磷处理粉煤灰可作农业土壤磷源

粉煤灰(简称CCP或ash)具有改良土壤,增加植物产量的功能。此外,由于它特殊的多孔结构,也可用作吸纳并承载植物养分的载体。用NaH2PO4配制成含磷0.10mol/L浓度的溶液,对采自加拿大西安大略省Sarnia地区Lambton电厂的底灰(bottomash)进行振荡浸渍处理。结果表明,振荡浸渍66h后的粉煤灰中磷含量可达784×10-6。以磷处理粉煤灰、未进行磷处理的粉煤灰和石英砂按比例混合,作为基本生长介质进行玉米种植实验,其中实验配方设计为生长介质中含磷量分别为标准含磷浓度(50×10-6)的10%、25%、50%、75%和100%。生长26、34和46d后分别与不含磷的空白配方、施加含氮-磷-钾为0-20-0标准磷肥并控制磷含量为标准浓度(50×10-6)配方进行生物产量对比。生长实验结果表明,以磷处理粉煤灰供磷的生长介质,当含磷量为标准浓度的25%至100%时,其植物生长量就比添加标准浓度磷肥的配方好。种植46d后的生物生长量统计结果显示,含磷分别为标准浓度50%、75%和100%的实验介质中,玉米杆的鲜重较施标准磷肥介质中玉米分别增长39.46%、42.73%和46.13%;玉米杆干重依次增加29.71%、13.39%和28.87%;根鲜重平均增加16.62%;根干重平均增加14.03%。上述实验结果启示,粉煤灰可以很好地吸纳承载磷养分,并持续供给植物吸收生长,如果采用吸纳磷(或其他养分)的粉煤灰改良砂质土壤将有重要意义。     

A robust-symmetric mean: A new way of mean calculation for environmental data

Environmental data seldom follow normal distributions, so how to calculate their means is a very important problem. Commonly used methods for mean calculation, such as arithmetic mean, geometric mean, and median, were evaluated. Arithmetic means should only be used when datasets follow normal distributions. Geometric means are suitable for datasets which follow log-normal distributions. Medians are a kind of robust treatment. However, their efficiency is very low. Based on the methods described, two new ideas are developed: robust and symmetric, for calculating means. As far as the symmetric feature is concerned, Box-Cox power transformation is better than logarithmic transformation. Robust statistics and Box-Cox transformation are combined to produce the robust-symmetric mean. As environmental data often follow log-normal or skewed distributions, this method is better than the previous ones and also is appropriate.     

坡地农林复合系统的结构类型与效益分析─以长江三峡库区坡地农业为例

本义认为现代术语的农林复合系统来源于生产实践,体现了农业与林业的有机结合、品种生态和经济的有机结合、产品多样化以及管理科学化4个方面相统一的特点。文章在分析三峡库区农林复合系统的类型结构基础上,提出了农林复合系统可以进行层次结构划分的观点。最后,以典型案例研究方法入手,对1种农林结构类型进行效益分析,结果表明,采用植物篱农林复合坡地系统,是现阶段生产力水平下实现坡地生态经济协调发展的有效途径,值得广泛推广。     

黑龙江省与呼伦贝尔盟土地类型的划分及其分布规律

本文就土地研究的几个主要概念,即土地、土地分类、土地分级作了简要讨论,并结合黑龙江省及呼伦贝尔盟的具体条件,对为农、林、牧业服务的土地分类原则进行了初步探讨,还拟订了该区土地分级系统——土地类和土地型,及适合于大比例尺制图的土地组。在此基础上,将全区分为18个土地类、71个土地型。文章还从水平带性、垂直带性和土地结构三个方面,介绍了该区土地类型分布的一般规律。     

论Eppley PIR精密红外辐射仪的测量精度

本文依据红外辐射表(PIR)的结构、性能和工作原理讨论了测量精度及有关影响因素,比较了粗测和精测两种方法的特点,在此基础上提出了各测量方法的适用范围和精度范围以及提高测量精度的措施,同时也给出了一些特定场合下的测量实例及提高测量精度的具体方法。分析表明:精测方法具有很好的测量精度以及很强的环境适应性。粗测在限定的温度范围内具有测量简单、换算方便、易于实现自动化等优点,精度尚能满足一般要求,但在限定的温度范围以外,测量精度急剧恶化。在影响测量精度的各因素中以温度响应中表体热辐射测量的影响最大,在粗测方法中表内电池的性能与测量精度关系重大。强烈日射对测量精度有一定影响,经订正后可基本消除。     

