大气臭氧总量的经验计算方法

依据臭氧生消与紫外辐射(UV)能量利用相互作用的观点,考虑与臭氧有关的主要因子UV、大气中物质在化学和光化学反应中对UV能量的吸收、气溶胶粒子的散射等,在分析1990—1992年臭氧总量、太阳辐射、气象资料的基础上,建立了计算臭氧总量的经验模式,其优点是所用资料均可由常规气象站获得。结果表明,计算值与观测值符合得比较好。利用该经验模式计算了北京地区1979年1月—1996年6月的臭氧总量,计算值与观测值同样比较一致,二者相对偏差的最大值、最小值、平均值分别为15.2%、0.05%和4.9%,相对偏差在±10%之内的比例为91.4%,因而该经验模式是合理、可行的。1991年之后北京地区臭氧的下降与Pinatubo火山气溶胶的影响有关。     

利用MODTRAN 3计算我国太阳直接辐射和散射辐射

根据光的多次散射理论——离散纵标法,利用我国国家一级辐射测站的大气廓线,计算出晴空大气观测波段不同高度上的太阳直接辐射和向下散射辐射。将模式输出的地面辐射值与地面辐射观测资料进行比较,对不同高度的太阳直接辐射和向下散射辐射以及日变化进行了讨论。最终目的是直接由MODTRAN3计算我国辐射空白站的地面辐射值,以弥补我国辐射站稀少,时空分布短缺的不足。     

由卫星资料估算晴空大气太阳直接辐射和散射辐射

根据光的多次散射理论 ,对水汽、气溶胶、臭氧、混合气体等实行辐射参数化处理 ;利用中国探空站资料和诺阿 ( NOAA)气象卫星垂直业务探测器 ( TOVS)资料反演的探空资料 ,由离散纵标法计算了大气各高度上的太阳直接辐射和散射辐射 ,并与此同时的和同站点位置的卫星可见光、红外测值进行统计回归拟合 ,建立卫星测值与大气中太阳直接辐射和散射辐射的计算模式 ,据此可以利用卫星资料估算太阳直接辐射和太阳散射辐射 ,这对于大气环境光学特性和大气环流、气候变化的研究有重要意义。     

利用MODTRAN3计算我国太阳直接辐射和散射辐射

根据光的多次散射理论－离散纵标法，利用我国国家一级辐射测站的大气廓线，计算出晴空大气观测波段不同高度上的太阳直接辐射和向下散射辐射。将模式输出的地面辐射值与地面辐射观测资料进行比较，对不同高度的太阳直接辐射和向下散辐射以及日变化进行了讨论。最终目的是直接由MODTRAN3计算我国辐射空白站的地面辐射值，以弥补我国辐射站稀少，时空分布短缺的不足。     

地面臭氧光化学过程规律的初步研究

给出了1996年夏季在广东肇庆鼎湖山对光化辐射、地面O3、NO、NO2浓度的观测结果,对影响地面O3、NO、NO2的主要因子进行了分析。晴天,地面O3、NO、NO2浓度有明显的日变化;阴天,它们的日变化比较复杂。晴天和阴天,在lnQUVB/m和lnQvis/m(其中QUVB为紫外B辐射,Qvis为可见光辐射,m为大气质量)与地面O3、NO,NO2浓度、整层大气水汽含量(q1、q2、q3、q4)之间存在着很好的相关关系。利用得到的关系式计算了地面O3浓度,在紫外和可见光波段,计算值与观测值符合得都比较好。     

华北地区光合有效辐射的计算方法研究

2004年9月—2006年10月,选择华北地区的4个观测站开展了太阳辐射（光合有效辐射PAR、可见光辐射VIS、总辐射Q等）、气象参数等的综合测量,得到了PAR、VIS等的变化特征,结果表明：PAR/Q、VIS/Q、PAR/VIS相对稳定,有明显的日、逐日和季节变化,并受到水汽、散射因子、云等因素的影响。2004—2006年禹城、栾城、香河、兴隆地区VIS/Q,PAR/Q和PAR/VIS的平均值分别为0.39,1.95 mol/MJ和4.97 mol/MJ;0.39,1.94 mol/MJ和4.95 mol/MJ;0.43,2.16 mol/MJ和4.97 mol/MJ;0.42,2.03 mol/MJ和4.89 mol/MJ。建立了计算华北地区实际天气PAR、VIS小时累计值的经验公式及PAR与VIS转换关系式,计算值与观测值符合得都比较好。考虑水汽和散射因子时,PAR、VIS计算值与观测值的相对偏差分别为13.0%、12.4%。由于某些站点可能缺少直接或散射辐射,也可以只考虑水汽因子,此时,PAR、VIS的相对偏差分别为13.2%、12.8%。对于PAR、VIS的传输和计算来说,水汽因子的作用最为重要;散射因子的作用虽弱于水汽因子,但也不应该忽视。     

