共查询到14条相似文献,搜索用时 140 毫秒
1.
2.
钙稀土氟碳酸盐矿物中新多型体的HREM研究 总被引:1,自引:0,他引:1
利用高分辨电子显微术(HREM)研究了钙稀土氟碳酸盐矿物系列中氟碳铈矿(B)/直氟碳钙铈矿(S)的混层结构。发现并确定了B_5S_2(IH,3R)、B_5S_4(3R,6R)和B_(18)S_(10)(IH)规则混层矿物中5种新多型的晶体结构类型、晶胞参数以及理论晶体化学式等。HREM研究揭示出,在B_mS_n(m>n)型规则混层矿物新多型体的结晶过程中,成矿地质环境是复杂的。阐明了这些多型体是由该系列矿物中的氟碳铈矿(B)和直氟碳钙铈矿(S)结构单元层以不同比例沿c轴方向的有序堆垛构成。 相似文献
3.
四川冕西霓石碱性花岗岩中的稀土矿物主要为钙稀土氟碳酸盐矿物系列,通过选区电子衍射(SAED)和高分辨透射电子显微术(HRTEM)研究发现该系列矿物晶体结构中广泛发育复杂多样的微观地质异常现象,其主要类型有:(1)由该系列两个端员矿物氟碳铈矿结构层(B)与直氟碳钙铈矿结构层(S)以不同比例沿C轴方向有序堆垛形成的BmSn型规则混层结构;(2)无序堆垛形成的有序一无序结构晶畴;(3)由堆垛层错形成的无序混层结构,氟碳钙铈矿中不同多型体间的共格连生结构和相转变等;(4)氟碳铈矿结构中的平行于[001]方向的平移畴及一维无公度调制结构,该类调制结构可能是由于矿物中原子占位有序度的变化而形成的无序结构状态。 相似文献
4.
氟碳钙铈矿结构中晶体缺陷的高分辨电镜研究 总被引:1,自引:1,他引:1
用高分辨电子显微术(HREM)研究了氟碳钙铈矿(BS)晶体结构中的无序堆垛和体衍交生现象,结果表明该矿物的衍生多晶体是由钙-铈氟碳酸盐矿物中不同组分的氟碳铈矿(B)和直氟碳钙铈矿(S)结构单元层沿c方向无序堆垛而成。高分辨结构象揭示出氟碳钙铈矿衍生多晶体的微结构特征。讨论了氟碳钙铈矿结构中的堆垛层错等晶体缺陷现象。 相似文献
5.
6.
钙-铈氟碳酸盐矿物系列中新规则混层矿物的晶格象研究 总被引:5,自引:2,他引:5
本文用电子衍射和晶格象技术研究钙-铈氟碳酸盐矿物微结构特征。除确定有氟碳铈矿(B),氟碳钙铈矿(BS)、伦琴矿(BS_2)和B_3S_2规则混层矿物外,还首次发现了9种B_mS_n(m≥++n)型新的规则混层矿物。这些新规则混层矿物,往往以共格的形式共存于一个自然晶粒之中。大量的SAED和晶格象揭示了这类稀土矿物各成员之间的相互结构关系。研究表明:钙-铈氟碳酸盐矿物系列中矿物衍生体的微结构特征及其变化是相当复杂的,它们是由不同组分的氟碳铈矿(B)和直氟碳钙铈矿(S)的结构单元层在c轴方向通过不同比例堆垛方式,形成一系列新规则混层矿物及多型。 相似文献
7.
8.
根据HRTEM研究,在四川西昌地区的钙稀土氟碳酸盐矿物衍生多晶体中发现了四种不同的B10S8型[即氟碳怖矿(B)/直氟碳钙铈矿(S)为10:8]新规则混层矿物(B10S8-I,B10S8-Ⅱ,B10S8-Ⅱ和B10S8-Ⅳ)。用SAED和HREM方法确定了四种新规则混层矿物的晶体结构对称性、晶胞参数、结构堆垛模式及晶体化学式等。四种B10S8新规则混层矿物结构中,Ce-F离子层的堆垛层序以及两个Ce-F离子层之间的碳酸根离子层的排列方式均不同。同时还观察到该类矿物中的畸结构及堆垛层错等。 相似文献
9.
10.
采用CM12透射电镜,对我国四川昌北M稀土矿床中的氟碳钙矿微结构特征作了电子衍射分析和晶格象观察,揭示出氟碳钙铈矿晶体中混合多型体的堆垛序列,在不同部分观测到不同的多型体,其中以氟碳钙铈矿6R多型为常见普通多型体。本次工作发现42R,48R和16H三种新多型,并进一步证明,氟碳钙铈矿晶体中存在的多型结构相当复杂,但以长周期堆垛形成的多型体出现的几率要比短周期堆垛的多型体少得多。 相似文献
11.
12.
13.
Paleoproterozoic kimberlite from the Kimozero area in Karelia is the oldest rock of this type in Russia. It is strongly tectonized, metamorphosed, and it finally transformed into metakimberlite of the prehnite-pumpellyite facies with widespread lanthanide minerals: allanite-(Ce), bastnaesite-(Ce), bastnaesite-(La), parisite-(Ce), and monazite-(Ce). The contacts between their crystals and other metamorphic minerals, e.g., titanite, antigorite, and tremolite, are characterized by induction surfaces of concerted growth. Among lanthanide minerals, allanite-(Ce) is the most abundant. It occurs close to clinochlore pseudomorphs after phlogopite or as intergrowths with titanite in aggregates of tremolite–actinolite, calcite, and dolomite. Allanite crystals from the Kimozero area are not zonal, but vary in lanthanide contents and the Fe3+/Fe2+ ratio in grains no more than tens of microns from one another. Kimozero allanite mostly belongs to the allanite–ferriallanite series (up to 30% of ferriallanite endmember); the lesser amount corresponds to the allanite–Cr-bearing allanite series. At the late stage of metamorphism, allanite was partly replaced with parisite, bastnaesite, or monazite. 相似文献
14.
《Journal of Asian Earth Sciences》2011,40(6):701-712
Most of the karstic bauxite deposits in China are enriched in REE, and the REE has commonly been considered to be adsorbed on the surface of clay or diaspore minerals as ion state. However, occurrence of REE minerals in the bauxite deposits has not been reported by far. In the Quyang bauxite deposit from Guangxi province, we find REE minerals. The minerals are parisite and churchite. Parisite is widely distributed in the ooids and matrix, inducing positive Ce anomaly of the ores; whereas, churchite is rare and occurred in the core of ooid. The compositions of the REE minerals show the Eu anomaly can change gently during the weathering, and the Eu anomaly analyses suggest that the REE in the ores are mostly derived from the underlying carbonates. The parisite is formed in an alkaline condition, while churchite in an acidic situation; the co-existence of the two minerals in the ores suggests the Permian environment for bauxite formation is complex with great change of pH value. Moreover, parisite is inferred to be formed earlier than the churchite. 相似文献