赣东北地区早白垩世火山岩的Nd,Sr同位素地球化学特征

赣东北早白垩世处于陆内造山环境向陆内拉张环境过渡的过渡性构造环境，形成了一套富碱的火山岩组合。Nd,Sr同位素特征显示，酸性岩石具有较高的εSr(T)值与较低的εNd(T)值，其N^87Sr/N^86Sr初始比值为0.71020与0.71050，上壳端员组分介于67％－50％之间，表明其源区处于地壳中较深的位置，且有地幔流体的加入。玄武质岩石具有较高的εSr(T)值与负的εNd(T)值，其N^87Sr/N^86Sr初始比值为0.7063-0.7087，玄武质岩石在其形成过程中遭受过壳源岩浆的混合或大陆地壳物质的混染。     

西天山阿吾拉勒埃达克质岩石成因：Nd和Sr同位素组成的限制

西天山阿吾拉勒二叠纪钠质英安岩和钠长斑岩具有与埃达克岩一致的高Sr,低Y、Yb和Eu正异常等独特岩石地球化学特征。系统的Nd和Sr同位素组成研究表明，其（^143Nd/^144Nd)i为0．512384－0．512470，εNd(t)为正值（＋1．57－＋3．26）；（^87Sr/^86Sr)i为0．0751－0．7054，与本区同时代幔源玄武岩的Nd和Sr同位素组成特征相似，但与俯冲洋壳部分熔融成因埃达克岩的Nd和Sr同位素组成有显著区别。结合这些埃达克质岩石形成二叠纪后碰撞阶段构造背景，认为本区埃达克质岩浆最有可能由新底侵的玄武质下地壳在角闪岩相向榴辉岩相过渡或榴辉岩相的条件下部分熔融形成，是西天山晚古生代后碰撞阶段地幔玄武岩浆底侵作用和地壳垂向增生的重要岩石标志。     

崂山地区玄武质岩石的地球化学特征

晚白垩世（95Ma)，白垩纪末（69Ma)和古新(6765Ma)玄武质岩石，呈脉状零星露头产于燕山期崂山岗岩体中，岩性分别为碱性玄武岩，碧岩和斑玄武岩，碱性玄武岩和碧玄岩以高度富集LILE和LREE为特征，（La/Yb)N=25.5-46.6，两者表现为程度不等的Nb,Ta,Zt,Ti等高场强元素亏损，与我国华北新生代碱性玄武岩相比，Ba,Rb,Th更为富集，Sr,Nd同位素比值（碧玄岩）为^87Sr/^86Sr=0.705517,^143Nd/^144Nd=0.512777.它们很可能均起源一刊中生代扬子板块玄武岩类似，微量元素总量及LILE和LREE含量均较低，（La/Yb)N=4.7-6.4，其典型的微量元素比值（如Zr/Nb,Rb/Nb,Nb,Ta等）与EM1型OIB类似，^87Sr/686Sr=0.706054-0.706146;^143Nd/^144Nd=0.572387-0.512392,它可能起于受上涌软流圈交代的大陆岩石圈（软流圈顶部的“metasome”）的部分熔融，是软流圈流体与大陆岩石圈相互作用的产物。上述不同类型玄武岩的顺序侵位，可能反映在晚白垩世一早第三纪期间，本区曾经历地壳拉张强度逐渐增大一地壳持续减薄－软流圈不断上涌的动力学过程。     

北京周口店岩体地球化学特征及物源分析

通过对周口店岩体地球化学特征和构造环境及其与埃达克岩对比的分析，发现该岩体具有C型埃达克岩的地球化学特征。^143Nd／^144Nd-^87Sr／^86Sr图解发现该岩体的锶、钕同位素投影点均落在EMI型富集地幔区域内，表明其物质来源与EMI型富集地幔有关。而εNd（t）-ISr图解中，其投影点正好落在汉诺坝二辉麻粒岩包体范围内（汉诺坝二辉麻粒岩包体是幔源基性岩浆在晚古生代-中生代底侵到下地壳底部构成的年轻下地壳的一部分）。由此推测认为，周口店岩体是中生代新增生的华北克拉通下地壳的部分熔融的产物。     

