Effect of silica fume on compressive strength of oil-polluted concrete in different marine environments

In the present research, effect of silica fume as an additive and oil polluted sands as aggregates on compressive strength of concrete were investigated experimentally. The amount of oil in the designed mixtures was assumed to be constant and equal to 2% of the sand weight. Silica fume accounting for 10%, 15% and 20% of the weight is added to the designed mixture. After preparation and curing, concrete specimens were placed into the three different conditions: fresh, brackish and saltwater environments (submerged in fresh water, alternation of exposed in air & submerged in sea water and submerged in sea water). The result of compressive strength tests shows that the compressive strength of the specimens consisting of silica fume increases significantly in comparison with the control specimens in all three environments. The compressive strength of the concrete with 15% silica fume content was about 30% to 50% higher than that of control specimens in all tested environments under the condition of using polluted aggregates in the designed mixture.     

Inhibitory effects of chloride ions on concrete sulfate attack in the marine adsorption environment

To study the inhibitory effects of chloride ions on concrete sulfate attack in the marine adsorption environment, a series of cubic concrete specimens was fabricated. These specimens were totally submerged or partially submerged in 10% Na₂SO₄ solutions with 0, 0.5, 2, and 5% NaCl concentration. Three specific aspects, namely, superficial phenomenon, compressive strength degradation, and X-ray fluorescence spectrometry analysis, were studied during 450 days of long-term exposure. Results showed that Na₂SO₄ solution had a strong corrosive effect on concrete in both the adsorption and submersion zones, especially in the adsorption zone. Chloride ions exerted inhibitory effects on concrete sulfate attack in both the submersion and adsorption zones, and higher concentration of chloride ions will produce stronger inhibitory effects. However, given the different inhibitory effects of chloride ions on concrete sulfate attack with different corrosion mechanisms, the inhibitory effect of the same chloride concentration on concrete sulfate attack was a little lower in the adsorption zone than in the submersion zone.     

钢纤维自密实混凝土的流变参数及其剪切增稠特性研究

采用现代技术配制自密实混凝土,能有效拓展水泥基材料在现代海洋、交通以及水利等工程领域的应用范围。采用坍落扩展度等指标对钢纤维自密实混凝土的传统工作性能进行表征,使用流变仪对拌合物的流变特性进行了测试,并对硬化后的钢纤维自密实混凝土的抗压强度进行了测试。结果表明,对于钢纤维自密实混凝土,使用幂律型的Herschel-Bulkley方程获得的屈服应力、黏度系数和流动指数这三项流变参数能够很好地反映拌合物的流变性能。     

Effects of Curing Conditions on Strength Development of High Strength Concrete

This paper presents the results of a series of studies on the influence of curing conditions onthe strength development of high strength concrete.The 1-,3-,7-,14-and 28-day strengths of four dif-ferent mixes of Grade 75～80 concrete,with or without pulverized fuel ash and/or condensed silica fume,under five different curing regimes were investigated.It is revealed that the curing conditions have signifi-cant influence on both the short term and long term strength development of the concrete and that con-crete mixes of the same grade but containing different mineral admixtures show distinct favour for a cur-ing regime.These results will be helpful for evaluating suitable curing methods for high strength concretewith different mix proportions.     

Strength of Lightweight Concrete Under Triaxial Compression

The strength of lightweight concrete under triaxial compressive stress is studied experimentally with the concrete triaxial apparatus designed by the authors, and is compared with that of normal concrete under the same stress state. Ninety-five 100 mm cubes under twenty stress ratios are tested. As compared with normal concrete, it is found that not only the multiaxial compressive strength of lightweight concrete is small, but also the ratio of the multiaxial compressive strength to the uniaxial compressive strength is small. The influence of the intermediate principal stress on the multiaxial strength of lightweight concrete is discussed. The strength criteria which are expressed in the principal stresses and the octahedral stresses respectively are proposed.     

山东省海岸工程可持续发展的若干问题

从风暴潮、黄河口治理、海水地下入侵与咸水侵染、海岸及沿海污染、沿海滩涂与黄河三角洲开发、海上交通和港口发展、海岸和海上石油开采、海岸工业基地建设、沿海旅游和海岛开发 ,以及沿岸淡水资源开发与海水利用等 1 0个方面 ,对山东省海岸工程的可持续发展问题进行了分析和讨论 ,并针对具体问题 ,提出了解决可持续发展问题的对策与措施。     

软弱砂岩骨料碾压混凝土的配制及其特性研究

在东南亚和我国西南地区由于缺乏合适的原材料,必须采用软弱骨料配制混凝土。以东南亚某工程现场的软弱砂岩为原材料,开展碾压混凝土配制和性能试验工作,探讨了该骨料配制碾压混凝土的可行性。采用软化系数为0.71的软弱砂岩,配制强度等级分别为C18020的二级配碾压混凝土和C1807.5的三级配碾压混凝土。结果表明,采用该砂岩骨料可以配制出满足强度要求的碾压混凝土,其用水量比常规骨料高15~20 kg/m3,拌和物密度和抗压弹模较低。其中,二级配碾压混凝土采用50%粉煤灰掺量、0.55水胶比;三级配碾压混凝土采用60%粉煤灰掺量、0.65水胶比。骨料抗碾压破碎模拟试验表明该骨料在碾压过程中破坏程度很低,说明采用该软弱骨料配制碾压混凝土具有可行性。     

