不同储藏气压下含气土细观结构表征与重构研究

含气土的储藏气压与细观结构表征是研究浅层气地质灾害的关键因素。利用工业CT扫描测试系统,采用立式旋转扫描,微焦点X射线光源的位置固定,样品沿XY平面方向匀速旋转1周,设定旋转步长为0.3°/s,对反应釜内含气样品注气加压至2 MPa、4 MPa、6 MPa,充分考虑样品成像最佳分辨率、最佳探测范围等因素的影响。结果表明,CT扫描获得的切片图像与重构图像具有良好的实验效果;加压注气到2 MPa时,小气泡灰度值增加;加压到6 MPa时气体整体灰度值增加明显;增压过程中气泡数量随着气泡半径增加而减少;加压注气过程会导致固?液?气三相物质局部变化,表现为孔隙气、孔隙水的体积变化幅度整体大于土骨架,微观局部位置会有较大的升高或降低。当不同位置的气体含量上升且占据主导地位时,会驱动着孔隙水的减少与土骨架的移动。     

Experimental formation of massive hydrate deposits from accumulation of CH4 gas bubbles within synthetic and natural sediments

In order for methane to be economically produced from the seafloor, prediction and detection of massive hydrate deposits will be necessary. In many cases, hydrate samples recovered from seafloor sediments appear as veins or nodules, suggesting that there are strong geologic controls on where hydrate is likely to accumulate. Experiments have been conducted examining massive hydrate accumulation from methane gas bubbles within natural and synthetic sediments in a large volume pressure vessel through temperature and pressure data, as well as visual observations. Observations of hydrate growth suggest that accumulation of gas bubbles within void spaces and at sediment interfaces likely results in the formation of massive hydrate deposits. Methane hydrate was first observed as a thin film forming at the gas/water interface of methane bubbles trapped within sediment void spaces. As bubbles accumulated, massive hydrate growth occurred. These experiments suggest that in systems containing free methane gas, bubble pathways and accumulation points likely control the location and habit of massive hydrate deposits.     

Movement of large gas bubbles in unsaturated fine‐grained sediments

Abstract

Where undissolved gas occurs within fine‐grained marine sediments it usually takes the form of discrete bubbles that are much larger than the normal void spaces. The possibility of buoyancy‐induced movement of these relatively large bubbles must be included when considering the transport of gas through marine sediments. A theoretical analysis shows that, under static loading conditions, bubbles larger than a critical size should have sufficient buoyancy to move upward through a fine‐grained sediment stratum, whereas bubbles smaller than the critical size should remain fixed in position. The critical radius is directly proportional to sediment shear strength, and bubbles of a realistic size should move upward only in extremely weak sediments. Further theoretical analysis shows that the critical bubble size is reduced under cyclic loading conditions, but movement of typical‐sized bubbles should still be restricted to sediments of low shear strength. A simple laboratory experiment provides support for the conclusions of the theoretical analysis. The results indicate that buoyancy‐induced movement of relatively large gas bubbles in fine‐grained sediments is most likely to occur under storm loading conditions and is unlikely to occur at depths greater than a few meters below the seabed.     

