西北某喷流沉积型铁铜矿工艺矿物学研究

西北某铁铜多金属矿床规模大,具有铁、铜、金、铅锌等多金属矿化,属于海底喷流沉积型矿床。笔者采用工艺矿物学研究方法,查明了矿石工艺矿物学特性。研究结果表明,矿石的组成矿物种类较为复杂,铁矿物主要是磁铁矿、半假象―假象赤铁矿和菱铁矿,其次为赤铁矿,铜矿物主要包括黄铜矿和斑铜矿。矿石中铁矿物和铜矿物均具不均匀细粒―微细粒嵌布特征;通过选矿可获得铜精矿和铁精矿。     

鲁中莱芜地区矽卡岩铁矿的工艺矿物学性质

采用化学分析、X射线衍射分析、偏光显微镜下矿物组成分析和扫描电子显微镜对鲁中莱芜地区矽卡岩铁矿石的工艺矿物学性质进行研究,以期对选厂的生产工艺流程和选矿指标优化提供技术资料。研究发现,矿石中主要金属矿物为磁铁矿、黄铁矿、黄铜矿、辉铜矿,各金属矿物共生关系密切,磁铁矿含量为52%,矿石全铁品位为40.86%,其中磁性铁占有率为91.31%,磁铁矿嵌布粒度以中细粒为主,大多在0.1mm~0.01mm之间;铜矿物包括黄铜矿和辉铜矿以及少量孔雀石等氧化铜矿物,铜品位为0.131%,其中硫化铜占有率为65.65%,黄铜矿和辉铜矿均以微细粒嵌布为主,粒度主要在0.08 mm~0.01mm;矿石中钴品位为0.018%,其中硫化钴占有率为30.56%,大部分以氧化钴的形式存在于磁铁矿中。综合各金属矿物的工艺矿物学性质,该矿石中的铁矿物弱磁选铁理论回收率为91.31%,铜矿物浮选铜理论回收率为65.65%,而钴矿物浮选钴理论回收率为30.56%。     

云南思茅地区铜锌硫化矿工艺矿物学分析

云南思茅地区有大量难选铜锌多金属硫化矿资源,由于其矿石结构、成分及构造复杂,采用传统的镜下鉴定工艺矿物学分析对铜、锌等有价金属的赋存状态等难以自动准确定量。本文采用化学分析、偏光显微分析及矿物解离度分析(MLA)等多种现代分析测试方法,研究该地区矿石的主要元素组成、矿物种类、嵌布和包裹特性等。分析表明,铜锌硫化矿的主要元素及含量为Cu 3.03%、Zn 3.90%、S 27.44%、Pb 0.13%。金属矿物主要是黄铁矿、黄铜矿和闪锌矿,含少量方铅矿;目的矿物黄铜矿、闪锌矿主要与黄铁矿连生和被其包裹;其次黄铜矿和闪锌矿相互连生和被其包裹,且96%以上的黄铜矿、闪锌矿和黄铁矿均分布在粒度大于9.6μm的易选粒级范围。方铅矿多呈细粒嵌布状,与铜、锌、硫矿物之间的磨矿解离有一定困难。根据工艺矿物学研究结果,本文提出,思茅地区的铜锌硫化矿矿石需磨至约31μm方能实现铜-锌-硫矿物的解离,需磨至约14μm方能实现铅与其他矿物的解离,同时预测了铜锌硫化矿中铜和锌的理论选矿回收率分别为91.22%和84.92%。本文研究成果对该地区难选多金属硫化矿的选矿技术制定和指标选择具有实际的指导意义。     

新疆卡拉玛铜矿床伴生金工艺矿物学研究

文章对卡拉玛铜矿床中伴生金的工艺矿物学特征进行了研究.结果显示,矿石主要由黄铜矿、黄铁矿、菱铁矿和少量辉铜矿组成,伴生金主要呈独立矿物自然金产出,多数金矿物以脉型和裂隙型嵌布于矿石中,金矿物的粒度多分布在0.10～0.05mm,矿石中金的理想回收率为86.78%.     

