Pressure dependence of viscosity of rhyolitic melts

Viscosity of silicate melts is a critical property for understanding volcanic and igneous processes in the Earth. We investigate the pressure effect on the viscosity of rhyolitic melts using two methods: indirect viscosity inference from hydrous species reaction in melts using a piston cylinder at pressures up to 2.8 GPa and direct viscosity measurement by parallel-plate creep viscometer in an internally-heated pressure vessel at pressures up to 0.4 GPa. Comparison of viscosities of a rhyolitic melt with 0.8 wt% water at 0.4 GPa shows that both methods give consistent results. In the indirect method, viscosities of hydrous rhyolitic melts were inferred based on the kinetics of hydrous species reaction in the melt upon cooling (i.e., the equivalence of rheologically defined glass transition temperature and chemically defined apparent equilibrium temperature). The cooling experiments were carried out in a piston-cylinder apparatus using hydrous rhyolitic samples with 0.8-4 wt% water. Cooling rates of the kinetic experiments varied from 0.1 K/s to 100 K/s; hence the range of viscosity inferred from this method covers 3 orders of magnitude. The data from this method show that viscosity increases with increasing pressure from 1 GPa to 3 GPa for hydrous rhyolitic melts with water content ?0.8 wt% in the high viscosity range. We also measured viscosity of rhyolitic melt with 0.13 wt% water using the parallel-plate viscometer at pressures 0.2 and 0.4 GPa in an internally-heated pressure vessel. The data show that viscosity of rhyolitic melt with 0.13 wt% water decreases with increasing pressure. Combining our new data with literature data, we develop a viscosity model of rhyolitic melts as a function of temperature, pressure and water content.     

新疆阿勒泰市阿巴宫铁矿磷灰石微量和稀土元素特征及矿床成因探讨

阿巴宫铁矿床产于阿尔泰南缘晚志留世-早泥盆世的酸性火山岩中.矿体呈透镜状、脉状及似层状,受火山断裂构造控制,与围岩界线清楚;围岩蚀变不很发育,矿石品位较高;磷灰石与磁铁矿共生.其特征可以与瑞典北部Kiruna型铁矿床、宁芜玢岩铁矿床等进行对比.对阿巴宫铁矿床两个不同矿区磷灰石的稀土元素及微量元素组成的分析结果表明,磷灰石中∑REE变化于1352.96×10-6～6986.33×10-6之间,平均值为3717.70×10-6; (La/Yb)N比值变化于1.37～9.77之间,平均值5.22;δEu范围在0.22～0.30之间,平均值0.25;以轻稀土元素富集、轻重稀土元素分馏较弱和Eu的显著负异常为特征,与瑞典北部Kiruna型铁矿床、宁芜玢岩铁矿床相一致,表明阿巴宫铁矿床与上述铁矿床成因相同,均属岩浆分异成因.变质流纹岩稀土元素分布曲线形态与磷灰石的非常相似,微量元素特征也基本一致,表明铁的成矿作用与花岗质岩浆的分异-矿浆侵入有关.      

磷对过铝质岩浆液相线温度影响的实验研究

以宜春414岩体中的钠长花岗岩作为实验初始物,利用"RQV-快速内冷淬火"高温高压装置实验研究了100MPa压力、含5%H2O条件下,P对过铝质花岗岩液相线温度的影响.实验结果表明,碱性长石是最早结晶的矿物;随着体系中P2O5含量从0.27%增加到7.71%,液相线温度从最初的810℃降低到740℃,表明P有效地降低了过铝质岩浆体系的液相线温度.在过铝质岩浆体系中,P5+与Al3+的结合形成AlPO4,降低了熔体中碱性长石组分的活度,很可能是液相线温度降低的机制.     

