Geochemical survey of thermal system in Northeast China and their geothermometric characters

The chemical composition of several thermal springs around Changbaishan area has been investigated.Cenozoic basaltic rocks are widely distributed in Northeast China and geothermal characteristics have been described.About one hundred hot springs exist around Changbaishan Volcano at the border between China and D.P.R.Korea with high temperature about 82℃. The pH values of the spring water range from 6.9 to 7.1 and the total flow rate is about 4.8 L /sec. The chemical composition of the thermal springs is sodium carbonate; the high-mineral contents of thermal water are believed to have medicinal properties. Bathhouses are already built along the hot springs to take the advantage of the supposed healing properties. The high quality of those hot springs is believed to be utilitized for mineral water. The chemical equilibrium temperatures were estimated at about 160℃ based on the Na-K-Ca geochemical thermometer.     

胶东温泉地热水水化学及同位素特征研究

对胶东半岛出露的14处温泉的水化学特征、同位素特征进行了分析,得出胶东半岛温泉水的来源主要为大气降水补给、海水补给,年龄以现代水为主。胶东半岛温泉水与围岩矿物未达到完全平衡,不适宜用Na,K,Mg地热温标,玉髓的地热温标显示胶东半岛温泉热储温度在81．26～108．93℃之间。对下一步胶东半岛的温泉地热勘查、开发利用具有指导意义。     

Spatial differentiation in stable isotope compositions of surface waters and its environmental significance in the Issyk-Kul Lake region of Central Asia

Stable isotope values of oxygen(~(18)O) and hydrogen(~(2)H) of surface waters were used to study the origin and environmental significances in the Issyk-Kul basin of Kyrgyzstan in Central Asia, which is the most important intermountain basin in the modern Tien Shan orogen. This study is the first analysis of hydrochemical spatial differentiation in the stable isotopes of surface waters in this watershed.75 samples were collected from rivers, springs, lakes,rain and snow during the rainy season in July and August of 2016. Stable isotopes of ~(18)O and ~(2)H were studied for all samples, and cation ratios(Sr/Ca and Mg/Ca) were also determined for lake water samples.Stable isotope values from precipitation scattered around the Local Meteoric Water Line(determined from Urumqi Station of the global network of isotopes in precipitation(GNIP)), together with values of the Deuterium excess parameter(d) from 15.3‰ to30.5‰, with an average of 19.8‰, indicating that the moisture sources are primarily from regions with low relative humidity. The δ~(18)O and δ~(2)H values were significantly different between the river and lake samples, indicating that regional evaporation caused the isotopic enrichment of lake water. Geospatial autocorrelation, measured by Moran's I coefficient,indicated weak spatial autocorrelation within stable isotopes of oxygen and hydrogen in the surface waters of the studied area, which is primarily an effect of climate during the water chemistry evolution. The cation ratios Sr/Ca and Mg/Ca in lake water samples were not correlated with the concentration of total dissolved solids, but did show correlation with stable isotopic values, which is significant for paleoenvironmental reconstruction.     

基于水化学的沂源盆地地热田成热模式探讨

沂源盆地地热田为低温水热型岩溶热储地热系统,盖层为古近系、白垩系、石炭系,热储层为寒武纪、奥陶纪碳酸盐岩,区内发育的深大断裂如上五井断裂、韩旺断裂、傅家庄断裂等为沟通深部热源的良好通道。为掌握地热田热水的补给来源、热源、地热水年龄,进一步分析其形成机理,采集地热水样品进行了地热水水文地球化学分析、气体及其同位素分析。结果表明,该地热田地热水水化学类型为HCO3·Cl·SO4Na·Ca型、HCO3Ca·Mg型,矿化度小于1g/L;地热水补给来源为大气降水,具深循环特征;热源以壳源为主;地热水年龄10.51ka B.P.,为古地下水。结合地下水循环机理,将其地热水形成机理总结为小型断陷盆地深循环承压型。     

