富P过铝质岩浆体系的研究现状及存在的问题

高度演化的富P过铝质岩浆体系,具有鲜明的、不同于其他体系的地球化学行为.富P过铝质熔体以富P,高ASI,贫Fe、Mg、Ca,强烈亏损REE、Th、Y以及具有W、Sn、Nb、Ta等金属的矿化为特征.富P过铝质岩浆体系中的碱性长石为富P长石,长石中P可以有效地指示过铝质岩浆体系的演化历程;在岩浆演化的晚期,P与Li具强的亲和性,形成锂辉石-磷铝锂石-羟磷铝锂石的组合.已有的实验研究揭示,P能降低简单花岗岩的液相线和固相线温度、粘度以及增加H2O在熔体中的溶解度.然而,这一体系还存在许多问题亟待研究,P能否促进过铝质岩浆的液态不混溶,能否促使等价不相容元素在过铝质岩浆演化过程中的分异,是否在稀有金属成矿过程中起作用等都是值得关注的问题.     

富氟花岗岩中萤石岩浆成因的新证据

通过富氟花岗岩-HF-H2O体系的熔化-结晶实验,在620～700℃、1×108Pa条件下获得了石英+碱性长石+黄玉+云母+萤石的矿物组合.在该实验体系中首次发现了八面体萤石.实验结果表明,在岩浆条件下可以形成萤石,从而为富氟花岗岩中萤石的岩浆成因提供了新证据.     

花岗岩体系Qz-Or-Ab-An-H_2O的初熔

本文采用石英和人工合成长石的混合物配制成的原料在P_(H2O)=2～15千巴的压力范围内进行了Qz-Or-Ab-H_2O体系初熔的反演。在无钙长石的碱性长石花岗岩体系Qz-Or-Ab-H_2O中,其熔融温度随着增压,从2千巴时的690℃降低到17千巴时的630℃。在花岗岩体系Qz-Or-Ab-An-H_2O中,随着钙长石含量的增加其固相线温度的升高是非常小的。与碱性长石花岗岩体系相比较,如果钠长石被斜长石An20(An40)代替,其固相线温度升高3℃(7°D)。碱性长石花岗岩体系和石英—钙长石—透长石组合(Qz-Or-An-H_2O体系)的固相线温度间的差别接近50℃。随着水压增高,斜长石及斜长石—碱性长石组合就变得不稳定,并分别被黝帘石+蓝晶石+石英和黝帘石+白云母-钠云母_(固溶体)+石英代替。并发现这些组合的压力稳定范围在600℃时介于6和16千巴之间。在高水压条件下(10～18千巴)。黝帘石-白云母-石英组合稳定到700和720℃。这个组合的固相线在透长石-黝帘石-白云母-石英混合物开始熔融温度以上10～20℃。为产生足够量的熔体,把变质岩变成岩浆岩状的岩石所需要水量只是非常少的。在层状混合岩的情况下证明,1％的水(或甚至更少)就足以使片麻岩局部转变为(岩浆状的)浅色部分,高级变质岩石或许是比较干的,而花岗岩质和花岗闪长岩质成分的重熔岩浆通常处于水不饱和状态。     

过铝质岩浆-热液演化体系中磷的地球化学行为

泥质岩部分熔融产生的过铝质岩浆中的P2O5含量受控于源区磷灰石含量、部分熔融程度和岩浆中磷灰石的溶解度.过铝质岩浆中的Ca、REE以及Y的活度低,阻碍了磷灰石、独居石以及磷钇矿等的结晶,碱性长石成为过铝质岩浆中P的主要寄主矿物,直到岩浆演化晚期,Li的活度增大,P才与Li形成磷铝锂石-羟磷铝锂石.进入以晶体、熔体和流体相共存为特征的岩浆-热液过渡阶段体系后,P的地球化学行为主要受流体/熔体相分配的制约,P优先进入到熔体相, 不太可能形成富P的流体.在热液阶段,长石晶体在Al-Si有序化过程中释放的结构P与流体介质所携带的Ca离子形成次生磷灰石.在热液蚀变过程中所形成的富P流体,很可能是某些Sn、W、Mn和U热液矿床的主要载体.     

