泰安市地下水污染现状与成因分析

采用参数分级评分叠加型指数法对泰安市地下水污染现状进行的评价结果显示 ,泰安地下水已遭受严重污染。地下水污染以地下水中宏量组分、NO-3 、硬度、TDS的迅速上升高以及地下水遭受人为环境物质的污染为主要标志 ;地下水污染主要受地下水系统水文地质结构、纳污河流、污水灌溉及地下水开采控制和影响 ,地下水污染是人类活动影响的结果。     

用PCI中断实现射电望远镜跟踪的方法

讨论运用PCI 9054(美国PLX公司生产的接口芯片)作为接口芯片的PCI(Peripheral Component Interconnect)板卡的软硬件设计,以实现天线跟踪的两个时间同步中断。利用标准秒信号中断作为系统时钟同步信号,并同步产生时间间隔为20ms(或40、50ms,可选)的中断信号,来处理天线跟踪指令输出。中断信号通过PCI中断口INTA#接入计算机,在驱动中识别不同的中断信号,并在应用程序响应中断处理后,命令ACU(Antenna Control Unit)机,实现射电天文望远镜的同步跟踪。其控制过程分3部分阐述:硬件设计、驱动程序设计、安装及应用;着重讨论了前两者的设计方法及思路。     

The planets capture model of V838 Monocerotis: conclusions for the penetration depth of the planet(s)

V838 Mon is the prototype of a new class of objects. Understanding the nature of its multistage outburst and similar systems is challenging. So far, several scenarios have been invoked to explain this group of stars. In this work, the planets-swallowing model for V838 Mon is further investigated, taking into account the findings that the progenitor is most likely a massive B-type star. We find that the super-Eddington luminosity during the eruption can explain the fast rising times of the three peaks in the optical light curve. We used two different methods to estimate the location where the planets were consumed. There is a nice agreement between the values obtained from the luminosities of the peaks and from their rising time-scale. We estimate that the planets were stopped at a typical distance of one solar radius from the centre of the host giant star. The planets-devouring model seems to give a satisfying explanation to the differences in the luminosities and rising times of the three peaks in the optical light curve of V838 Mon. The peaks may be explained by the consumption of three planets or alternatively by three steps in the terminal falling process of a single planet. We argue that only the binary merger and the planets-swallowing models are consistent with the observations of the new type of stars defined by V838 Mon.     

基于WS-Security的安全动态电子商务

Web服务方式的动态电子商务是电子商务的最终目标，安全问题是制约动态电子商务实现的主要因素。在介绍了WS-Security规范后，给出了一个建立动态电子商务的案例，分析了这个过程中可能面临的安全风险，提出了一种如何实现电子商务中重要的机密性、完整性问题的方法。     

单片机在卫星天线控制系统中的应用

主要介绍卫星天线控制系统中天线旋转定位控制的软硬件设计和实现。该部分的主要功能是：接收红外遥控器的信号；检测前面板上的按键信号；检测传感器反馈的信号；根据所得信号作出相应的动作。     

An Example of Island-Arc Petrogenesis: Geochemistry and Petrology of the Southern Luzon Arc, Philippines