2004年北太平洋柔鱼钓产量分析及作业渔场与表温的关系

根据2004年5~11月我国鱿钓船在北太平洋生产数据,结合表温资料,按经纬度1°×1°的格式,利用Marineexplorer 4.0软件作图进行柔鱼钓产量及渔场与表温的关系分析。结果表明,5~7月在160°E以东海域作业,产量较低;8~10月在150°~160°E海域作业,为生产作业的产量高峰期,占总产量的62.5%;11月在150°E以西海域作业,产量也较低。在150°E以西海域CPUE最高,150°~160°E中部海域次之,160°E以东海域最低。作业渔场的适宜表温呈现出季节性变化。各月适宜表温分别为:5月12~14℃;6月15~16℃;7月14~16℃;8月18~19℃;9月16~17℃;10月15~16℃;11月12~13℃。     

隔档式构造区岩溶地下水流系统多级次嵌套结构的水化学识别

川东隔档式构造区岩溶地下水流系统表现出多级次嵌套结构的特征, 之前主要是定性的水文地质条件分析, 缺乏来自水化学方面的量化依据。利用41个浅层和19个深层岩溶水样的水化学资料开展分析, 发现浅层岩溶水为HCO₃-Ca·Mg型,ρ(Mg2+)较低, 深层岩溶水为SO₄-Ca·Mg型且ρ(Mg2+)明显偏高, 说明地下水在岩溶含水层中的滞留时间与ρ(Mg2+)具有正变关系。对典型剖面地下水流系统的分析表明, 优先采用ρ(Mg2+)来评价地下水滞留时间, 将地下水排泄点ρ(Mg2+)小于20, 50 mg/L分别作为划分局部-中间、中间-区域水流系统的依据。浅层岩溶水受地貌作用控制明显, 其中浅切沟谷泉点为局部地下水流系统的排泄点, 深切沟谷泉点一般属于中间或区域流动系统的排泄点。ρ(Mg2+)反映了泉水循环的滞留时间, 也能够反映钻孔所揭露的深循环特征。这种水化学识别方法可为相似岩溶区识别地下水流系统的多级次嵌套结构提供参考。      

TraceeElements in Leccinum scabrum mushrooms and topsoils from Kłodzka Dale in Sudety Mountains, Poland

In the current study, we determined concentrations and transfer rates of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, P, Rb, Sr and Zn to Brown Birch Scaber Stalks (Leccinum scabrum) mushrooms emerged in the area of Sudety Mountains (Sudetes) in Poland. Fruiting bodies and topsoil samples beneath L. scabrum were collected form the K odzka Dale. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES) for final measurement. Mushrooms contained Ag, Cr, Hg, Co, Ni and Sr at < 1.0 μg/g dry weight; Ba and Pb at ~1.0 μg/g dw; Cd at < 5 μg/g dw; Cu and Mn at > 10 μg/g dw; Al and Ca at ~100 μg/g dw; Fe, Na, Rb and Zn at 100 to 500 μg/g dw, Mg at ~1,000 μg/g dw; P at ~5,000 μg/g dw and K at ~30,000 μg/g dw. Ca, Mn and Ni were nearly equally distributed between stipes and caps; stipes compared to caps were enriched in Ba, Na and Sr, while caps were enriched in Ag, Al, Cd, Co, Cr, Cu, Fe, K, P, Pb, Rb and Zn. The values of bioconcentration factor (BCF) varied highly depending on chemical element and were >1 for Ag, Cd, Cu, K, Mg, Na, P, Rb and Zn, while <1 for Al, Ba, Ca, Co, Cr, Fe, Mn, Ni, Pb and Sr. Topsoil showed elevated content of lead and mean concentration was 99 ± 32 μg/g dw, while cadmium was at 0.41 ± 0.15 and those two highly toxic to human elements occurred in edible caps of L. scabrum at 4.5 ± 2.2 and 2.9 ± 2.0 μg/g dw, respectively.     

