Potential use of faujasite–phillipsite and phillipsite–chabazite tuff in purification of treated effluent from domestic wastewater treatment plants

Characterization of zeolitic tuff from Jabal Hannoun (HN) and Mukawir (MR) was carried out to examine the ability of using low-cost natural materials in domestic wastewater treatment. The grain size between 0.3 and 1 mm (0.3–1 mm) of the HN and MR has the highest total zeolite grade (faujasite–phillipsite and phillipsite–chabazite) and suitable cation exchange capacity. They were used as fixed-bed ion exchangers and adsorbents. The zeolitic tuff efficiently removed the organic and nitrogen compounds, Pb and Zn from the effluent. One bed volume (1 BV) of the zeolitic tuff is capable to remove up to 95 % of total organic carbon form 500 BV of the effluent. The removal percent of total nitrogen by HN and MR is close to 95 and 90 %, respectively. The zeolitic tuff has an excellent efficiency to remove Pb and Zn from the effluent. 1 BV of HN completely cleans Zn and Pb from 680 and 730 BV of the effluent, respectively, whereas 1 BV of MR is able to clean completely Zn and Pb from 500 and 685 BV of the effluent, respectively. The greater performance of the HN compared with the MR may be explained by its higher zeolites grade and presence of faujasite.     

Ionization State in PDR (IC 63 nebula)

We investigated the chemical evolution in IC 63 nebula, a photo-dominated region (PDR). The chemical structure and the ionization state depend directly on the intensity of the incident UV radiation. The electron density is also affected by the incident UV radiation. It decreases gradually with the increase of the depth in the cloud varying from 5.9×10^-5 at the surface to 9.6×10^-9 in the core. Ionic carbon(C⁺) dominates the electron density in the outer region while ionic metals and other ions (H⁺, CH₂D⁺, and HCO⁺) are the most dominant in the deepest region. Our results at A _V = 6.7 mag are in good agreement with observations except in the case of H₂S, where the calculated value is lower than the observed value by about two orders of magnitude.     

Radiolarian biochronology of Mesozoic deep-water successions in NW Syria and Cyprus: implications for south-Tethyan evolution

ABSTRACT New radiolarian biostratigraphical data have shed light on the Mesozoic tectonic evolution of South-Tethys in the Baer–Bassit region of NW Syria. Radiolarian assemblages of Late Triassic, Middle Jurassic and Early Cretaceous age were extracted from radiolarites in five measured sections. The results are compared with published radiolarian ages from the Mamonia Complex, western Cyprus. These two areas are interpreted as preserved fragments of the conjugate margins of a small South Tethyan oceanic basin formed by Triassic rifting. In the southerly (i.e. Arabian) margin, proximal successions were dominated by shallow-water-derived carbonate, whereas distal successions reveal seamount-type alkaline/peralkaline volcanism, dated as both Late Triassic and Middle Jurassic–Early Cretaceous. Along the inferred northern margin (i.e. western Cyprus) proximal successions are dominantly terrigenous, whereas distal settings include Late Triassic oceanic crust and seamount-type lavas.     

New occurrence of potential phosphate resource in northeast Jordan

An exploration program aided by field investigation, exploration drilling, detailed sampling, lithological and petrological studies, geochemical investigation, and resource calculation leads to the discovery of a potential phosphate resource in northeast Jordan close to the international border with Saudi Arabia and Iraq. The studied phosphate is of the Middle Eocene age that belongs to the Wadi Shallala Formation. It is equivalent to the phosphate deposits recorded in the lower part of the Umm Wual Formation in the Turayf region of Saudi Arabia and the Eocene Ratga Formation in the Ethna phosphate deposit west of Iraq. The phosphorites in the region are broadly similar in mineralogical composition and geochemical affinities. X-ray diffraction indicates the presence of francolite with variable amounts of calcite and quartz. Most samples consist of phosphate clasts embedded in carbonate and silica matrix and cement. P₂O₅ content is up to 32.3 % with an average equal to 18.6 %. The impurity is caused by the presence of variable amounts of SiO₂ and CaO. The F% and F/P₂O₅ ratio in studied phosphates is lower compared with that in phosphates from Jordan and Saudi Arabia. The geological and geochemical results were integrated for resource estimation. Three high-grade phosphate layers with ≥23 % P₂O₅ were considered in the calculations. The phosphate resource is classified as an inferred resource. The total volume of the resource is about 649 million tons. The average P₂O₅ content is 24.57, and the stripping ratio is 1:5.8.     

