Experimental research on the mechanical properties of methane hydrate-bearing sediments during hydrate dissociation

This paper describes studies of the effect of hydrate dissociation on the safety and stability of methane hydrate-bearing sediments. Methane hydrates within the sediments were dissociating under the conditions of a confining pressure of 0.5 MPa, 1 MPa, 2 MPa and a temperature of −5 °C. After 6 h, 24 h, or 48 h, a series of triaxial compression tests on methane hydrate-bearing sediments were performed. The tests of ice-clay and sediments without hydrate dissociation were performed for comparison. Focusing on the mechanical properties of the sediments, the experimental results indicated that the shear strength of the ice-clay mixtures was lower than that of the methane hydrate-bearing sediments. The strength of the sediments was reduced by hydrate dissociation, and the strength tended to decrease further at the lower confining pressures. The secant modulus E_S of the sediments dropped by 42.6% in the case of the dissociation time of the hydrate of 48 h at the confining pressure of 1 MPa; however, the decline of the initial yield modulus E₀ was only 9.34%. The slower hydrate dissociation rate contributed to reducing the failure strength at a declining pace. Based on the Mohr–Coulomb strength theory, it was concluded that the decrease in strength was mainly affected by the cohesive reduction. Moreover, the mathematical expression of the M–C criterion related to the hydrate dissociation time was proposed. This research could be valuable for the safety and stability of hydrate deposits in a permafrost region.     

Effects of dissociation on the shear strength and deformation behavior of methane hydrate-bearing sediments

A series of tests were conducted in order to investigate the shear strength and deformation behavior of methane hydrate-bearing sediments during dissociation using the thermal recovery method or depressurization method. An innovative temperature-controlled high pressure triaxial apparatus which can reproduce the in situ conditions of hydrate reservoirs was used. The results indicate that: (1) the failure strength of isotropically consolidated methane hydrate-bearing sediments which dissociated completely using the thermal recovery method is less than that of pure Toyoura sand. However, the initial stiffness and volumetric strain are higher than that of pure Toyoura sand. (2) The thermal recovery method will cause the failure of methane hydrate-bearing sediments when the axial load is higher than the strength of methane hydrate-bearing sediments after dissociation. (3) The depressurization method will not cause collapse of methane hydrate-bearing sediments during depressurization. However, water pressure recovery will lead to failure when the axial load is larger than the strength of the methane hydrate-bearing sediments after dissociation. (4) The depressurization rate shows little effect on the ultimate deformation of methane hydrate-bearing sediments, while the initial deformation rate increases with increasing depressurization rate. (5) The larger the reduction of pore pressure, the larger axial strain and volumetric strain.     

Submarine slope stability analysis during natural gas hydrate dissociation

ABSTRACT

The purpose of this paper is to analyze the stability of submarine slope during the natural gas hydrate dissociation. A model is deduced to calculate the excess pore fluid pressure. In addition, a new method is proposed to define and calculate the factor of safety (FoS) of the submarine slope. Case study is also performed, results of which show that dissociation of hydrates would decrease the stability of submarine slope. If the cohesion of the hydrate-bearing sediments is small, the submarine slope would become unstable because of the shear failure. If the cohesion of the hydrate-bearing sediments is large enough, the tensile failure would happen in the hydrate-bearing sediments and the excess pore pressure may explode the submarine slope. Under the drained condition, the submarine slope may remain stable because the buildup of excess pore fluid pressure could not take place. Moreover, FoS would be underestimated by the assumption that natural gas hydrates dissociate in the horizontally confined space, but would be overestimated by only taking into account of the base of the natural gas hydrate-bearing sediments. The compressibility factor of natural gas should also be considered because treating natural gas as ideal gas would underestimate the stability of submarine slope.     