High Performance Concrete and Its Typical Mixes

- With the modern development of chemical and mineral admixtures, it is now possible to produce much higher performance concrete than before. Higher performance does not only mean higher strength, but also better durability, lower risk of thermal cracking and higher dimensional stability etc. The three most effective admixtures for producing high performance concrete are superplastieizer, pulverized fuel ash and condensed silica fume. This paper outlines the properties of these materials and presents some practical guidelines for their usage.     

海砂颗粒形态评价与海拌混凝土性能研究

为初步评估海洋资源用作混凝土原材料的可行性，先通过数字图像技术求取海砂与河砂颗粒样本的椭圆率、圆度及坚固性参数，对两者颗粒形态特征做出综合评价，然后采用RCT法检测海拌混凝土游离氯离子含量，并测定混凝土不同龄期的抗压强度及碳化深度。结果表明，海砂与河砂颗粒细长程度、棱角及内凹曲面显著程度均非常接近，颗粒形态不存在本质差异；天然海水有助于混凝土早期强度的提升，对后期强度及碳化深度的影响则较为微弱；商品海砂会对混凝土力学性能产生轻微负面影响，并使抗碳化性能大幅下降。     

广东近海水域油污染的初步分析

广东近岸、河口、港湾、航道及主要锚地水域中的油类含量较高,其余海区较低;表层含量一般较底层高。文中对影响广东近海水域中油类分布的主要因素进行了讨论。     

Effect of salt on strength development of marine soft clay stabilized with cement-based composites

Abstract

Marine soft clay with a high salt concentration is widely distributed in coastal areas. In this study, cement-based composites consisting of cement, silica fume, plant ash and NaOH were used as a substitute for ordinary Portland cement, and the effect of salt (sodium chloride) on the strength development of clay was investigated by unconfined compressive strength (UCS) testing and scanning electron microscopy (SEM). With the addition of sodium chloride (NaCl), the amount of cementitious materials decreased, and the salt (sodium chloride) was considered to consume the cement-based composites. The consumption effect could be quantitatively evaluated by the consumption index of salt (CIS) and the clay-water/cement ratio hypothesis. The relationship between the CIS and curing period and an UCS prediction model of clay stabilized with cement-based composites with different salt contents and curing times were established. The CIS gradually decreased with increasing curing time and cement-based composites content. The accuracy of the prediction model was evaluated by a comparative analysis between the measured strengths and predicted strengths; the deviation was mostly within 10%. SEM analyses were employed to describe the changes in the microstructure of the specimens and the influencing mechanism of salt on clay stabilized with cement-based composites.     

青岛海水拌和混凝土力学性能试验研究

海水拌和的水泥净浆在标准稠度用水量和体积安定性方面与淡水拌和的水泥净浆没有明显差别,但凝结时间提前。水泥胶砂和混凝土的抗压、抗折强度与淡水拌和的相当。海水拌和的混凝土配合比可以采用淡水混凝土的配合比。     

普强高性能混凝土受压应力-应变全曲线试验研究

通过普强高性能混凝土和普通混凝土的应力-应变全曲线试验研究，得到一系列应力-应变曲线。对普强高性能混凝土和普通混凝土的立方体抗压强度与棱柱体抗压强度的关系、棱柱体抗压强度与峰值应力所对应应变的关系及棱柱体抗压强度与初始弹性模量的关系进行了分析。结果表明，虽然普强高性能混凝土的力学性能与普通混凝土的力学性能存在一定的差别，但主要力学性能还是相似的。说明在不改变混凝土的力学性能的基础上通过对普通强度混凝土原材料的优选和配合比的优化能够提高混凝土的耐久性能。     

事故性溢油对湄洲湾环境影响的预测

本文采用已建立的湄洲湾潮流场和水质点拉格朗日运动模型，利用概率预测模式，描述一旦发生事故性溢油，海上表面油膜的漂移和扩展过程，预测最大可能的污染海域范围；并建立海上溢油动力模式，探讨连续排放溢油的漂移和扩展过程，通过Mackay公式算出在油膜覆盖下水体的油含量。     

深海腐蚀检测用水密电子舱设计

设计了一种可在300 m 水深条件下进行腐蚀电化学在线检测作业的水密电子舱, 它主要由耐压水密壳体以及集成在壳体外部的插接件式电极系统和多孔屏蔽罩组成。耐压壳体由圆柱形筒体和加强型平盖构成, 满足设计条件下的强度、密封、防腐要求。三电极系统采用水密接插件式设计, 安装在加强型平盖上; 电极系统与外部多孔罩组成开放屏蔽式电解池, 可在水下进行在线电化学测试。     

Long-term sublethal and short-term high dose effects of physically and chemically dispersed oil on accumulation and clearance from various tissues of juvenile coho salmon, Oncorhynchus kisutch

The toxicity of crude oil and the dispersant BP1100X was tested in sea water and in each case was much less than the toxicity to fish in fresh water. Uptake of oil from water, with or without dispersant, was similar after a short exposure to 200 ppm. The oil was cleared from the fish in three weeks. A long-term exposure to oil or oil plus dispersant at a concentration of 5 ppm showed a slow accumulation but significantly above exposure levels. Thus, salmon exposed to oil in sea water can take up the hydrocarbons but appear to cleanse themselves rapidly.     

