污水-海水混合过程中磷转移的动力学

模拟研究厦门市污水排海时污水-海水混合过程中磷含量和形态的变化,及其在海水-颗粒物界面交换的动力学过程;提供转移模式,确定转移速率,进行磷的容量校正,为厦门西海域环境容量估算和水质控制提供定量参数和理论依据。     

An Approach to Stability Analysis of Embedded Large-Diameter Cylinder Quay

The large-diameter cylinder structure, which is made of large successive bottomless cylinders placed on foundation bed or partly driven into soil, is a recently developed retaining structure in China. It can be used in port, coastal and off-shore works. The method for stability analysis of the large-diameter cylinder structure, especially for stability analysis of the embedded large-diameter cylinder structure, is an important issue. In this paper, an idea is presented that is, em-bedded large-diameter cylinder quays can be divided into two types, i.e. the gravity wall type and the cylinder pile wall type. A method for stability analysis of the large-diameter cylinder quay of the cylinder pile wall type is developed and a method for stability analysis of the large-diameter cylinder quay of the gravity wall type is also proposed. The effect of sig-nificant parameters on the stability of the large-diameter cylinder quay of the cylinder pile wall type is investigated through numerical calculation.     

SOLID-LIQUID INTERFACE PROCESS OF HEAVY METALS IN THE CHANGJIANG ESTUARYKINETICS OF ADSORPTION OF Pb, Cu AND Cd ON HFO

The adsorption kinetics of Pb, Cu and Cd on hydrous ferrk oxide (HFO) has been approached in tthe simulated environmental conditions of the Changjiang Estuary. The forward adsorption rate constants of different systems under different temperatures have been determined, and the activation energies of the adsorption for Pb and Cu evaluated (Pb=7 kcal/mol, Cu= 11 kcal/mol). The results show that Pb and Cu are strongly adsorbed by HFO; the order of their adsorption rate is found to be Pb≥Cu≥Cd, which follows thte order of their theonody-namic equilibrium constants. It has been demonstrated that the surface exchange-adsorption is the determining step of the solid-liquid interface process. The field investigation results are theoretically explained by the kinetic mechanism.     

Sediment Transport in Rivers and Coastal Waters

Following Bagnold's approach, a relationship between sediment transport and energy dissipation is developed. The major assumption made in the study is that the near bed velocity plays a dominant role in the process of sediment transport. A general relationship between energy dissipation and sediment transport is first proposed. Then the equations for total sediment transport are derived by introducing the appropriate expression of energy dissipation rate under different conditions, such as open channel flows, combination of wave and current, as well as longshore sediment transport. Within the flows investigated, the derived relationships are fairly consistent with the available data over a wide range of conditions.     

Dynmnic Response Analysis for Embedded Large-Cylinder Breakwaters Under Wave Excitation

A numerical model is developed for dynamic analysis of large-cylinder breakwaters embedded in soft soil. In the model, the large cylinder is taken as a rigid body divided into elements and the soft soil is replaced by discrete 3D nonlinear spring-dashpot systems. The numerical model is used to simulate the dynamic response of a large-cylinder breakwater to breaking wave excitation. The effects of the dynamic stress-strain relationship models of the soil, the radius and embedded depth of the cylinder, the nonlinear behaviors of the soil, and the limit strength condition of the soil on the dynamic responses of the large-cylinder structure are investigated with an example given. It is indicated that the above-mentioned factors have significant effects on the dynamic responses of an embedded large cylinder breakwater under breaking wave excitation.     

建设杭州湾北岸滨海地区经济带的构想

分析杭州湾北岸滨海地区发展战略地位、机遇及其有关基本问题,论述该区经济与社会发展总体战略。     

钛胶海水提铀动力学研究Ⅱ——吸附机理的推断

海水提铀机理的研究,已逐渐受到重视,然而,至今研究还不是很深入,观点也各有差别.例如,Keen等[1]认为钛胶从海水中吸附铀是阳离子交换过程,即海水中的铀是UO₂2+离子的形式与钛胶进行交换;尾方升等[2]则倾向于阴离子吸着,即铀是以UO₂(CO₃)₃4-的形式被吸附.我们曾于1973年在海洋局系统的一次会议上提出阳离子给合交换的看法,并在后来的两次专业会议上予以补充发展.张正斌[3]认为是阳离子交换或一价阳离子失水络合.最近崔清晨[4]提出可能是UO₂(OH)₃-的络合吸附.根据几年来的工作,我们仍认为,钛胶从海水中的吸铀机理可能是一种阳离子形式的络合交换过程.     

中太平洋北部锰结核的地球化学

本文测定了中太平北部锰结核及其伴生沉积物Fe,Mn,Cu,Co,Ni,Pb和Zn等金属的含量,分析了各元素之间以及它们与沉积环境之间的相互关系.发现锰结核中Cu,Ni和Zn富集于Mn相,Co平Pb富集于Fe相.同相各元素之间有很好的正相关,不同相各元素之间有一定的负相关.Fe相元素可能主要来源于海水的缓慢沉积,Mn相元素可能来源于间隙水.     

乐清湾近期海岸演变研究

乐清湾是一个与东海相通的半封闭型强潮海湾。通过对1934,1968和1992年的海图对比研究表明:近期乐清湾各等深线所围水域面积持续减小。后一阶段,围垦使岸线推进速度加快,滩涂面积由前一阶段的不断增加转变为不断减小。1934到1968年,西南部最大潮滩华岐潮滩岸线和零米线平均外推速率分别为4.88m/a和13.24m/a;1968到1992年平均淤进速率分别为6.17m/a和8.08m/a。实地采样分析表明:表层水样平均悬沙浓度为0.1043kg/m3,从湾顶向湾口呈不断增加的趋势。悬沙浓度虽较低,但湾内处于低能动力沉积环境,有利于细颗粒沉积物落淤,这是湾内地貌演变的要因。长江入海南移和陆架区再悬浮的细颗粒物质是乐清湾主要的泥沙来源。泥沙自然淤积和人类活动影响是近期乐清湾大部分岸线处于淤进状态的原因。漩门二期工程前后乐清湾的纳潮量减小了5.73%,落潮流相对携沙能力降低为工程前的79%。而根据实测落潮平均流速计算得围垦后落潮流的相对携沙能力减弱为原来的54%。而从1934年到漩门二期围垦工程后,纳潮量减小了22.57%。开辟盐田和围垦造陆工程等人类活动,对海岸演变的影响显著。