Analyses of bottom simulating reflections offshore Arauco and Coyhaique (Chile)

Two seismic sections offshore Arauco and Coyhaique, Chile, have been analysed to better define the seismic character of hydrate-bearing sediments. The velocity analysis was used to estimate the gas-phase concentration, which can serve to correlate hydrate presence to the geological features. The velocity model allowed us to recognise the hydrate layer above the bottom simulating reflector (BSR), and the free gas layer below it. The velocity field is affected by strong lateral variation, showing maximum (above the BSR) and minimum (below the BSR) values in the southern sector. Here, highest gas hydrate and free gas concentrations were calculated (15% and 2.7% of total volume respectively). The estimated geothermal gradient ranges from 35 to 95°C/km. In the northern sector, the highest gas hydrate and free gas concentrations are 15% and 0.2% of total volume respectively, and the geothermal gradient is uniform and equal to about 30°C/km.     

Characteristics of Pore Water Pressure of Saturated Silt Under Wave Loading

The characteristics of dynamic stress in the seabed under wave loading are constant principal stress and continuous rotation of the principal stress direction.Cyclic triaxial-torsional coupling shear tests were performed on saturated silt by the hollow cylinder apparatus under different relative densities,deviator stress ratios and vibration frequencies to study the development of pore water pressure of the saturated silt under wave loading.It was found that the development of pore water pressure follows the trend of "fast～steady～drastic".The turning point from fast to steady stage is not affected by relative density and deviator stress ratio.However,the turning point from steady to drastic stage relies on relative density and deviator stress ratio.The vibration cycle for the liquefaction of saturated silt decreases with increasing deviator stress ratio and increases with relative density.The vibration cycle for the liquefaction of the saturated silt increases with vibration frequency and reaches a peak value,after which it decreases with increasing vibration frequency for the relative density of 70%.But the vibration cycle for the liquefaction of saturated silt increases with vibration frequency for the relative density of 30%.The development of pore water pressure of the saturated silt is influenced by relative density and vibration frequency.     

不同制样方式下含水合物粉细砂静力学特性研究

利用高压低温三轴仪对含水合物粉细砂进行剪切试验。分别用气饱和法与水饱和法制样，实现不同水合物饱和度和围压条件的三轴剪切，并分析含水合物砂的胶结作用对剪切特性的影响。试验结果表明：低饱和度时，气饱和与水饱和试样的偏应力差别不大；高饱和度时，制样方式对偏应力的影响较显著；水饱和试样的剪胀性大于气饱和试样，剪胀性随饱和度的升高和围压的降低而增大。峰值偏应力和稳态偏应力由黏聚力和摩擦力两部分组成，水合物的存在对稳态内摩擦角影响不大。     

天然气水合物超声和时域反射联合探测技术

首次将超声探测技术和时域反射技术集成于一个系统中,可实时探测沉积物中水合物饱和度和声学参数。进行了58个轮次的水合物生成与分解实验,超声、时域反射和温压异常3种方法所探测到的生成点、分解点吻合,这说明利用超声技术和时域反射技术联合探测沉积物中水合物的饱和度与声速是十分有效的,将有助于更好地了解含水合物沉积层的物理性质,为海洋天然气水合物的地球物理勘探和资源评价提供基础性参数。     

Acoustic wave attenuation in the gas hydrate-bearing sediments of Well GC955H,Gulf of Mexico

A better understanding of wave attenuation in hydrate-bearing sediments is necessary for the improved geophysical quantification of marine gas hydrates. Here we compare the attenuation behavior of hydrate-saturated vs water-saturated sediments at site GC955H, in the Gulf of Mexico, which was surveyed during the JIP Leg II expedition. We compute the P-wave attenuation of the gas hydrate bearing sediments using the median frequency shift method on the monopole waveforms. The results show that P-wave attenuation due to low saturation (<?0.4) in hydrate-filled fractures of fine-grained sediment is comparable to that of the water-filled fracture case. On the contrary, P-wave attenuation due to high saturation (>?0.4) in the hydrate-filled pores of coarse-grained sediments can be up to as much as three times more than that of the water-saturated case. The correlation analysis shows that the P-wave attenuation increases with the increasing gas hydrate saturation for the highly saturated gas hydrate-bearing sand interval while the correlation of the P-wave attenuation and hydrate saturation is weak for low saturated gas hydrate-bearing shale interval. The results show that P-wave attenuation is more likely to be used as a geophysical proxy for gas hydrate quantification of highly concentrated coarse-grained sediment rather than for that of fine-grained sediment. To examine the P-wave behavior in sand, we use the improved LCAM model, which accounts for physical factors such as grain boundary roughness and squirt flow to explain the observed differences in P-wave attenuation between hydrate and water-saturated coarse-grained sediment. Our results provide further geophysical evidences for P-wave behavior in the gas hydrate-bearing sediments in the field.     