天然气水合物的重要特征与评价及其在中国海域的勘探前景

从勘探技术和资源评价的角度综述了甲烷水合物生成和聚集的重要特征, 如地震反射剖面、测井曲线资料、地球化学特点等以及对未知区的地质勘探和选区评价 .甲烷水合物在地震剖面上主要表现为BSR(似海底反射)、振幅变形(空白反射)、速度倒置、速度-振幅结构(VAMPS)等,大规模的甲烷水合物聚集可以通过高电阻率(＞100欧姆.米)声波速度、低体积密度等号数进行直接判读.此项研究实例表明,沉积物中典型甲烷水合物具有低渗透性和高毛细管孔隙压力特点,地层孔隙水矿化度也呈异常值,并具有各自独特的地质特征.现场计算巨型甲烷水合物储层中甲烷资源量的方法可分为:测井资料计算法公式为:SW＝(abRw/φm.Rt)1/n;地震资料计算法公式为:ρp＝(1-φ)ρm+(1-s)φρw+sφρh、VH＝λ.φ.S.对全球甲烷水合物总资源量预测的统计达20×1015m3以上.甲烷水合物形成需满足高压、低温条件,要求海水深度＞300 m.因此,甲烷水合物的分布严格地局限于两极地区和陆坡以下的深水地区,并具有3种聚集类型:1.永久性冻土带;2.浅水环境;3.深水环境.深海钻探计划(DSDP)和大洋钻探计划(ODP)已在下述10个地区发现大规模的甲烷水合物聚集,他们是:秘鲁、哥斯达黎加、危地马拉、墨西哥、美国东南大西洋海域、美国西部太平洋海域、日本海域的两个地区、阿拉斯加和墨西哥湾地区.在较浅水沉积物岩心样中发现甲烷水合物的地区,包括黑海、里海、加拿大北部、美国加里福尼亚岸外、墨西哥湾北部、鄂霍茨克海的两个地区.在垂向上,甲烷水合物主要分布于海底以下2 000 m以浅的沉积层中.最新统计表明又主要分布于二个深度区间:200～450 m和700～920 m,前者是由ODP995～997站位发现的;后者在加拿大麦肯齐河三角洲马立克2L-38号井中897～922 m处发现.中国海域已发现多处甲烷水合物可能赋存地区,包括东沙群岛南部、西沙海槽北部、西沙群岛南部以及东海海域地区.姚伯初报道了南海地区9处地震剖面速度异常值的发现,海水深度为420～3 920 m,海洋地质研究所则在东海海域解释了典型BSR反射的剖面,具有速度异常、弱振幅、空白反射、与下伏反射波组具不整合接触关系(VAMPS)等,大致圈定了它们的分布范围,表明在中国海域寻找甲烷水合物具有光明的前景.     

深海能源土含气储层力学特性三轴试验研究

为研究深海能源土在负压开采过程中含气储层的力学特性,基于含气土赋存理论,提出一种能够控制含气量及气泡大小的制样方法,通过GDS标准应力路径三轴试验系统,开展深海能源土含气储层的固结排水试验研究,分析深海能源土在不同黏土含量及不同含气量下的力学响应规律。研究结果表明：围压变化对深海能源土含气储层的抗剪强度峰值大小影响显著,围压越大抗剪强度峰值越高;黏土含量是决定应力应变曲线变化趋势的关键影响因素,黏土含量越高试样抗剪强度越低,试样抵抗应变软化效应的能力越强;含气土比饱和土体承载能力更低,且承载能力随含气量的增大呈衰减趋势;黏土含量和含气量是深海能源土含气储层抗剪强度指标的重要影响因素,黏土含量、含气量越高,土体自身的总抗剪强度值越低。     

Experimental study on mechanical properties of gas hydrate-bearing sediments using kaolin clay

A triaxial system is designed with a temperature range from-20 ℃ to 25 ℃ and a pressure range from 0 MPa to 30 MPa in order to improve the understanding of the mechanical properties of gas hydrate-bearing sediments.The mechanical properties of synthetic gas hydrate-bearing sediments (gas hydrate-kaolin clay mixture) were measured by using current experimental apparatus.The results indicate that:(1) the failure strength of gas hydrate-bearing sediments strongly depends on the temperature.The sediment’s strength increases with the decreases of temperature.(2) The maximum deviator stress increases linearly with the confining pressure at a low-pressure stage.However,it fluctuates at a high-pressure stage.(3) Maximum deviator stress increases with increasing strain rate,whereas the strain-stress curve has no tremendous change until the axial strain reaches approximately 0.5%.(4) The internal friction angles of gas hydrate-bearing sediments are not sensitive to kaolin volume ratio.The cohesion shows a high kaolin volume ratio dependency.     

Seismic Characterisation of Gas-rich Near Surface Sediments in the Arkona Basin, Baltic Sea

Gas in sediments has become an important subject of research for various reasons. It affects large areas of the sea floor where it is mainly produced. Gas and gas migration have a strong impact on the environmental situation as well as on sea floor stability. Furthermore, large research programs on gas hydrates have been initiated during the last 10 years in order to investigate their potential for future energy production and their climatic impact. These activities require the improvement of geophysical methods for reservoir investigations especially with respect to their physical properties and internal structures. Basic relationships between the physical properties and seismic parameters can be investigated in shallow marine areas as they are more easily accessible than hydrocarbon reservoirs. High-resolution seismic profiles from the Arkona Basin (SW Baltic Sea) show distinct ‘acoustic turbidity’ zones which indicate the presence of free gas in the near surface sediments. Total gas concentrations were determined from cores taken in the study area with mean concentrations of 46.5 ml/l wet sediment in non-acoustic turbidity zones and up to 106.1 ml/l in the basin centre with acoustic turbidity. The expression of gas bubbles on reflection seismic profiles has been investigated in two distinct frequency ranges using a boomer (600–2600 Hz) and an echosounder (38 kHz). A comparison of data from both seismic sources showed strong differences in displaying reflectors. Different compressional wave velocities were observed in acoustic turbidity zones between boomer and echosounder profiles. Furthermore, acoustic turbidity zones were differently characterised with respect to scattering and attenuation of seismic waves. This leads to the conclusion that seismic parameters become strongly frequency dependent due to the dynamic properties of gas bubbles.     

