油气化探中甲烷碳同位素应用、存在问题与对策研究

阐述了在地表油气化探实践当中甲烷碳同位素对地表土壤烃气成因判别的有效性，但有时也会遇到判断错误的情况。通过对应用实例的分析，指出因忽略了土壤中异常甲烷是一种混合成因甲烷，从而导致判断失误。为全面解决这一问题，提出了同时选送数量相当的背景土壤样品和异常样品进行甲烷同位素测定，然后通过教学方法计算出真实反映来源于油气藏中的甲烷的碳同位素值的对策方案。     

罕见矿物--六方球方解石的发现及特征

大庆油田部分三元复合驱抽油井结垢现象比较严重。井中结垢损害抽油设备，增加了生产成本。通过运用XRD，IR，SEM和化学分析手段对抽油井垢的研究发现，垢的主要化学成分为CaO和SiO2，其含量分别为67％和28％，油井垢中的主要矿物成分是罕见矿物——六方球方解石。六方球方解石呈微晶状(1—10μm)，并常常以微晶聚集的球粒状出现，同时伴生有无定形SiO2。呈游离态的SiO2和有机质对于六方球方解石的形成起到了重要作用。     

华南热水成因硅质岩建造的稀土元素地球化学特征

本文在华南地区若干个重要层位热水成因硅质岩建造的稀土元素地球化学数据的基础上,讨论了热水成因硅质岩的REE特征及其与形成环境的关系。指出典型热水沉积建造的δCe为负异常,而δEu为正异常,且LREE>HREE;这种热水成因的硅质岩REE总量普遍较低,且有从热水喷口向外REE总量增高的趋势。热水成因硅质泥岩与正常沉积成因硅质泥的混合存在使稀土元素分布状况变得更复杂。     

兰坪白秧坪铜银多金属矿床成矿物质来源的铅和硫同位素示踪

白秧坪铜银多金属矿床主要产于白垩系下统景星组石英砂岩、粉砂岩中，矿石铅同位素组成特征与景星组砂岩的铅同位素组成比较接近，表明壳源物质参与了成矿作用。作ZartMan图解和△γ—△β图解表明，矿石铅属于壳幔混合来源。矿石铅μ值介于9．43—9．65之间，Th/U比值介于3．72—3．87之间，表明矿石铅为壳幔混合铅。该矿床硫同位素组成表明，硫来源于深部地幔硫遭受地壳硫的混入。该矿床的成矿作用发生于开放体系之中，成矿物质来源为深部幔源物质混合了壳源物质。     

河南东濮凹陷古近系沙河街组盐岩沉积特征及成因

东濮凹陷是渤海湾盆地的一个次级构造单元，其古近系的两个沉积旋回发育了四套盐岩，分别位于沙河街组第三段的第四亚段(S34)、第三亚段(S33)、第二亚段(S32)和沙河街组的第一段(S1)。主要分布在凹陷北部。每套盐岩又由若干个盐韵律组成，每一单韵律由盐岩和泥岩组成。两套等时对比标志层（深湖沉积）之间盐岩与砂泥岩存在着相变关系。盐岩是在深盆背景下干旱成因的，盐类物质来自地下深处上涌的卤水，分层卤水是盐形成的基本形式，上涌通道是基底大断裂，动力基础是岩浆活动。盐的阻隔作用使其对下部地层的温度、压力均有影响，这种影响有利于加快盐下地层中的有机质成熟与演化。盐又是良好的盖层，且在高温、高压下盐呈塑性状态。勘探实践看出东濮凹陷的岩性油气藏与盐岩的沉积有密切的关系，因此搞清盐岩的分布规律对东濮凹陷下步勘探有着极为重要的意义。     

江西银山多金属矿床高盐度包裹体及其成因意义

流体包裹体岩相学和显微测温学研究表明，银山矿床石英斑岩和金金属矿床中都发现须含石盐的高盐度流体包裹体，表明至少在成矿作用的早期成矿流体为高盐度流体，高盐度流体不是由热水溶液的不混溶作用或沸腾作用形成的，而是直接从饱和水的结晶岩浆熔体中出溶的，银山矿床的成矿流体与斑岩铜矿的成矿流体具有相似性，证实矿床深部可能有隐伏斑岩铜矿。     

Hydrochemical and isotopic characteristics of groundwater in the Souss Upstream Basin, southwestern Morocco

Heterogeneous shallow Plio-Quaternary formations of the Souss Plain represent the most important aquifer in southern High Atlas Mountains in Morocco. The present work was conducted in the Souss Upstream Basin to identify the chemical characteristics and the origin of groundwater in an aquifer under semi-arid climate. Isotopic and hydrochemical compositions combined with geological and hydrogeological data were used for this purpose. The total dissolved solids vary from 239 to 997 mg l⁻¹, and the following groundwater types are recognized: Ca²⁺–Mg²⁺–HCO₃⁻, Ca²⁺–Mg²⁺–SO₄²⁻ and Ca²⁺–Mg²⁺–Cl⁻. The groundwater is saturated and slightly supersaturated with respect to carbonate minerals and undersaturated with respect to evaporite minerals, which means that the groundwater composition is largely controlled by the dissolution of carbonate rocks known in the basin. The isotopic contents of groundwaters ranged from −8‰ to −5.2‰ for δ¹⁸O, from −52‰ to −34‰ for δD, and from 0 to 5.5 TU for tritium. The hydrogen (δD) and oxygen (δ¹⁸O) isotope signatures reveal a significant infiltration before evaporation takes place, indicating a major recharge directly from fractures in the crystalline and limestone formations of Atlas Mountains (above 800 m a.s.l.) and infiltration of surface water in the alluvial cones at the border of the Atlas basins. The very low tritium values suggest that the groundwater recharge follows a long flow path and a mixing between old and modern water is shown. However, a slight evaporation effect is noted in the southern part of the basin close to the Anti-Atlas Mountains.     