Increasing critical sensitivity of the Load/Unload Response Ratio before large earthquakes with identified stress accumulation pattern

The Load/Unload Response Ratio (LURR) method is proposed for short-to-intermediate-term earthquake prediction [Yin, X.C., Chen, X.Z., Song, Z.P., Yin, C., 1995. A New Approach to Earthquake Prediction — The Load/Unload Response Ratio (LURR) Theory, Pure Appl. Geophys., 145, 701–715]. This method is based on measuring the ratio between Benioff strains released during the time periods of loading and unloading, corresponding to the Coulomb Failure Stress change induced by Earth tides on optimally oriented faults. According to the method, the LURR time series usually climb to an anomalously high peak prior to occurrence of a large earthquake. Previous studies have indicated that the size of critical seismogenic region selected for LURR measurements has great influence on the evaluation of LURR. In this study, we replace the circular region usually adopted in LURR practice with an area within which the tectonic stress change would mostly affect the Coulomb stress on a potential seismogenic fault of a future event. The Coulomb stress change before a hypothetical earthquake is calculated based on a simple back-slip dislocation model of the event. This new algorithm, by combining the LURR method with our choice of identified area with increased Coulomb stress, is devised to improve the sensitivity of LURR to measure criticality of stress accumulation before a large earthquake. Retrospective tests of this algorithm on four large earthquakes occurred in California over the last two decades show remarkable enhancement of the LURR precursory anomalies. For some strong events of lesser magnitudes occurred in the same neighborhoods and during the same time periods, significant anomalies are found if circular areas are used, and are not found if increased Coulomb stress areas are used for LURR data selection. The unique feature of this algorithm may provide stronger constraints on forecasts of the size and location of future large events.     

The Wuchiapingian–Changhsingian boundary (Upper Permian) at Meishan of Changxing County, South China

Section D at Meishan, Changxing County in the Zhejiang Province, China, has been extensively studied in various aspects of the stratigraphy during the past 20 years. It was ratified by the International Union of Geological Sciences (IUGS) as the Global Standard Stratotype Section and Point (GSSP) for the Permian–Triassic boundary in 2000, and is also a potential stratotype for the Wuchiapingian–Changhsingian boundary. However, the contact relationship between the Longtan (Wuchiapingian) and Changxing (Chainghsingian) formations has been a controversial subject for years. Recent studies on Section C, about 300 m west of Section D, at Meishan confirm a complete depositional succession around the boundary and suggest that the proposed boundary level, the FAD of Clarkina wangi within the lineage from C. longicuspidata to C. wangi, is consistent with the first appearance of the index Changhsingian fusulinid Palaeofusulina sinensis and tapashanitid ammonoids.     

The Ore-forming Fluid of the Gold Deposits of Muru Gold Belt in Eastern Shandong, China - a Case Study of Denggezhuang Gold Deposit

Abstract. Denggezhuang gold deposit is an epithermal gold‐quartz vein deposit in northern Muru gold belt, eastern Shandong, China. The deposit occurs in the NNE‐striking faults within the Mesozoic granite. The deposit consists of four major veins with a general NNE‐strike. Based on crosscutting relationships and mineral parageneses, the veins appear to have been formed during the same mineralization epochs, and are further divided into three stages: (1) massive barren quartz veins; (2) quartz‐sulfides veins; (3) late, pure quartz or calcite veinlets. Most gold mineralization is associated with the second stage. The early stage is characterized by quartz, and small amounts of ore minerals (pyrite), the second stage is characterized by large amounts of ore minerals. Fluid inclusions in vein quartz contain C‐H‐O fluids of variable compositions. Three main types of fluid inclusions are recognized at room temperature: type I, two‐phase, aqueous vapor and an aqueous liquid phase (L+V); type II, aqueous‐carbonic inclusions, a CC₂‐liquid with/without vapor and aqueous liquid (LCO₂+VCC₂+Laq.); type III, mono‐phase aqueous liquid (Laq.). Data from fluid inclusion distribution, microthermometry, and gas analysis indicate that fluids associated with Au mineralized quartz veins (stage 2) have moderate salinity ranging from 1.91 to 16.43 wt% NaCl equivalent (modeled salinity around 8–10 wt% NaCl equiv.). These veins formatted at temperatures from 80d? to 280d?C. Fluids associated with barren quartz veins (stage 3) have a low salinity of about 1.91 to 2.57 wt% NaCl equivalent and lower temperature. There is evidence of fluid immiscibility and boiling in ore‐forming stages. Stable isotope analyses of quartz indicate that the veins were deposited by waters with δ^O and δD values ranging from those of magmatic water to typical meteoric water. The gold metallogenesis of Muru gold belt has no relationship with the granite, and formed during the late stage of the crust thinning of North China.     