宜昌长江南岸岩溶地下水中水生动物群落分布特征及其环境响应

为探究宜昌长江南岸岩溶区地下水中水生动物群落分布特征及环境响应规律,在2018年7月至8月对宜昌长江南岸15处表层岩溶泉及9处岩溶大泉中水生动物进行采集,同时对地下水理化指标进行测试。共采集到809个动物个体,共有13个亚纲,同时包括多个物种的暗层和非暗层种。结果发现:①不同动物在地下水空间分布上各异,在表层岩溶泉,Copepoda的暗层种和Ostracoda的暗层种大量存在(31.3%, 23.7%),Trichoptera和Diptera少量存在(0.4%, 2.9%);在岩溶大泉,Copepoda(非暗层种)和Amphipoda大量存在(25.0%, 8.3%),Ostracoda的暗层种少量存在(2.2%)。②不同地下水的环境也表现出差异,区内岩溶大泉pH, Na+, Ca2+, Mg2+等指标的极差(分别为0.64, 1.25, 34.0, 22.1 mg/L)小于表层岩溶泉(分别为2.45, 5.68, 59.6, 33.4 mg/L),表现出更稳定的环境特征。③通过对各环境因子以及不同物种的逐步回归分析得出,表层岩溶泉的主控环境因子为pH, Na+, Mg2+,岩溶大泉的主控环境因子为pH, SO₄2-, Mg2+;表层岩溶泉的主要代表性生物群落为Ostracoda, Diptera, Turbellaria的暗层物种,岩溶大泉的主要代表性生物群落为Mollusca, Diptera, Decapoda。④通过路径分析发现,生物通过种间相互作用,对环境因子具有直接与间接响应。在表层岩溶泉,Diptera主要通过与Ostracoda的种间关系对Na+和Mg2+起间接响应,另外Ostracoda, Diptera, Turbellaria的暗层种对pH有直接响应;在岩溶大泉,Mollusca主要通过Diptera对pH起间接响应,Diptera通过Decapoda对SO₄2-起间接响应,另Mollusca, Diptera, Decapoda对Mg2+直接响应。研究发现生物分布规律是对于环境因子的直接作用和生物之间的间接作用共同响应结果。      

2006年北太平洋柔鱼作业渔场时空变化及其与表温的关系

<正>柔鱼(Ommastrephes bartramii)广泛分布在北太平洋,20世纪70年代初首先由日本鱿钓船开发,我国大陆于1993年开始利用该资源,1994年进行较大规模地商业性生产。目前北太平洋鱿钓渔业已成为我国远洋渔业的支柱[1]。据估计,历史上北太平洋柔     