Mechanical Behavior of Light-Weight Soil Under Consolidated Drained Shear Condition

To reveal the influence of material composition on mechanical properties of light-weight soil, stress-strain -volumetric strain characteristics and Poisson's ratio of mixed soil were researched by consolidated drained shear tests. The results show that light-weight soil is a kind of structural soil, so its mechanical properties are affected by mixed ratio and confining pressure, and mixed soil possesses structural yield stress. When confining pressure is less than the structural yield stress, strain softening occurs; when confining pressure is more than the structural yield stress, strain hardening is observed. There are two kinds of volume change behavior: shear contraction and shear dilatancy. Shear dilatancy usually leads to strain softening, but there isn't an assured causal relationship between them. Poisson's ratio of mixed soil is a variational state parameter with the change of stress state, it decreases with increased confining pressure, and it increases with increased stress level. When axial strain is near 5%, Poisson’ ratio is gradually close to a steady value. The main range of Poisson's ratio is 0.25～0.50 when confining pressure changes from 50 to 300 kPa. When unconfined compressive strength of mixed soil is less than 328 kPa, its stress-strain-volumetric strain characteristics can be predicted very well by Duncan-Chang model (E-B model). However, when the range of unconfined compressive strength is [328 kPa, 566 kPa], the model can't predict stress-strain characteristics accurately when confining pressure is under 200 kPa, and it also can't predict the strong shear dilatancy phenomenon of mixed soil under low confining pressure.     

Study of the Shear Strength of Sediments in Main Sedimentation Stages

The shear strength properties of sediments are relevant to many practical problems, including those related to predicting the bearing capacity of the man-made crust lying over dredged disposal sites and those associated with estimating the erosion resistance and the bearing capacity of sediments. In this study, an experimental apparatus and method is developed for sedimentation. This apparatus consists of a settling column, pore measurement apparatus, shear vane apparatus, and multilayer extraction sampling apparatus. The change regulation of interface height, density, excess pore pressure, peak undrained shear strength, residual undrained shear strength, and sensitivity varies before and after the excess pore pressure dissipates to zero in the self-weight consolidation stage. The higher the water content, the greater the particle segregation degree. Particles are mainly segregated in the settling stage, and they are not segregated further in the self-weight consolidation stage. Before excess pore pressure dissipates to zero in the self-weight consolidation stage, shear strength is related to water content, effective stress, and the formed structure of sediments. After excess pore pressure dissipates to zero, peak undrained shear strength is mainly associated with the structure (thixotropy) of sediments. Residual undrained shear strength increases because of the slight decrease in water content. The mechanisms of thixotropy can be expressed as the increase in the original and curing cohesions of sediments with time as determined from microscopic aspects.     