100MPa、800℃下磷对铌锰矿和钽锰矿在简单花岗质熔体中溶解度影响的实验研究

选取人工合成的简单花岗岩玻璃以及铌锰矿和钽锰矿晶质矿物作为实验初始物,实验研究了100MPa、800℃条件下铌锰矿和钽锰矿在水饱和(或近水饱和)的无磷和含磷简单花岗质熔体中的溶解度。实验结果显示,在过碱质熔体中铌锰矿和钽锰矿的溶解度远高于它们在准铝质和过铝质熔体中的溶解度,但两者之间的溶解度相差不大;在准铝质和过铝质熔体中,铌锰矿的溶解度要明显低于钽锰矿。在过碱质熔体中,铌锰矿、钽锰矿的溶解度与体系中P2O5的含量存在负的线性相关性,即lgKspNb=-0.29×P2O5-2.05(R2=0.96)和1gKspTa=-0.29×P2O5-1.79(R22=0.98);在准铝质熔体中,铌锰矿、钽锰矿的溶解度则随体系中P2O5含量的增大呈逐渐升高趋势;在过铝质熔体中,铌锰矿、钽锰矿的溶解度随体系中P205的含量增大,先表现为降低的趋势,但是当P2O5的含量大于约3%时铌锰矿、钽锰矿的溶解度在误差范围内随P205含量的升高基本保持恒定。上述实验结果产生的主要原因很可能与铌、钽在硅酸盐熔体中的溶解机制以及磷在不同化学组成的硅酸盐熔体中不同的结构作用有关。     

花岗岩+P2O5-H2O体系中W、Sn、Be、Nb、Ta在流体/熔体间分配的实验研究

实验研究了W、Sn、Be、Nb、Ta在不同压力(150 MPa、100MPa和50 MPa)、温度(850℃和800℃)条件下,于水饱和含P过铝质岩浆体系(P2O5分别为0.32%、1.98%、4.91%和7.78%)中流体-熔体间的分配.研究结果显示,W、Sn、Be、Nb、Ta在流体/熔体相间的分配系数Di＜0.1,表明它们强烈分配进入熔体相.W、Nb、Ta在流体/熔体相间的分配显示压力相关性随压力降低而降低.     

硅酸盐-磷酸盐平衡反应对熔体中磷制约实验

目前，根据磷灰石溶解度模型、P在碱性长石与熔体相间的分配以及黑云母、锰铝榴石、透锂长石与对应的磷酸盐（包括斜磷锰铁矿、磷铝锂石-羟磷锂铝石）的平衡研究，已对过铝质岩浆中P的归宿进行了有效的平衡。但未见锰铝榴石-磷灰石的平衡研究。由于锰铝榴石-磷灰石矿物共生组合是花岗岩和LET型伟晶岩中最常见的矿物组合，直到岩浆演化晚期才出现锂辉石-磷铝锂石-羟磷锂铝石的组合。为此，本文实验研究锰铝榴石-磷灰石平衡反应，对过铝质岩浆体系中P溶解度起控制作用。     

东昆仑白干湖钨锡矿床成矿岩体岩石学、年代学和地球化学

白干湖钨锡矿田是近年来在我国西部地区新发现的一个具超大型远景规模的矿田,由白干湖、柯可卡尔德、巴什尔希和阿瓦尔四个矿床组成。矿床与加里东期巴什尔希岩浆序列具有密切联系,但对其岩石成因及与成矿关系尚有争议。本文选取白干湖矿床与成矿有关的花岗岩开展了岩石学、年代学和地球化学研究。镜下鉴定其为正长花岗岩。LA-MC-ICP-MS锆石U-Pb年龄为413.6±2.4Ma(MSWD=0.36,n=30)。结合前人资料,认为巴什尔希岩浆序列形成于后碰撞构造环境,岩体年龄集中于中志留世-早泥盆世(ca.433~413Ma),具有S型花岗岩和A型花岗岩伴生的特点。其中白干湖正长花岗岩含有原生锰铝榴石和白云母等过铝质矿物,A/CNK和A/NK分布范围分别为1.07~1.11和1.45~1.49,锆石饱和温度和高场强元素含量相对较低,属于弱过铝质高钾钙碱性S型花岗岩,形成于巴什尔希岩浆序列岩浆活动晚期,与区内钨锡成矿关系密切,矿区内下步找矿应对隐伏或岩枝状产出的正长花岗岩更加重视。而巴什尔希岩浆序列中的二长花岗岩和碱长花岗岩含有角闪石和黑云母等暗色矿物并主要呈他形晶充填于长石和石英晶隙,K2O含量为5.25%~6.29%,属于钾玄岩系列,A/CNK为0.92~1.02,其锆石饱和温度(866~917℃)、全碱含量(8.30%~9.69%)、稀土总量(200×10-6~413×10-6)和Zr、Nb、Ce、Y等高场强元素含量(Zr+Nb+Ce+Y=556×10-6~1006×10-6)都明显偏高,为准铝质或弱过铝质A型花岗岩,在该区及外围可能具有形成与A型花岗岩有关的稀有稀土金属矿床的潜力。     

