西藏尼雄矿田日阿铜矿床矽卡岩矿物学特征及地质意义

尼雄矿田位于冈底斯成矿带西段中部隆格尔南木林岩浆岩带的北侧.日阿铜矿床位于尼雄矿田的东南端,矿体产于晚白垩世侵入岩与下拉组灰岩接触带的矽卡岩或矽卡岩化大理岩中,主要矽卡岩矿物有石榴子石、透辉石、蛇纹石、金云母、绢云母、硅镁石、阳起石、透闪石、绿帘石、绿泥石等.电子探针分析表明,矿区石榴子石主要为钙铁榴石,次为钙铝榴石;辉石以透辉石为主;金云母明显富镁贫铁,且富含挥发分F;闪石类矿物属钙角闪石系列;绿泥石富镁贫铁.推断成矿流体大致经历了5个演化阶段:①干矽卡岩阶段,高温(＞450℃)、低pH值、氧化-弱氧化;②湿矽卡岩阶段,温度降低,pH值和氧逸度逐渐升高;③氧化物阶段,温度进一步降低,pH值升高(碱性),氧逸度则呈降低趋势;④石英硫化物阶段,中等温度(200～300℃),高pH值(碱性),低氧逸度;⑤碳酸盐阶段,低温(160～203℃),低pH值,低氧逸度.此外,矿区还存在多金属矿化的可能.     

Skarn Mineral and Stable Isotopic Characteristics of Tonglushan Cu-Fe Deposit in Hubei Province

湖北大冶铜绿山铜铁矿床是长江中下游西段鄂东南矿集区一个大型夕卡岩矿床.围岩为三叠系大理岩及白云质大理岩,决定了其发育丰富的钙镁质复合夕卡岩矿物组合,包括石榴子石、辉石、角闪石、绿帘石、金云母、绿泥石等.本文详细描述了夕卡岩不同阶段矿物的特征,并对矿物进行了电子探针分析(EPMA)及碳、氧、硫稳定同位素研究.结果表明石榴子石形成于三期,成分上属于钙铝—钙铁系列,且从早到晚具有从钙铝向钙铁榴石演化趋势,反映出成矿溶液由酸性向碱性演化.环带结构的石榴子石和绿帘石从核部到边部Fe含量增高,说明磁铁矿是在Fe浓度升高的碱性溶液中沉淀.辉石为透辉石.角闪石属于单斜角闪石中的钙质角闪石,包括透闪石,韭闪石和少量阳起石.矿物成分分析表明辉石和石榴子石的Mn/Fe值与矿化金属元素存在一定的联系.相对于钙质夕卡岩,镁质或含镁质夕卡岩是铜铁矿体交代的更有利岩石.矿床硫化物的δ34 SV-CDT均为正值且变化范围较窄,介于0.6‰～3.8‰.成矿阶段方解石δ13CV-PDB变化于-2.9‰～6.3‰,δ18OV-SMOW变化于9.6‰ ～ 12.6‰,成矿后方解石的同位素值明显增大,δ13CV-PDB为-0.9‰ ～ 1.3‰,δ18OV-SMOW为15.2‰ ～ 17.3‰,趋向于围岩的同位素值.研究结果说明成矿阶段的硫和碳来自于深源或地幔,而成矿后期碳与地层发生明显的同位素交换反应.     

新疆阿尔泰南缘加尔巴斯套铁矿床成矿时代及成矿作用研究

加尔巴斯套铁矿床位于阿尔泰南缘克兰火山沉积盆地中。该矿床与产于额尔齐斯构造带北侧的可斯尔鬼花岗岩有直接的成因关系,属于典型的矽卡岩型富铁矿。岩体SHRIMP U-Pb年龄表明,该矿床略晚于287 Ma形成;流体包裹体和稳定同位素研究显示,成矿阶段流体除岩浆水外,还有较多大气降水的参与,成矿流体主要表现为中低温、低盐度、中低密度特征;成矿物质主要来源于走滑-伸展背景下的可斯尔鬼花岗岩。结合前人研究成果,笔者认为在晚石炭世—早二叠世时期,阿尔泰南缘由走滑-伸展引发的大规模岩浆作用造就了区内有关铜、锌、镍、金、铁等广泛的成矿作用。     