北太平洋洋面太阳辐射收支的计算

本文用参数化方法计算了北太平洋地面泣面的太阳辐射收支各分量。在计算方案中考虑了大气水汽、二氧化碳气体、臭氧和尘埃等的吸收作用，同时计算了北太平洋上空整层大气的大阳辐射增温率，给出了上述各结果的分布特征图，描述了北太平洋地区洋面太阳辐射收支的基本特征及其主要影响因子。     

西安市臭氧污染特征及其与气象条件的关系

基于2014-2017年西安市环保局臭氧观测资料、泾河气象站总辐射和气象资料以及长安气象站紫外辐射和气象资料,对西安市臭氧污染特征及其与气象条件的关系进行了研究。结果表明:西安市臭氧质量浓度的日变化和月变化均呈明显的单峰形态;日最小值22.2μg/m^3和最大值100.7μg/m^3分别出现在07时和16时;臭氧日最大8 h平均质量浓度(用C8h(O3)表示)月均值最大为148.5μg/m^3,最小为30.0μg/m^3,分别出现在7月和11月。总辐射日最大辐照度、日总辐射曝辐量和日紫外辐射曝辐量与C8h(O3)之间具有显著的正相关关系,并且以日紫外辐射曝辐量与C8h(O3)的相关性最高,表明紫外辐射对近地面臭氧质量浓度的影响更为强烈。日最高气温、平均气温、日照时数和C8h(O3)正相关,风速、相对湿度与C8h(O3)负相关,表明晴空时高温、低湿、小风更有利于近地面臭氧的形成。统计关系显示,在5-8月,当日最高气温大于35℃或日最低相对湿度小于40%时,需要警惕臭氧超标污染的发生。     

东莞市辐射强度特征及影响因子

东莞观测站采用地面辐射基准站网(BSRN)通用的荷兰Kipp & Zonen设备,进行太阳短波辐射和地面、大气长波辐射观测。利用2010年8月—2011年7月的观测数据,用统计分析的方法,得到地面太阳短波辐射和地面、大气长波辐射强度的变化特征,并初步分析了影响辐射强度变化的因子。结果表明,东莞市各月的太阳总辐射平均值呈现单峰值变化,且夏季＞秋季＞春季＞冬季,短波辐射各分量的日变化也呈明显单峰型变化特征;长波辐射的日、月变化趋势较平缓;东莞市全年各月净辐射通量平均值均为正值。云是影响太阳辐射强度变化的显著因子,对直接辐射的衰减更明显,多云天气的总辐射、直接辐射全年平均衰减率分别为11%、34%,阴天总辐射、直接辐射全年平均衰减率分别达到47%、83%。大气透明度对短波辐射和长波辐射强度变化均产生影响,无霾日总辐射、直接辐射、反射辐射强度均比灰霾日强,而散射辐射则较弱,灰霾日的天空长波辐射及地面长波辐射强度稍强于无霾日。还探讨了总辐射观测值与理论值的差异,推测水汽对短波辐射的衰减是造成太阳短波辐射平衡存在差异的原因之一。      

北京地区太阳紫外辐射的观测与分析研究

利用北京地区太阳辐射和其它常规气象观测资料，得到了到达地面的太阳紫外辐射的计算公式，并将计算值与观测值进行了比较，两者吻合得比较好。最后给出了北京地区地面太阳紫外总辐射的变化趋势，计算结果表明，地面太阳紫外总辐射对大气浑浊度的变化比对大气臭氧总量的变化敏感得多。     

鼎湖山森林地区臭氧及其前体物的变化特征和分析

通过对鼎湖山森林地区近地面O3和NOx浓度、太阳辐射、气象参数等为期一年的观测和资料分析,给出了地面O3和NOx浓度、太阳辐射的变化规律及其相互之间的关系.地面O3、NOx、CO、SO2浓度以及紫外辐射、太阳总辐射等有明显的日变化和季节变化.不同因子对O3的敏感性试验结果表明,晴天和实际天气,O3浓度对NO、NO2浓度的变化最为敏感,其次是水汽、气溶胶,最后是紫外辐射.所有因子的变化均引起O3在湿季比干季更大的变化率,因此在研究臭氧化学和光化学时,应该考虑水汽以及OH自由基的重要作用.对于晴天和实际天气的逐时值和日平均值而言,O3浓度与NO2/NO之间存在很好的正相关关系,比值NO2/NO可以作为判断O3峰值出现的一个指标.O3极值的出现既受NO和NOx影响,也受气象因素(温湿度、云、风、雾、降雨)和辐射的影响.周末O3、NOx浓度及NO2/NO有规律的增大,表明实验地点的大气受到人为污染源的影响.     