Eustatic and tectonic controls on Quaternary Ras Leona marine terraces (Strait of Gibraltar, northern Morocco)

Well-preserved Quaternary staircased marine terraces appear on Ras Leona limestone relief. This is a peculiar sector of the Betic-Rif Cordillera, lying in the four-way junction between the Atlantic and the Mediterranean, and Europe and Africa. The age and altitude correlation of the Ras Leona terraces with travertine-covered lateral equivalent terraces fashioned in the neighbouring Beni Younech area, and comparison with those along the Moroccan Atlantic coasts, would suggest that the Ras Leona terraces were mainly formed by eustatic factors. The importance of the eustasy is supported by further comparisons with Spanish and Moroccan Mediterranean terraces and with different marine terraces developed on passive-margin coasts around the world. A tectonic event occurred mainly during the period between the formation of the Maarifian and the Ouljian terraces (i.e., between 370 and 150 ka). The moderate Quaternary tectonic uplift deduced from the marine terraces and its comparison with uplifted marine terraces developed in active subduction setting disagrees with the model of an active eastwards subduction below the Gibraltar tectonic arc.     

Multiobjective analysis of chaotic dynamic systems with sparse learning machines

Sparse learning machines provide a viable framework for modeling chaotic time-series systems. A powerful state-space reconstruction methodology using both support vector machines (SVM) and relevance vector machines (RVM) within a multiobjective optimization framework is presented in this paper. The utility and practicality of the proposed approaches have been demonstrated on the time series of the Great Salt Lake (GSL) biweekly volumes from 1848 to 2004. A comparison of the two methods is made based on their predictive power and robustness. The reconstruction of the dynamics of the Great Salt Lake volume time series is attained using the most relevant feature subset of the training data. In this paper, efforts are also made to assess the uncertainty and robustness of the machines in learning and forecasting as a function of model structure, model parameters, and bootstrapping samples. The resulting model will normally have a structure, including parameterization, that suits the information content of the available data, and can be used to develop time series forecasts for multiple lead times ranging from two weeks to several months.     

Influence of the soil–structure interaction on the fundamental period of buildings

This paper includes an investigation of the influence of the soil–structure interaction (SSI) on the fundamental period of buildings. The behaviour of both the soil and the structure is assumed to be elastic. The soil‐foundation system is modelled using translational and rotational discrete springs. Analysis is first conducted for one‐storey buildings. It shows that the influence of the SSI on the fundamental frequency of building depends on the soil–structure relative rigidity K_ss. Analysis is then extended for multi‐storey buildings. It allows the generalization of the soil–structure relative rigidity K_s to such complex structures. Charts are proposed for taking into account the influence of the SSI in the calculation of the fundamental frequency of a wide range of buildings. Copyright © 2007 John Wiley & Sons, Ltd.     

Petrological and mineralogical studies of Pan-African serpentinites at Bir Al-Edeid area, central Eastern Desert, Egypt

The studied serpentinites occur as isolated masses, imbricate slices of variable thicknesses and as small blocks or lenses incorporated in the sedimentary matrix of the mélange. They are thrusted over the associated island arc calc-alkaline metavolcanics and replaced by talc-carbonates along shear zones. Lack of thermal effect of the serpentinites upon the enveloping country rocks, as well as their association with thrust faults indicates their tectonic emplacement as solid bodies. Petrographically, they are composed essentially of antigorite, chrysotile and lizardite with subordinate amounts of carbonates, chromite, magnetite, magnesite, talc, tremolite and chlorite. Chrysotile occurs as cross-fiber veinlets traversing the antigorite matrix, which indicate a late crystallization under static conditions. The predominance of antigorite over other serpentine minerals indicates that the serpentinites have undergone prograde metamorphism or the parent ultramafic rocks were serpentinized under higher pressure. The parent rocks of the studied serpentinites are mainly harzburgite and less commonly dunite and wehrlite due to the prevalence of mesh and bastite textures. The serpentinites have suffered regional metamorphism up to the greenschist facies, which occurred during the collisional stage or back-arc basin closure, followed by thrusting over a continental margin. The microprobe analyses of the serpentine minerals show wide variation in SiO₂, MgO, Al₂O₃, FeO and Cr₂O₃ due to different generations of serpentinization. The clinopyroxene relicts, from the partly serpentinized peridotite, are augite and similar to clinopyroxene in mantle-derived peridotites. The chromitite lenses associated with the serpentinites show common textures and structures typical of magmatic crystallization and podiform chromitites. The present data suggest that the serpentinites and associated chromitite lenses represent an ophiolitic mantle sequence from a supra-subduction zone, which were thrust over the continental margins during the collisional stage of back-arc basin.     

中国稻田甲烷产生和排放研究 Ⅱ.模式研究和减排措施

主要介绍了近 2 0年来稻田甲烷排放的模式研究和排放量的估算以及减少稻田甲烷排放的措施。数值模式是估算稻田甲烷排放量的一条有效途径 ,模式的研究现在正处于发展阶段。介绍了几个主要的模型 ,既有物理过程模型也有经验模型。年排放量的估算范围为 6 79～ 4 1 4Tg ,随着技术的发展和大量实验的进行估算值的精度正得到不断的提高。减排措施是减少稻田甲烷排放的必要手段 ,但是目前的减排技术均处于研究阶段 ,应用还不成熟