Grain coarsening in polymineralic contact metamorphic carbonate rocks: The role of different physical interactions during coarsening

The microstructural evolution of polymineralic contact metamorphic calcite marbles (Adamello contact aureole) with variable volume fractions of second-phase minerals were quantitatively analyzed in terms of changes in grain size and nearest neighbor relations, as well as the volume fractions, dispersion and occurrences of the second phases as a function of changing metamorphic conditions. In all samples, the calcite grain size is controlled by pinning of grain boundaries by second phases, which can be expressed by the Zener parameter (Z), i.e., the ratio between size and volume fraction of the second phases. With increasing peak metamorphic temperature, both the sizes of matrix grains and second phases increase in dependence on the second-phase volume fraction. Two distinct coarsening trends are revealed: trend I with coupled grain coarsening limited by the growth of the second phases is either characterized by large-sized or a large number of closely spaced-second phase particles, and results finally in a dramatic increase in the calcite grain size with Z. Trend II is manifest by matrix controlled grain growth, which is retarded by the presence of single second-phase particles that are located on calcite grain boundaries. It is supported by grain boundary pinning induced by triple junctions, and the calcite grain size increases moderately with Z. The two different grain coarsening trends manifest the transition between relatively pure polymineralic aggregates (trend II) and microstructures with considerable second-phase volume fractions of up to 0.5. The variations might be of general validity for any polymineralic rock, which undergoes grain coarsening during metamorphism. The new findings are important for a better understanding of the initiation of strain localization based on the activation of grain size dependent deformation mechanisms.     

Post-deformational annealing of calcite rocks

The evolution of microstructure and crystallographic preferred orientation (CPO) during post-deformational annealing was studied on three calcite rock types differing in purity and grain size: Carrara marble (98% calcite, mean grain size of 115 μm), Solnhofen limestone (96%, 5 μm) and synthetic calcite aggregates (99%, 7 μm). Samples were first deformed in torsion at 727 °C at a shear strain rate of 3 × 10^{− 4} s^{− 1} to a shear strain of 5 and subsequently heat-treated at 727 °C for various durations between 0 and 24 h. Microstructures and CPOs were analysed by optical microscopy, image analysis and electron backscatter diffraction (EBSD).All rock types deformed in the dislocation creep field at the same applied conditions, but their microstructures and CPOs after deformation and after annealing differed depending on starting grain size and material composition. In Carrara marble and in the synthetic calcite aggregate, a strong CPO developed during deformation accompanied by dynamic recrystallisation with significant changes in grain size. During annealing, widespread grain growth and subtle changes of CPO occurred, and equilibrated foam microstructures were approached after long annealing times. The CPO is the only feature in annealed samples indicating an earlier deformation phase, although it is not always identical to the CPO formed during deformation. In the more impure Solnhofen limestone, secondary phases on grain boundaries suppressed grain boundary mobility and prevented both the formation of a recrystallisation CPO during deformation and grain size modification during deformation and annealing.     

Fluid-assisted fracturing,cataclasis, and resulting plastic flow in mylonites from the Moresby Seamount detachment,Woodlark Basin

The Moresby Seamount detachment (MSD) in the Woodlark Basin (offshore Papua New Guinea) is a large active low-angle detachment excellently exposed at the seafloor, and cutting through mafic metamorphic rocks. Hydrothermal infiltration of quartz followed by that of calcite occurred during cataclastic deformation. Subsequent deformation of these a priori softer minerals leads to mylonite formation in the MSD. This study aims at a better understanding of the deformation mechanism switch from cataclastic to plastic flow. Deformation fabrics of the fault rocks were analyzed by light-optical microscopy. Rheologically critical phases were mapped to determine distributions and area proportions, and EBSD was used to measure crystallographic preferred orientation (CPO). Strong calcite CPOs indicate dominant dislocation creep. Quartz CPOs, however, are weak and more difficult to interpret, suggesting at least some strain accommodation by diffusion creep mechanisms. When quartz aggregates are intermixed with the polymineralic mylonite matrix diffusion creep grain boundary sliding may be dominant. The syntectonic conversion from mafic cataclasites to more siliceous and carbonaceous mylonites induced by hydrothermal processes is a critical weakening mechanism enabling the MSD to at least intermittently plastic flow at low shear stresses. This is probably a crucial process for the operation of low-angle detachments in hydrated and dominantly mafic crust.     