干热岩勘查评价指标与形成条件

干热岩具有利用率高、无污染、储量巨大、分布较广、持续稳定、安全性好等特点,被全球公认为在21世纪能够取代化石能源的一种最优质的、可再生的新型清洁能源。目前对于干热岩的成因机理还没有定论,而对于干热岩的勘探寻找、远景区的圈定以及资源评价也有不同的观点,为了有利于干热岩勘探开发,本文在综述前人研究工作基础上,总结归纳了干热岩勘查评价指标,几个重要的指标及其特征如下。第一个指标是岩石圈厚度和莫霍面埋深,岩石圈厚度较小并且莫霍面埋深比较浅,是评价干热岩远景区的一个重要指标。莫霍面埋深较浅指示深部热源（幔源热）更加接近地表,故埋深较浅（较薄的厚度）并具有上隆的特征有利于深部的热量向上传导,为干热岩的孕热环境提供良好的条件。第二个指标是居里等温面,埋深较浅的居里等温面是干热岩远景区一个重要的评价指标。居里等温面是地球内部一个非常特殊的温度（热物质）界面,它不仅能指示地下温度场的分布特征,还可指示地壳深部热能分布特征,对干热岩及地震的成因研究具有十分重要的意义;如果居里面埋深较浅,则热量传导到地表的距离比较短,深部的热流活动更容易向地表传送,不仅是有利的高温干热岩孕热环境,也有利于储存的热能快速向上传导。第三个指标为地温梯度,地温梯度较大是寻找干热岩远景区的一个重要指标;如果一个地区具有较高的地温梯度（≥ 35℃/km）,则随着深度的增加深部的地温增加较快,在相对较浅的地方就可以获得温度较高的岩石体。第四个指标是大地热流,大地热流值较大（≥ 75 mW/m2）就指示地球深部有存在高温岩石体的可能;大地热流是地温场的综合性热参数,能够准确地反映区域内的地温场特征。第五个指标是新构造运动,这也是人们寻找干热岩时容易忽略的一个重要指标。新构造运动包括火山、地震及活动断裂构造等。地震和火山是极具破坏性的自然灾害,两者的发生都表明了地球内部的热能汇聚到一定程度,从而打破了地球内部平衡状态而以地震或火山的形式把热量进行释放的地球系统行为。该指标中,如地震震级大（>3级）、震源深度浅（10~15 km）、频度大,火山活动时间新（活火山、休眠火山、中新世以来的死火山）规模大都说明地球深部存在不稳定的高热状态,易形成干热岩;如果能提前找到该区域的干热岩,可以先取出其中的热,那么地震和火山就有可能不会发生,这样可以达到取热减灾减排的作用。活动的深大断裂即能产生一部分热,也能将深部的热传输到浅部,尤其是活动性强的走滑拉张断裂,其深部具有韧性剪切特征,直接指示了深部的高温体的存在。第六个指标是高温温泉与气田等。温泉、气田的形成通常与深部的热储关系密切,一般认为地下水沿某个通道向下渗透接触到深部高温热储被加热后再沿某一通道流出地表而形成温泉;所以,温泉的出露指示了深部存在高温的岩石体（干热岩）;区域地温场异常明显,地表热泉等高温水热型地热田较密集的区域有望在深部寻找到干热岩,这也是一种就热（水热）找热（干热）的常规方法。作为固体矿产资源的干热岩,其形成具备四个必要条件:源、通、储、盖。第一个条件是要有丰富的动态热源如来源于深部地幔（幔源热）,来源于晚新生代活动的控热构造系统-活动的韧性剪切带,来源于地壳内的低速低阻体（中下地壳热）以及来源于高放射性中新生代花岗岩体（壳源热）。第二个条件是要有优良的导热通道,如壳内15~25 km低速层不仅是热源,同时具有将深部地幔热能向上传导的作用;软流圈地幔上隆时具活动性的深大断裂（深部具韧性特征、浅部具脆性特征）常常具有很好的导热功能;地壳浅表层次的脆性断裂系统往往不是干热岩的热通道,而是水热型地热能的导水、释热构造。第三个条件是要有巨大的储热岩石体,除埋深要适中（3~6 km）并具有较高温度（≥150℃）外,其规模要大（蕴含丰富的热能）,热导率大（>2 W/mK）,裂隙少（不含水或含少量不流动的水）;当然热储层可以是变质岩、岩浆岩,也可以为沉积岩。第四个条件是要有良好的保热盖层,盖层（被子）导热率低（< 2 W/mK）、厚度适中（>1 km）（具有良好的保温效果）,地温梯度高（≥40℃/km）、大地热流值高（≥70 mW/m2）（指示深部存在高温特征）是深部赋存有高温地热资源的必要条件。      

高温热泉中稀土元素的地球化学行为及其指示意义: 以西藏搭格架水热区为例

西藏搭格架水热区位于拉萨-冈底斯地块南缘, 毗邻印度河-雅鲁藏布江缝合带中段, 区内出露酸性泉、中性泉和弱碱性泉, 为不同类型地热水中REE分布特征及其地球化学成因研究提供了理想场所。通过在搭格架采集不同类型热泉样品, 开展了样品REE浓度测试、配分模式分析和赋存形态计算, 旨在揭示高温地热环境中REE地球化学行为的指示意义。研究结果表明, 搭格架热泉中REE的地球化学行为呈非保守性, 其ΣREE浓度受热泉环境中富Fe, Al矿物(或无定形态固体)而非硫酸盐矿物的吸附过程的影响; 热泉REE配分模式和形态分布则主要受热储内氧化-还原条件及流体-岩石相互作用的控制, 是其地质成因和总体水化学特征的反映。虽然搭格架热泉中宏量组分水化学特征指示热储围岩应主要为长英质岩石, 但中、碱性热泉呈现的Ce负异常意味着热储中也可能存在碳酸盐岩。本研究为高温热泉稀土元素地球化学研究提供了典型范例。      

CHANGE OF NUTRIENT IMPORT AND EXPORT IN PROCESS OF RAINFALL IN AILAO MOUNTAIN OF YUNNAN PROVINCE

ＣＨＡＮＧＥ　ＯＦ　ＮＵＴＲＩＥＮＴ　ＩＭＰＯＲＴ　ＡＮＤ　ＥＸＰＯＲＴ　ＩＮ　ＰＲＯＣＥＳＳ　ＯＦ　ＲＡＩＮＦＡＬＬ　ＩＮ　ＡＩＬＡＯ　ＭＯＵＮＴＡＩＮ　ＯＦ　ＹＵＮＮＡＮ　ＰＲＯＶＩＮＣＥＧａｎＪｉａｎｍｉｎ（甘健民）；ＸｕｅＪｉｎｇｙｉ（薛敬意...     

