闽东干旱概况及夏季人工增雨作业天气形势分析

对闽东干旱的成因和干旱的环流形势进行了探讨,着重分析了夏旱期间人工增雨作业的天气形势以及不同形势、不同云型下的降水情况。结果表明:闽东干旱的形成与大型环流形势、地理因素、土壤植被等有关,平均而言,沿海干旱明显多于内陆山区;夏季发生干旱的机率最大而且强度级别高,西太平洋副热带高压是致旱的主要天气系统;在夏季,台风型(T)、弱流场型(R)是进行人工增雨作业的优势天气型,Cb、Cu、Sc云是开展人工增雨作业比较适合的作业云。这些结果为夏旱期间开展人工增雨作业提供了理论依据。     

Direct Current Plasma Emission Spectrometric Determination of Major, Minor and Trace Elements in Microwave Oven Acid Leachates of Powdered Whole Coal Samples

Major concentrations of Al₂O₃, Fe₂O₃, MgO, CaO, Na₂O and K₂O, minor levels of TiO₂, P₂O₅ and thirty petrologically, geochemically and environmentally significant trace elements have been determined in microwave oven acid leachates of whole powdered coal samples by direct current plasma‐atomic emission spectrometry (DCP‐AES). A single sample preparation procedure was suitable for all the determinations with no additional dilution step for major elements solution. Dried samples (0.5 g) were treated in low‐pressure PFA digestion vessels with HF/HCl/HNO₃/HClO₄ acids to quantitatively extract the analytes from the bulk material, while leaving the major part of organic matrix as a residue. The major constituents of geological samples, in particular the easily ionised elements (EIEs) such as alkali and alkaline earths, may complicate the instrumental determinations in DCP‐AES because of differential enhancements of elemental emission intensities and stray light interferences. Taking account of these factors, the coal matrix is considered to have very low major oxide totals as compared to many other common geo‐environmental and related materials (rocks, sediments, soil, ashes etc.). The sample size employed here, while yielding a relatively concentrated solution to cover a wide range of elemental determinations, provided a sample matrix that significantly diminished interferences for DCP measurements. The need for closely matching the unknowns and calibrators was eliminated except for overall acidity and an excess quantity of caesium for EIE buffering. Calibration of the spectrometer was accomplished by simple aqueous single element solutions as high concentration calibrators in addition to a reagent blank as a low concentration calibrator. Two point working curves were established to allow for the maximum concentrations of each element expected in the unknowns. The precision of determinations under routine conditions as well as the reproducibility of the leaching and precision of instrumental measurements have been evaluated. Relative standard deviations (RSD) were of 1–2% for those elements whose concentrations in solid samples were well above the limits of quantification. Method detection limits in the buffered solutions were also evaluated. To evaluate the accuracy of the microwave oven‐DCP method a suite of eight certified coal reference materials of differing rank, were analysed with good agreement with the certified and/or available published data. Results are presented for the uncertified major oxides in the AR series reference materials.     

Classification of glacial lakes using integrated approach of DFPS technique and gradient analysis using Sentinel 2A data

It is important to identify and locate glacial lakes for assessing any potential hazard. This study presents a combination of semi-automatic method Double-Window Flexible Pace Search (DFPS) and edge detection technique to identify glacial lakes using Sentinel 2A satellite data. Initially, Normalized Difference Water Index (NDWI) has been used to identify water and non-water areas, while DFPS and Edge detection technique has been used to identify an optimum threshold value to distinguish between water and shadow areas. The optimal threshold from DFPS process is 0.21, while threshold value of gradient magnitude using edge detection process is 0.318. The number of glacial lakes identified using the above algorithm is in close agreement with previously published results on glacial lakes in Gangotri glacier using different techniques. Thus, a combination of DFPS and edge detection process has successfully segregated glacial lakes from other features present in Gangotri glacier.     

Clinoform architecture and along‐strike facies variability through an exhumed erosional to accretionary basin margin transition

Exhumed basin margin‐scale clinothems provide important archives for understanding process interactions and reconstructing the physiography of sedimentary basins. However, studies of coeval shelf through slope to basin‐floor deposits are rarely documented, mainly due to outcrop or subsurface dataset limitations. Unit G from the Laingsburg depocentre (Karoo Basin, South Africa) is a rare example of a complete basin margin scale clinothem (>60 km long, 200 m‐high), with >10 km of depositional strike control, which allows a quasi‐3D study of a preserved shelf‐slope‐basin floor transition over a ca. 1,200 km² area. Sand‐prone, wave‐influenced topset deposits close to the shelf‐edge rollover zone can be physically mapped down dip for ca. 10 km as they thicken and transition into heterolithic foreset/slope deposits. These deposits progressively fine and thin over tens of km farther down dip into sand‐starved bottomset/basin‐floor deposits. Only a few km along strike, the coeval foreset/slope deposits are bypass‐dominated with incisional features interpreted as minor slope conduits/gullies. The margin here is steeper, more channelized and records a stepped profile with evidence of sand‐filled intraslope topography, a preserved base‐of‐slope transition zone and sand‐rich bottomset/basin‐floor deposits. Unit G is interpreted as part of a composite depositional sequence that records a change in basin margin style from an underlying incised slope with large sand‐rich basin‐floor fans to an overlying accretion‐dominated shelf with limited sand supply to the slope and basin floor. The change in margin style is accompanied with decreased clinoform height/slope and increased shelf width. This is interpreted to reflect a transition in subsidence style from regional sag, driven by dynamic topography/inherited basement configuration, to early foreland basin flexural loading. Results of this study caution against reconstructing basin margin successions from partial datasets without accounting for temporal and spatial physiographic changes, with potential implications on predictive basin evolution models.     

