内蒙古宝音图岩群变质基性火山岩锆石U-Pb年龄及意义

内蒙古达茂旗宝音图岩群是在达茂旗、查干呼绍地区15万区调和白云鄂博幅125万区调过程中从过去的巴特敖包群和白云鄂博群未分岩组解体出来的中级变质岩系.通过对宝音图岩群中阳起钠长片岩、二云片岩(原岩均为基性火山岩)进行单颗粒锆石U-Pb法年龄测定,获得了两条不一致线上交点年龄(2 486±42)Ma、(2 496±26)Ma,代表了宝音图岩群基性火山岩及宝音图岩群的形成时代；在不一致线之外不同成因的锆石的(207)Pb／(206)Pb表面年龄(2 227±15)Ma,寓示着2 200 Ma左右发生了一次区域性变质热事件；下交点年龄(319±486)Ma和(406±46)Ma,代表了250～480 Ma时期该区大面积岩浆侵位及宝音图岩群后期变形变质改造的时期,两个年龄样的获得为研究古元古代古陆的裂解及白云鄂博海槽的形成提供了直接依据.     

内蒙古宝音图岩群变质基性火山岩锆石U-Pb年龄及意义

内蒙古达茂旗宝音图岩群是在达茂旗、查干呼绍地区 1:5万区调和白云鄂博幅 1:2 5万区调过程中从过去的巴特敖包群和白云鄂博群未分岩组解体出来的中级变质岩系。通过对宝音图岩群中阳起钠长片岩、二云片岩 (原岩均为基性火山岩 )进行单颗粒锆石U -Pb法年龄测定 ,获得了两条不一致线上交点年龄 (2 486± 42 )Ma、(2 496± 2 6 )Ma ,代表了宝音图岩群基性火山岩及宝音图岩群的形成时代 ;在不一致线之外不同成因的锆石的2 0 7Pb/ 2 0 6Pb表面年龄 (2 2 2 7± 15 )Ma ,寓示着 2 2 0 0Ma左右发生了一次区域性变质热事件 ;下交点年龄 (319±486 )Ma和 (40 6± 46 )Ma ,代表了 2 5 0～ 480Ma时期该区大面积岩浆侵位及宝音图岩群后期变形变质改造的时期 ,两个年龄样的获得为研究古元古代古陆的裂解及白云鄂博海槽的形成提供了直接依据。     

内蒙古宝音图岩群变质基性火山岩锆石U-Pb年龄及意义

内蒙古达茂旗宝音图岩群是在达茂旗、查干呼绍地区1：5万区调和白云鄂博幅1：25万区调过程中从过去的巴特敖包群和白云鄂博群未分岩组解体出来的中级变质岩系.通过对宝音图岩群中阳起钠长片岩、二云片岩(原岩均为基性火山岩)进行单颗粒锆石U-Pb法年龄测定,获得了两条不一致线上交点年龄(2 486±42)Ma、(2 496±26)Ma,代表了宝音图岩群基性火山岩及宝音图岩群的形成时代；在不一致线之外不同成因的锆石的(207)Pb／(206)Pb表面年龄(2 227±15)Ma,寓示着2 200 Ma左右发生了一次区域性变质热事件；下交点年龄(319±486)Ma和(406±46)Ma,代表了250～480 Ma时期该区大面积岩浆侵位及宝音图岩群后期变形变质改造的时期,两个年龄样的获得为研究古元古代古陆的裂解及白云鄂博海槽的形成提供了直接依据.     

内蒙古中部大青山北西乌兰不浪紫苏斜长麻粒岩锆石U-Pb年龄

内蒙古西乌兰不浪北紫苏斜长麻粒岩是15万石兰哈达幅和125万白云鄂博幅从加里东期斜长花岗岩和华力西期花岗闪长岩中解体出来的古老花岗质侵入体.通过对紫苏斜长麻粒岩进行单颗粒锆石U-Pb法年龄测定,获得不一致线与谐和线上、下交点年龄分别为(2 511.4±4.9)Ma和(818±159)Ma.结合区调成果认为(2 511.4±4.9)Ma年龄代表古老花岗岩侵入体上侵就位时代,(818±159)Ma代表后期叠加变形变质热事件时代.这两组年龄为大青山中段地壳演化提供了直接证据.     