贵州威宁沉积型赤铁矿矿石工艺矿物学研究

对贵州威宁沉积型赤铁矿石进行了工艺矿物学研究,重点研究了该矿石的矿物组成、主要矿物嵌布特征和主要含铁矿物赤铁矿的单体解离情况。研究表明,该矿石属于低磷、低硫、微细粒嵌布的赤铁矿石;矿石中主要铁矿物以赤铁矿为主,其次为磁铁矿和褐铁矿,主要脉石矿物以石英为主,其次为绿泥石、云母、高岭石等粘土矿物;赤铁矿嵌布粒度极细,平均粒度0.015mm,且赤铁矿与脉石矿物嵌布关系复杂。本研究为该矿石的开发利用提供基础资料。     

河南嵩县下蒿坪金矿工艺矿物学研究

通过化学分析、扫描电镜以及工艺矿物学自动定量分析系统(MLA)等测试方法对河南嵩县下蒿坪金矿进行了系统的工艺矿物学研究,包括原矿化学组成、矿物组成、金的赋存状态、主要载金矿物嵌布特征以及矿物解离特性等。结果表明,该金矿中主要可回收的有价金属为金,其品位为3.75×10^-6。该金矿的原矿矿物主要由石英、钾长石、钠长石、黄铁矿和铁白云石组成,此外还有少量的赤铁矿、萤石、白云石以及方解石。原矿中的金主要赋存在黄铁矿中,而黄铁矿大部分以细粒、微细粒形式嵌布在石英和长石颗粒中。原矿中自然金的含量非常少,多以单独的自然金颗粒形式存在。原矿磨至P₈₀=0.074 mm(-0.074 mm粒级含量占80%)时载金矿物黄铁矿、方铅矿、闪锌矿的单体解离度相对较高,有利于通过浮选回收。     

X射线衍射-扫描电镜等技术研究秘鲁铜硫矿石选矿工艺矿物学特征

秘鲁铜硫矿石的主要回收对象是铜和硫矿物,由于铜矿物嵌布复杂、粒度过细以及与各种脉石矿物或金属矿物交生关系紧密,利用传统工艺矿物学研究方法如化学分析、光学显微镜检测等较难准确定量其工艺矿物学参数。本文采用化学分析、X射线衍射、扫描电镜、偏光显微镜及矿物参数自动分析系统(MLA)等技术手段,研究秘鲁铜硫矿石的化学成分、矿物组成和主要矿物的嵌布特征、粒度分布及单体解离特性等,并对影响选矿指标的主要矿物学因素进行分析。结果表明:矿石中主要元素为Cu(0.65%)和S(9.53%)。矿石中黄铁矿(16.57%)含量较高,形态较为规则,与其他矿物之间的交生关系相对简单,粒度普遍偏粗,其中粒径大于0.30mm的黄铁矿占95.06%。铜矿物主要以不规则粒状、皮壳状、网脉状、纤维状、尘粒状、斑点状分布于脉石中或与黄铁矿、闪锌矿、磁铁矿等金属矿物交生紧密,粒度极不均匀,使得铜矿物解离难度加大,且矿石中云母(12.51%)、绿泥石(3.74%)、滑石(3.34%)、高岭石、蒙脱石(3.59%)等黏土质矿物含量较高,在磨矿过程中易发生泥化从而恶化分选环境。根据该类型矿石的工艺矿物学特性,本文建议采用"粗磨-部分优先浮铜-铜硫混浮-混合精矿再磨再选分离"的工艺流程,可得到质量高的铜、硫精矿。     

云南斑岩型多金属金矿的嵌布特征及赋存状态研究

云南西部有大量低品位金矿资源,且具有嵌布粒度不均匀、矿石结构复杂、解离不完全等特点,传统工艺矿物学分析不易快速、准确测定金赋存状态及载金矿物的嵌布特征。本文利用矿物自动分析系统(MLA)、化学分析等方法对滇西多金属金矿进行系统的工艺矿物学研究,查明了该矿的矿物组成、嵌布粒度、连生及包裹关系,同时阐明了载金矿物的工艺矿物学性质对金回收率的影响。结果表明:金主要以游离态自然金的形式存在,嵌布粒度极细,主要集中在0.01~0.02 mm粒度级别;小于0.074 mm粒级的金占原矿总金量的50.08%,其余金以微细包裹体分散于黄铁矿、磁铁矿、黄铜矿等载金矿物中。但载金矿物粒度较细,解离性差,嵌布不均匀,因此提高载金矿物解离度是提高金回收率的一个重要参考方向。     