横流环境中水下溢油输移扩散的实验研究

文章基于自制的组合式环形水槽（周长9.7 m、宽0.45 m、深1.0 m）,分别以阿曼原油及其消油剂混合物和淡水（含示踪剂）为模拟污染物,开展水下溢油的物理模拟实验,以浮射流输移轨迹、污染物扩散范围和油滴粒径分布为考察指标,研究横流环境和消油剂的使用对水下溢油输移扩散的影响。实验结果表明:在横流环境中,浮射流输移轨迹开始弯曲的高度随着流速的增加而降低;与淡水浮射流主要在水中输移扩散的情况不同,当污染物为原油时,大粒径油滴脱离浮射流主体并上浮至水面,导致扩散范围更大;消油剂的添加会使原油浮射流内部油滴的体积中值粒径变小,油滴粒径分布曲线向小尺寸方向偏移。实验结果可为后续的物理模拟实验和数值模拟研究提供参考。     

AHP树脂水相成型及吸铀机理的探讨

应用有机吸附剂从海水中提取铀,资料上已有若干报道.Davies.R.J,等曾经报道过用甲醛、间苯二酚胂酸缩合的树脂,虽然这种树脂交换容量大(通水112天,1010微克铀/克),选择性好,提取率高,但它在水中缓慢水解,吸附能力下降,溶损也较大(2.3%初量/周),因而没有得到进一步的发展.Bayer,E.提出用聚乙二醛三氨基苯酚和经硅藻土烧结的聚丙烯氧肟酸树脂,从海水中提取铀和铜等金属,但吸附量不很高,树脂的强度也差,因此很快就中断了研究.苏联一些学者也报道了用AH、等阴离子交换树脂提取铀的研究工作.AH-2Φ树脂具有一定的吸附量(30微克铀/克),在海水中比较稳定,但交换容量很低,价格也较贵.     

养鲍自污染水净化处理的初步研究

用孔石莼变异株Ulvapertusa、活性炭纤维（ACF）和二氯异氰尿酸钠（NaDDT）对养殖皱纹盘鲍HaliotisdiscushannaiIno产生的自污染水进行净化,并用于饲养幼鲍。结果表明,孔石莼变异株能有效地吸收对幼鲍生长产生影响的水化因子──氨氮、亚硝酸盐,而活性炭纤维对污水中的COD_Mn和细菌的吸附率分别达82％和99．98％,经孔石莼变异株处理后的养鲍污水与未处理的养鲍污水对幼鲍生长影响明显不同。文中同时提出了用活性炭纤维、孔石莼变异株和二氯异氰尿酸钠净化养鲍污水的循环反馈投饵养殖模式。     

Predicting survival of western rock lobsters Panulirus cygnus using discriminant analysis of haemolymph parameters taken immediately following simulated handling treatments

Instances of morbidity amongst rock lobsters (Panulirus cygnus) arriving at factories in Western Australia (WA) have been attributed to stress during post‐harvest handling. This study used discriminant analysis to determine whether physiological correlates of stress following a period of simulated post‐harvest handling had any validity as predictors of future rejection or morbidity of western rock lobsters. Groups of 230 western rock lobsters were stored for 6 h in five environments (submerged/flowing sea water, submerged/recirculating sea water, humid air, flowing seawater spray, and recirculated seawater spray). The experiment was conducted in late spring (ambient sea water 22°C), and repeated again in early autumn (ambient sea water 26°C). After 6 h treatment, each lobster was graded for acceptability for live export, numbered, and its haemolymph was sampled. The samples were analysed for a number of physiological and health status parameters. The lobsters were then stored for a week in tanks in the live lobster factory to record mortality. The mortality of lobsters in the factory was associated with earlier deviations in haemolymph parameters as they emerged from the storage treatments. Discriminant analysis (DA) of the haemolymph assays enabled the fate of 80–90% of the lobsters to be correctly categorised within each experiment. However, functions derived from one experiment were less accurate at predicting mortality when applied to the other experiments. One of the reasons for this was the higher mortality and the more severe patho‐physiological changes observed in lobsters stored in humid air or sprays at the higher temperature. The analysis identified lactate accumulation during emersion and associated physiological and haemocyte‐related effects as a major correlate of mortality. Reducing these deviations, for example by submerged transport, is expected to ensure high levels of survival. None of the indicators tested predicted mortality with total accuracy. The simplest and most accurate means of comparing emersed treatments was to count the mortality afterwards.