metal sulfides and led the precipitation of chalcopyrite, molybdenite, pyrite and other sulfide.     

山东省齐河—禹城富铁矿勘查区工作进展及对策

近年来,在山东省齐河—禹城地区矽卡岩型铁矿勘查工作取得了重大突破,该勘查区内相继发现了李屯、大张和潘店矽卡岩型铁矿床,同时科研工作也取得了较大进展。本文在全面收集和综合分析区内矿产勘查和科研成果的基础上,对该区以往勘查经验和研究现状进行总结,分析该区勘查研究过程中主要制约因素和亟待解决的关键问题。通过对制约因素和关键问题开展对策研究,为今后该区铁矿勘查工作提供借鉴。通过分析表明该区矽卡岩型铁矿的成矿地质体（即燕山晚期中基性侵入岩）应属于沂南序列。勘查区内深部地质体三维空间特征精细刻画、深部地质体控矿构造研究、物探数据深度解译、矿产勘查空间拓展、铁矿成矿规律和矿体赋存规律深入研究等多个方面将是下一步勘查研究工作的重点,加强对上述方面的研究有助于促进区内铁矿勘查工作顺利开展。在加强对物探异常西半环已发现矿体的勘查和类似异常的查证工作的同时,对物探异常东半环加强勘查研究工作对于拓展整个齐河—禹城地区矽卡岩型铁矿的勘查空间具有十分重要的意义。     

南岭东段钨锡多金属矿床地质特征、成矿模式及找矿方向

南岭东段地区是世界著名的钨多金属矿集区。近年来中国地质调查局在该区实施钨多金属矿调查评价,找到了一批具有中大型远景的与花岗岩有关的新类型钨锡多金属矿床,特别是在复式岩体中的花岗岩型新类型钨钼多金属矿床（简称＂体中体＂式钨钼多金属矿床）和受中、上泥盆统地层控制的层控矽卡岩型钨锡多金属矿床的发现,不仅实现了南岭东段地区找矿新突破,而且对整个南岭乃至我国华南地区钨锡多金属矿找矿具有重要指导作用。本文根据近年来南岭东段地区钨锡多金属矿找矿新成果,通过该区钨锡多金属矿床地质特征的总结,建立了南岭东段地区钨锡多金属矿成矿模式,提出了南岭东段地区今后钨锡多金属矿找矿方向应重点注意与燕山期复式花岗岩有关的＂体中体＂式钨钼多金属矿床和中、上泥盆统控制的层控矽卡岩型钨锡多金属矿床的寻找。     

Felsic magmatic phases and the role of late-stage aplitic dykes in the formation of the world-class Cantung Tungsten skarn deposit, Northwest Territories, Canada

A field and petro-chemical classification of felsic magmatic phases (FMPs) at the world-class Cantung W skarn deposit was undertaken to document the evolution of magmatism and the relationships between different FMPs, metasomatism, and mineralization. Early FMPs include moderately differentiated (Zr/Hf = 18–26, Ti/Zr = 14–15) biotite monzogranitic plutons and early biotite-rich granitic dykes, and compositionally similar quartz–feldspar porphyry dykes. Late, highly fractionated (Zr/Hf = 8–17, Ti/Zr = 3–13) FMPs sourced from a deeper monzogranitic intrusion include: (1) leucocratic biotite- or tourmaline-bearing dykes derived from localized entrapments of residual magma; and, (2) sub-vertical NE-trending aplitic dykes derived from a larger segregation of residual fluid- and incompatible element-enriched magma. The aplitic dykes have textures, morphologies, spatial associations, and a pervasive calcic metasomatic mineral assemblage (Ca-plagioclase + quartz or clinozoisite) indicative of syn-mineralization emplacement. Very late-stage overpressuring and initiation of sub-vertical fractures into the overlying plutonic carapace and country rocks by supercritical magmatic fluid led to an interaction with calcareous country rocks that resulted in an increased aCa²⁺ in the fluid and the concurrent precipitation of W skarn. Residual magma also ascended with, and quenched in equilibrium with the magmatic fluid to from the aplitic dykes, then was metasomatized by the fluid as it interacted with calcareous country rocks. Overall, highly fractionated and moderately to very highly undercooled FMPs at Cantung provide evidence for a large and evolving felsic magmatic system at depth that segregated and maintained a stable fluid- and incompatible element-enriched residual magma until the latest stages of crystallization. The detailed study of FMPs associated with magmatic-hydrothermal mineral deposits allow us to refine our understanding of these mineralizing systems and better define metallogenic and exploration models for intrusion-related mineralization.     