滇西铜多金属硫化矿的工艺矿物学特性

云南西部地区有大量铜多金属硫化矿资源,主要金属矿物之间连生、包裹及嵌布状态复杂,传统的工艺矿物学研究方法难以对矿物的特性参数实现快速自动定量。为此采用现代工艺矿物学研究系统MLA,对滇西铜多金属硫化矿的化学组成、物相组成,矿物组成、元素分布、嵌布粒度、连生及包裹关系等进行分析,结果表明:滇西铜多金属硫化矿含Cu 1.29%,Zn 2.10%,Pb 0.43%,S 24.93%,有价矿物主要为黄铜矿、闪锌矿和黄铁矿,铜矿物和锌矿物主要与黄铁矿相互连生和包裹,有价矿物中有88%以上分布在大于10μm的易选粒级范围,磨矿粒度达到-15.77μm时,铜矿物和锌矿物能实现单体解离,计算得到铜多金属硫化矿中铜、锌、硫的选矿理论回收率分别为88.49%,92.10%和89.20%。研究结果对该矿的选矿工艺流程制定和选别指标的提高提供了依据和指导,有助于该地区矿产资源的综合开发利用。     

甘肃阳山金矿区黄铁矿的赋存状态与分布特征

甘肃阳山金矿是迄今为止中国发现的最大金矿。已发现的6个矿段均赋存于泥盆系中,矿石中金属矿物主要为黄铁矿和毒砂。黄铁矿有3种类型:微细粒浸染状、半自形颗粒集合体、自形单晶大颗粒;主要分布在千枚岩、花岗闪长岩、石英脉里,具有多期次多类型的特点。根据黄铁矿的特征,金矿化与石英脉体中细粒浸染状的一期黄铁矿有关。黄铁矿为重要的载金矿物之一,自然金(Au)主要以微细粒的形式赋存于黄铁矿晶体的裂隙内以及晶体与晶体的空隙间。黄铁矿赋存状态和分布特征的研究,对矿区进一步找矿具有指导意义。     

Efficient separation of zinc from zinc containing copper sulfide concentrate by chemical leaching

As the most abundant copper containing resource and zinc containing resource, chalcopyrite and sphalerite/marmatite commonly coexist as Cu-Zn mixed ores in deposits. However, it is difficult to completely separate sphalerite and chalcopyrite by flotation, thus resulting in the existence of zinc impurity in copper concentrate. Sphalerite/marmatite existed in copper sulfide concentrate as impurity may lead to severe damage of the smelting equipment, and cause the waste of copper and Zn resources, it will also decrease of the sale price of copper concentrates. Therefore, the deep separation of zinc from zinc bearing copper sulfide concentrate is of great significance. In this work, selective chemical leaching was developed to efficiently remove zinc from zinc containing copper sulfide concentrate. Under the optimal condition (i.e., sulfuric acid concentration exceed 100 g/L, temperature of 80 °C, pulp density of 10%, leaching time of 48 h), over 85% Zn was extracted into the leaching solution together with only about 10% Cu and Fe, according to the leaching experiment. Leaching slurry had good solid-liquid separation characteristics, and zinc can be further effectively recovered from the leaching solution. According to X-ray diffraction (XRD) and scanning electron microscope/energy dispersive spectrometer (SEM/EDS) analysis, chalcopyrite was the main mineralogical phase in the residues, which can be regarded as high quality copper concentrate for metallurgy. Accordingly, a new process for deep and efficient separation of Cu-Zn mixed ores has been proposed.     

新疆克兰盆地红墩铅锌矿床与铁木尔特铅锌矿床的对比研究

虽然红墩铅锌矿床与铁木尔特铅锌矿床均产于新疆阿尔泰山南缘中部的克兰裂谷盆地,且二者的矿体产状与地层走向一致,具有明显的纹层状构造,但是在某些主要地质特征上,二者却存在显著的差异.例如,前者赋存于中泥盆统阿勒泰镇组的沉积碎屑岩,与海相基性火山岩有关,表现为锌多铅少,不含铜,且闪锌矿为含铁较少的低温闪锌矿;而后者却赋存于下泥盆统康布铁堡组的火山碎屑-碳酸盐岩中,与海相酸性火山岩有关,表现为铅多锌少,富含铜,且闪锌矿为含铁较多的高温闪锌矿.综合对比研究表明,红墩铅锌矿床属于SEDEX型铅锌矿床,而铁木尔特铅锌矿床则属于VHMS型铅锌矿床.     

