Precipitation chemistry and ozone and sulfate concentrations in the ocean atmosphere observed by multi-year cruising in East Asia and West Oceania (35°N–35°S, 100–135°E) in August and September

A comprehensive study on the chemistry of deposition and the concentration of tropospheric ozone and particulate sulfate in the ocean atmosphere was carried out for the data sets in 1990’s. It is important to study the atmospheric situation over the past years as well as the latest, especially in the East Asian region where emission amount of anthropogenic air pollutants have increased year by year due to rapid economic growth. The survey was conducted for 5 years in East Asia and West Oceania (35°N–35°S, 100–135°E) in August and September in 1990’s. The purpose of the survey was to study and understand the chemistry of deposition and the concentration of tropospheric ozone and particulate sulfate in the ocean atmosphere comprehensively in one project. Rainfall over the ocean was insufficiently neutralized. Gas and aerosol over the ocean were mature, i.e., well-mixed, during the period of the transportation. The characteristic latitudinal dependence was observed in the tropospheric ozone concentration, namely, higher in the southern hemisphere and lower in the northern hemisphere (approximately 25 ppb in the 10–40°S region and 5–15 ppb in the 20–40°N region). On the other hand, high concentrations of tropospheric ozone of over 30 ppb were observed in the northern hemisphere, which was attributable to the long-range transportation. The TSP concentration was approximately under the level of 40 μg m^?3 irrespectively of the latitude; in contrast, the nss-SO₄ ^2- concentration showed a clear latitudinal dependence, i.e., higher in the northern hemisphere and lower in the southern hemisphere. The background levels of the nss-SO₄ ^2- concentration were approximately 0.5 μg m^?3 in the 10–40°S region and 2–3 μg m^?3 and 4–5 μg m^?3 in the 0–20°N and 20–40°N regions, respectively.     

Primary proton spectrum around the knee deduced from the emulsion-chamber data obtained at Mts. Fuji and Kanbala

We have done extensive Monte Carlo simulations using the new simulation codes of CORSIKA and COSMOS to compare with the gamma-family data obtained at Mts. Fuji (3750 m above sea level) and Kanbala (5500 m above sea level). Then, we estimated the primary proton and helium spectra around the knee energy region using a multiple-layered feed-forward neural network as a classifier of primary particle kind. The selection efficiency of proton-induced family events is estimated to be 82%. The flux value of protons at 2×10¹⁵ eV is (5.5±1.5)×10⁻¹⁴ (m⁻² s⁻¹ sr⁻¹ GeV⁻¹). The result suggests heavy-enriched primary composition around the knee region.     

Impact fragmentation experiments of basalts and pyrophyllites

Results of impact fragmentation experiments for basalts and pyrophyllites are reported. Aluminum cylindrical projectiles were impacted on cubic basalt and pyrophyllite targets at velocities of 70 to 990 m/sec. The targets and projectiles were 20 g to 3.3 kg and 2 to 20 g in weight respectively. Weights of the fragments produced by impacts were measured and the size distributions of fragments were examined. Data of the largest fragment mass (m_L) normalized to the original target mass (M_t), m_L/M_t, correlate better with the nondimensional impact stress, P_I, a new scaling parameter introduced by H. Mizutani, Y. Takagi, and S. Kawakami (1984, in preparation) than the conventional projectile's kinetic energy per unit target mass, E/M_t, used in the previous studies. All the m_L/M_t data for basalts obtained in the present study are summarized by m_L/M_t = 2.95 × 10^?2P_I^?1 where P_I = P₀L³/YR³, P₀ = peak shock pressure, L = projectile size, R = target size and Y = material strength of target. For aluminum targets, however, the m_L/M_t is 2.5 orders of magnitude larger than that for brittle targets at impacts with the same P_I. Size distributions of fragments expressed in a log N - log (m/M_t) diagram divided into three regimes bounded by two inflection points. In each regime the curve is expressed by $\text{N (>}\text{m}\text{M}{}_{\mathrm{t}}\text{) = A (}\text{m}\text{M}{}_{\mathrm{t}}\text{)}{}^{\mathrm{?a}}$. The slopes, a, of the log $\text{N -}\text{log}\text{(}\text{m}\text{M}{}_{\mathrm{t}}\text{)}$ curves in the regimes of a large and a medium size range are positively correlated with the nondimensional impact stress, P_I, and expressed as a = C₃ + a₃log P_I. The slopes, a, in the smallest size range are, on the other hand, nearly constant and have values of $\text{0.5}\text{to}\text{0.7 (}\text{1}\text{2}\text{?}\text{2}\text{3}\text{)}$. Present results indicate that the impact fragmentation is scaled well by the new scaling parameter, P_I, of Mizutani, Takagi, and Kawakami and that the present experimental data may shed new light on planetary impact processes.     