禹城地区光合有效辐射的计算方法

利用2005年7月-2006年10月在山东禹城对太阳辐射（包括光合有效辐射PAR、可见光辐射VIS、总辐射Q等）、气象要素等进行的4次综合观测资料,初步得到了朋R,VIS的日、季节变化特征并对其进行了分析,结果表明：各辐射的小时累计之比vIS／Q,PAR／Q,PAR／VIS相对稳定,其平均值分别为0．39,1．95（mol／MJ）,4．97（mol／MJ）,但它们均有明显的日、逐日、季节变化,并受水汽、气溶胶、云等因素的影响。同时建立了实际天气PAR,VIS的小时累计经验公式及其转换关系,计算值与观测值均比较接近。当考虑水汽和散射因子时,PAR,VIS的计算值与观测值的相对偏差分别为11．1％,10．6％。限于实际情况,可以只考虑水汽因子的作用来计算PAR和VIS的小时累计值,它们的相对偏差分别为13．3％,12．6％。水汽因子对于PAR,VIS的传输和计算具有重要作用。     

Analysis of 40 year records of solar radiation data in Shanghai,Nanjing and Hangzhou in Eastern China

Summary In this paper, we analyze global, direct and diffuse solar radiation data on a horizontal surface observed at stations in Shanghai, Nanjing and Hangzhou for the period of 1961 to 2000. The data include monthly averages of the daily clearness index (G/G₀: the ratio of global to extraterrestrial solar radiation) and the diffuse fraction (D/G: the ratio of diffuse to global solar radiation. The present study has processed and analyzed the data, including variables or statistics of mean, and annual monthly and daily total, the diurnal variation and the frequency of daily totals of global solar radiation. A correlation between daily values of clearness index and diffuse fraction is obtained and recommended correlation equations were calculated. The annual variations and trend of yearly series are analyzed for daily global, direct and diffuse radiation on a horizontal surface, as well as for daily clearness index and diffuse fraction in Shanghai, Nanjing and Hangzhou. The results show: 1) the east China is characterized by a decrease in global and direct radiation and a little increase in diffuse radiation and a negative linear relationship was obtained between clearness index and diffuse fraction. 2) The annual variations of global, direct and diffuse radiation for Shanghai, Nanjing and Hangzhou are similar with relative low values of global and direct radiation in June due to the Meiyu period. 3) The acceleration of air pollution and decrease of relative sunshine are the possible causes for the decrease of global and direct radiation.     

A Possible Photochemical Link Between Stratospheric and Near-Surface Ozone on Swiss Mountain Sites in Late Winter

Record high near-surface ozone concentrations at two elevated sites (Chaumont, 1140 m asl, and Rigi, 1030 m asl) in Switzerland were observed simultaneously with extremely low total ozone during a fair weather period in mid-February 1993. An analysis of ozone, temperature, humidity, and wind profiles suggests that the surface ozone peaks were most possibly generated within the region in a layer between about 1000 and 1500 m asl. Mean diurnal cycles of ozone concentration during the period shows a strong increase from late morning to late afternoon at Chaumont and at the same time a decrease at the high alpine site Jungfraujoch (3580 m asl). The different diurnal ozone cycles can both be explained photochemically by taking into account the large difference in NOx concentrations (about two orders of magnitude) between the sites. Photochemical processes are also indicated by the diurnal cycles of NO2 and NO concentration. As a strong photochemical activity is not expected in mid-February at 47°N, we hypothesize that the extremely low total ozone played a role. Total ozone controls the amount of UV-B radiation reaching the troposphere and thus influences photochemical processes. Using a radiation model, we calculated an increase in ozone photolysis at Chaumont and Jungfraujoch of 73% and 83%, respectively, on the day with the lowest total ozone (243 DU) compared to average February conditions (335 DU). It is suggested that total ozone changes have the potential to stimulate photochemistry sufficiently to produce the observed surface ozone peaks at Chaumont and Rigi of 61 and 64 ppbv, respectively. A fog layer just below Chaumont during these days probably also influenced photochemistry, but on a smaller spatial scale. Our empirical results on the influence of changing UV radiation on tropospheric photochemistry are in close agreement with model studies of other groups. Although this case study represents unique conditions, a distinct anticorrelation between near-surface ozone at Chaumont and total ozone also appears in other years (1992–1997) when selecting fair weather days in mid-February. However, other influences cannot be excluded. The selected days provide evidence of a significant photochemical source of ozone in the mid-latitude lower troposphere in late winter.     