藏北羌塘地块新生代火山岩中麻粒岩捕虏体的岩石学和地球化学研究:对青藏高原新生代火山岩成因及下地壳性质的约束

青藏高原北部羌塘地块的新生代高钾钙碱性火山岩中含有很多下地壳捕虏体,这些捕虏体的主要岩石类型为二辉石麻粒岩和单斜辉石麻粒岩。本文对鸟兰乌拉湖南侧枕头崖地区新生代高钾钙碱性火山岩中的9个麻粒岩样品(6个基性麻粒岩和3个酸性麻粒岩)进行了系统的岩石学,矿物化学,地球化学和Sr-Nd-Pb同位素地球化学研究。其中,紫苏辉石具有高MgO FeO,低Al_2O_3的特征,单斜辉石具有低Al_2O_3和TiO_2的特征,黑云母具有高TiO_2的特征,这些特征都表明这些矿物为变质成因。矿物温压计算表明二辉石麻粒岩形成的平衡温度为783℃～818℃。单斜辉石麻粒岩形成压力在0.845～0.858GPa之间,来源深度约28km。表明它们可能是来自青藏高原加厚陆壳中部的岩石样品。基性麻粒岩的SiO_2=48.76%～58.61%,Al_2O_3=18.34%～24.50%,Na_2O=3.16%～5.41%,K_2O=1.58%～3.01%,低Mg~#(30～67),富集轻稀土(LREE)和大离子亲石元素(LILE),其具有较高的Rb/Sr(0.09～0.21)和(La/Yb)_N(17.32～49.35),具有较低的Nb/Ta (9.76～14.92),其Eu异常变化于0.19～0.89之间。基性麻粒岩的Sr-Nd-Pb同位素地球化学表现为~(87)Sr/~(86)Sr=0.710812～0.713241,ε_(Sr)=169.13～203.88,~(143)Nd/~(144)Nd=0.512113～0.512397;ε_(Nd)=-4.70～-10.05,~(206)Pb/~(204)Pb=18.7000～-18.9565,~(207)Pb/~(204)Pb=15.7135～-15.7662,~(208)Pb/~(204)Pb=39.1090～39.4733。和基性麻粒岩类似,酸性麻粒岩也表现出富集轻稀土(LREE)和大离子亲石元素(LILE)的特征,它们的~(87)Sr/~(86)Sr=0.712041～0.729088,ε_(Sr)=180.71～430.59,~(143)Nd/~(144)Nd=0.512230～-0.512388;ε_(Nd)=-4.74～-7.96,~(206)Pb/~(204)Pb=18.9250～-19.1717,~(207)Pb/~(204)Pb=15.7662～-15.7720,~(208)Ph/~(204)Pb=39.2109～39.6467。上述地球化学特征表明这些基性麻粒岩的源岩是下地壳岩石,而非地幔岩或玄武质堆晶岩,而酸性麻粒岩的源岩极有可能是准铝质的花岗质岩石。这就表明青藏高原新生代下地壳的地温梯度很高,并含有部分沉积岩,而非典型的辉长质下地壳。而且,详细的研究表明,这种特殊的下地壳可能对青藏高原新生代高钾钙碱性和橄榄粗安质岩浆的起源有重要作用。因此目前所认为的超钾质-橄榄粗安质岩浆源于富集岩石圈地幔在对流减薄作用下发生部分熔融的观点值得重新考虑。     