湘南多金属矿集区燕山期成矿花岗岩的主元素地球化学特征和成因探讨

湘南地区燕山期成矿花岗岩的主元素地球化学特征可划分为3种类型,不同成矿花岗岩形成的岩浆演化机理有明显差异:(1)成矿花岗岩的K_2O/Na_2O比值较高,均显示高钾钙碱性-钾玄岩系列特征。(2)MC型与CM型早期次单元花岗岩相对贫硅、碱.富钙、镁、铁,铝质指数(A/KNC)较低,碱度指数(KN/A)都不高,属镁质-铁质准铝质的高钾钙碱性系列花岗岩类,总体显示出I型花岗岩的特征。C型和CM型晚期次单元花岗岩相对富硅碱、贫镁钙,属铁质弱过铝质-过铝质钾玄岩系列-高钾钙碱性系列花岗岩类:岩石的FeO~T/MgO值明显高于一般I型和M型花岗岩.较高的FeO~T值又与高分异的I型花岗岩相区别,总体显示出S型花岗岩的特征。(3)成矿花岗岩的F或Cl含量高.岩浆向过铝质方向或过碱性方向演化,晚期岩浆中的高场强元素浓度增大,导致MC型与CM型的花岗岩的早期次单元多有Cu、Pb、Zn、Sb等多金属化,C型和CM型的晚期次单元花岗岩则常有大型Sn、W、Pb、Zn、Nb、Ta和稀土等矿化。(4)成矿花岗岩的形成与壳幔岩浆混合作用有关.形成MC型和CM型早期次单元花岗岩的岩浆演化主要是岩浆混合作用.而CM型花岗岩晚期次的花岗岩类和C型花岗岩类的岩浆演化可能还存在分离结晶作用。     

中国东部燕山期强过铝质花岗岩的地球动力学意义——以冀晋辽地区和广东吴川-四会地区为例

强过铝质花岗岩的岩石化学特征可以提供地壳发生部分熔融时的温压条件的信息。在冀晋辽地区和广东省吴川 -四会地区均有燕山期强过铝质花岗岩出露。它们的岩石化学成分表现出高钾质的特征。冀晋辽地区燕山期强过铝质花岗岩的Al2 O3/ Ti O2 比值变化于 5 0到 2 5 0之间 ,暗示其熔融温度在 80 0到 90 0℃之间 ;而燕山期强过铝质花岗岩 ,其大多数的 Al2 O3/ Ti O2 比值较低 ,暗示其源区熔融温度在 875℃以上。它们的稀土元素配分形式指示其熔融源区的残留矿物组合中含有斜长石、单斜辉石、石榴子石和角闪石 ,表明这些强过铝质岩浆形成于 0 .9～ 1.7GPa的压力条件下。这表明中国大陆东部地区燕山期深部热背景存在南北差异。在造山作用特征方面 ,华南在燕山期表现出“热”造山带的特点 ,华北则表现出过渡型的特点。     

Petrogenesis of Cretaceous Peraluminous Granite Suites with Low Initial Sr Isotopic Ratios, Kyushu Island, Southwest Japan Arc

Cretaceous granitic rocks are widely distributed in the northern to central parts of Kyushu Island, southwest Japan arc, and are divided into two types, granite and tonalite-granodiorite. These rocks are clearly defined by their mineral assemblage, that is, the granite contains mostly muscovite and/or garnet and does not have hornblende, whereas the tonalite-granodiorite is always observed with hornblende. Many workers suggest that most of the granite has low initial Sr isotopic ratios (SrI_{90 Ma}: 0.7052-0.7059) whose values are similar to those of tonalite-granodiorite (SrI_{90 Ma}: 0.7050-0.7056).