Mineral compositions and fluid evolution of the Tonglushan skarn Cu–Fe deposit,SE Hubei,east-central China

The Tonglushan Cu–Fe deposit (1.12 Mt at 1.61% Cu, 5.68 Mt at 41% Fe) is located in the westernmost district of the Middle–Lower Yangtze River metallogenic belt. As a typical polymetal skarn metallogenic region, it consists of 13 skarn orebodies, mainly hosted in the contact zone between the Tonglushan quartz-diorite pluton (140 Ma) and Lower Triassic marine carbonate rocks of the Daye Formation. Four stages of mineralization and alterations can be identified: i.e. prograde skarn formation, retrograde hydrothermal alteration, quartz-sulphide followed by carbonate vein formation. Electron microprobe analysis (EMPA) indicates garnets vary from grossular (Ad_20.2–41.6Gr_49.7–74.1) to pure andradite (Ad_47.4–70.7Gr_23.9–45.9) in composition, and pyroxenes are represented by diopsides. Fluid inclusions identify three major types of fluids involved during formation of the deposit within the H₂O–NaCl system, i.e. liquid-rich inclusions (Type I), halite-bearing inclusions (Type II), and vapour-rich inclusions (Type III). Measurements of fluid inclusions reveal that the prograde skarn minerals formed at high temperatures (>550°C) in equilibrium with high-saline fluids (>66.57 wt.% NaCl equivalent). Oxygen and hydrogen stable isotopes of fluid inclusions from garnets and pyroxenes indicate that ore-formation fluids are mainly of magmatic-hydrothermal origin (δ¹⁸O = 6.68‰ to 9.67‰, δD = –67‰ to –92‰), whereas some meteoric water was incorporated into fluids of the retrograde alteration stage judging from compositions of epidote (δ¹⁸O = 2.26‰ to 3.74‰, δD= –31‰ to –73‰). Continuing depressurization and cooling to 405–567°C may have resulted in both a decrease in salinity (to 48.43–55.36 wt.% NaCl equivalent) and the deposition of abundant magnetite. During the quartz-sulphide stage, boiling produced sulphide assemblage precipitated from primary magmatic-hydrothermal fluids (δ¹⁸O = 4.98‰, δD = –66‰, δ³⁴S values of sulphides: 0.71–3.8‰) with an extensive range of salinities (4.96–50.75 wt.% NaCl equivalent), temperatures (240–350°C), and pressures (11.6–22.2 MPa). Carbonate veins formed at relatively low temperatures (174–284°C) from fluids of low salinity (1.57–4.03 wt.% NaCl equivalent), possibly reflecting the mixing of early magmatic fluids with abundant meteoric water. Boiling and fluid mixing played important roles for Cu precipitation in the Tonglushan deposit.     

接触交代矽卡岩型铜矿床地球化学勘查预测指标

根据接触交代矽卡岩型铜矿床的地层、岩体、控矿构造、蚀变带、矿物地质地球化学特征,结合矿床元素组合、原生异常、元素异常分带规律等,总结出矽卡岩型矿床的岩体评价、剥蚀程度、隐伏矿预测3类地球化学勘查指标,为该类矿床的勘查研究提供了科学依据.     

青海省格尔木市哈西亚图地区铁多金属矿床的发现及意义

通过钻探工程验证高精度磁测异常,2010年青海省核工业地质局发现了格尔木市哈西亚图地区矽卡岩型铁多金属矿,初步估算铁资源量规模已达中型。赋矿地层为古元古界金水口岩群下岩组,华力西期灰色石英闪长岩与成矿密切相关。这一突破性发现对环柴达木盆地古元古界金水口岩群分布区的铁多金属矿找矿具有重要指导意义。     

Fluid Inclusions and Hydrogen,Oxygen, Sulfur Isotopes of Nuri Cu‐W‐Mo Deposit in the Southern Gangdese,Tibet