西江干流河水主要离子及锶同位素地球化学组成特征

水环境中锶（Sr）含量及其同位素组成特征的研究有助于认识区域水文地球化学特征及流域盆地岩石风化速率等地球化学行为,因此河流环境中Sr的地球化学行为是地球化学研究的重要课题之一。对中国南方西江干流及其支流河水主要阴阳离子及sr同位素组成进行了分析,发现其水化学组成主要以Ca^2＋、Mg^2＋、HCO3^-和SO4^2-离子为主,分别占阴阳离子组成的80％以上。郁江河水具有较高的Sr同位素比值（^87St／^86Sr=0．71049）和较低的Sr含量（0．0263mg／L）,而西江河水具有较低的Sr同位素比值以及较高的Sr含量,其Sr含量变化范围在0．0667．0．187mg／L之间,平均含量为0．136mg／L;Sr同位素比值变化范围在0．70856．0．70936之间,平均比值为0．70894。与世界主要河流水体中Sr含量平均值（0．078mg／L）及Sr同位素比值（^87Sr／^86Sr=0．7119）相比,西江干流水体具有较高的Sr含量及较低的Sr同位素比值。两条河流河水中主要离子及Sr的来源存在显著差异,西江干流河水中的主要溶解离子及Sr同位素主要源于碳酸盐岩（石灰岩和白云岩）的风化作用,主要受黔江及其上游红水河等化学组成所控制,而郁江则主要受碎屑岩风化作用的影响;同时,中上游地区的酸沉降及人类活动的输入可能导致西江干流水体受到一定程度的污染,而郁江受污染程度则相对较小。     

新疆西准噶尔地区赞岐岩（sanukite）的地球化学特征、成因机制及其与铜金矿化的关系

西准噶尔地区广泛发育高镁质闪长质岩墙。对全岩样品的Ar-Ar测年获得了321Ma的坪年龄,显示其主要形成于石炭纪末。这些岩墙样品以富Si（SiO2 52．3％～56．9％）、Mg（Mg〉60）、Cr（134—204μg／g）、Ni（59,141μg／g）、Sr（468～724pg／g）、Ba（316～676μg／g）为特征且K／Na比值在0．38—0．63之间,类似于日本中新世Setouehi火山岩带中的赞岐岩。这些岩墙大多具有不同程度的Eu正异常并具有高的Ba／La比值（27～124）,反映其主要来自消减带环境下受流体交代的地幔源区的部分熔融。赞岐岩和区内同时代埃达克质岩石的共生组合意味着该区在晚石炭世末曾受到热消减机制的影响。这种热的洋壳俯冲机制,不仅在石炭纪末期产生了大量的岩浆活动,而且也导致了铜金等成矿元素的富集。深入了解赞岐岩-埃达克岩共生组合与铜金矿化之间的密切关系将有助于正确评价区内成矿潜力。     

金川铜镍矿床成矿模式、控矿因素分析与找矿

金川岩浆Cu-Ni-PGE硫化矿床与世界上其它几个大型硫化铜镍矿相比,具有矿化比例极高,岩体的岩相分带和矿体产状与原地熔离机制不协调等地质和成因特点.论文通过对金川铜镍矿地质构造及矿化特征、成矿模式系统分析,指出金川铜镍硫化物矿床形成和定位的主要控制因素表现为:同源岩浆控制和后期构造控制.侵入体成矿后期的构造变形对矿化的控制主要表现在对侵入体形态产状的改变,并影响到矿区深部、外围及区域矿化及分布特征,因而对矿区深部、外围及区域找矿具有指示意义.据此提出了矿区深部、外围及区域找矿新思路,并在矿床外围及区域与龙首山隆起平行的金川超镁铁岩带确定了两个勘探靶区一金川东延靶区和金川远东靶区.     