北大别白垩纪花岗岩多期侵位与造山带演化的关系

大别造山带白垩纪花岗岩的多期侵位与地壳结构变化的关系,是研究大别造山带演化的热点和前沿问题之一.北大别造山带产出三期白垩纪花岗岩,通过对石鼓尖岩体、天堂寨岩体和薄刀锋岩体进行锆石U-Pb年龄和Sr-Nd同位素研究,探讨了北大别白垩纪三期花岗岩的侵位时间和造山带地壳结构的演化.石鼓尖石英二长岩年龄为142±4Ma,(87Sr/86Sr)t比值范围为0.707 801~0.707 870,εNd(t)值范围为-17.94~-17.09;天堂寨斑状二长花岗岩年龄为132±4Ma,(87Sr/86Sr)t比值范围为0.708 390~0.708 934,εNd(t)值范围为-16.89~-13.86;薄刀锋细粒花岗岩的年龄为130±4Ma,(87Sr/86Sr)t比值范围为0.711 424~0.714 972,εNd(t)值范围为-14.88~-12.97.这样的同位素组成显示花岗岩的多期侵位与地壳结构演化的密切关系,第一期花岗岩形成于增厚的基性下地壳部分熔融,第二期花岗岩来源于大别造山带伸展垮塌过程的中酸性中下地壳的部分熔融,晚期无变形花岗岩形成于造山带伸展垮塌后,酸性中上地壳的部分熔融.     

济阳拗陷第三纪玄武岩的Nd—Sr同位素研究

本文报道了济阳拗陷29个第三纪玄武岩的Nd，Sr同位素组成。结果表明，该区早、晚第三纪玄武岩的Nd-Sr同位素组成变化且具有一定的区别：早经三纪玄武岩的εNd值为0．70481－0．70830；晚第三纪玄武央的εNd值为0．1－2．3，^87Sr/^86Sr比值为0．70421－0．70530。鉴于εNd与1/Nd有^87Sr/^86Sr与1／Sr之间不存在相关特征，Nb正异常以及SiO2与MgO，Fe2O3 FeO,P2O5呈负相关，与Al2O3呈正相关，但与K2I为不存在相关特征，因此，地壳混染作用并不是第三纪玄武岩同位素组成变化的主要原因。玄武岩^87Sr/^86Sr比值的升高是由热液蚀变造成的，而εNd值的变化而归因于源区混合。如果热液蚀变作用没有发生，这些玄武岩的所有数据点在Nd-Sr相关图上将可能位于地幔系列内部。这表明第三纪玄武岩主要是由DMM和EMI两个端员组分不同程度混合形成，EMII的贡献是次要的。     

北大别早白垩纪花岗岩类的Sm-Nd和锆石Hf同位素及其构造意义

大别造山带产出两期早白垩纪造山后花岗岩类:早期(≈132Ma)变形的角闪石英二长岩和斑状二长花岗岩具高钾的类埃达克岩的地球化学特征,形成于增厚地壳(>50km)的下地壳部分熔融;晚期(≈128Ma)未变形的花岗岩包括细粒二长花岗岩和钾长花岗(斑)岩,属于正常安山岩-英安岩-流纹岩系列岩石,它们形成于相对薄的地壳(<35km)的下地壳部分熔融。早期变形的花岗岩类中,角闪石英二长岩的(~(87)Sr/~(86)Sr)_i=0.7066～0.7076,ε_(Nd)(t)=-20.3～-27.8,类似于扬子下地壳基性麻粒岩的Sr-Nd同位素特征,其中白垩纪岩浆锆石(≈132Ma)Hf同位素初始比值(ε_(Hf)(t))和两阶段Hf模式年龄(t_(DM2))分别为-29.30.5和303065Ma;我们认为角闪石英二长岩源于锆石Hf模式年龄约3.0Ga的基性下地壳部分熔融。早期斑状二长花岗岩的(~(87)Sr/~(86)Sr)_i=0.7078～0.7083,ε_(Nd)(t)=-15.8～-20.0,类似于北大别英云闪长质-花岗质片麻岩的Sr-Nd同位素特征,其白垩纪岩浆锆石(≈132Ma)的ε_(Hf)(t)和t_(DM2)分别为-24.80.5和274434Ma。我们认为宽状二长花岗岩源于约2.7Ga的中酸性下地壳部分熔融。晚期未变形的花岗岩的(~(87)Sr/~(86)Sr)_i=0.7069～0.7105,ε_(Nd)(t)=-16.4～-22.1,类似于北大别英云闪长质-花岗质片麻岩的Sr-Nd同位素特征;其白垩纪岩浆锆石(≈128Ma)的ε_(Hf)(t)具有较大的变化范围(-25.2～7.4),主要峰值为-22.5±0.5,次要峰值为-16.3±0.7,并有少量正的ε_(Hf)(t)值5.8～7.4,与ε_(Hf)(t)值对应的t_(DM2)分别为2600±40Ma、2211±68Ma和743±130Ma。我们认为晚期未变形的花岗岩源于锆石Hf模式年龄约2.6～2.2Ga的中酸性下地壳部分熔融,源区夹杂新元古代新生的陆壳。在大别造山带垮塌之前(>132Ma),增厚地壳(>50km)的下地壳存在双层结构:锆石Hf模式年龄约为3.0Ga的基性下地壳基底和约2.7Ga的中酸性(英云闪长质-花岗质)上部下地壳.在大别造山带伸展垮塌的晚期阶段(≈128Ma),减薄的下地壳(<35km)主要为锆石Hf模式年龄约2.6～2.2Ga的中酸性(英云闪长质-花岗质)岩石,并夹杂少量新元古代Rodinia超大陆裂解时形成的新生陆壳。     