香河地区光合有效辐射的测量和计算

2004年9月12日—2006年10月31日,在河北省香河县对太阳辐射（包括光合有效辐射PAR、可见光辐射VIS和总辐射Q等）、气象参数等进行了综合测量,初步得到了PAR、VIS等的变化特征。观测表明,小时累计之比PAR/Q、VIS/Q、PAR/VIS相对稳定,2004—2006年的平均值分别为2.164、0.434 mol•MJ-1和4.967 mol•MJ-1,同时它们表现出明显的日、逐日和季节变化特征,并受到水汽、气溶胶、云等因素的影响。建立了实际天气条件计算PAR、VIS小时累计值的经验公式以及PAR与VIS转换关系式,计算值与观测值符合得较好。在考虑水汽和散射因子时,PAR、VIS计算值与观测值的相对偏差分别为9.9%和10.8%。限于实际情况,也可以只考虑水汽因子的作用来计算PAR和VIS小时累计值,它们的相对偏差分别为11.1%和11.8%。对于PAR、VIS的传输和计算来说,水汽因子的作用至关重要。散射因子的作用虽然弱于水汽因子,但它的作用不容忽视。     

The effect of ozone and aerosols on the surface erythemal UV radiation estimated from OMI measurements

Surface erythemal UV radiation is mainly affected by total column ozone, aerosols, clouds, and solar zenith angle. The effect of ozone on the surface UV radiation has been explored many times in the previous studies due to the decrease of ozone layer. In this study, we calculated the effect of aerosols on the surface UV radiation as well as that of ozone using data acquired from Ozone Monitoring Instrument (OMI). First, ozone, aerosol optical depth (AOD), and surface erythemal UVB radiation measured from satellite are compared with those from ground measurements. The results showed that the comparison for ozone was good with r ² of 0.92. For aerosol, there was difference between satellite measurements and surface measurements due to the insufficient information on aerosol in the retrieval algorithm. The r ² for surface erythemal UV radiation was high (～0.94) but satellite measurements showed about 30% larger values than surface measurements on average by not considering the effect of absorbing aerosols in the retrieval process from satellite measurements. Radiative amplification factor (RAF) is used to access the effect of ozone and aerosol quantitatively. RAF for ozone was 0.97～1.49 with solar zenith angle. To evaluate the effect of aerosol on the surface UV radiation, only clear-sky pixel data were used and solar zenith angle and total column amount of ozone were fixed. Also, RAF for aerosol was assessed according to the single scattering albedo (SSA) of aerosols. The results showed that RAF for aerosol with smaller SSA (< 0.90) was larger than that for with larger SSA (> 0.90). The RAF for aerosol was 0.09～0.22 for the given conditions which was relatively small compared to that for ozone. However, considering the fact that aerosol optical depth can change largely in time and space while the total column amount of ozone does not change very much, it needs to include the effect of aerosol to predict the variations of surface UV radiation more correctly.     

广西地面太阳辐射分布特征以及对人体健康的影响

选用2001-2010年广西桂林、南宁、北海3个地面太阳辐射站的总辐射资料及日照时数资料,分析了总辐射日总量、日最大值的年变化规律,时总量的日变化规律,日最大值出现时间频率的分布区间等,结果表明：（1）广西太阳总辐射的日总量、日最大值强度的年变化规律明显。总体呈现夏季最大,春秋季次之,冬季最小的特点。大多数情况下,随着纬度由北向南递减,总辐射值递增。日总量与日照时数的年变化趋势存在正向的线性相关。（2）广西太阳总辐射的时总量的日变化规律明显。总体呈现中午前后强．早晚弱的特点。最大值一般出现在一天中的10-14时这个区间．     

DISTRIBUTIONS AND VARIATIONS OF SURFACE OZONE IN CHANGSHU, YANGTZE DELTA REGION*

Through one and half year continuous in-situ measurements,the distributions and variations of surface ozone and its precursors at a typical mixed agricultural and metropolitan area-Changshu,Yangtze Delta region,were studied.The preliminary analysis on the concentration levels and variations of surface ozone indicated the obvious seasonal and diurnal cycles during the experiment.The hourly averaged concentrations of surface ozone were high,in about 17% of total valid hours the surface ozone concentration exceeded 50 ppb,and in 22 days the hourly averaged ozone concentration was greater than 100 ppb.There were about 40% of the days in that the daily maximum 8-hour ozone concentration was greater than 50 ppb.The days with daily maximum 8-hour ozone concentration greater than 80 ppb were about 33 days that accounted for about 8% of the observational days.The variations of 5-day moving averaged ozone concentrations depended both on the weather conditions and on the changes of ozone in background atmosphere.Photochemical process had the significant impacts on ozone productions.