Change of deltaic depositional environment and its impacts on reservoir properties—A braided delta in South China Sea

Depositional environment can change through geological time. This paper describes a delta that evolved from river-dominated into tide-dominated. The delta is located in the Ya13-1 field of the South China Sea. Understanding the change that occurred in the deltaic setting is important because the change in depositional environments led to changes in spatial distribution of facies and other rock properties.The Oligocene sediments of the third member of the Lingshui Formation in the Ya13-1 field were deposited in a river-dominated delta, and later impacted by marine flooding, fluvial and tidal currents. As a result of these different influences, the early-stage depositional micro-facies and the sandbody distributions are quite different from those of the later stage. At the early stage, fluvial influences prevailed, resulting in a fluvial-dominated delta plain and deposition of many linguoid sand bars in the delta front. During the late stage of deposition, tide-dominated delta fronts were developed extensively and finger sand bars deposited abundantly in the delta front as a result of the tidal influence.Ya13-1 gas field is laterally divided into two large subareas and vertically into eight stratigraphic packages. Because of the different influences of marine flooding that resulted in different interbeds and intercalations, the number of stratigraphic packages in the south is different from that in the north. The change of deltaic depositional environments also resulted in different reservoir properties between the northern and southern regions as the reservoir properties of mouth bars are generally better than distributary channels. These depositional characteristics significantly impact the development of the field.     

南海北部水道活动引起的不同类型滑塌体对应的水合物赋存模式

2015~2016年在神狐新钻探区钻遇大量水合物岩心，证实南海北部神狐新钻探区具有较好的水合物成藏环境和勘探前景。结合2008~2009年该区采集的地震资料，我们对晚中新世以来细粒峡谷的沉积特征及其相应的水合物成藏模式进行了分析。通过对大量地震剖面进行解释，发现该区峡谷两侧的隆起上发育大量的滑塌体。本文通过岩心粒度分析，地震相识别分析和水合物测井响应分析等手段综合识别出对水合物成藏有控制作用的三种类型的滑塌体：原生滑塌体、峡谷切割滑塌体、和同生断裂滑塌体。结合沉积速率、流体流速分析和峡谷迁移等沉积学要素对滑塌体成因进行分析，认为峡谷切割滑塌体由于后期峡谷迁移对前期滑塌体切割形成的、同生断裂滑塌体是由于隆起区基底不平引起差异性沉降而形成的。不同类型的滑塌体发育位置不同：原生滑塌体常发育在隆起中坡度较缓的区域、峡谷切割成因滑塌体常发育在不定向迁移的峡谷两侧、同生断裂滑塌体常发育在隆起中坡度起伏较大的区域。三种类型滑塌及其相应的水合物成藏模式不同，其中原生滑塌体有利于水合物成藏，而另外两种类型的滑塌体由于其不能对自由气进行有效封堵而不利于水合物成藏。根据三种滑塌体对水合物成藏的响应指出在粗粒的含有孔虫粉砂岩储层上，覆盖细粒的泥岩对自由气进行封堵有利于水合物成藏，并且多层的泥岩覆盖是造成水合物稳定带中水合物多个分层成矿现象出现的原因。     

Experiment and analysis of the formation,expansion and dissipation of gasbag in fine sediments based on pore water pressure survey

Deep-seated gas in seabed sediments migrates upwards from effect of external factors, which easily accumulates to form gasbags at interface of shallow coarse-fine sediments. Real-time monitoring of this process is important to predict disaster. However, there is still a lack of effective monitoring methods, so we attempt to apply multi-points pore water pressure monitoring technology when simulating forming and dissipation of gasbags in sediments through laboratory experiment. This study focuses...     