藏北祖尔肯乌拉山地区新生代高钾钙碱岩系火山岩同位素地球化学研究

通过对藏北祖尔肯乌拉山地区新生代高钾钙碱岩系火山岩Sr,Nd,Pb同位素成分的系统测试分析表明,火山岩具有相对高的^87Sr／^86Sr和低的^143Nd／^144Nd值及高的Pb同位素组成特点,且Sr,Nd,Pb同位素比值变化范围很窄,反映了其具有同源岩浆的特点,并且经历了类似的地球化学动力学过程。Sr,Nd,Pb同位素组成及相关图解判别表明,藏北祖尔肯乌拉山地区新生代高钾钙碱岩系火山岩来源于被大洋沉积物和地壳物质所混合的不均一富集地幔源区,显示源区具有壳幔混源性质,与EMⅡ型富集地幔源特征一致。     

太古宙TTG的Nb/Ta变化特征:对“Nb-Ta悖论”的启示

英云闪长岩-奥长花岗岩-花岗闪长岩(TTG)是地球早期大陆地壳最重要的组成部分。TTG的Nb/Ta比值变化不仅与它的成因相关,而且与早期构造环境和地壳分异过程关系紧密。本文选择阴山地块出露的TTG片麻岩及下地壳斜长角闪岩/麻粒岩包体作为研究对象,开展了寄主花岗闪长岩和同源镁铁质包体中的角闪石和黑云母的原位微区矿物的微量元素分析工作,以及TTG与非同源斜长角闪岩包体的全岩主微量元素分析工作。矿物化学研究结果表明,花岗闪长岩和同源镁铁质包体的角闪石具有相似的Mg^#值,但是两者具有明显不同的Nb/Ta比值。镁铁质包体中的角闪石更富Cr、Ta,Nb/Ta比值为30~50;TTG岩石中的角闪石Cr和Ta含量偏低,但具有更高的Nb/Ta比值(38~70)。TTG和镁铁质包体中的角闪石Cr含量与Nb/Ta具有较好的负相关关系。全岩地球化学分析结果揭示,TTG片麻岩的具有高Nb/Ta比值(13~65,平均值31),斜长角闪岩和麻粒岩包体具有变化的Nb/Ta比值(10~56)。太古宙绿岩带中玄武质岩石的Nb/Ta平均值为~15,阴山地块斜长角闪岩和麻粒岩包体具有高的Nb/Ta比值,反映了这些代表基性下地壳的岩石经历了部分熔融作用或后期的交代作用,使其Nb/Ta比值发生改变。研究区具有高Nb/Ta比值的TTG可能来源于高Nb/Ta比值基性下地壳部分熔融,并继承了源区高Nb/Ta比值的特征。通过本文研究揭示,高Nb/Ta比值的TTG并非一定形成于俯冲带洋壳榴辉岩相部分熔融,下地壳富角闪石和黑云母的岩石部分熔融是形成高Nb/Ta比值TTG的一种重要途径。     