Petrographic and mineralogical study of hydrothermal alteration of the Rokko Granite at Hakusui-kyo and Horai-kyo along the Arima-Takatsuki Tectonic Line in western Japan

Field, hand specimen, and microscopic investigations alongside X-ray diffraction analyses revealed four types of hydrothermal alteration (Type-A, -B, -C, and -D) based on the mode of occurrence of altered rocks and alteration mineral assemblage at Hakusui-kyo and Horai-kyo along the Arima-Takatsuki Tectonic Line (ATTL) in western Japan. Type-A alteration locally occurred as gray alteration halos with sulfide minerals. Type-B and -C alterations were confined to fault gouge veins and occurred as greenish-gray veins and brown veins, respectively. Type-C alteration crosscut Type-B alteration. These alterations were associated with a number of granitic fragments including cohesive breccia and micrographic facies. Type-D alteration occurred locally in brown sediments. Different mineralogical features in the four alterations are summarized as (Type-A) illite; (Type-B) chlorite; (Type-C) limonite (Fe³⁺ hydroxides and goethite) and calcite; and (Type-D) limonite. We propose that the alterations can be broadly divided into Paleocene hydrothermal alteration (Type-A) and post-Late Miocene hydrothermal alteration (Type-B, -C, and -D): Type-A alteration occurred at approximately 200 °C during hydrothermal activity after a granitic intrusion in Late Cretaceous; Type-B, -C and -D alterations occurred under hydrothermal activity accompanying deep fluids with repeated ascents invoked by the seismicity of the ATTL after the Late Miocene. The fluids may have been the “Arima-type thermal waters” (i.e., mixtures of convective groundwater and Na-Ca-Cl-HCO₃-type fluids). Type-B alteration occurred in fractures at depths where the temperature was ≥150 °C. Type-C alteration overprinted Type-B alteration as a result of mixing of new deep fluids and descending oxidized meteoric water near the surface. Fe³⁺ hydroxides and calcite precipitated from the fluids due to the oxidation of Fe²⁺ and the degassing of CO₂, respectively, at ambient to near-boiling temperatures. When the ascending fluids gushed out from the fractures, they generated Type-D alteration at the surface under similar temperature conditions due to the oxidation of Fe²⁺.     

Out‐of‐plane stability of buckling‐restrained braces including moment transfer capacity

Buckling‐restrained braces (BRBs) are widely used as ductile seismic‐resistant and energy‐dissipating structural members in seismic regions. Although BRBs are expected to exhibit stable hysteresis under cyclic axial loading, one of the key limit states is global flexural buckling, which can produce an undesirable response. Many prior studies have indicated the possibility of global buckling of a BRB before its core yields owing to connection failure. In this paper, BRB stability concepts are presented, including their bending‐moment transfer capacity at restrainer ends for various connection stiffness values with initial out‐of‐plane drifts, and a unified simple equation set for ensuring BRB stability is proposed. Moreover, a series of cyclic loading tests with initial out‐of‐plane drifts are conducted, and the results are compared with those of the proposed equations. © 2013 The Authors. Earthquake Engineering & Structural Dynamics published by John Wiley & Sons Ltd.     