西藏错那地热田水化学特征与物源机制

错那县位于西藏自治区山南地区南部、喜马拉雅山脉中段,是我国重要的边境口岸。为了研究错那地区地热田的水化学特征与物源机制,通过对研究区的温泉点水样的水化学数据进行化验分析,结合研究区的地热地质条件,使用piper三线图和Gibbs图等分析了水化学特征和物质来源。在阐明几种主要的地热温度计原理和适用条件的基础上,利用各种地球化学温度计和多矿物平衡图解法对研究区地下热水进行了温度估算。基于综合分析,最终得出热储温度为117℃左右,分析出地下热水的水化学类型以HCO₃-Na型为主,并进行了相应的地热资源评价。这有助于查明地下热水物质来源,探明该地区地热资源,以便在今后为该地区的地热资源开发利用提供技术支持,同时也推动了生态环境的保护和能源结构的逐步改变。      

鲁东构造型地热田回灌过程中压力对回灌量的影响研究——以威海市宝泉汤为例

鲁东出露有多处温泉,且开发历史较久,均为典型的构造裂隙型地热田。近年来随着开采规模的日益增加,热储压力不断降低,温泉已不自涌,水位、水温逐渐降低,为实现其可持续利用,对其进行回灌势在必行,为此进行了回灌试验,在回灌试验中压力对回灌量的变化有较大的影响,该文详细的论述了其影响的程度及变化,得出了基本的结论。     

A simple method to model the reduced environment of lake bottom sapropel formation

The Kambala and Barchin brackish lakes(Baraba steppe,southern West Siberia) contain an organic-rich sapropel layer that was formed in oxygen-depleted waters.We measured the bulk sediment elemental composition,the water chemistry and determined the mineralogical composition and predominant biota species(Diatoms and Cyanobacteria in phytoplankton community respectively) in the lakes.The result indicates that the first lake has a siliceous type of sapropel and the second a carbonaceous one.A computer thermodynamic model was developed for chemical interaction in water-bottom sediment systems of the Kambala and Barchin Lakes.The surface sodium bicarbonate waters are supersaturated with respect to calcite,magnesite(or low Mg-calcite),quartz and chlorite with minor strontianite,apatite and goethite(pH8.9-9.3,Eh 0.3 V).Nevertheless,it is shown that during sapropel deposition,deep silt waters should be anoxic(Eh0 V).The virtual component CH_2O has been used to create an anoxic environment suitable for pyrite formation due to the biotic community impact and abiotic reduction.Thermodynamic calculation has shown that silt water is not necessarily euxinic(anoxic and sulfidic).Depending on Eh,sulfate sulfur can dominate in solution,causing the formation of gypsum together with pyrite.An attempt was made to find a reason for solution supersaturation with respect to Ca and Mg ions due to their complexation with humic acids.     

2000年西南大西洋阿根廷滑柔鱼产量分布及其与表温关系的初步研究

根据2000年中国鱿钓船在西南大西洋的生产统计和表温资料,按经纬度1°×1°进行统计,并用渔业地理信息软件MarineExplorer4 .0进行叠加分析。结果表明, 1~5月阿根廷滑柔鱼分布中心集中在45°S、60°W附近海域。各月产量和平均日产量有较大的变动,其中以2~3月为最高。1~5月作业渔场的适宜表温范围为7~14℃,并经过K S检验。但各月的适宜表温有所不同, 2月为11 ~12℃, 3月为10 ~12℃, 4月为8 ~9℃, 5月为7 ~8℃。在表温比往年稍偏高的作业海域,有利于渔场的形成和产量提高。     