Effects of basement composition and age on silicic magmas across an accreted terrane-Precambrian crust boundary,Sierra Madre Occidental,Mexico

Trace element and isotopic compositions of mid-Tertiary siliceous magma sequences from two localities of the Sierra Madre Occidental, northern Mexico, display differences that reflect the composition and age of the basement through which they erupted. The crust beneath the section at San Buenaventura is thicker and more evolved and forms part of the North American basement, while that under El Divisadero consists of allochthonous terranes of island arc/oceanic? crust accreted during the Mesozoic.The volcanics are highly differentiated and range in composition from basalt to rhyolite (SiO₂=50–76%). Those erupted through the accreted terranes display a small range of isotope ratios and have lowest initial (age-corrected) Sr isotope ratios (>0.7044) and the highest Nd (<0.5126) and Pb isotope ratios (²⁰⁶Pb/²⁰⁴Pb ∼18.9). Isotope ratios of the continental suite are more variable and form an array which trends away from that of the accreted terrane suite toward compositions more typical of old crust (to ⁸⁷Sr/⁸⁶Sr ∼0.710 and ¹⁴³Nd/¹⁴⁴Nd ∼0.5123). The volcanics in the continental zone are relatively more enriched in moderately incompatible elements compared with those within the accreted terranes (Ce/Yb=25–45 vs. 13–33, respectively), but are depleted in some highly incompatible elements such as U and Rb (e.g., Th/U=3.8–7.5 vs. 2.5–4.0, respectively). Those higher in the stratigraphic sections have higher ⁸⁷Sr/⁸⁶Sr, ²⁰⁸Pb/²⁰⁴Pb, and Th/U ratios, and lower ¹⁴³Nd/¹⁴⁴Nd ratios than those lower in the sections.The data have implications for the nature of the sources and the petrogenesis of these volcanics. The isotope ratios of both suites fall between those of mafic magma compositions from the Sierra Madre Occidental, and intermediate and felsic lower crustal xenoliths in northern Mexico and the southwestern USA. The relationship between the isotope ratios of the sequences and the age of the basement, combined with the fact that the overall data set forms well-defined isotopic arrays, demonstrates the strong effects of the crust on the chemistry of the silicic magmas. In the continental suite, isotope ratios covary with Th/Pb and U/Pb ratios, approaching the compositions found in the intermediate and felsic granulite facies xenoliths, strongly indicating that they are not anatectic melts of the lower crust but rather reflect interaction between mantle-derived basaltic parental magmas and the crust. Crustal contributions appear to be large, on the order of 20–70%. The small range of isotope ratios in the accreted terrane suite appears to reflect interaction of the basaltic parent with relatively juvenile crust whose isotopic composition is similar to the mantle-derived magmas. High Th/U and Th/Rb ratios indicate that the crustal contamination occurs in the lower crust. Moreover, the less radiogenic ²⁰⁶Pb/²⁰⁴Pb and ²⁰⁷Pb/²⁰⁴Pb ratios in the continental suite indicate that the depletion in highly incompatible elements in the continental lower crust is an old feature. The secular changes in the isotope ratios within the stratigraphic sections indicate increasingly shallow crustal contributions with time, initially by predominantly mafic deep lower crust and later by more felsic middle crust. Using lavas from outside of the two heavily sampled stratigraphic sections, the differences in the isotopic compositions between volcanics erupted through the accreted terranes and the continental basement help to delineate the location of the boundary.     

Baseline determination of the atmospheric Pb,Sr and Nd isotopic compositions in the Rhine valley,Vosges mountains (France) and the Central Swiss Alps