Understanding the dynamical-microphysical-electrical processes associated with severe thunderstorms over the Beijing metropolitan region

The Dynamical-microphysical-electrical Processes in Severe Thunderstorms and Lightning Hazards(STORM973)project conducted coordinated comprehensive field observations of thunderstorms in the Beijing metropolitan region(BMR)during the warm season from 2014 to 2018.The aim of the project was to understand how dynamical,microphysical and electrical processes interact in severe thunderstorms in the BMR,and how to assimilate lightning data in numerical weather prediction models to improve severe thunderstorm forecasts.The platforms used in the field campaign included the Beijing Lightning Network(BLNET,consisting of 16 stations),2 X-band dual linear polarimetric Doppler radars,and 4 laser raindrop spectrometers.The collaboration also made use of the China Meteorological Administration’s mesoscale meteorological observation network in the Beijing-Tianjin-Hebei region.Although diverse thunderstorm types were documented,it was found that squall lines and multicell storms were the two major categories of severe thunderstorms with frequent lightning activity and extreme rainfall or unexpected local short-duration heavy rainfall resulting in inundations in the central urban area,influenced by the terrain and environmental conditions.The flash density maximums were found in eastern Changping District,central and eastern Shunyi District,and the central urban area of Beijing,suggesting that the urban heat island effect has a crucial role in the intensification of thunderstorms over Beijing.In addition,the flash rate associated with super thunderstorms can reach hundreds of flashes per minute in the central city regions.The super(5%of the total),strong(35%),and weak(60%)thunderstorms contributed about 37%,56%,and 7%to the total flashes in the BMR,respectively.Owing to the close connection between lightning activity and the thermodynamic and microphysical characteristics of the thunderstorms,the lightning flash rate can be used as an indicator of severe weather events,such as hail and short-duration heavy rainfall.Lightning data can also be assimilated into numerical weather prediction models to help improve the forecasting of severe convection and precipitation at the cloud-resolved scale,through adjusting or correcting the thermodynamic and microphysical parameters of the model.     

高分七号卫星双波束激光测高仪在轨几何检校与试验验证

高分七号卫星装载了国内首台双波束对地观测激光测高仪,用于辅助两线阵光学相机实现1:1万立体测图.由于卫星发射时的振动及入轨后空间环境变化,激光测高仪在轨指向等参数相对于实验室标定值发生较大偏移,直接影响激光测高精度.针对高分七号双波束激光测高仪,本文提出了由粗到精的"两步法"在轨几何检校方案.首先,构建单波束激光在轨几何检校模型,基于特殊波形分析来估算激光足印落点位置信息,实现单波束激光指向粗检校;然后,以单波束激光在轨几何检校模型为基础,构建双波束激光在轨几何检校模型,在大气延迟改正、潮汐改正等基础上,采用地面探测器阵列捕获光斑,实现双波束激光指向测距联合检校.最后,采用平静湖面上的激光测高数据和地面控制数据,分别验证激光检校后相对和绝对高程测量精度.试验结果表明:高分七号卫星激光高程测量相对精度优于0.06 m(1σ),平坦地区的绝对测高精度达到0.10m(1σ).     

无/缺水下地形数据的高原堰塞湖水量遥感估算

水量遥感动态监测对于高原堰塞湖风险评估、预报预警和处置决策等具有重要意义。针对高原无资料或缺资料区,充分利用空天遥感技术,文章提出了一种无/缺水下地形数据的高原堰塞湖水量遥感定量估算方法。该方法首先通过遥感水域面积提取,获取堰塞湖淹没空间范围;进而采用不规则复杂多边形中线定位算法,确定堰塞湖中心线位置;然后基于河道中心特定点高程信息,结合局部河道比降估算,生成堰塞湖水下地形河道中线约束因子;再根据河道边坡高程信息和水下地形约束因子自适应拟合出局部堰塞河道的水下未知地形;最后通过三维曲面离散积分实现堰塞湖水量遥感动态定量估算。实验以东帕米尔高原的萨雷兹堰塞湖为研究区,展开遥感水量调查与局部验证研究,结果表明:萨雷兹堰塞湖当前水域面积约为89.09 km²,水量约为162.49亿m³;这一结果与专家预估的水资源量155—165亿m³基本吻合。经局部模拟实验精度对比验证,模拟结果与实际数据动态误差总体控制在10%以内,相关系数达到0.95(P<0.01,双尾),进一步证明了算法的鲁棒性和估算结果的可信度。为无/缺水下地形数据的高原堰塞湖水量遥感估算提供了一种有效的方法,实现了水下地形未知的高原堰塞湖水量遥感快速反演与定量测算。