Wetting-induced axial and volumetric strains of a sandstone mudstone particle mixture

In this study, the deformation induced by the first wetting typically referred to as wetting deformation of a sandstone–mudstone particle mixture is examined. Wetting deformation can lead to collapse-inducing cracks. The cracks may weaken the strength of the structure. To investigate the first wetting-induced deformation of the sandstone and mudstone particle mixture, three triaxial tests were conducted. Two of the triaxial tests used saturated soil and dry soil. These tests were used to calculate the strain under the condition of minimized deviator stress ratio at wetting. The third triaxial test accesses various deviator stress ratios at wetting. Additionally, the influence on axial and volumetric strain of wetting at varying levels of the confining stress and deviator stress ratios at wetting was evaluated. The wetting axial and volumetric strains were found to increase with an increased confining stress and deviator stress ratio at wetting. The relationships between the wetting axial strain and deviator stress ratio at wetting yielded a logarithmic curve for various levels of confining stress. In contrast, the wetting volumetric strain yielded a direct relationship with the deviator stress ratio at wetting for various levels of confining stress. Based on these results, two equations for predicting the wetting axial and volumetric strains are suggested.     

The potential influence of shallow gas and gas hydrates on sea floor erosion of Rock Garden, an uplifted ridge offshore of New Zealand

Regional erosion of the Rock Garden ridge top, a bathymetric high within New Zealand’s Hikurangi Subduction Margin, is likely associated with its gas hydrate system. Seismic data reveal gas pockets that appear partially trapped beneath the shallow base of gas hydrate stability. Steady-state fluid flow simulations, conducted on detailed two-dimensional geological models, reveal that anomalous fluid pressure can develop close to the sea floor in response to lower-permeability hydrate-bearing sediments and underlying gas pockets. Transient simulations indicate that large-scale cycling of fluid overpressure may occur on time scales of a few to tens of years. We predict intense regions of hydro-fracturing to preferentially develop beneath the ridge top rather than beneath the flanks, due to more pronounced overpressure generation and gas migration through hydrate-bearing sediments. Results suggest that sediment weakening and erosion of the ridge top by hydro-fracturing could be owed to fluid dynamics of the shallow gas hydrate system.     

Formation history and physical properties of sediments from the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

The synthesis of available geological information and surface temperature evolution in the Alaska North Slope region suggests that: biogenic and deeper thermogenic gases migrated through fault networks and preferentially invaded coarse-grained layers that have relatively high hydraulic conductivity and low gas entry pressures; hydrate started forming before the beginning of the permafrost; eventually, the permafrost deepened and any remaining free water froze so that ice and hydrate may coexist at some elevations. The single tested specimen (depth 620.47-620.62 m) from the D unit consists of uncemented quartzitic fine sand with a high fraction of fines (56% by mass finer than sieve #200). The as-received specimen shows no evidence of gas present. The surface texture of sediment grains is compatible with a fluvial-deltaic sedimentation environment and shows no signs of glacial entrainment. Tests conducted on sediments with and without THF hydrates show that effective stress, porosity, and hydrate saturation are the major controls on the mechanical and geophysical properties. Previously derived relationships between these variables and mechanical/geophysical parameters properly fit the measurements gathered with Mount Elbert specimens at different hydrate saturations and effective stress levels. We show that these measurements can be combined with index properties and empirical geomechanical relationships to estimate engineering design parameters. Volumetric strains measured during hydrate dissociation vanish at 2-4 MPa; therefore, minimal volumetric strains are anticipated during gas production at the Mount Elbert well. However, volume changes could increase if extensive grain crushing takes place during depressurization-driven production strategies, if the sediment has unexpectedly high in situ porosity associated to the formation history, or if fines migration and clogging cause a situation of sustained sand production.     

Particle Flow Simulation on Collapse Characteristics of Silt Under Mutation of Principal Stress Orientation