Terrane assembly and geodynamic evolution of central–western Hoggar: a synthesis

After a review of the rock sequences and evolution of the eastern and central terranes of Hoggar, this paper focusses on the Neoproterozoic subduction-related evolution and collision stages in the central–western part of the Tuareg shield. Rock sequences are described and compared with their counterparts identified in the western and the eastern terranes exposed in Hoggar and northern Mali. The Pharusian terrane that is described in detail, is floored in the east by the Iskel basement, a Mesoproterozoic arc-type terrane cratonized around 840 Ma and in the southeast by Late Paleoproterozoic rock sequences (1.85–1.75 Ga) similar to those from northwestern Hoggar. Unconformable Late Neoproterozoic volcanosedimentary formations that mainly encompass volcanic greywackes were deposited in troughs adjacent to subduction-related andesitic volcanic ridges during the c. 690–650 Ma period. Abundant arc-related pre-collisional calc-alkaline batholiths (650–635 Ma) intruded the volcanic and volcaniclastic units at rather shallow crustal levels prior to collisional processes. The main E–W shortening in the Pharusian arc-type crust occurred through several stages of transpression and produced overall greenschist facies regional metamorphism and upright folding, thus precluding significant crustal thickening. It was accompanied by the shallow emplacement of calc-alkaline batholiths and plutons. Ages of syn-collisional granitoids range from 620 Ma in the western terranes, to 580 Ma in the Pharusian terrane, thus indicating a severe diachronism. After infill of molassic basins unconformable above the Pan-African greenschists, renewed dextral transpression took place in longitudinal domains such as the Adrar fault. The lithology, volcanic and plutonic suites, deep greenschist facies metamorphism, structures and kinematics from the Adrar fault molassic belt previously considered as Neoproterozoic are described in detail. The younger late-kinematic plutons emplaced in the Pharusian terrane at 523 Ma [Lithos 45 (1998) 245] relate to a Cambrian tectonic pulse that post-dates molasse deposition. The new geodynamic scenario presented considers several paleosubductions. The major east-dipping subduction, corresponding to the closure of a large Pan-African oceanic domain in the west (680–620 Ma) post-dates an older west-dipping “Pharusian” subduction (690–650 Ma?) to the east of the eastern Pharusian terrane. Such a diachronism is suggested by the 690 Ma old eclogites of the western part of the LATEA terrane of central Hoggar [J. African Earth Sci. this volume (2003)] that are nearly synchronous with the building up of the Pharusian terrane, thus suggesting that the 4°50^′ lithospheric fault represents a reactivated cryptic suture.     

铜陵中生代中酸性侵入岩特征及成因

铜陵地区中酸性侵入岩可以划分为橄榄安粗岩系列和高钾钙碱性系列 ,橄榄安粗岩系列的岩石组合为辉石二长闪长岩 +二长闪长岩 +石英二长岩 ,这些岩石的里特曼指数大于 4(变化于 4.2～ 5 .8之间 ) ,岩石的稀土总量 ((REE)变化于2 11× 10 -6～ 2 6 4× 10 -6之间 ,且与金矿床关系较密切。高钾钙碱性系列侵入岩岩石组合为闪长岩 +石英二长闪长岩 +花岗闪长岩 ,岩石的里特曼指数小于 4(1.8～ 3 .2 ) ,ΣREE为 130× 10 -6～ 188× 10 -6,与铜矿床关系较为密切。结合包体岩石学研究得出 ,橄榄安粗岩系列岩浆为幔源碱性基性岩浆分异的产物 ,高钾钙碱性系列岩浆是分异的幔源岩浆和壳源酸性岩浆混合的产物。     

东昆仑造山带花岗岩类Pb-Sr-Nd-O同位素特征

本文报道了东昆仑造山带三叠纪辉长岩、花岗岩类及其包裹体的Pb、Sr、Nd和O同位素组成。东昆仑造山带花岗质岩石全岩和长石Pb同位素组成相差不大，具明显的造山带Pb同位素特征；Sr同位素初始值(ISr)变化于0．70144～0．70972之间，暗示幔源成因；εNd值变化于-4．49939～-9．19258之间，具壳源成因特点；Nd同位素模式年龄(tDM)在1．38～1．761Ga之间，与中元古代变质岩相当；O同位素组成变化范围7．8～9．5，表明花岗岩类成岩物质主要来自地壳。综合岩石的同位素组成，结合矿物学、岩石地球化学的研究，表明花岗岩浆主要起源于地壳，但与来自地幔的基性岩浆曾发生过混合作用，从而导致同位素组成趋于一致。