Dolomite microstructures between 390° and 700 °C: Indications for deformation mechanisms and grain size evolution

Dolomitic marble on the island of Naxos was deformed at variable temperatures ranging from 390 °C to >700 °C. Microstructural investigations indicate two end-member of deformation mechanisms: (1) Diffusion creep processes associated with small grain sizes and weak or no CPO (crystallographic preferred orientation), whereas (2) dislocation creep processes are related with larger grain sizes and strong CPO. The change between these mechanisms depends on grain size and temperature. Therefore, sample with dislocation and diffusion creep microstructures and CPO occur at intermediate temperatures in relative pure dolomite samples. The measured dolomite grain size ranges from 3 to 940 μm. Grain sizes at T_max >450 °C show an Arrhenius type evolution reflecting the stabilized grain size in deformed and relative pure dolomite. The stabilized grain size is five times smaller than that of calcite at the same temperature and shows the same Arrhenius-type evolution. In addition, the effect of second phase particle influences the grain size evolution, comparable with calcite. Calcite/dolomite mixtures are also characterized by the same difference in grain size, but recrystallization mechanism including chemical recrystallization induced by deformation may contribute to apparent non-temperature equilibrated Mg-content in calcite.     

The effect of second-phase particles on stable grain size in regionally metamorphosed polyphase calcite marbles

Samples of the calcite-rich Shelburne Marble collected at the Pfizer Quarry in Adams, Massachusetts, show an order of magnitude variation in grain size. Calcite grain size ranges from 94 to 1101  μm. Because these calcite marbles share the same pressure, temperature and strain histories, some other factor must be responsible for the grain size variation.
Grain size appears to be controlled by the concentration of impurity or second-phase particles. Large calcite grain size occurs where the volume fraction of second-phase particles is low and grain size decreases as second-phase volume fraction increases. The relationship between calcite grain size ( D ), second-phase grain size ( d ) and second-phase volume fraction (  f  ) can be described by the power law D / d =1.4/ f   ^0.36, a result that is consistent with models based upon short-term (hours or days) laboratory experiments with metals and ceramics and computer simulations of grain growth. Grain growth appears to be greatly restricted by as little as a few per cent of second-phase particles, with a transition from highly restricted to almost unrestricted grain growth occurring at ≈5% volume of second-phase particles. These results indicate that second-phase particles exercise an important control on grain size and can effectively inhibit grain growth in metamorphic rocks. The behaviour of second-phases in short-term laboratory experiments may closely approximate the behaviour of second-phases in grain growth lasting several orders of magnitude longer in the metamorphic environment.     

High Temperature Mylonitization of Quartzofeldspathic Gneisses: Example from the Schirmacher Hills, East Antarctica

In the Schirmacher Hills, most of the ductile shearing took place under high to medium grade amphibolite facies metamorphism. The microstructure of the mylonites shows characteristic features of high temperature deformation and thus gives us an idea of deformation mechanisms of the constituent minerals at great crustal depth. The variation in microstructure of the sheared rock is partly due to heterogeneity of the intensity of strain from domain to domain, producing protomylonites, orthomylonites and ultramylonites. However, a large part of the microstructural variation has resulted from syn- to post-tectonic recrystallization and grain growth of constituent minerals. Both quartz and feldspar have deformed by crystal plastic processes with dominant grain boundary migration. The present aspect ratio of the feldspar grains is a result of various degrees of dynamic recrystallization along the grain boundary. The ratio varies between 1.5 and 2. Presence of exsolution lamellae in perthites and formation of myrmekite at the strained grains of K-feldspar suggest diffusion assisted dislocation creep. These mylonites are characterized by the presence of weakly strained or unstrained long quartz ribbons. The development of quartz ribbons with the absence of significant strain suggests grain recovery and grain growth during high temperature mylonitization. The growth of quartz ribbons took place by coalescing neighbouring grains both along and across the ribbon length. At the ultramylonite stage the fine-grained matrix of quartz and feldspar mostly accommodates the bulk strain.     