The SiO₂ contents of the granite (67.9 to 78.0 wt.%) are higher than that of tonalite-granodiorite (54.2 to 68.2 wt.%). The granite is characterized by peraluminous compositions, while the tonalite-granodiorite shows metaluminous to peraluminous compositions. The petrogenetic relation between granite and tonalite-granodiorite is examined by a modal batch melting model, which referred to results of already published experiments. The result of the model suggests that the petrogenesis of the peraluminous granitic magma can be explained by an anatexis of metaluminous tonalite in the tonalite-granodiorite under lower to middle crustal conditions and variable fH₂O.

Rocks of tonalite to granodiorite in a subduction system generally have low initial Sr isotopic ratios (<0.705), which imply that the magma derived from a highly metaluminous origin such as mafic magma, mafic lower crust and/or subducting slab. In this study, it is regarded that the peraluminous granitic magma can be directly produced by an anatexis of metaluminous tonalite. Therefore, peraluminous granite with low initial Sr isotopic ratios may imply to a first step of recycling of the granitic layer in an active plate margin.     

过铝花岗岩的成因类型与构造环境研究综述

概述了过铝花岗岩类的成因类型及形成的构造背景，特别介绍了过铝花岗岩岩浆的来源及其鉴别标志，指出过铝花岗岩岩浆按物质来源可分为壳源、幔源和壳幔混源三种类型，是地壳、地幔以及地壳物质与地幔物质相互混合和相互作用的结果，各种不同类型之间可能存在一种地壳源与地幔源之间的连续谱系，并简要介绍CPG和MPG两种主要过铝花岗岩的成因机制。提出了过铝花岗岩形成环境的综合判别准则，指出过铝花岗岩不仅要以形成于碰撞造山过程中的挤压性构造环境，而且可以形成于与岩石圈伸展作用相关的张性构造环境。     

腾冲地块高地热异常区晚白垩世-始新世钾玄质强过铝花岗岩岩石地球化学、年代学特征及构造意义

腾冲地块高地热异常区清水左所营初糜棱岩化黑云母二长花岗岩岩体、新华黑石河热田强糜棱岩化黑云母二长花岗岩岩体、热海热田硫磺塘硅化碎裂正长花岗岩岩体变形变质、岩石地球化学及锆石年代学的研究表明,晚白垩世(73Ma)初糜棱岩化黑云母二长花岗岩岩体为高温钾玄质强过铝花岗岩,形成于活动大陆边缘火山弧-后碰撞转换或过渡构造环境,并经历强烈伸展变形作用,普遍发育早期近水平-低角度(30°)韧性伸展剪切糜棱面理,局部发育晚期高角度右旋走滑挤压韧性糜棱面理;始新世(48~46Ma)强糜棱岩化黑云母二长花岗岩岩体、硅化碎裂正长花岗岩岩体为中-高温钾玄质强过铝花岗岩,并具铝质A型花岗岩特征,形成于后碰撞-板内构造环境,以发育晚期高角度(70°~87°)右旋走滑挤压韧性糜棱面理为特征,其右旋走滑韧性剪切变形时代晚于始新世(48~46Ma)。晚白垩世-始新世钾玄质强过铝花岗岩的形成与俯冲-碰撞造山隆升后的伸展垮塌、拆沉地幔物质上涌玄武质岩浆底侵和地壳部分熔融作用密切相关。始新世-第四纪岩浆活动与高地热异常区(带)空间上密切伴生,新近纪晚期-第四纪构造活动主要表现为脆性走滑-拉张正断层和构造拉分断陷盆地的形成,构造断陷边界断裂与深部岩浆活动是导致腾冲地区高地热异常区(带)中-高温地热温泉沿走滑-拉张断裂带集中分布的主要原因。     

Phase relations of a F-enriched peraluminous granite: an experimental study of the Kymi topaz granite stock,southern Finland

