Benthic nutrient fluxes along the Laurentian Channel: Impacts on the N budget of the St. Lawrence marine system

Water column concentrations and benthic fluxes of dissolved inorganic nitrogen (DIN) and oxygen (DO) were measured in the Gulf of St. Lawrence and the Upper and Lower St. Lawrence Estuary (USLE and LSLE, respectively) to assess the nitrogen (N) budget in the St. Lawrence (SL) system, as well as to elucidate the impact of bottom water hypoxia on fixed-N removal in the LSLE. A severe nitrate deficit, with respect to ambient phosphate concentrations (N*∼−10 μmol L⁻¹), was observed within and in the vicinity of the hypoxic bottom water of the LSLE. Given that DO concentrations in the water column have remained above 50 μmol L⁻¹, nitrate reduction in suboxic sediments, rather than in the water column, is most likely responsible for the removal of fixed N from the SL system. Net nitrate fluxes into the sediments, derived from pore water nitrate concentration gradients, ranged from 190 μmol m⁻² d⁻¹ in the hypoxic western LSLE to 100 μmol m⁻² d⁻¹ in the Gulf. The average total benthic nitrate reduction rate for the Laurentian Channel (LC) is on the order of 690 μmol m⁻² d⁻¹, with coupled nitrification-nitrate reduction accounting for more than 70%. Using average nitrate reduction rates derived from the observed water column nitrate deficit, the annual fixed-N elimination within the three main channels of the Gulf of St. Lawrence and LSLE was estimated at 411 × 10⁶ t N, yielding an almost balanced N budget for the SL marine system.     

Calcite and aragonite precipitation from seawater solutions of various salinities: Precipitation rates and overgrowth compositions

The reaction rate and composition of calcite and aragonite overgrowths precipitated from seawater solutions of various salinities (i.e. S=5, 15, 25, 35, 44) were determined at 25°C and 10^−2.5-atm. CO₂ partial pressure using a constant disequilibrium seeded technique. The rate data were fitted to an empirical rate law of the form:

logR=n(ω_{c(or a)}-1)+logk

where n is the empirical reaction order; and k is the rate constant. Calcite precipitation rates in seawater solutions do not vary appreciably as a result of salinity variations over the range investigated, while those for aragonite show an increase in going from the higher (i.e. S=35, 44) to the lower (i.e. S=5, 15, 25) salinity range. This study also confirms previously published findings that above a given saturation state (i.e. Ω_c>/2.6) aragonite precipitates more rapidly than calcite at 25°C.

The incorporation of Sr²⁺ in aragonite and Mg²⁺ in calcite overgrowths are independent of the precipitation rate. The partition coefficient of Sr²⁺ in aragonite is approximately equal to unity and is unaffected by salinity variations between 5 and 44. However, the Mg²⁺ partition coefficient in calcite, increases with decreasing salinity of the parent seawater solutions, possibly as a result of variations in the sulfate content of the solutions and solids.

The experimental results were discussed in the context of a number of geological environments.     

Approaches to analyse and model changes in impacts: reply to discussions of “How to improve attribution of changes in drought and flood impacts”*

ABSTRACT

We thank the authors, Brunella Bonaccorso and Karsten Arnbjerg-Nielsen for their constructive contributions to the discussion about the attribution of changes in drought and flood impacts. We appreciate that they support our opinion, but in particular their additional new ideas on how to better understand changes in impacts. It is great that they challenge us to think a step further on how to foster the collection of long time series of data and how to use these to model and project changes. Here, we elaborate on the possibility to collect time series of data on hazard, exposure, vulnerability and impacts and how these could be used to improve e.g. socio-hydrological models for the development of future risk scenarios.     

Organic carbon isotope ratios of recent sediments from coastal lagoons of the Gulf of Mexico,Mexico

The stable carbon isotope composition sedimentary organic carbon was determined in the sediments of seven coastal lagoons of the Gulf of Mexico, Mexico. For most of the lagoons the δ¹³C values for sediments ranged from ?20.1 to ?23.9%. Anomalously low values, ?26.8 to 29.3%. were determined in sediments of two of the studied lagoons, probably due to the presence of organic carbon from anthropogenic sources, naturally absent in these environments. The δ¹³C values determined in the tissues of oysters collected at the same time in the different lagoons were very similar to those recorded in the sediments.     

The ignored but common nemertine Psammamphiporus elongatus from the Galician beaches (Spain), affected by the Prestige oil spill

Nemerteans have been recorded in several studies of the sandy beaches, but usually these specimens have been only regarded as members of the Phylum, with no attempt at identification at any taxonomic level. This lack of identification is partly because of the sampling procedures used to collect beach macroinfauna. Nemerteans are fragile and need special care. They must be isolated and observed in vivo before using histological procedures, which must be employed for the taxonomical studies. This study deals with a sandy beach hoplonemertean, Psammamphiporus elongatus ( Stephenson 1911 ), only known for seven specimens from the Firth of Clyde (UK). This species is recorded for the first time from the Galician sandy beaches (NW Spain) where it reaches its maximum abundance. The species is described and illustrated and new data on its morphology and ecology are provided. The species was apparently affected by the 'Prestige' oil spill, and would be a good indicator of beach quality.     

Meteorites at Meridiani Planum provide evidence for significant amounts of surface and near‐surface water on early Mars

Abstract– Six large iron meteorites have been discovered in the Meridiani Planum region of Mars by the Mars Exploration Rover Opportunity in a nearly 25 km‐long traverse. Herein, we review and synthesize the available data to propose that the discovery and characteristics of the six meteorites could be explained as the result of their impact into a soft and wet surface, sometime during the Noachian or the Hesperian, subsequently to be exposed at the Martian surface through differential erosion. As recorded by its sediments and chemical deposits, Meridiani has been interpreted to have undergone a watery past, including a shallow sea, a playa, an environment of fluctuating ground water, and/or an icy landscape. Meteorites could have been encased upon impact and/or subsequently buried, and kept underground for a long time, shielded from the atmosphere. The meteorites apparently underwent significant chemical weathering due to aqueous alteration, as indicated by cavernous features that suggest differential acidic corrosion removing less resistant material and softer inclusions. During the Amazonian, the almost complete disappearance of surface water and desiccation of the landscape, followed by induration of the sediments and subsequent differential erosion and degradation of Meridiani sediments, including at least 10–80 m of deflation in the last 3–3.5 Gy, would have exposed the buried meteorites. We conclude that the iron meteorites support the hypothesis that Mars once had a denser atmosphere and considerable amounts of water and/or water ice at and/or near the surface.