Grain boundary dissolution porosity in quartzofeldspathic ultramylonites: Implications for permeability enhancement and weakening of mid-crustal shear zones

Quartzofeldspathic ultramylonites from the Alpine Fault Zone, one of the world's major, active plate boundary-scale fault zones have quartz crystallographic preferred orientations (CPO) and abundant low-angle (<10° misorientation) boundaries, typical microstructures for dislocation creep-dominated deformation. Geometrically necessary dislocation density estimates indicate mean dislocation densities of ∼10⁹ cm⁻². A significant proportion (∼30%) of grain boundaries (>10° misorientation) are decorated by faceted pores, commonly with uniformly-oriented pyramidal shapes. Only grain boundaries with >10° misorientation angles in polymineralic aggregates are decorated by pores. Mean grain boundary pore densities are ∼5 × 10⁸ cm⁻². Grain boundary pores are dissolution pits generated during syn-deformational transient grain boundary permeability, nucleating on dislocation traces at dilatant grain boundary interfaces. They have not been removed by subsequent grain boundary closure or annealing. Pore decoration could have led to grain boundary pinning, triggering a switch in the dominant deformation mechanism to grain boundary sliding, which is supported by evidence of CPO destruction in matrix quartz. Pore-decorated grain boundaries have significantly reduced surface area available for adhesion and cohesion, which would reduce the tensile and shear strength of grain boundaries, and hence, the bulk rock. Grain boundary decoration also significantly decreased the mean distance between pores, potentially facilitating dynamic permeability. Consequently, these microstructures provide a new explanation for strain weakening and evidence of fluid flow along grain boundaries in mylonites at mid-crustal conditions.     

The effect of different second-phase particle regimes on grain growth in two-phase aggregates: insights from in situ rock analogue experiments

The aim of the study was to investigate the effect of rigid second phases on grain growth of a matrix phase. For this purpose, variable mixtures of norcamphor as the matrix phase, with glass beads (0.08–0.51 volume fraction) as second phase, were used to perform see-through rock-analogue experiments under static conditions at constant temperatures (50°C). Irrespective of the second-phase content, grain-size evolution of all mixtures can be subdivided into a stage of continuous grain growth, a transient stage and a stage of a finally stabilized grain size. On the grain-scale, the second phases affect the migrating grain boundaries either by pinning by single particles, by multiple particles or even by particle clusters. Summed up over the entire aggregate, these pinning regimes affect the average bulk grain size of the matrix grains, such that the changes in matrix grain size directly correlate with the amount of second phases, their dispersion and their degree of clustering. In this way, the matrix grain size decreases with increasing second-phase content, which can be expressed as a Zener relationship. Originating from the modification of an ordinary grain growth law, a new mathematical expression is defined, which allows the calculation of changes in the matrix grain size as a function of different second-phase volume fractions and particle sizes. Such models will be helpful in the future to predict microstructural changes in polymineralic rocks at depth.     

Crystal plasticity and superplasticity in quartzite; A natural example

Plastically deformed quartzites from the Betic Movement Zone (Betic Cordilleras, Spain) exhibit microstructures indicative of crystal plasticity on a mineral grain scale. Quartzites with dynamically recrystallized grain sizes larger than 10 μm have strong crystallographic preferred orientations, narrow grain boundaries, little creep damage, and an inverse proportionality of dislocation density and grain size. Mylonites with grain sizes smaller than 10 μm have low crystallographic preferred orientations, wide grain boundaries (up to 1000 Å), abundant creep damage, and decreasing dislocation density with diminishing grain size. This is thought to reflect a clear-cut shift in deformational regimes from dislocation creep to superplastic flow at 10 μm grain size. Superplasticity can be acquired by quartzites which suffer dynamic recrystallization to grain sizes smaller than 10 μm during an initial dislocation creep stage. Dislocation motion is the major accomodating mechanism for strain incompatibilities that arise during grain-boundary sliding in the mylonites.It seems reasonable to estimate flow stresses from unbound dislocation densities and dynamically recrystallized grain sizes in the tectonite specimens. In the mylonites, dynamically recrystallized grain size probably reflects the stress magnitude before the shift in deformational mechanisms, and an estimate for late stage stresses is provided by unbound dislocation densities. In both deformational regimes the flow strength appears to depend on the extent of dynamic recrystallization.     