老挝长山成矿带与花岗岩有关的铜金铁矿床的成矿模式

老挝作为＂特提斯成矿域＂的重要组成部分,具有丰富的矿产资源,尤其是铜、金、铁、铝、钾盐等优势矿产与中国具有很强的互补性。初步论述了老挝的成矿地质背景和近年来发现的与花岗岩类有关的斑岩型铜-金矿床、矽卡岩型铁矿床的矿化地质特征、矿石矿物特征、矿化与岩体的空间关系,在此基础上初步建立了其成矿模式。基于同位素定年数据和Hf-Rb-Ta元素判别图,推测这些花岗岩及与其相关的矿床形成于晚石炭世华南地块向印支地块俯冲产生的火山岛弧环境。     

新疆磁海铁矿床中黑柱石的发现及其地质意义

黑柱石是一种不常见的夕卡岩标型矿物,本次研究在新疆磁海矿区首次发现黑柱石。本文对磁海矿区的黑柱石产出地质环境、矿物共生组合、化学成分、光学性质等进行了研究。化学成分均由电子探针分析求得,计算化学简式为Ca0.98(Fe1.72Mn0.07Mg0.11)1.902+(Fe0.95Al0.03)0.983+[Si2.00O7]O(OH)。磁海矿区黑柱石的形成与基性次火山热液活动有关,是一种特殊的退变质(蚀变)夕卡岩矿物;在成矿作用晚期,随着热液活动加强,早期夕卡岩矿物可退变质形成黑柱石。黑柱石形成时间较晚,对早期形成的磁铁矿起贫化作用。将磁海矿区黑柱石与国内外其它矿区黑柱石的化学成分进行了对比,认为磁海矿区黑柱石为普通黑柱石。黑柱石在常用的矿物中较少提及,应该引起重视。     

内蒙古黄岗锡铁矿床夕卡岩矿物学特征及其成矿指示意义

为进一步查明黄岗锡铁矿矿床成因、夕卡岩矿物成分与金属矿化类型之间的联系,利用电子探针对研究区主要夕卡岩矿物的化学成分进行了详细的分析。测试结果表明,成矿早期石榴石的端员组分以钙铁榴石为主,主成矿期石榴石的端员组分以钙铝榴石为主;辉石端员组分变化较大,主要为透辉石和钙铁辉石。石榴石和辉石的矿物组分分别为Adr28.69～96.44Grs2.00～67.38(Prp+Sps)0.67～5.69和Di11.8～94.12Hd4.08～81.28Jo1.79～20.02,其较大的成分变化特征反映出夕卡岩不是在一个完全封闭的平衡条件下形成的。角闪石大多为镁铁钙角闪石,个别属于铁角闪石,成分变化较大的原因可能是由于氧化还原条件改变导致不同程度的AlⅥSi←→(Na,K)的置换作用,属于一种固相线下的转变。角闪石中四次配位的Si、Al及六次配位的Al、Ti和A位置的阳离子数变化范围很大,可能是由于接触交代作用过程中岩浆的成分差异或结晶时的物理化学条件改变所引起的。富锰的辉石夕卡岩是岩浆流体顺层间破碎带渗滤交代形成的,富锰辉石可作为本区寻找Sn、Cu、Zn等多金属的找矿标志,外接触带夕卡岩和其附近的大理岩中是多金属成矿的有利部位。     

胶东辽上金矿床成因与找矿方向研究

位于山东烟台的辽上金矿床为一中型金矿,矿床赋存于新元古代玲珑超单元二长花岗岩与古元古代荆山群的接触带附近,发育矽卡岩化,矿体的产出严格受接触带构造控制.区内出露的中生代岩体为石英二长闪长岩.通过研究每个矿体的宏观产出特征,发现金矿体与石英二长闪长岩有关,区域上部分金矿体赋存于石英二长闪长岩中,而与新元古代玲珑超单元二长...     

内蒙古乌尼克吐铅锌矿电法异常特征及试验

以时间域中梯装置激发极化、偶极—偶极装置相位激电测深和可控源音频大地电磁测深在内蒙古乌尼克吐铅锌矿试验结果为例,验证综合电法在寻找矽卡岩型铅锌矿床中的作用及找矿效果。试验结果表明,在激发极化普查测量中应注意供电电极与异常体之间相互关系,否则会产生虚假异常;在勘查区岩矿石电性条件较好的情况下,激发极化面积测量基本能够反映出异常源平面分布情况。在矿(体)与围岩之间的电阻率差异不明显的条件下,较相位激电测深,可控源音频大地电磁测深基本能够推断出矿体的空间赋存位置。所以,时间域中梯装置激发极化与可控源音频大地电磁测深的电法组合在有色金属矿产勘查中可以发挥更大作用。