Seismic character of gas hydrates on the Southeastern U.S. continental margin

Gas hydrates are stable at relatively low temperature and high pressure conditions; thus large amounts of hydrates can exist in sediments within the upper several hundred meters below the sea floor. The existence of gas hydrates has been recognized and mapped mostly on the basis of high amplitude Bottom Simulating Reflections (BSRs) which indicate only that an acoustic contrast exists at the lower boundary of the region of gas hydrate stability. Other factors such as amplitude blanking and change in reflection characteristics in sediments where a BSR would be expected, which have not been investigated in detail, are also associated with hydrated sediments and potentially disclose more information about the nature of hydratecemented sediments and the amount of hydrate present.Our research effort has focused on a detailed analysis of multichannel seismic profiles in terms of reflection character, inferred distribution of free gas underneath the BSR, estimation of elastic parameters, and spatial variation of blanking. This study indicates that continuous-looking BSRs in seismic profiles are highly segmented in detail and that the free gas underneath the hydrated sediment probably occurs as patches of gas-filled sediment having variable thickness. We also present an elastic model for various types of sediments based on seismic inversion results. The BSR from sediments of high ratio of shear to compressional velocity, estimated as about 0.52, encased in sediments whose ratios are less than 0.35 is consistent with the interpretation of gasfilled sediments underneath hydrated sediments. This model contrasts with recent results in which the BSR is explained by increased concentrations of hydrate near the base of the hydrate stability field and no underlying free gas is required.     

板876地下储气库水砂体评价与扩容利用

由常规枯竭型气藏改建的地下储气库仍然以气藏砂体(气砂体)为研究目标,与气藏砂体相邻的含水层(水砂体)亦能作为地下储气库的扩容空间,但这部分砂体很少被关注。板876地下储气库在储层精细描述基础上,结合气藏和气库的注采动、静态分析结果,评价了水砂体的分布范围和发育规模,利用精细地质模型计算了水砂体的总孔隙体积、未动用的及可动用的孔隙体积,应用板876地下储气库数值模拟技术对水砂体的扩容空间进行了验证,结果表明水砂体储集空间对地下储气库的扩容和运行效率具有现实意义。     

Submarine slope stability analysis during natural gas hydrate dissociation

ABSTRACT

The purpose of this paper is to analyze the stability of submarine slope during the natural gas hydrate dissociation. A model is deduced to calculate the excess pore fluid pressure. In addition, a new method is proposed to define and calculate the factor of safety (FoS) of the submarine slope. Case study is also performed, results of which show that dissociation of hydrates would decrease the stability of submarine slope. If the cohesion of the hydrate-bearing sediments is small, the submarine slope would become unstable because of the shear failure. If the cohesion of the hydrate-bearing sediments is large enough, the tensile failure would happen in the hydrate-bearing sediments and the excess pore pressure may explode the submarine slope. Under the drained condition, the submarine slope may remain stable because the buildup of excess pore fluid pressure could not take place. Moreover, FoS would be underestimated by the assumption that natural gas hydrates dissociate in the horizontally confined space, but would be overestimated by only taking into account of the base of the natural gas hydrate-bearing sediments. The compressibility factor of natural gas should also be considered because treating natural gas as ideal gas would underestimate the stability of submarine slope.     

MDT测试资料确定气水界面的方法研究

通过对MDT测压资料的分析,发现了造成测试点压力值存在误差的主要原因有两个方面：一方面是由于部分测压点储层物性差,测试探针抽吸地层流体后储层压力恢复需要的时间较长,然而由于实际原因测试压力恢复无法等待足够的测试时间;另一方面是由于部分物性较差储层较难形成好的泥饼,以至于受到比较严重的泥浆侵入使得测试点产生超压现象,测试得到的地层压力和实际压力相比偏大.同时分析发现物性较好的储层往往能够得到相对可靠的测试压力.合理的气水界面对于计算探明地质储量有着很重要的意义,尤其是高温高压气田,气水过渡带往往较大,可能会达到30m左右,这种情况下无法仅从钻遇情况分析气水界面,此时可以结合MDT测压资料分析气水界面,从而确定合理的地质储量.通过分析实际MDT测压资料,对不同测压点进行了误差分析并在此基础上提出了压力数据点的筛选原则.通过实际检验认为新的回归方法确定出的气水界面科学合理.     