The Nuri Cu‐W‐Mo deposit is located in the southern subzone of the Cenozoic Gangdese Cu‐Mo metallogenic belt. The intrusive rocks exposed in the Nuri ore district consist of quartz diorite, granodiorite, monzogranite, granite porphyry, quartz diorite porphyrite and granodiorite porphyry, all of which intrude in the Cretaceous strata of the Bima Group. Owing to the intense metasomatism and hydrothermal alteration, carbonate rocks of the Bima Group form stratiform skarn and hornfels. The mineralization at the Nuri deposit is dominated by skarn, quartz vein and porphyry type. Ore minerals are chalcopyrite, pyrite, molybdenite, scheelite, bornite and tetrahedrite, etc. The oxidized orebodies contain malachite and covellite on the surface. The mineralization of the Nuri deposit is divided into skarn stage, retrograde stage, oxide stage, quartz‐polymetallic sulfide stage and quartz‐carbonate stage. Detailed petrographic observation on the fluid inclusions in garnet, scheelite and quartz from the different stages shows that there are four types of primary fluid inclusions: two‐phase aqueous inclusions, daughter mineral‐bearing multiphase inclusions, CO₂‐rich inclusions and single‐phase inclusions. The homogenization temperature of the fluid inclusions are 280°C–386°C (skarn stage), 200°C–340°C (oxide stage), 140°C–375°C (quartz‐polymetallic sulfide stage) and 160°C–280°C (quartz‐carbonate stage), showing a temperature decreasing trend from the skarn stage to the quartz‐carbonate stage. The salinity of the corresponding stages are 2.9%–49.7 wt% (NaCl) equiv., 2.1%–7.2 wt% (NaCl) equiv._, 2.6%–55.8 wt% (NaCl) equiv. and 1.2%–15.3 wt% (NaCl) equiv., respectively. The analyses of CO₂‐rich inclusions suggest that the ore‐forming pressures are 22.1 M Pa–50.4 M Pa, corresponding to the depth of 0.9 km–2.2 km. The Laser Raman spectrum of the inclusions shows the fluid compositions are dominated in H₂O, with some CO₂ and very little CH₄, N₂, etc. δD values of garnet are between ?114.4‰ and ?108.7‰ and δ¹⁸O_H2O between 5.9‰ and 6.7‰; δD of scheelite range from ?103.2‰ to ?101.29‰ and δ¹⁸O_H2O values between 2.17‰ and 4.09‰; δD of quartz between ?110.2‰ and ?92.5‰ and δ¹⁸O_H2O between ?3.5‰ and 4.3‰. The results indicate that the fluid came from a deep magmatic hydrothermal system, and the proportion of meteoric water increased during the migration of original fluid. The δ³⁴S values of sulfides, concentrated in a rage between ?0.32‰ to 2.5‰, show that the sulfur has a homogeneous source with characteristics of magmatic sulfur. The characters of fluid inclusions, combined with hydrogen‐oxygen and sulfur isotopes data, show that the ore‐forming fluids of the Nuri deposit formed by a relatively high temperature, high salinity fluid originated from magma, which mixed with low temperature, low salinity meteoric water during the evolution. The fluid flow through wall carbonate rocks resulted in the formation of layered skarn and generated CO₂ or other gases. During the reaction, the ore‐forming fluid boiled and produced fractures when the pressure exceeded the overburden pressure. Themeteoric water mixed with the ore‐forming fluid along the fractures. The boiling changed the pressure and temperature, oxygen fugacity, physical and chemical conditions of the whole mineralization system. The escape of CO₂ from the fluid by boiling resulted in scheelite precipitation. The fluid mixing and boiling reduced the solubility of metal sulfides and led the precipitation of chalcopyrite, molybdenite, pyrite and other sulfide.     