Phase relations of F-rich Kymi equigranular topaz granite have been investigated experimentally at 100–500 MPa as a function of water activity and F content. Fluorite and topaz can crystallize as liquidus phases in F-rich peraluminous systems, but the F content of the melt should exceed 2.5–3.0 wt% for the crystallization of topaz. In peraluminous F-bearing melts containing more than 1 wt% F, topaz and muscovite are expected to be the first F-bearing phases to crystallize at high pressure, whereas fluorite and topaz should crystallize first at low pressure. Following reaction models the saturation of fluorite and topaz: CaAl₂Si₂O₈ (plagioclase) + 2[AlF₃]_melt = CaF₂ (fluorite) + 2Al₂SiO₄F₂ (topaz). The obtained partition coefficient for F between biotite and glass D(F)^Bt/glass ranges from 1.89 to 0.80 (average value 1.29) and can be used as an empirical fluormeter to determine the F content of coexisting melts. Combined petrological and experimental studies of the Kymi equigranular topaz granite indicate that plagioclase was the liquidus phase at nearly water-saturated (fluid-saturated) conditions and that the F content of the melt was at least 2 wt%. The mean F content of natural biotite (3.92 wt%) suggests that the late-stage crystallization of biotite occurred in melts containing about 3 wt% F. The early crystallization of biotite and the presence of muscovite in our experiments at 200 MPa contrasts with the late-stage crystallization of biotite and the absence of muscovite in the natural assemblage, indicating that crystallization pressure may have been lower than 200 MPa for the granite. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.     

内蒙古东乌珠穆沁旗查干哈达音亨嘎高温型强过铝质花岗岩年代学、地球化学特征及其地质意义

内蒙古东乌珠穆沁旗查干哈达音亨嘎强过铝质岩体位于华北板块与西伯利亚板块之间的中亚-蒙古造山带中东段的兴蒙褶皱带,主要岩石类型为含石榴子石二云母二长花岗岩。基于锆石U-Pb同位素定年、地球化学分析和构造环境判别,结合区域对比,认为查干哈达音亨嘎岩体源区可能与变质泥岩部分熔融有关,晚古生代,强过铝质花岗岩形成之前,二连—东乌旗一带已经发生了碰撞造山作用,之后为后碰撞-造山后的伸展扩张时期。经研究确定,查干哈达音亨嘎岩体为鲜有报道的石炭纪—早二叠世具有典型后碰撞特征的高温型强过铝质S型花岗岩类。     

Solubility of columbite, (Mn,Fe)(Nb,Ta)<Subscript>2</Subscript>O<Subscript>6</Subscript>, in granitoid and alkaline melts at 650–850°C and 30–400 MPa: An experimental investigation

This paper reports experimental data on columbite solubility in model water-saturated Li- and F-rich silicic melts with different contents of alumina and alkalis. It was found that the columbite solubility is strongly affected by melt composition and is maximal in peralkaline melt. The maximum contents of Ta and Nb in subaluminous and peraluminous melts at the contact with columbite are lower by at least an order of magnitude. The peralkaline melt is relatively enriched in Nb, and the peraluminous melt is enriched in Ta. The temperature dependence of solubility is positive but less pronounced than the effect of melt composition. It is most distinct in the subaluminous melts. The Nb/Ta ratio of melt usually decreases with decreasing temperature. The effect of pressure is relatively small. It was shown that columbite cannot crystallize on the liquidus of both peralkaline and peraluminous magmas. Perhaps, columbite crystallization from a melt is possible only at final near-solidus stages at the high degrees of crystallization of strongly evolved low-temperature melts.     

Sr and Nd isotopic compositions, age and petrogenesis of A-type granitoids of the Vernon Supersuite, New Jersey Highlands, USA

Voluminous late Mesoproterozoic monzonite through granite of the Vernon Supersuite underlies an area of approximately 1300 km² in the Highlands of northern New Jersey. The Vernon Supersuite consists of hastingsite±biotite-bearing granitoids of the Byram Intrusive Suite (BIS) and hedenbergite-bearing granitoids of the Lake Hopatcong Intrusive Suite (LHIS). These rocks have similar major and trace element abundances over a range of SiO₂ from 58 to 75 wt.%, are metaluminous to weakly peraluminous, and have a distinctive A-type chemistry characterized by high contents of Y, Nb, Zr, LREE, and Ga/Al ratios, and low MgO, CaO, Sr and HREE. Whole-rock Rb–Sr isochrons of BIS granite yield an age of 1116±41 Ma and initial ⁸⁷Sr/⁸⁶Sr ratio of 0.70389, and of LHIS granite an age of 1095±9 Ma and initial ⁸⁷Sr/⁸⁶Sr ratio of 0.70520. Both suites have similar initial ¹⁴³Nd/¹⁴⁴Nd ratios of 0.511267 to 0.511345 (BIS) and 0.511359 to 0.511395 (LHIS). Values of _Nd are moderately high and range from +1.21 to +2.74 in the BIS and +2.24 to +2.95 in the LHIS. Petrographic evidence, field relationships, geochemistry, and isotopic data support an interpretation of comagmatism and the derivation of both suites from a mantle-derived or a juvenile lower crustal parent with little crustal assimilation. Both suites crystallized under overlapping conditions controlled by P–T–f_H2O. Lake Hopatcong magma crystallized at a liquidus temperature that approached 900°C and a pressure of about 6 kbar, and remained relatively anhydrous throughout its evolution. Initial P–T conditions of the Byram magma were ≥850°C and about 5.5 kbar. BIS magma was emplaced contemporaneous with, or slightly preceding LHIS magma, and both magmas were emplaced during a compressional tectonic event prior to granulite facies metamorphism that occurred in the Highlands between 1080 and 1030 Ma.     