The behaviors of granular material and influencing factors under complex dynamic loading are studied by more and more researchers with particle flow method. Only the strain-controlled loading has been generally used in the current study, although this method was not consistent with the practice of engineering in many situations. In this article, stress-controlled dynamic simulation tests were carried out with particle flow method, which were used to study the collapse characteristics of silt under mutation of principal stress orientation. The tests were performed by PFC2D. The simulation results and the laboratory real tests’ results had a high degree of similarity, particularly in the collapse strain and vibration times. It was very useful to forecast the silt's critical failure state. Based on the verification data, the effects of confining pressure and cyclic shear stress ratio on the collapse characteristics of silt were studied further. With the increase of cyclic shear stress ratio, the deviator strain amplitude increased and the required vibration times gradually reduced to achieve the same strain level. Under the same dynamic shear stress ratio and vibration times, the initial dynamic elastic modulus slightly increased with the increase of initial confining pressure, and the variation range of final collapse deviator strain was small. In the analysis of micro-structural evolution, the redistribution of internal stress of sample was revealed during cyclic loading. With the increase of vibration times, the development of distribution gradually stabilized, and then the high shear stress appeared in some connected regions. On that stage, the particle system developed to instability and failure. The PFC simulation results confirmed that the collapse state was the critical stage to trigger the liquefaction of silt.     

南海神狐海域含水合物层底栖有孔虫群落结构与同位素组成

为评价水合物甲烷对底栖有孔虫群落结构和同位素的影响,对南海北部神狐海域获取天然气水合物的钻孔BY3岩心,进行底栖有孔虫群落结构和稳定同位素分析,发现含水合物层底栖有孔虫丰度、分异度下降,群落中以内生种占绝对优势,有孔虫破碎率增加;与不含水合物层中的底栖有孔虫相比,含水合物层的底栖有孔虫碳同位素值出现较明显的负偏移。含水合物层中的Uvigerinaspp.、Cibicidesspp.和Oridorsalisspp.的δ13C平均值分别为-1.61‰、-0.79‰和-1.80‰,而在不含水合物层它们的δ13C平均值分别为-0.88‰、-0.27‰和-1.04‰;其中Uvigerinaspp.和Oridorsalisspp.的δ13C最轻值均出现在含水合物层,分别为-1.83‰和-2.29‰。这些说明底栖有孔虫在生长和埋藏过程中可能受到沉积物中甲烷水合物形成和演化的影响。     

Comparison Between Shear Behaviors of Overconsolidated Nakdong River Sandy Silt and Silty Sand

From this research, overconsolidated undrained and drained behaviors of specimens with high sand content were highly dilatant. According to the comparison results of laboratory tests, the deviator stresses of silty sand were greater than sandy silt due to high sand content under increasing OCRs, and both silty sand and sandy silt were presented strain softening tendency after failure under undrained loading. The pore water pressure increased with increasing fines content under increasing OCRs. Silty sand exhibited more dilatancy and increasing shear strength than sandy silt because pore water pressures of silty sand were lower than sandy silt under higher OCRs. In overconsolidated drained tests, silty sand is higher strength than sandy silt because silty sand has a lower volumetric strain and higher deviator stress than sandy silt under increasing OCRs. As the degree of overconsolidation increased, similar behaviors of silty sand and sandy silt observed that volumetric strain decreased to negative values due to dilatancy effect and low-cohesion under current effective confining pressures.     

An experimental study on microscopic characteristics of gas-bearing sediments under different gas reservoir pressures

Gas-bearing sediments are widely distributed in five continents all over the world. Most of the gases exist in the soil skeleton in the form of discrete large bubbles. The existence of gas-phase may increase or decrease the strength of the soil skeleton. So far, bubbles’ structural morphology and evolution characteristics in soil skeleton lack research, and the influence of different gas reservoir pressures on bubbles are still unclear. The micro characteristics of bubbles in the same sediment sample were studied using an industrial CT scanning test system to solve these problems. Using the image processing software, the micro variation characteristics of gas-bearing sediments in gas reservoir pressure change are obtained. The results show that the number and volume of bubbles in different equivalent radius ranges will change regularly under different gas reservoir pressure. With the increase of gas reservoir pressure, the number and volume of tiny bubbles decrease. In contrast, the number and volume of large bubbles increase, and the gas content in different positions increases and occupies a dominant position, driving the reduction of pore water and soil skeleton movement.     