Mineral and fluid inclusions in zircon of UHP metamorphic rocks from the CCSD-main drill hole: A record of metamorphism and fluid activity

The Chinese Continental Scientific Drilling (CCSD) main drill hole (0–3000 m) in Donghai, southern Sulu orogen, consists of eclogite, paragneiss, orthogneiss, schist and garnet peridotite. Detailed investigations of Raman, cathodoluminescence, and microprobe analyses show that zircons from most eclogites, gneisses and schists have oscillatory zoned magmatic cores with low-pressure mineral inclusions of Qtz, Pl, Kf and Ap, and a metamorphic rim with relatively uniform luminescence and eclogite-facies mineral inclusions of Grt, Omp, Phn, Coe and Rt. The chemical compositions of the UHP metamorphic mineral inclusions in zircon are similar to those from the matrix of the host rocks. Similar UHP metamorphic P–T conditions of about 770 °C and 32 kbar were estimated from coexisting minerals in zircon and in the matrix. These observations suggest that all investigated lithologies experienced a joint in situ UHP metamorphism during continental deep subduction. In rare cases, magmatic cores of zircon contain coesite and omphacite inclusions and show patchy and irregular luminescence, implying that the cores have been largely altered possibly by fluid–mineral interaction during UHP metamorphism.

Abundant H₂O–CO₂, H₂O- or CO₂-dominated fluid inclusions with low to medium salinities occur isolated or clustered in the magmatic cores of some zircons, coexisting with low-P mineral inclusions. These fluid inclusions should have been trapped during magmatic crystallization and thus as primary. Only few H₂O- and/or CO₂-dominated fluid inclusions were found to occur together with UHP mineral inclusions in zircons of metamorphic origin, indicating that UHP metamorphism occurred under relatively dry conditions. The diversity in fluid inclusion populations in UHP rocks from different depths suggests a closed fluid system, without large-scale fluid migration during subduction and exhumation.     

Equation of state of MgGeO3 perovskite to 65 GPa: comparison with the post-perovskite phase

The equation of state of MgGeO₃ perovskite was determined between 25 and 66 GPa using synchrotron X-ray diffraction with the laser-heated diamond anvil cell. The data were fit to a third-order Birch–Murnaghan equation of state and yielded a zero-pressure volume (V ₀) of 182.2 ± 0.3 Å³ and bulk modulus (K ₀) of 229 ± 3 GPa, with the pressure derivative (K′₀ = (?K ₀/?P) _T ) fixed at 3.7. Differential stresses were evaluated using lattice strain theory and found to be typically less than about 1.5 GPa. Theoretical calculations were also carried out using density functional theory from 0 to 205 GPa. The equation of state parameters from theory (V ₀ = 180.2 Å³, K ₀ = 221.3 GPa, and K′₀ = 3.90) are in agreement with experiment, although theoretically calculated volumes are systematically lower than experiment. The properties of the perovskite phase were compared to MgGeO₃ post-perovskite phase near the observed phase transition pressure (～65 GPa). Across the transition, the density increased by 2.0(0.7)%. This is in excellent agreement with the theoretically determined density change of 1.9%; however both values are larger than those for the (Mg,Fe)SiO₃ phase transition. The bulk sound velocity change across the transition is small and is likely to be negative [?0.5(1.6)% from experiment and ?1.2% from theory]. These results are similar to previous findings for the (Mg,Fe)SiO₃ system. A linearized Birch–Murnaghan equation of state fit to each axis yielded zero-pressure compressibilities of 0.0022, 0.0009, and 0.0016 GPa^?1 for the a, b, and c axis, respectively. Magnesium germanate appears to be a good analog system for studying the properties of the perovskite and post-perovskite phases in silicates.