Volcanism throughout the Luzon arc is associated with eastwardsubduction of the South China Sea floor along the Manila Trench.The southern section of the arc, the focus of this study, extendsfrom the Lingayen-Dingalan fault to the small islands just southof Luzon. Two segments appear to exist along this section ofthe arc the northern Bataan and southern Mindoro segments whichare separated by the Macolod Corridor. The volcanic rocks have typical arc phenocryst mineralogies:olivine, clinopyroxene, plagioclase, and titanomagnetite inthe most mafic rocks and clinopyroxene, plagioclase, orthopyroxene,titanomagnetite, ? amphibole in the more felsic samples. Complexzoning, sieve textures, and decoupling of incompatible traceelements suggest that processes such as assimilation have takenplace. The rocks from the study area range from basalts to rhyolitesand show typical calc-alkaline features. The rocks of the MacolodCorridor and Mindoro segment are particularly enriched in largeion lithophile elements (LILE), light rare earth elements (LREE),and radiogenic Sr compared with the Bataan segment. The datafall within the mantle array on Sr-Nd isotopic diagrams andgrade toward higher Sr and lower Nd isotopic values from northto south. A likely source for the volcanics of this study is either amid-ocean ridge basalt (MORB)-type mantle that undergoes higherdegrees of partial melting than regions involved in MORB generationor a previously depleted source. We suggest that the high fieldstrength element (HFSE) anomalies have been derived throughdifferential element partitioning during fluid transport fromthe subducted lithosphere to the mantle wedge. Continental crustal material seems to play a significant roleparticularly in the Macolod Corridor and the Mindoro segment,based on the high LILE, La/Sm ratios, radiogenic Sr isotopes,and ¹⁸O values. The Macolod Corridor and the Mindoro segmenthave undergone source contamination by crustal material fromthe North Palawan-Mindoro crustal block either during the collisionof this block with the Manila Trench or by subduction of sedimentsrich in this crustal material. A similar component has alsobeen detected in the Bataan segment but in minor amounts. Thetrace element and isotopic differences between the northernand southern sections of the arc are interpreted in terms ofvariable composition (i. e., variable amounts of a crustal componentintroduced from the Palawan-Mindoro crustal terrain) of themetasomatic fluids released into the source.     

碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。     

Modeling of water–rock interactions in an aquitard of sandy clay in the coastal area near Beihai,China

Unconsolidated sand, gravel and clay deposits near Beihai and in the Leizhou Peninsula in southern China form an unconfined aquifer, aquitard and a confined aquifer. Water and soil samples were collected from the two aquifers in the coastal Beihai area for the determination of chemical compositions, minerals and soluble ions. Hydrogeochemical modeling of three flow paths through the aquitard are carried out using PHREEQC to determine water–rock interactions along the flow paths. The results indicate that the dissolution of anorthite, fluorite, halite, rhodochrosite and CO₂, and precipitation of potash feldspar and kaolinite may be occurring when groundwater leaks through the aquitard from the unconfined aquifer to the confined aquifer. Cation exchanges between Na and Ca can also happen along the flow paths.     

Mo稳定同位素研究进展

随着表面热离子质谱(TIMS)和多接收器电感耦合等离子体质谱(MC-ICP-MS)的广泛应用以及同位素分析方法的改进,近10年来非传统稳定同位素(Cu、Zn、Fe、Se、Mo、Cr、Hg等)的研究得到迅速发展.其中,由于Mo同位素的分馏明显受氧化还原条件的控制,使其在指示古环境及古气候的变化方面有独特的地球化学指示意义.同时,Mo同位素在指示成矿物质来源和海洋Mo循环等方面也取得较大成果.因此,Mo同位素地球化学研究已成为国际地学领域的一个前沿和热点.本文综合前人的研究成果,结合近期自己的工作,论述了Mo同位素地球化学研究领域的一些重要进展,详细介绍了Mo同位素的化学分离、提纯和质谱分析技术,并对其应用前景进行了展望.     

Cd2+在甘肃靖远坡缕石粘土上的吸附作用研究

以提纯后的甘肃靖远坡缕石粘土作吸附剂,常温下对水中Cd2 进行吸附实验,考察了吸附时间、吸附剂用量、振荡速率及pH值对吸附效果的影响,并对吸附动力学过程和吸附平衡进行了探讨.XRD和红外光谱分析结果显示,原矿在提纯后杂质石英被有效分离,得到了坡缕石含量较高的提纯样品.吸附实验结果显示,约60 min吸附反应可达平衡;pH值对吸附效果有显著影响,吸附率随pH值的升高而增加,当平衡溶液pH>8时吸附率超过99%;吸附过程与pseudo-second-order Lagergren动力学模型方程有较好的一致性,吸附平衡同时符合Langmuir和Freundlich等温吸附模型,由Langmuir方程得到饱和吸附量为31.65 mg/g.