Marble mylonites in the Bancroft shear zone, Ontario, Canada: microstructures and deformation mechanisms

Mylonitization of medium-grade marbles in the Bancroft shear zone, Ontario, Canada, is characterized by decreasing grain-size of both calcite and graphite, and a variety of textures. Calcite grain-sizes vary from several millimeters in the protolith, to 50–200 μm in mylonite, to <30 μm in ultramylonite. Corresponding calcite grain shapes are equant in the protolith, elongate in protomylonite (first-developed dimensional preferred orientation), equant in coarse mylonite, elongate in fine mylonite (second-developed dimensional preferred orientation) and generally equant in ultramylonite, which suggests that external energy (applied stress) that tends to elongate grains competed with internal energy sources (e.g. distortional strain) that favor equant shapes. Graphite grain-size changes from several millimeters to centimeters in the protolith to submicroscopic in ultramylonite. In the mylonitic stages, graphite is present as dark bands, while in the ultramylonitic stage it is preserved as a fine coating on calcite grains.Based on textural evidence, twinning (exponential creep; regime I), dynamic recrystallization (power law creep; regime II) and possibly grain boundary sliding superplasticity (regime III) are considered the dominant deformation mechanisms with increasing intensity of mylonitization; their activity is largely controlled by calcite grain-size. Calcite grain-size reduction occurred predominantly by the process of rotation recrystallization during the early stages of mylonitization, as indicated by the occurrence of core and mantle or mortar structures, and by the grain-size of subgrains and recrystallized grains. Grain elongation in S-C structures indicates the activity of migration recrystallization; these structures are not the result of flattening of originally equant grains. Differential stress estimates in coarse mylonites and ultramylonites, based on recrystallized grain-size, are 2–5 and 14–38 MPa, respectively. Initial grain-size reduction of graphite occurred by progressive separation along basal planes, analogous to mica fish formation in quartzo-feldspathic mylonites.Calcite-graphite thermometry on mylonitic and ultramylonitic samples shows that the metamorphic conditions during mylonitization were 475 ± 50°C, which, combined with a differential stress value of 26 MPa, gives a strain rate of 1.2 x 10⁻¹⁰s⁻¹ based on constitutive equations; corresponding displacement rates are <38 mmyr⁻¹.     

糜棱岩化过程中矿物变形温度计

对有效确定中—低温下糜棱岩变形温度一直以来都没有比较理想的方法，而在研究韧性剪切带过程中对其变形温度的确定又常是必不可少的。根据近年来国际上对天然石英、长石、方解石等矿物变形的研究成果，总结了利用矿物变形指示变形温度的方法。在不同的温度条件下，长石与石英的变形方式具有阶段性，其变形与动态重结晶型式与温度具有明显的对应关系。石英变形中的滑移系及其C 轴组构图主要受变形温度的控制。低温变形中的方解石e 双晶纹形态也与温度呈密切的相关性。观测这些矿物变形的显微构造，可以很好地估计韧性剪切带糜棱岩化过程中的变形温度。     

THE DEFORMATION BEHAVIOUR OF HORNBLENDE IN THE FLORENCE SHEAR ZONE,CENTRAL AUSTRALIA

角闪石在低温变形中通常显示脆性变形行为,通过对中澳洲Ｆｌｏｒｅｎｃｅ剪切带的铁镁质糜棱岩的观察研究表明,角闪石在这些高温变形环境形成的糜棱岩中显示出显著的塑性变形行为,表现在角闪石遭强应变后,无碎裂出现,而具明显的晶内塑性应变现象和强烈的晶体优选定向,角闪石的细粒化是由边界重结晶迁移所致。本文探讨了引起角闪石塑性变形的一些因素,认为岩石发生糜棱岩化时的高温环境增强了角闪石的韧性,几何软化对角闪的塑性变形行为也起到一定的作用。     