虾池浮游微藻的种类组成、数量和多样性变动

报道了在集约化养虾中应用有益微生物制剂对虾池浮游微藻的影响,分析了整个养虾周期浮游微藻的种类组成、生物量、优势种及多样性指数的周期变化情况。结果表明,早期虾池浮游微藻细胞数量维持在1×103~3×103mL-1的水平,养殖中期开始呈指数增长状态,后期达到顶峰,并维持在70×103~160×103mL-1的水平,生物量比自然海区高。优势种类明显,前期为中肋骨条藻和伏氏海毛藻等硅藻类,后期则为绿球藻和栅列藻等绿藻类,水色及藻相呈良好状态,而不施加芽孢杆菌制剂的对照池则在后期出现较大比例的有害的蓝藻。虾池藻类多样性指数、均匀度指数和种类丰度均呈现前期高后期低的趋势,而优势度指数则相反,呈现前期低后期高的趋势。浮游植物的多样性指数为0.60~3.80,平均为1.88,均匀度指数为0.14~0.83,平均为0.45;种类丰度为0.80~2.46,平均为1.38;优势度指数在0.17~0.85,平均为0.41。多样性指数和均匀度均比粤东海域低,但优势度则甚高。     

A Preliminary Analysis of Trace-Elemental Signatures in Statoliths of Different Spawning Cohorts for Dosidicus gigas off EEZ Waters of Chile

We applied solution-based ICP-MS method to quantify the trace-elemental signatures in statoliths of jumbo flying squid, Dosidius gigas, which were collected from the waters off northern and central Chile during the scientific surveys carried out by Chinese squid jigging vessels in 2007 and 2008. The age and spawning date of the squid were back-calculated based on daily increments in statoliths. Eight elemental ratios(Sr/Ca, Ba/Ca, Mg/Ca, Mn/Ca, Na/Ca, Fe/Ca, Cu/Ca and Zn/Ca) were analyzed. It was found that Sr is the second most abundant element next to Ca, followed by Na, Fe, Mg, Zn, Cu, Ba and Mn. There was no significant relationship between element/Ca and sea surface temperature(SST) and sea surface salinity(SSS), although weak negative or positive tendency was found. MANOVA analysis showed that multivariate elemental signatures did not differ among the cohorts spawned in spring, autumn and winter, and no significant difference was found between the northern and central sampling locations. Classification results showed that all individuals of each spawned cohorts were correctly classified. This study demonstrates that the elemental signatures in D. gigas statoliths are potentially a useful tool to improve our understanding of its population structure and habitat environment.     

Determination of Ca,K, Mg and Fe in four fish species by FAAS

A method for determining calcium(Ca),potassium(K),magnesium(Mg) and iron(Fe) in four fish species was optimized and validated.It included microwave mineralization of the samples and subsequent quantification by flame atomic absorption spectroscopy(FAAS) with Zeeman-effect background correction.Using HNO3(65%) and H2O2(33%) as extraction solutions,the optimal conditions of extraction were established as follows:0.5 g of sample mass;microwave time program of 300 W/5 min and 600 W/5 min.The method was free of matrix interferences.The linear correlation coefficients were ≥0.9991,the recovery percentage of analytes was from 99.31% to 103.70% and the RSD(relative standard deviation) was lower than 2.06%.The detection limits obtained were 32.3,43.2,14.0 and 68.6 ng mL-1 for Ca,K,Mg and Fe in FAAS respectively.It is shown that the method is rapid,simple,sensitive and accurate.The method was applied to the studies of digestibility and measurement of these nutrients in samples of fish collected from Norway,Japan and China.     

卡帕藻的营养成分分析及综合比较

于1999年元月在海南陵水黎安港采集卡帕藻，应用HPLC、原子吸收等分析手段，系统测定其营养成分（主要包括蛋白质、氨基酸、脂肪、粗纤维、粗灰分、矿物质及微量元素等），并与其它几种大型藻类比较，综合评价卡帕藻的营养价值。结果表明卡帕藻蛋白质含量为6.20%，而粗脂肪和粗灰分较高，分别为2.88%和39.04%；卡帕藻中富含K、Na、Ca、Mg、P、Fe、Zn、Mn、Se等矿物元素，尤其是Se的含量远高于其它几种大型藻类。