Deep water observations of extreme waves with moored and free GPS buoys

Point-positioning GPS-based wave measurements were conducted by deep ocean (over 5,000 m) surface buoys moored in the North West Pacific Ocean in 2009, 2012, and 2013. The observed surface elevation bears statistical characteristics of Gaussian, spectrally narrow ocean waves. The tail of the averaged spectrum follows the frequency to the power of ?4 slope, and the significant wave height and period satisfies the Toba’s 3/2 law. The observations compare well with a numerical wave hindcast. Two large freak waves exceeding 13 m in height were observed in October 2009 and three extreme waves around 20 m in height were observed in October 2012 and in January 2013. These extreme events are associated with passages of a typhoon and a mid-latitude cyclone. Horizontal movement of the buoy revealed that the orbital motion of the waves at the peak of the wave group mostly exceed the weakly nonlinear estimate. For some cases, the orbital velocity exceeded the group velocity, which might indicate a breaking event but is not conclusive yet.     

Lunar photometric properties at wavelengths 0.5-1.6 μm acquired by SELENE Spectral Profiler and their dependency on local albedo and latitudinal zones

The lunar photometric function, which describes the dependency of the observed radiance on the observation geometry, is used for photometric correction of lunar visible/near-infrared data. A precise photometric correction parameter set is crucial for many applications including mineral identification and reflectance map mosaics. We present, for the first time, spectrally continuous photometric correction parameters for both sides of the Moon for wavelengths in the range 0.5-1.6 μm and solar phase angles between 5° and 85°, derived from Kaguya (SELENE) Spectral Profiler (SP) data. Since the measured radiance also depends on the surface albedo, we developed a statistical method for selecting areas with relatively uniform albedos from a nearly 7000-orbit SP data set. Using the selected data set, we obtained empirical photometric correction parameter sets for three albedo groups (high, medium, and low). We did this because the photometric function depends on the albedo, especially at phase angles below about 20° for which the shadow hiding opposition effect is appreciable. We determined the parameters in 160 bands and discovered a small variation in the opposition effect due to the albedo variation of mafic mineral absorption. The consistency of the photometric correction was checked by comparing observations made at different times of the same area on the lunar surface. Variations in the spectra obtained were lower than 2%, except for the large phase angle data in mare. Lastly, we developed a correction method for low solar elevation data, which is required for high latitude regions. By investigating low solar elevation data, we introduced an additional correction method. We used the new photometric correction to generate a 1° mesh global lunar reflectance map cube in a wavelength range of 0.5-1.6 μm. Surprisingly, these maps reveal that high latitude (?75°) regions in both the north and south have much lower spectral continuum slopes (color ratio r_1547.7nm/r_752.8nm ? 1.8) than the low and medium latitude regions, which implies lower degrees of space weathering.     

Influence of fine sediment on the fluidity of debris flows

Debris flows include a great diversity of grain sizes with inherent features such as inverse grading, particle size segregation, and liquefaction of fine sediment. The liquefaction of fine sediment affects the fluidity of debris flows, although the behavior and influence of fine sediment in debris flows have not been examined sufficiently. This study used flume tests to detect the effect of fine sediment on the fluidity of laboratory debris flows consisting of particles with various diameters. From the experiments, the greatest sediment concentration and flow depth were observed in the debris flows mixed with fine sediment indicating increased flow resistance. The experimental friction coefficient was then compared with the theoretical friction coefficient derived by substituting the experimental values into the constitutive equations for debris flow. The theoretical friction coefficient was obtained from two models with different fine-sediment treatments: assuming that all of the fine sediments were solid particles or that the particles consisted of a fluid phase involving pore water liquefaction. From the comparison of the friction coefficients, a fully liquefaction state was detected for the fine particle mixture. When the mixing ratio and particle size of the fine sediment were different, some other cases were considered to be in a partially liquefied transition state. These results imply that the liquefaction of fine sediment in debris flows was induced not only by the geometric conditions such as particle sizes, but also by the flow conditions.