The Pb, Sr and Nd isotopic compositions of biomonitors (lichen, moss, bark) and soil litter from different regions in the Rhine valley, as well as of <0.45 μm particles separated out of ice of the Rhône and Oberaar glaciers and lichens from the Swiss Central Alps, have been determined in order to deduce the natural baseline of the atmospheric isotopic compositions of these regions, which are suggested to be close to the isotopic compositions of the corresponding basement rocks or soils at the same sites. ²⁰⁶Pb/²⁰⁷Pb and ⁸⁷Sr/⁸⁶Sr isotope ratios are positively correlated. Most polluted samples from traffic-rich urban environments have the least radiogenic Pb and Sr isotopic compositions with ²⁰⁶Pb/²⁰⁷Pb and ⁸⁷Sr/⁸⁶Sr ratios of 1.11 and 0.7094, respectively. These ratios are very different from those of the atmospheric baseline for the Vosges mountains and the Rhine valley (²⁰⁶Pb/²⁰⁷Pb: 1.158–1.167; ⁸⁷Sr/⁸⁶Sr: 0.719–0.725; ε_Nd: −7.5 to −10.1). However, this study indicates that the baseline of the atmospheric natural Pb and Sr isotopic compositions is affected by anthropogenic (traffic, industrial and urban) emissions even in remote areas. Lichen samples from below the Rhône and Oberaar glaciers reflect the baseline composition close to the Grimsel pass in the Central Swiss Alps (⁸⁷Sr/⁸⁶Sr: 0.714 − 0.716; ε_Nd: −3.6 to −8.1). The ¹⁴³Nd/¹⁴⁴Nd isotope ratios are highly variable (8ε units) and it is suggested that the variation of the ¹⁴³Nd/¹⁴⁴Nd is controlled by wet deposition and aerosols originating from the regional natural and industrial urban environments and from more distant regions like the Sahara in North Africa. The least anthropogenetically affected samples collected in remote areas have isotopic compositions closest to those of the corresponding granitoid basement rocks.     

中天山卡瓦布拉克杂岩带中-基性岩的成因及其构造意义:元素地球化学和Sr Nd Pb同位素约束

研究中天山地块卡瓦布拉克杂岩带的成因,对重建中天山南缘古生代洋陆构造格局及其演变过程具有重要意义。在查明杂岩带中-基性岩主体岩类矿物学及岩石学特征的基础上,分析了该岩类的主、微量元素和Sr Nd Pb同位素组成。结果显示:其属于偏基性的富钠、低钾岩石系列,富集大离子亲石元素(Rb、U、Sr)和轻稀土元素(LREE),亏损高场强元素(Nb、Ta、Zr)和重稀土元素(HREE)。全岩Sr Nd同位素组成具有较低的锶初始比值(ISr=0706~0709)和较高的εNd(t)值(684~976),并具有较低的放射性成因铅同位素组成,初始铅同位素比值(206Pb/204Pb)i=18015~18239、(207Pb/204Pb)i=15573~15593、(208Pb/204Pb)i=37871~38207。结合前人研究成果和区域地质资料,认为其母岩浆应该来自被交代的年轻富集岩石圈地幔,代表岛弧岩浆,说明卡瓦布拉克杂岩带中-基性岩可能代表该区晚古生代岩浆弧的一部分。     

Geochemical Evolution of Akagi Volcano, NE Japan: Implications for Interaction Between Island-arc Magma and Lower Crust, and Generation of Isotopically Various Magmas

Major and trace element, and Sr, Nd and Pb isotopic compositionswere determined for whole-rock samples from the ‘isotopicallyanomalous’ Akagi volcano in the volcanic front of theNE Japan arc. Sr and Nd isotopic compositions of phenocrystswere also analyzed together with their major and trace elementcompositions. Compared with the other volcanoes from the volcanicfront, the whole-rock isotope compositions of Akagi show highlyenriched characteristics; ⁸⁷Sr/⁸⁶Sr = 0·7060–0·7088,     