Iron–phosphorus relationship in the iron and phosphorite ores of Egypt

Iron and phosphorite ores are very common in the geological record of Egypt and exploitable for economic purposes. In some cases these deposits belong together to the same geographic and geologic setting. The most common deposits include phosphorites, glauconites, and iron ores. Phosphorites are widely distributed as a belt in the central and southern part of Egypt. Sedimentary iron ores include oolitic ironstone of Aswan area and karstified iron ore of Bahria Oasis. Glauconites occur in the Western Desert associated with phosphorites and iron ores. As these ores are exploitable and phosphorus in iron ores and iron in phosphorites are considered as gangue elements, the iron–phosphorus relationship is examined in these deposits to clarify their modes of occurrences and genetic relationship based on previously published results.Phosphorus occurs mainly as carbonate fluorapatite (francolite). Iron, on the other hand, occurs in different mineralogical forms such as glauconites, hematite, limonite and goethite.In P-rich rocks (phosphorites) no relationship is observed between iron and phosphorus, which in turn indicates that the FeP model is unlikely to interpret the origin of the late Cretaceous phosphorites and the association of phosphorites and glauconites in Egypt. In Fe-rich rocks (iron ores and glauconites) also no relationship between iron and phosphorus is observed. The present work, therefore, does not support the hypothesis that there is a genetic relationship between phosphorus and iron in sedimentary rocks.     

Mode of occurrence of phosphorus in iron ores of eastern limb,Bonai Synclinorium,eastern India

The eastern limb of horse shoe shaped “Bonai Synclinorium” in India hosts Banded Iron Formations (BIFs), consisting of major high grade iron deposits. Phosphorus (P) gets adsorbed in the iron ore by way of ion exchange mechanism of clay minerals and hydrated secondary iron oxide minerals. Its concentration is lesser in hard ores and blue dust types of ores, while the highest in case of lateritic ores. P content reduces with increase in iron (Fe) content in individual ore types. Along the eastern limb, phosphorus content gradually reduces from north to south direction. Since phosphorus is mainly associated with secondary lateritization process, its concentration is very high in top weathered profile and along the weaker zones.     

西北某钒钛磁铁矿矿石的工艺矿物学研究

西北某矿石属低硫含磷的酸性低品位原生钒钛磁铁矿矿石,通过镜下鉴定、X射线衍射分析和扫描电镜分析等多种手段对原矿的化学成分、矿物组成及含量、矿物的产出形式、矿石的结构构造、主要目的矿物的嵌布粒度等进行了详细的工艺矿物学研究,查明矿石的工艺学特性.研究结果表明,该矿石具浸染状构造和交代构造,其中铁矿物主要是钛磁铁矿和赤铁矿,钛矿物包括钛铁矿、金红石和榍石等.钛磁铁矿和钛铁矿均属不均匀细粒—微细粒嵌布特征,在-400目占95%左右的磨矿细度条件下,通过选矿可获得铁精矿和钛精矿两种产品.     

宁乡式沉积铁矿床的时空分布和演化

宁张式铁矿是我国最重要的沉积型铁矿床,广泛分布于我国南部的鄂、湘、赣、川、滇、黔、桂诸省以及甘南地区。含矿建造主要赋存于中上泥盆统,而以上泥盆统为主,可划分出７个成矿区,其中最重要的鄂西－湘西北成矿区。在１个矿床中通常有１～４层铁矿,其中有１个是主矿层,矿石主要由鲕状赤铁矿组成,次有菱铁矿、鲕绿泥石和褐铁矿,含铁品位一般为３０％～４５％,含磷通过偏高,介于０．４％～１．１％,中泥盆世和晚泥盆世沉积铁矿在分布范围、矿床规模、赋太和围岩建造和矿石特征等方面有一定差异,文章对鄂西－湘西北成矿区的矿宋时空演化作了重点论述,对铁矿的分布与岩相古地理的关系及矿床生成条件进行了讨论,指出含矿建造大多产于海侵程序的沉积岩系中,在湿热环境下较封闭或半封闭的古海盆,古海湾或潮坪中的浅海－滨海相沉积组合是有利的成矿古地理条件,提出要     