山东省齐河—禹城富铁矿勘查区工作进展及对策

近年来,在山东省齐河—禹城地区矽卡岩型铁矿勘查工作取得了重大突破,该勘查区内相继发现了李屯、大张和潘店矽卡岩型铁矿床,同时科研工作也取得了较大进展。本文在全面收集和综合分析区内矿产勘查和科研成果的基础上,对该区以往勘查经验和研究现状进行总结,分析该区勘查研究过程中主要制约因素和亟待解决的关键问题。通过对制约因素和关键问题开展对策研究,为今后该区铁矿勘查工作提供借鉴。通过分析表明该区矽卡岩型铁矿的成矿地质体（即燕山晚期中基性侵入岩）应属于沂南序列。勘查区内深部地质体三维空间特征精细刻画、深部地质体控矿构造研究、物探数据深度解译、矿产勘查空间拓展、铁矿成矿规律和矿体赋存规律深入研究等多个方面将是下一步勘查研究工作的重点,加强对上述方面的研究有助于促进区内铁矿勘查工作顺利开展。在加强对物探异常西半环已发现矿体的勘查和类似异常的查证工作的同时,对物探异常东半环加强勘查研究工作对于拓展整个齐河—禹城地区矽卡岩型铁矿的勘查空间具有十分重要的意义。     

南岭东段钨锡多金属矿床地质特征、成矿模式及找矿方向

南岭东段地区是世界著名的钨多金属矿集区。近年来中国地质调查局在该区实施钨多金属矿调查评价,找到了一批具有中大型远景的与花岗岩有关的新类型钨锡多金属矿床,特别是在复式岩体中的花岗岩型新类型钨钼多金属矿床（简称＂体中体＂式钨钼多金属矿床）和受中、上泥盆统地层控制的层控矽卡岩型钨锡多金属矿床的发现,不仅实现了南岭东段地区找矿新突破,而且对整个南岭乃至我国华南地区钨锡多金属矿找矿具有重要指导作用。本文根据近年来南岭东段地区钨锡多金属矿找矿新成果,通过该区钨锡多金属矿床地质特征的总结,建立了南岭东段地区钨锡多金属矿成矿模式,提出了南岭东段地区今后钨锡多金属矿找矿方向应重点注意与燕山期复式花岗岩有关的＂体中体＂式钨钼多金属矿床和中、上泥盆统控制的层控矽卡岩型钨锡多金属矿床的寻找。     

Felsic magmatic phases and the role of late-stage aplitic dykes in the formation of the world-class Cantung Tungsten skarn deposit, Northwest Territories, Canada

A field and petro-chemical classification of felsic magmatic phases (FMPs) at the world-class Cantung W skarn deposit was undertaken to document the evolution of magmatism and the relationships between different FMPs, metasomatism, and mineralization. Early FMPs include moderately differentiated (Zr/Hf = 18–26, Ti/Zr = 14–15) biotite monzogranitic plutons and early biotite-rich granitic dykes, and compositionally similar quartz–feldspar porphyry dykes. Late, highly fractionated (Zr/Hf = 8–17, Ti/Zr = 3–13) FMPs sourced from a deeper monzogranitic intrusion include: (1) leucocratic biotite- or tourmaline-bearing dykes derived from localized entrapments of residual magma; and, (2) sub-vertical NE-trending aplitic dykes derived from a larger segregation of residual fluid- and incompatible element-enriched magma. The aplitic dykes have textures, morphologies, spatial associations, and a pervasive calcic metasomatic mineral assemblage (Ca-plagioclase + quartz or clinozoisite) indicative of syn-mineralization emplacement. Very late-stage overpressuring and initiation of sub-vertical fractures into the overlying plutonic carapace and country rocks by supercritical magmatic fluid led to an interaction with calcareous country rocks that resulted in an increased aCa²⁺ in the fluid and the concurrent precipitation of W skarn. Residual magma also ascended with, and quenched in equilibrium with the magmatic fluid to from the aplitic dykes, then was metasomatized by the fluid as it interacted with calcareous country rocks. Overall, highly fractionated and moderately to very highly undercooled FMPs at Cantung provide evidence for a large and evolving felsic magmatic system at depth that segregated and maintained a stable fluid- and incompatible element-enriched residual magma until the latest stages of crystallization. The detailed study of FMPs associated with magmatic-hydrothermal mineral deposits allow us to refine our understanding of these mineralizing systems and better define metallogenic and exploration models for intrusion-related mineralization.