南海北部陆坡峡谷区海底沉积物工程地质特征及区域稳定性评价

The upper part of the continental slope in the northern South China Sea is prone to submarine landslide disasters,especially in submarine canyons. This work studies borehole sediments, discusses geotechnical properties of sediments, and evaluates sediment stability in the study area. The results show that sediment shear strength increases with increasing depth, with good linear correlation. Variations in shear strength of sediments with burial depth have a significantly greater rate of change in the canyon head and middle part than those in the canyon bottom. For sediments at the same burial depth, shear strength gradually increased and then decreased from the head to the bottom of the canyon, and has no obvious correlation with the slope angle of the sampling site. Under static conditions, the critical equilibrium slope angle of the sediments in the middle part of the canyon is 10° to 12°, and the critical slope angle in the head and the bottom of the canyon is 7°. The results indicate that potential landslide hazard areas are mainly distributed in distinct spots or narrow strips on the canyon walls where there are high slope angles.     

Monitoring of a methane-seeping pockmark by cabled benthic observatory (Patras Gulf, Greece)

A new seafloor observatory, the gas monitoring module (GMM), has been developed for continuous and long-term measurements of methane and hydrogen sulphide concentrations in seawater, integrated with temperature (T), pressure (P) and conductivity data at the seafloor. GMM was deployed in April 2004 within an active gas-bearing pockmark in the Gulf of Patras (Greece), at a water depth of 42 m. Through a submarine cable linked to an onshore station, it was possible to remotely check, via direct phone connection, GMM functioning and to receive data in near-real time. Recordings were carried out in two consecutive campaigns over the periods April–July 2004, and September 2004–January 2005, amounting to a combined dataset of ca. 6.5 months. This represents the first long-term monitoring ever done on gas leakage from pockmarks by means of CH₄+H₂S+T+P sensors. The results show frequent T and P drops associated with gas peaks, more than 60 events in 6.5 months, likely due to intermittent, pulsation-like seepage. Decreases in temperature in the order of 0.1–1°C (up to 1.7°C) below an ambient T of ca. 17°C (annual average) were associated with short-lived pulses (10–60 min) of increased CH₄+H₂S concentrations. This seepage “pulsation” can either be an active process driven by pressure build-up in the pockmark sediments, or a passive fluid release due to hydrostatic pressure drops induced by bottom currents cascading into the pockmark depression. Redundancy and comparison of data from different sensors were fundamental to interpret subtle proxy signals of temperature and pressure which would not be understood using only one sensor.     

Multi-frequency seismic study of gas hydrate-bearing sediments in Lake Baikal,Siberia

In this paper we present and discuss the frequency-dependent behaviour of the acoustic characteristics of methane hydrate-bearing sediments in Lake Baikal, Siberia. Five different types of seismic sources (airgun-array, two types of single airguns, watergun and sparker) are used, encompassing a frequency bandwidth from 10 up to 1000 Hz. On low-frequency airgun-array data, the base of the hydrate stability zone (HSZ) is observed as a high-amplitude bottom-simulating reflection (BSR) with reversed polarity. The amplitude and continuity of the BSR decrease or even disappear on medium- to high-frequency data, a feature explained in terms of vertical and horizontal resolution. The increasing reflection amplitude of the BSR with increasing offset, the calculated reflection coefficient of the BSR and the occurrence of enhanced reflections below the BSR suggest the presence of free gas below the HSZ. The observation of some enhanced reflections extending above the BSR may be interpreted as an indication for free gas co-existing with hydrates within the HSZ. Amplitude blanking above the BSR is highly variable while the BSR itself appears to act as a low-pass frequency filter for medium- to high-frequency data.New single-channel airgun profiles provide the first seismic information across the Baikal Drilling Project (BDP-97) deep drilling site, at which hydrate-bearing sediments were retrieved at about 200 m above the base of the local HSZ. At the drilling site there are no seismic characteristics indicative of the presence of hydrates. Combination of the drilling and seismic information has allowed us to make a rough estimation of the volume of hydrates and carbon stored in the sediments of Lake Baikal, which lead us to conclude that the Lake Baikal gas hydrate reservoirs do not form a prospective energy resource.