The Pb-Sr-Nd isotope geochemistry of some recent circum-Mediterranean granites

Pb, Sr and Nd isotopic compositions have been analyzed in recent granites from Northern Africa, Northern Italy and Greece. Lead isotope compositions of K-feldspars are rather homogeneous, and cluster close to the modern lead of Stacey and Kramers (1975) but with slightly higher²⁰⁷Pb/²⁰⁴Pb and²⁰⁸Pb/²⁰⁴Pb ratios. The Cyclades samples, however, have higher²⁰⁶Pb/²⁰⁴Pb ratios. Addition of mantle-derived lead was probably very limited, which supports a quasi-closed system evolution of this element in the continental crust. The Sr, Nd data fall in the enriched part of the¹⁴³Nd/¹⁴⁴Nd vs.⁸⁷Sr/⁸⁶Sr diagram and define a smooth hyperbolic mixing curve. Over a wide area, straddling different orogens, most granites may be accounted for by a binary mixture between a recycled crustal component and a depleted mantle-like component. No correlation is observed between either Pb and Sr or Nd isotopic ratios, or any isotopic ratio and major element contents. Quantitative modelling suggests that two cases fit the Sr and Nd characteristics of these granites: they both require anatexis of the crust on a scale large enough to average the isotopic properties of heterogeneous terranes. In the first case, the mantle-derived component may be represented by differentiated Island Arc-type magmas, and the granites result from mixing these magmas with anatectic melts. In the second case, mantle-derived igneous rocks, such as obducted ophiolites, are part of the crustal source and their variable involvement in the anatectic process causes isotopic variations.CRPG Contribution n 630.     

山东蓬莱、临朐新生代碱性玄武岩的钕、锶同位素组成

本文报道了鲁东和鲁西新生代碱性玄武岩13个样品的Nd、Sr同位素组成,~(143)Nd/~(144)Nd=0.512967—0.512744,~(87)Sr/(86)Sr=0.70349—0.70450。它们在地质剖面上呈现规律性变化,可能与其地幔源区同位素组成的层状分带有关。鲁西地幔源区具有较鲁东更加亏损的组份。两地地幔源区在演化中都曾发生过地幔交代(或富集)作用,根据玄武岩Nd同位素模式年龄估计地幔交代作用发生的时间为0.45Ga。     

Isotopic relationships of volatile and lithophile trace elements in continental ultramafic xenoliths

The concentrations and isotopic compositions of Sr, Nd, Pb, He and C have been determined for suites of xenoliths from Bullenmerri (Australia), Ichinomegata (Japan), Geronimo (Arizona), and East Africa. The wehrlites and pyroxenites from Bullenmerri have Sr, Nd and Pb isotopic compositions that are generally similar to those found for alkali basalts in the region. The spinel lherzolites, in contrast, have higher ⁸⁷Sr/⁸⁶Sr and ²⁰⁶Pb/²⁰⁴Pb and lower ¹⁴³Nd/¹⁴⁴Nd ratios. Whereas the isotopic compositions of He are generally within the range of mid-ocean-ridge basalts (MORB) and do not covary with those of other trace elements, there is an apparent correlation between the ¹³C/¹²C and ¹⁴³Nd/¹⁴⁴Nd ratios for each of the two petrologic groups. These relationships, if substantiated for other xenolith suites, greatly limit the possible mechanisms for generating lithophile and volatile isotopic variations in the continental lithosphere. The helium isotopic compositions for all of the xenoliths fall within the range for MORB. This includes those from Ichinomegata, suggesting that the lower ³He/⁴He ratios found for He sampled at the surface at subduction zones result from mixing mantle He with near-surface crustal He rather than with subducted radiogenic He. Measured C isotopic compositions (relative to Peedee belemnite) for the Ichinomegata xenoliths include values that are both lighter and heavier than those in MORB, and are compatible with contributions from subducted carbon. The Nd and Sr isotopic compositions of the Ichinomegata xenoliths exhibit a correlation over a substantially greater range of values than typically observed for other light-rare-earth-element (LREE)-depleted xenoliths, and include more radiogenic Sr and less radiogenic Nd compositions. The carbon isotopic compositions found for the East African and Geronimo xenoliths extend to values that are lighter than those typically found for MORB.     