多尺度细节增强的遥感影像超分辨率重建

鉴于现有超分辨率重建方法难以突显重建影像细节信息的问题,提出多尺度细节增强的遥感影像超分辨率重建模型框架。首先,通过最小二乘滤波方法将序列影像分解成包含大尺度边缘的平滑信息和包含中小型尺度的细节信息;其次,利用插值方法得到相应的高分辨率细节信息和平滑信息,构造纹理细节增强函数,提升中小型细节的增强幅度;最终,融合细节信息和平滑信息,得到初始的超分辨率重建结果,并利用局部优化模型进一步改善重建影像质量。选取同时相和多时相遥感影像作为试验数据。试验结果表明,本文重建结果与插值方法、TV方法和MAP方法相比,在客观评价指标上均有显著提高,明显改善了重建影像的纹理细节。论文提出的多尺度细节增强的超分辨率重建方法,可以使重建影像提供更多高频细节信息,具有较好鲁棒性和普适性。     

SAR影像与光学影像的高斯伽玛型边缘强度特征匹配法

提出了一种基于影像边缘强度图描述的SAR影像与光学影像匹配方法。首先对影像进行粗纠正,消除影像之间的尺度和旋转变化;其次,改进相位一致性特征检测方法,提取对影像相干斑噪声稳健的特征点;然后基于高斯伽玛型双边窗口比值算子计算影像边缘强度图,在此基础上构造不变特征描述符;最后联合几何约束条件,实现SAR影像与光学影像匹配。试验结果证明,与现有方法相比,本文方法能够大幅提高SAR影像与光学影像匹配结果中的正确匹配特征数量以及影像配准精度。     

一种四叉树和测地线活动轮廓模型相结合的海陆影像分割方法

海陆影像分割对于后续的海岸线提取、潮间带地形反演、海岸演化状况分析等都具有十分重要的意义。本文在分析了四叉树、测地线活动轮廓(GAC)模型和Canny边缘检测算子等在海陆影像分割中优缺点的基础上,提出了一种四叉树、Canny算子和GAC模型相结合的海陆影像分割方法。该方法综合利用上述各方法的优点,将Canny算子边缘检测结果融入到基于四叉树初分割的GAC模型中,重构边界停止函数,演化水平集方程,实现海陆影像分割。试验结果表明,该方法具有海陆影像分割速度快、精度高、可靠性强和自动化程度高等优点,对于弱边缘以及严重凹陷边缘,都能实现自动和准确分割。     

热红外与可见光数据的云边缘高度匹配

高分辨率数据中云高度的差异性突显,特别是边缘处高度在云阴影识别和地表辐射估算等方面成为需要考虑的重要因素。热红外数据获取云高度分辨率较低、缺乏细部差异性特征,为解决这一问题,首先将对应的热红外和可见光数据进行特征点配准,再将基于热红外数据计算的云高度重采样至高分辨率,然后以基于欧式距离变换的围线搜索方法及距离加权将热红外云边缘高度匹配至对应的可见光图像,最后根据云阴影的相似度匹配方法确定真实云高度。结果表明,算法在遵循热红外云高信息分布变化规律的同时,可以得到较准确的高分辨率云边缘高度,一定程度上解决了热红外技术获取云高在分辨率上的局限,扩展了其在云高反演方面的作用。     

高压下天然菱铁矿的压缩性和电子结构研究

采用同步辐射光源和金刚石对顶砧(DAC)技术,对天然菱铁矿的压缩性和电子结构进行了原位X射线衍射(XRD)和X射线吸收近边结构谱(XANES)测试研究。在室温下随着压力逐渐升高至50.2 GPa,菱铁矿保持方解石型结构不变,但是逐渐向Na Cl型结构转变;刚性[CO3]2-基团平行于ab-平面定向排列使c轴的压缩性大于a轴。菱铁矿在44.6~47.1 GPa之间发生电子由高自旋态(HS)向低自旋态(LS)的转变,表现为体积塌陷8%。HS菱铁矿的等温状态方程参数为K0=112(5)GPa和K'0=4.6(3)。首次采用XANES技术对菱铁矿中Fe2+的电子结构进行了研究,结果表明:随着压力升高至37.3 GPa,Fe2+的配位和局域对称并未发生明显变化;此后电子结构开始转变,Fe2+的3d轨道分裂能降低,电子跃迁概率增大,呈现LS特性。     

Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).