内蒙古宝音图-霍各乞地区宝音图岩群的时代约束及构造属性

宝音图隆起的构造归属仍然存在争议,有学者认为是兴蒙造山带中的微陆块,也有观点认为是华北克拉通的一部分.作为宝音图隆起的重要组成部分,探究宝音图岩群的形成时代、构造归属是解决这一问题的重要途径.通过对宝音图岩群3件石英岩样品进行锆石U-Pb同位素测试,在一岩组（石英岩和石英片岩岩组）、二岩组（石英岩岩组）、三岩组（片岩岩组）中分别获得较可靠的碎屑锆石最小谐和年龄为1 284 Ma、1 319 Ma、1 395 Ma,代表各岩组的沉积上限.结合侵入宝音图岩群中的变质基性脉岩的锆石U-Pb年龄为895.5±6.8 Ma,将研究区宝音图岩群一-三岩组的沉积时代大致限定在895.5~1 284.0 Ma之间,位于中元古代晚期至新元古代早期;可以和相邻区域大致形成于同一时期的阿拉善地区阿拉善群、白云鄂博地区白云鄂博群上亚群、化德-康保地区化德群上亚群对比.斜长角闪岩地球化学特征反映其形成于大陆边缘裂谷环境,可能为Rodinia超大陆裂解在本区的响应.宝音图岩群与邻区同时代沉积建造的碎屑锆石年龄谱较为相似,其主要峰值反映的地质事件与华北克拉通所经历的主要构造-热事件可以较好对应,说明宝音图岩群的物源来自于华北克拉通,为华北克拉通边缘的沉积.宝音图隆起应当为华北的一部分.      

陕西宽坪岩群变基性熔岩锆石U-Pb年龄

宽坪岩群广东坪岩组绿片岩岩石学、岩石化学、稀土、微量元素、副矿物等研究表明其原岩为基性火山岩。对商州市板桥地区基性熔岩变质而成的绿片岩区域地质、地球化学特点、锆石特征进行了详细研究和单颗粒锆石U-Pb同位素年龄测定。放射性成因铅丢失最少的岩浆成因锆石的206Pb/238U表面年龄为1154Ma,变质成因锆石的206Pb/238U表面年龄为444Ma。5个锆石颗粒构成的不一致线上交点年龄为1827±11Ma,代表基性熔岩形成年龄;下交点年龄为418±8Ma,代表加里东期变质年龄。综合认为宽坪岩群形成时代为早元古代。     

白云鄂博矿田碳酸岩墙年代学再研究

白云鄂博地区发育侵入于白云鄂博群的碳酸岩墙。碳酸岩墙(00BYC19)中锆石的SHRIMPU-Pb下交点年龄为1984±180Ma,其ID-TIMS上交点年龄为2085±330Ma。碳酸岩墙(02BY80)中锆石SHRIMP的上交点年龄为2035±51Ma;02BY81中锆石的ID-TIMS上交点年龄为1934±64Ma。主矿北碳酸岩墙(00BYC21)的全岩Pb-Pb等时线年龄为1236±300Ma。本文及前人对白云鄂博地区的碳酸岩墙的定年结果表明该地区碳酸岩墙至少有两个阶段的侵入事件,第一阶段在2.0Ga左右,第二阶段在1.2Ga左右。前者是白云鄂博地区以至阴山地块北缘的一次主要的构造—岩浆事件,标志白云鄂博裂谷和白云鄂博群地层的形成。第二阶段的碳酸岩墙,代表白云鄂博裂谷在中元古代的活化,且与成矿有密切关系。     