郯庐断裂带南段桴槎山韧性剪切带糜棱岩的变形条件和组分迁移系

本文对郯庐断裂带南段主干断裂典型的韧性剪切带进行了系统的剖析。从糜棱岩塑性变形的亚颗粒化、动态重结晶和矿物成分特征及岩石组分迁移变化等入手进行系统的研究工作，计算了岩石形成的温度、压力和流动应力和流变速率参数；模拟计算了岩石在剪切变形作用下的体积亏损及组分迁移的量值，探讨了变形－变质及流体的相关关系     

多相糜棱岩内第二相对应变局部化的影响——以秦岭群花岗质糜棱岩为例

糜棱岩韧性变形发生的应变局部化过程,尤其是多相糜棱岩第二相对基质相变形的影响一直是显微构造研究难点.研究表明糜棱岩借助颗粒边界滑移实现多相混合,形成多矿物相集合体.在多相糜棱岩内,第二相在基质相颗粒边界施加齐纳阻力,牵制基质相颗粒边界的迁移速率,破坏基质相颗粒的动态平衡过程,使基质相颗粒位于古应力计对应的颗粒粒度以下,导致基质相整体的表面积增大,促进扩散交换过程,提高了扩散蠕变,降低了基质相位错蠕变和结晶学优选方位(CPO)形成的效率,使变形机制从颗粒粒径不敏感蠕变机制(GSI)过渡为颗粒粒径敏感蠕变机制(GSS).另外,多相糜棱岩内的第二相具有诱导应变局部化的效应,使塑性应变局部化更为强烈,引起物质强度的变化,进而引起岩石变形过程和岩石圈流变行为的改变.选取秦岭群花岗质糜棱岩进行多相矿物糜棱岩定量化研究,结果显示花岗质糜棱岩伴随着云母含量的增多以及各相混合程度的增大,石英的颗粒粒度明显减小,CPO强度显著降低,基质相显微变形受第二相控制逐渐增强.     

Yielding of rockfill in relative humidity-controlled triaxial experiments

The paper reports the results of suction-controlled triaxial tests performed on compacted samples of two well-graded granular materials in the range of coarse sand–medium gravel particle sizes: a quartzitic slate and a hard limestone. The evolution of grain size distributions is discussed. Dilatancy rules were investigated. Dilatancy could be described in terms of stress ratio, plastic work input and average confining stress. The shape of the yield locus in a triaxial plane was established by different experimental techniques. Yielding loci in both types of lithology is well represented by approximate elliptic shapes whose major axis follows approximately the K₀ line. Relative humidity was found to affect in a significant way the evolution of grain size distribution, the deviatoric stress–strain response and the dilatancy rules.     

石英结晶学优选与应用

石英集合体的结晶学优选可由位错滑移、双晶滑移、定向成核与生长等形成,其中位错滑移是塑性变形岩石中石英结晶学优选产生的最重要的机制。影响变形石英结晶学优选的因素有温度、应变速率、应变、差应力、水、复矿物岩石中各种矿物间的相互作用、初始结晶学方向等。系统总结了石英晶体变形与滑移系,结晶学优选的测量与表达,多种条件下石英的结晶学优选,以及在判断剪切方向、计算运动学涡度、判定变形温度、分析变形历史等方面的应用,并认为应用石英组构作运动学和动力学解析时需与其它微观、宏观现象相结合。     

Evidence for dominant grain-boundary sliding deformation in greenschist- and amphibolite-grade polymineralic ultramylonites from the Redbank Deformed Zone, Central Australia

