用实测波浪数据确定JONSWAP谱参数

本文给出应用实测波浪数据确定JONSWAP谱参数的方法，若Hs,Tz,Tc分别为实的有效波高，平均上跨零线周期，平均峰－峰周期并令y=Tz/Tc，本文导出求解谱参数γ值的方程f（γ，y）＝0。根据这个方程的解并应用最小二乘法，γ作为y的函数的表达式可写为（对于2.54≤γ≤15.34及1.6≤y≤1.79）。     

量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。     

Experimental Research on Microscopic Indicators of Temperature＇ s Returning-to-Zero in Deformation of Calcite and Discussions of Correlation Problem

In order to determine the degree of returning-to-zero of temperatures of deformed calcite, a series of rock-breaking experiments were designed to test calcite-rich limestone samples under fixed confining pressures and different temperatures. The consolidated deformed samples in their initial state were observed under a microscope and the microscopic indicators in different zero-returning states were put forward, thus providing a microscopic foundation for evaluation of reliability of dating values of deformation in calcite. At last, the correction of dating values of deformation for samples whose temperature has not yet returned to zero is discussed.