内蒙古西北部宝音图群Sm—Nd和Rb—Sr地质年代学研究

内蒙古西北部的宝音图群由角闪岩相的变质地层组成。该群中斜长角闪片岩的Sm-Nd全岩等时线年龄为2485±128Ma,可代表宝音图群的形成年龄。等时线的ε_(Nd)(t)值为2.73±2.81,说明岩浆来源于亏损的地幔源区。相同样品的Rb-Sr全岩等时线年龄为623±36Ma,显然反映后期Rb-Sr体系重新均一化的强烈影响,因此该年龄被解释为变质年龄。上述结果表明宝音图群形成于古元古代早期,应属华北板块北缘已知的最古老岩石地层单位,并保留了新元古代末期构造—变质事件的记录。这些认识有助于查明华北板块北缘元古宙构造演化的历史。     

桂东南云开地区变质杂岩锆石SHRIMP U-Pb年代学

对位于华夏古陆东南部的广西云开地区大面积出露的晚前寒武纪变质杂岩中的主体花岗质片麻岩、中深变质的天堂山岩群石榴辉石岩和中浅变质的云开岩群洋中脊型变质基性火山岩(斜长角闪岩)进行了高精度锆石SHRIMP U-Pb定年.获得天堂山岩群石榴辉石岩的形成年龄为1894Ma±17Ma和1847Ma±59Ma,表明其时代为古元古代;云开岩群洋中脊型变质基性火山岩(斜长角闪岩)的喷发年龄为1462Ma±28Ma,证明该地区存在中(-新)元古代的古洋壳残片;获得花岗质片麻岩的侵入年龄为906Ma±24Ma,应为1000Ma前后发生的全球性Grenville期(四堡期)造山作用的产物,并获得2702Ma±13Ma的继承碎屑锆石年龄,这是云开地区乃至华夏古陆目前获得的最古老年龄,证明华夏古陆曾存在新太古代陆壳物质.     

山东省日照市官山闪长玢岩锆石SHRIMP年龄:印支期岩浆热事件及其对超高压变质岩折返历史的限定

对苏鲁超高压变质带日照官山地区侵入于榴辉岩中的原生块状闪长玢岩进行了锆石SHRIMP年龄分析。结果显示,数据点构成的不一致线与一致线上交点年龄为(876±62)Ma,下交点年龄为(201±20)Ma。上交点年龄为残余锆石年龄,下交点年龄大致代表了闪长玢岩的形成时代。苏鲁超高压变质带中存在较广泛的印支期岩浆热事件。假定超高压变质作用发生于228Ma,推算出闪长玢岩侵位前超高压变质岩的折返速率大致为3.63mm/a,闪长玢岩侵位后超高压变质岩的折返(剥蚀)速率大致为0.03mm/a。     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义

在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Geology, mineralogy, and PGE mineralization of the copper-nickel occurrences of the Kvinum ore field, Sredinny Range, Kamchatka