Microstructural and textural investigations by scanning (SEM) and transmission electron microscopy (TEM) techniques have been performed on samples taken across two quartzo-feldspathic mylonite zones from the Redbank Deformed Zone, Central Australia. One has been deformed at greenschist-facies (GS), the second at amphibolite-facies (Am), conditions. With increasing strain the rock type changes from protomylonite to mylonite to ultramylonite. The protomylonites and mylonites consist of alternating quartz and polymineralic quartz-feldspar bands. At the highest strains a homogeneous, fine-grained polymineralic ultramylonite occurs. Shear-zone geometry and microscale structures indicate that these ultramylonites experienced higher strains and were weaker than the encapsulating protomylonites and mylonites. TEM and SEM studies of the ultramylonites reveal a rectangular to square grain shape, a continuous alignment of grain and interphase boundaries across several grain diameters, a grain size (GS 0.5 μm; Am 5–11 μm) less than the equilibrium subgrain size, and open and void-containing grain and interphase boundaries. Analysis of local textures by electron back-scatter diffraction (EBSD) in the SEM showed a very weak crystallographic preferred orientation (CPO) for the quartz. The grain misorientation relationships are not consistent, with dislocation creep being the dominant deformation mechanism. All structures are of the type expected if grain-boundary sliding processes had contributed significantly to the deformation. Consequently, the deformation of such quartzo-feldspathic rocks, and by implication the rheology of the Redbank Deformed Zone, must have been controlled by the mechanical properties of these fine-grained polymineralic ultramylonites, deforming by grain-boundary sliding processes. This is in contrast to the pure quartz bands which deformed by dislocation-creep mechanisms and were less important in the rheology of the Redbank Deformed Zone.     

Comparison of quartz microfabric with strain in recrystallized quartzite

The relationship between quartz c-axis microfabric and strain is examined in six specimens of recrystallized quartzite conglomerate in which strain was measured using pebble shapes. Four rocks subjected to plane strain display a direct relationship between the strength of preferred orientation and the strain intensity. The c-axis distributions in these rocks, as well as a rock subjected to moderate extensional strain, are crossed-girdles with maxima near the intermediate principal strain axis and connecting girdles at acute angles to the direction of maximum shortening. A rock subjected to moderate flattening strain has several maxima clustered near the direction of maximum shortening and a weak connecting girdle through the intermediate principal strain axis.These results are generally similar to those of other studies comparing strain and tectonite fabrics and also with experimental and computer simulation studies of fabrics. The degree of preferred orientation is related to total strain, and therefore microfabrics in quartzites may be cautiously interpreted as qualitative indicators of strain intensity. Uncertainties are greater, however, for correlations of fabric patterns with shapes of the strain ellipsoid. An observed increase in recrystallized grain sizes with increasing strain suggests that flow stress was lower in the more strained rocks.     

Quartz vein fabrics coupled to elevated fluid pressures in the Stawell gold deposit,south-eastern Australia

Shear and extensional veins formed during the reactivation of the Magdala shear system at Stawell in western Victoria, Australia, contribute to the formation of the auriferous Central and Basalt Contact lodes. Within this shear system is a range of fault rocks accompanied by steep-dipping (>65°) quartz-rich laminated shear veins and relatively flat-lying extensional veins. Both vein sets appear to have been a primary source for the host rock permeability during fluid flow in a regime of significant deviatoric stresses. The macro- and microstructures suggest that the dilatancy, that produced mineralized veins, formed under conditions of overpressure generated by fluid infiltration late in a tectonic regime. A new microfabric analysis technique is used to investigate the quartz-rich veins, which allows rapid integration of the microstructure with the crystallographic preferred orientations (CPOs). Both the shear and extensional quartz veins have a random CPO with ∼120° dihedral angles between the quartz–quartz grains, which is typical of a metamorphic equilibrium microfabric. The microstructures indicate that the quartz has undergone extensive grain adjustment in the solid-state, with grain shape and size affected by interfacial solution (pressure solution) effects. These features are consistent with inferences from experimental rock deformation studies, where grain boundary migration is enhanced in a water-rich environment. The onset of solution-transfer processes (pressure solution) developed as the quartz microfabric stabilized and continued to modify the CPO and microstructure significantly. It is concluded that grain growth and pressure solution are coupled diffusive mass transfer processes, related to fluctuations in pore fluid pressures in a region undergoing deformation at near lithostatic pressures.