Grenvillian thermal event and remnant charnockite: Isotopic evidence from the Chilka Lake granulite-migmatite suite in the Eastern Ghats belt, India

Spectacular exposures of granulite-migmatite occur in the Chilka Lake area of the Eastern Ghats belt. The garnetiferous granite gneiss of peraluminous granitic composition, often contains restitic metapelite inclusions and is demonstrably a product of biotite-dehydration melting in pelitic rocks. On the other hand, older layers and bands of charnockitic rocks frequently occur as dismembered patches within the peraluminous granite, thus imparting a measled appearance of the granite exposures. The partial melting and emplacement of the peraluminous granite represent the Grenvillian thermal event, as evidenced by Rb-Sr whole rock and Pb-Pb zircon dating. On the other hand, minor patches of charnockite represent migmatized relict, as evidenced by some older zircons, in addition to those of Grenvillian age.     

The petrochemistry characteristics and petrogenesis of peraluminous granite in Tibet

There are 61 major peraluminous granitic bodies in Tibet (TPGs) along the south of the Bangong Co-Gêrzê-Amdo-Nujiang suture, whose lithology includes tourmaline granite, muscovite granite and two-mica granite. The TPGs have SiO₂ = 65.7%−79.52%, K₂O + Na₂O = 2.20%−12.51%, K₂O/Na₂O = 0.49−1.04 and A/CNK = 1.04−1.38. Al₂O₃ gradually decreases and the other oxides disperse with the increase in SiO₂. The rock series is mainly calc-alk series with high potassium. It has typical characteristics of strongly peraluminous granite. Based on the aluminum saturation index and QAP plots, the peraluminous granite plot is mostly within the continental collision granite (CCG) field, indicating that the peraluminous granites in Tibet formed in a continental collisional setting. Ab-Or-Q-H₂O phase diagram indicates the pressure of 0.5 × 10⁸−2 × 10⁸ Pa in TPGs, from which it can be deduced that the forming temperature was under 700°C. The TPGs mainly occurred at the collision stage between two continental crust plates, and the original magma is rooted in the remelting from the upper crust. It is the S-type granite in petrogenesis. The South Gandise belt and the Lhagoi Kangri belt have similar characteristics, suggesting that the two belts have the same magma source and the same tectonic setting. Translated from Acta Geologica Sinica, 2006, 80(9): 1329–1341 [译自: 地质学报]     

Fluid and melt inclusion evidence for the origin of idiomorphic quartz crystals in topaz-bearing granite from the Salmi batholith, Karelia, Russia

Idiomorphic quartz crystals in topaz-bearing granite from the Salmi batholith contain primary inclusions of silicate melt and abundant mostly secondary aqueous fluid inclusions. Microthermometric measurements on melt inclusions give estimates for the granite solidus and liquidus of 640–680°C and 770–830°C, respectively. Using published solubility models for H₂O in granitic melts and the obtained solidus/liquidus temperatures from melt inclusions, the initial water concentration of the magma is deduced to have been approximately 3 wt.% and the minimum pressure about 2 kbar. At this initial stage, volatile-undersaturation conditions of magma were assumed. These results indicate that the idiomorphic quartz crystals are magmatic in origin and thus real phenocrysts. During subsolidus cooling and fracturing of the granite, several generations of aqueous fluid inclusions were trapped into the quartz phenocrysts. The H₂O inclusions have salinities and densities of 1–41 wt.% NaCl eq. and 0.53–1.18 g/cm³, respectively.