青藏高原新生代埃达克质岩的厘定及其意义

常量、微量及Sr-Nd-Pb同位素研究表明,青藏高原藏北石水河—浩波湖—多格错仁北部分布的一套新近纪(9.4～26.9 Ma)安山质-英安质-流纹质火山岩具有埃达克岩的地球化学特征。岩石ω(SiO_2)>58％,ω(Sr)>350×10~(-6),低Y和Yb,高La/Yb比,无铕异常。岩石N(~(87)Sr)/N(~(86)Sr)=0.706 365～0.708 156,N(~(208)Pb)/N(~(204)Pb)=38.955～39.052,N(~(207)Pb)/N(~(204)Pb)=15.651～15.672,N(~(206)Pb)/N(~(204)Pb)=18.679～18.839,N(~(143)Nd)/N(~(144)Nd)=0.512 411～0.512 535,ε(Nd)=—2.01～—4.43,充分表明它们为一套典型的壳源中酸性火山岩系,源自高原加厚陆壳下部的一个榴辉岩质源区的部分熔融。     

钾玄岩系列:藏东玉龙铜矿带含矿斑岩Sr、Nd、Pb同位素组成

西藏东部玉龙铜矿带,包括玉龙、扎拉尕、莽总、多霞松多和马拉松多含矿斑岩,马牧普钾质碱性斑岩和总郭碱性火山岩等Sr、Nd、Pb同位素组成比较一致,其数据点均分布在地幔演化区,接近EMI地幔端元,暗示其物质来源于交代地幔源区。     

Isotopic and Geochemical Investigation of the Chilwa Island Carbonatite Complex, Malawi: Evidence for a Depleted Mantle Source Region, Liquid Immiscibility, and Open-System Behaviour

Initial Nd, Pb, and Sr isotopic data from carbonatites and associatedintrusive silica-undersaturated rocks from the early Jurassic,Chilwa Island complex, located in southern Malawi, central Africa,suggest melt derivation from a Rb/Sr- and Nd/Sm-depleted butTh/Pb- and U/Pb-enriched mantle source. Initial ¹⁴³Nd/¹⁴⁴Nd(0.51265–0.51270) isotope ratios from the Chilwa Islandcarbonatites are relatively constant, but their initial ⁸⁷Sr/⁸⁶Sr(0.70319–0.70361) ratios are variable. The ¹⁸O_smow (9.53–14.15%0)and ¹³C_PDB (–3.27 to –1.50%0) isotope ratios ofthe carbonates are enriched relative to the range of mantlevalues, and there is a negative correlation between ¹⁸O andSr isotope ratios. The variations in Sr, C, and O isotopic ratiosfrom the carbonatites suggest secondary processes, such as interactionwith meteoric groundwater during late-stage carbonatite activity.The initial ¹⁴³Nd/¹⁴⁴Nd (0.51246 0.51269) and initial ⁸⁷Sr/⁸⁶Sr(0.70344–0.70383) isotope ratios from the intrusive silicaterocks are more variable, and the Sr more radiogenic than thosefrom the carbonatites. Most of the Pb isotope data from Chilwa Island plot to the rightof the geochron and close to the oceanic regression line definedby MORBs and OIBs. Initial Pb isotopic ratios from both carbonatites(²⁰⁷Pb/²⁰⁴Pb 15.63–15.71; ²⁰⁶Pb/²⁰⁴Pb 19.13–19.78)and silicate rocks (²⁰⁷Pb/²⁰⁴Pb 15.61–15.72; ²⁰⁶Pb/²⁰⁴Pb18.18–20.12) show pronounced variations, and form twogroups in Pb-Pb plots. The isotopic variations shown by Nd, Pb, and Sr for the ChilwaIsland carbonatites and intrusive silicates suggest that thesemelts underwent different evolutionary histories. The chemicaldata, including isotopic ratios, from the carbonatites and olivinenephelinites are consistent with magmatic differentiation ofa carbonated-nephelinite magma. A model is proposed in whichdifferentiation of the carbonatite magma was accompanied byfenitization (metasomatic alteration) of the country rocks bycarbonatite-derived fluids, and subsequent alteration of thecarbonatite by hydrothermal activity. The chemical and isotopicdata from the non-nephelinitic intrusive silicate rocks reveala more complex evolutionary history, involving either selectivebinary mixing of lower-crustal granulites and a nephelinitemagma, or incremental batch melting of a depleted source andsubsequent crustal contamination.