南海北部陆坡深水区浅层天然气藏特征

南海北部陆坡深水区的浅层天然气藏是一种伴随天然气水合物的新型油气藏, 具有埋藏浅、规模大的特点, 其埋藏深度一般小于300m。浅层天然气藏由深部裂解气沿断裂上升被天然气水合物封盖而形成, 识别似海底反射(BSR)是寻找浅层天然气藏有效方法。浅层天然气藏的气源主要有热解气、生物气和混合气, 陆坡张性断裂是气体运移的主要通道, 水合物下部的砂层是浅层天然气藏的主要储集层, 水合物层则是封盖层。从南海发现的天然气水合物分布特征看, 浅层天然气藏在陆坡深水区广泛分布且气藏厚度大, 潜在资源量非常可观, 是一种新型的开采成本相对低廉的油气藏。     

Influence of microfossils and pyrites on the behaviour of oceanbed sediments

An attempt has been made to investigate the microfabric and mineralogical features of marine sediments collected from the north-east coastal region of Singapore. A limited laboratory studies on shear strength, consolidation and chemical analysis were carried out to examine the geotechnical characteristics of marine sediments. Emphasis has been focussed on the microfabric aspects of microfossils (diatom) and pyrite, and their influence on the soil properties. Test results indicated the predominant presence of microfossils (diatom) and pyrite, and their impact on the marine sediments behaviour has been discussed briefly. The abundant presence of microfossils results in an increase in strength, compressibility and hydraulic conductivity due to the presence of large voids between the skeleton structures.     

松辽盆地登娄库—永安地区油气成藏模式研究

在已了解的松辽盆地登娄库—永安地区构造和沉积演化特点的基础上,利用现有钻井的岩心资料、测井资料和地震资料,对该地区的成藏模式特征从运移方式和生储盖空间组合两个方面上进行了研究和分类,分析了各自形成的主控因素.研究表明,该区域地层具有断坳双层结构,按油气运移类型划分,在断陷期主要发育两种油气成藏模式,分别为原生油气成藏模式和次生油气成藏模式;在坳陷期主要发育次生油气成藏模式和混生油气藏.从储层与烃源岩的空间组合上来看,区域内主要发育有上生下储、下生上储和自生自储这三种油气成藏模式.形成这些不同成藏模式的主要因素是该区深至基底的大型断裂构造和继承性断裂、反转构造以及固有沉积环境等.     

带水凝析气藏采收率标定废弃条件确定

废弃产量和废弃压力是标定凝析气藏可采储量的重要参数。在一年一度可采储量标定工作中发现,目前所提及的废弃条件的确定方法对于带水凝析气藏而言或说法不确切,或计算方法不适应,或精度不高。根据多年可采储量标定的经验,针对东海带水凝析气藏实际情况,提出一套适应于东海地区带水凝析气藏废弃产量和废弃压力的确定方法,且以东海XX气藏YY井为例,结合油藏工程、采油工艺等专业,介绍计算方法具体运用,对于具有同样地质特征气藏具有一定的借鉴意义。     

State-of-the-Art of Gas Hydrates and Relative Permeability of Hydrate Bearing Sediments

The methane gas production potential from its hydrates, which are solid clathrates, with methane gas entrapped inside the water molecules, is primarily dependent on permeability characteristics of their bearing sediments. Moreover, the dissociation of gas hydrates, which results in a multi-phase fluid migration through these sediments, becomes mandatory to determine the relative permeability of both gaseous and aqueous fluids corresponding to different hydrate saturations. However, in this context, the major challenges are: (1) obtaining undisturbed in-situ samples bearing gas hydrates; and (2) maintenance of the thermodynamic conditions to counter hydrate dissociation. One of the ways to overcome this situation is synthesis of gas hydrates in laboratory conditions, followed by conducting permeability tests on them. In addition, empirical relationships that relate permeability of the gas hydrate bearing sediments to pore-structure characteristics (viz., pore size distribution and interconnectivity) can also be conceived. With this in view, a comprehensive review of the literature dealing with different techniques adopted by researchers for synthesis of gas hydrates, permeability tests conducted on the sediments bearing them, and analytical and empirical correlations employed for determination of permeability of these sediments was conducted and a brief account of the same is presented in this article.     

The cause of the acoustically impenetrable,or turbid,character of Chesapeake Bay sediments

Many shallow water, fine-grained sediments are almost acoustically impenetrable to the energy from high resolution, low energy continuous seismic profilers. It has been alleged that this anomalous acoustic behavior is the result of interstitial gas bubbles that produce reverberation within the sediment, but no analyses were made until recently to test this hypothesis. Determinations of the compressibility of sediments from acoustically impenetrable, or turbid, zones and from contiguous zones of good penetration in Chesapeake Bay showed that the acoustically turbid sediments are several orders of magnitude more compressible than acoustically clear sediments of very similar grain size. The increased compressibility is a result of the presence of interstitial gas bubbles. Other acoustically turbid zones are produced by buried shell beds, and do not show an increase in compressibility.Contribution No. 181, Chesapeake Bay Institute, The Johns Hopkins University, Baltimore, Md. 21218, U.S.A.