The geology and mineralogy of host metamorphic rocks, the mineralogy of sulfide ores, and the distribution of PGE mineralization were studied in detail for the Kvinum-1 and Kvinum-2 copper-nickel occurrences of the Kvinum ore field, which are the most promising targets for the copper-nickel-PGE mineralization of the Sredinny Range of Kamchatka. It was established that stringer-disseminated and massive copper-nickel ores are localized in amphibole peridotites, cortlandites, and form ore bodies varying from tens of centimeters to 5–20 m thick among the layered cortlandite-gabbroid massifs. The massive sulfide ores were found only at the bottom of cortlandite bodies and upsection grade into stringer-disseminated and disseminated ores. Pyrrhotite, chalcopyrite, and pentlandite are the major ore minerals with a sharply subordinate amount of pyrite, sphalerite, galena, arsenopyrite, and löllingite. Besides pentlandite, the Ni-bearing minerals include sulforasenides (gersdorffite), arsenides (nickeline), and tellurides (melonite) of nickel. It was found that PGE mineralization represented by antimonides (sudburyite) and tellurobismuthides (michenerite) of Pd with sharply subordinate platinum arsenide (sperrylite) is confined to the apical parts of massive sulfide zones and the transition zone to the stringer-disseminated ores. Ore intervals enriched in arsenides and tellurides of Ni, Pd, and Bi contain high-purity gold. In the central parts of the orebodies, the contents of PGE and native gold are insignificant. It is suggested that the contents of major sulfide minerals and the productivity of PGE mineralization in the cortlandites are defined by combined differentiation and sulfurization of ultramafic derivatives under the effect of fluids, which are accumulated at the crystallization front and cause layering of parental magmas with different sulfur contents. The fluid-assisted layering of mafic-ultramafic massifs resulted in the contrasting distribution of PGM in response to uneven distribution of sulfur (as well as As, Te, and Bi) during liquid immiscibility. The productivity of PGE mineralization significantly increases with increasing contents of S, As, Te, and Bi (elements to which Pt and, especially, Pd have high affinity) in fluids.     

Depth of the base of the Jackson aquifer, based on geophysical exploration, southern Jackson Hole, Wyoming, USA

 A geophysical survey was conducted to determine the depth of the base of the water-table aquifer in the southern part of Jackson Hole, Wyoming, USA. Audio-magnetotellurics (AMT) measurements at 77 sites in the study area yielded electrical-resistivity logs of the subsurface, and these were used to infer lithologic changes with depth. A 100–600 ohm-m geoelectric layer, designated the Jackson aquifer, was used to represent surficial saturated, unconsolidated deposits of Quaternary age. The median depth of the base of the Jackson aquifer is estimated to be 200 ft (61 m), based on 62 sites that had sufficient resistivity data. AMT-measured values were kriged to predict the depth to the base of the aquifer throughout the southern part of Jackson Hole. Contour maps of the kriging predictions indicate that the depth of the base of the Jackson aquifer is shallow in the central part of the study area near the East and West Gros Ventre Buttes, deeper in the west near the Teton fault system, and shallow at the southern edge of Jackson Hole. Predicted, contoured depths range from 100 ft (30 m) in the south, near the confluences of Spring Creek and Flat Creek with the Snake River, to 700 ft (210 m) in the west, near the town of Wilson, Wyoming. Received, May 1997 · Revised, February 1998 · Accepted, April 1998     

西藏南木林县秦马弄地区二长花岗岩体岩石成因

以出露在西藏南木林县秦马弄地区二长花岗岩体为研究对象,从野外地质调查、岩石学、LA-ICP-MS锆石U-Pb定年、元素和Lu-Hf同位素地球化学等方面对其进行了分析研究。结果显示：秦马弄地区二长花岗岩体类似于A型花岗岩,形成于古近纪(E1),其LA-ICP-MS锆石U-Pb年龄为(62.0±0.5)~(63.0±0.5) Ma;岩体形成的温度较高(锆石饱和温度为745~805 ℃,平均766 ℃);岩石富SiO2(72.6%~75.0%)、Na2O(2.86%~3.59%)和K2O(4.12%~5.25%),贫CaO(0.72%~1.39%)和MgO(0.26%~0.36%),高FeOT/MgO值(7.26~10.3),属高钾钙碱性系列,弱过铝质;岩石具明显的负Eu异常(Eu/Eu*=0.40~0.70),普遍表现出Ba、Sr、P、Ti元素的亏损和Rb、Th、K、Zr、Hf元素的富集。εHf(t)值为-4.7~-1.8,其两阶段地壳Hf模式年龄tDM2为(1.1~1.3) Ga。秦马弄A型花岗岩体是冈底斯基底地壳物质部分熔融的岩浆产物,形成于古近纪印度板块与欧亚板块俯冲碰撞引起的总体为岛弧背景下的局部拉张构造环境。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.