The Processing Mineralogy for Lead and Zinc Oxide Ore in Sichuan

Using variety of modern testing methods, the processing mineralogical characteristics for a lead and zinc oxide ore in Sichuan were studied systematically. The chemical analysis result shows that the lead and zinc oxide content exceeding the minimum industrial grade and iron ore, total iron content reaches a minimum industrial grade and associated with gold and silver; The mineralogical analysis result shows that lead and zinc mineral composition and configuration are very complexity. The zinc minerals and zinciferous minerals are sphalerite, hemimorphite, Smithsonite, Hydrozincite, zinc chlorite, limonite, zinc dolomite and zincocalcite; lead minerals and plumbiferous minerals are mainly galena, cerussite, anglesite, limonite and Coronadite; The minerals disseminated grain size are very fine and mineral dissemination characteristics are very complex ; expected theoretical recoveries for lead and zinc were 72% and 67% respectively. The results of this study provide basic data and theoretical basis for ore dressing.     

Mineralogy,geochemistry and origin of Mn in the high-Mn iron ores,Bahariya Oasis,Egypt

Although Mn is one of the major impurities in the economic iron ores from the Bahariya Oasis, information on its modes of occurrence and origin is lacking in previous studies. High-Mn iron ores from El Gedida and Ghorabi–Nasser iron mines were subjected to detailed mineralogical, geochemical, and petrographic investigations using X-ray diffraction (XRD), infrared absorption spectrometry (IR), Raman spectroscopy, X-ray fluorescence (XRF), scanning electron microscopy (SEM), and electron probe microanalyzer (EPMA) to clarify the modes of occurrence of Mn in these deposits and its origin. The results showed that the MnO₂ contents range between 0.03 and 13.9 wt.%. Three mineralogical types have been identified for the Mn in the high-Mn iron ores, including: (1) inclusions within the hematite and goethite and/or Mn accumulated on their active surfaces, (2) coarse-grained and crystalline pyrolusite, and (3) fine-grained cement-like Mn oxide and hydroxide minerals (bixbyite, cryptomelane, aurorite, romanechite, manjiroite, and pyrochroite) between the Fe-bearing minerals. The Mn carbonate mineral (rhodochrosite) was detected only in the Ghorabi–Nasser high-Mn iron ores. Since IR patterns of low-Mn and high-Mn samples are almost the same, a combination of XRD analysis using non-filtered Fe-Kα radiations and Raman spectroscopy could be the best way to identify and distinguish between different Mn minerals.Assuming that both Fe and Mn were derived from the same source, the occurrence of high-Mn iron ores at the base of the stratigraphic section of the deposits overlain by the low-Mn iron ores indicated a supergene origin of the studied ores by descending solutions. The predominance of Mn oxide and hydroxide minerals in botryoidal shapes supports this interpretation. The small grain size of Mn-bearing minerals as well as the features of microbial fossils such as spherical, elliptical, and filamentous shapes of the Fe-bearing minerals suggested a microbial origin of studied iron ores.Variations in the distribution and mineralogy types of Mn in the iron ores of the Bahariya Oasis demanded detailed mineralogical and petrographic characterizations of the deposits before the beneficiation of high-Mn iron ores from the Bahariya Oasis as feedstock for the ironmaking industries in Egypt by magnetizing reduction. High Mn contents, especially in the Ghorabi–Nasser iron ore and occurrence of Mn as inclusions and/or accumulated on the surface of the Fe-bearing minerals would suggest a possible utilization of the high-Mn iron ores to produce ferromanganese alloys.     

玻利维亚铜金锡铁主要矿床类型及资源潜力

玻利维亚的铜矿规模以中小型为主,主要成矿类型为红层型(砂岩层)、沉积相关脉状型、VMS型和IOCG型等。金矿规模以中小型为主,主要成矿类型有火山成因浅成热液型、与深成岩相关的脉状矿床、造山型矿床和砂金矿。锡矿发育众多大型、超大型矿床,成矿类型以玻利维亚型多金属脉状矿床和与长英质深成岩相关的脉状矿床为主,少量砂锡矿。铁矿以El Mutún超大型BIF型铁锰矿著称。西科迪勒拉和玻利维亚高原有重要的浅成低温热液贵金属资源潜力;东科迪勒拉北部主要为钨、锡、金、锑资源,中部为锡、银、金、锑资源,南部有金、锑、银、铅、锌潜力;次安第斯带南部有银-锌资源潜力;查科-贝尼平原带有广泛的砂金矿资源;前寒武纪克拉通内金、铂、镍、钽、铜和铁锰资源潜力丰富。