The geochemistry of lead in rivers,estuaries and the continental shelf of the Southeastern United States

Transport by southeastern rivers has insignificant influence on the lead concentration of southeastern shelf waters. If the rate of mobilization and transport of lead by these rivers is representative of uncontaminated fluvial transport during the Pleistocene, only about 5% of the prehistoric output of lead to the North Atlantic can be accounted for by river input.Lead concentrations in southeastern shelf waters are similar to those of North Atlantic Water from the upper 1000 m, which is probably similar to the intrusion source water for the shelf. Atmospheric inputs to the shelf of the same magnitude as observed for the Western North Atlantic are difficult to reconcile given the residence time of shelf waters and their lead concentration unless the rate of loss of lead to shelf sediments is about the same as the atmospheric flux.     

Finite element formulation and algorithms for unsaturated soils. Part II: Verification and application

The finite‐element formulation and integration algorithms developed in Part I are used to analyse a number of practical problems involving unsaturated and saturated soils. The formulation and algorithms perform well for all the cases analysed, with the robustness of the latter being largely insensitive to user‐defined parameters such as the number of coarse time steps and error control tolerances. The efficiency of the algorithms, as measured by the CPU time consumed, does not depend on the number of coarse time steps, but may be influenced by the error control tolerances. Based on the analyses presented here, typical values for the error control tolerances are suggested. It is also shown that the constitutive modelling framework presented in Part I can, by adjusting one constitutive equation and one or two material parameters, be used to simulate soils that expand or collapse upon wetting. Treating the suction as a strain variable instead of a stress variable proves to be an efficient and robust way of solving suction‐dependent plastic yielding. Moreover, the concept of the constitutive stress is a particularly convenient way of handling the transition between saturation and unsaturation. Copyright © 2003 John Wiley & Sons, Ltd.     

Numerical simulations of high-speed solar wind streams within 1 AU and their signatures at 1 AU

A parametric study of the evolution within, and signatures at, 1 AU of high-speed streams is performed with the use of a MHD, 21/2-D, time-dependent model. This study is an extension of an earlier one by Smith and Dryer (1990) who examined the ecliptic plane consequences of relatively short-duration, energetic solar disturbances. The present study examines both the erupting and corotating parts of long-duration, high-speed streams characteristic of coronal hole flows. By examining the variation of the simulated plasma velocity, density, temperature, and magnetic field at 1 AU, as well as the location of the solar coronal hole sources relative to the observer at 1 AU, we are able to provide some insight into the identification of the solar sources of interplanetary disturbances. We present and discuss two definitions for angle locating the solar source of interplanetary disturbances at 1 AU.We apply our results to the suggestion by Hewish (1988) that low-latitude coronal holes are suitably positioned to be the sources of major geomagnetic storms when the holes are in the eastern half of the solar hemisphere at the time of the commencement of the storm. Our results indicate that, for these cases, the streams emanating from within the hole must be very fast, greater than 1000 km s^–1, or very wide, greater than 60°, at the inner boundary of 18 solar radii in our simulation.     

Late Quaternary landscapes in Central Australia: sedimentary history and palaeoecology of Puritjarra rock shelter

Puritjarra rock shelter provides a long record of late Quaternary vegetation in the Australian arid zone. Analysis of the sedimentary history of this rock shelter is combined with reanalysis of charcoal and phytolith records to provide a first‐order picture of changing landscapes in western Central Australia. These show a landscape responding to increasing aridity from 45 ka with deflation of clay‐rich red palaeosols (<45 ka) and sharp declines in grassland and other vegetation at 40–36 ka, and at the beginning of the Last Glacial Maximum (LGM) (24 ka). Vegetation in the catchment of the rock shelter recovered after 15 ka with expansion of both acacia woodland and spinifex grasslands, registering stronger summer rainfall in the interior of the continent. By 8.3 ka re‐vegetation of local palaeosols and dunes had choked off sediment supply to the rock shelter and the character of the sediments changed abruptly. Poaceae values peaked at 5.8 ka, suggesting the early–mid Holocene climatic optimum in Central Australia is bracketed between 8.3 and 5.8 ka. Local vegetation was disrupted in the late Holocene with a sharp decline in Poaceae at 3.8 ka, coinciding with an abrupt intensification of ENSO. Local grasslands recovered over the next two millennia and by 1.5 ka the modern vegetation appears to have become established. Copyright © 2009 John Wiley & Sons, Ltd.     

The integrated optical spectrum of the Crab nebula and evidence for its fading synchrotron continuum

A flux-calibrated optical spectrum integrated over the entire Crab nebula was obtained by making drift scans with a long-slit spectrograph. Compared to observations obtained over the past 40 years, these new data confirm an earlier controversial result that the [O iii ]  λλ4959, 5007  equivalent width is increasing with time, although the rate of ∼0.9 per cent yr⁻¹ is somewhat slower than that measured previously. Additionally, the Hβ equivalent width is increasing at a comparable rate, but the measured fluxes of both Hβ and [O  iii ] have changed less than their respective equivalent widths. The different rates of change in the measured fluxes and equivalent widths of these lines suggest that the optical synchrotron continuum from the Crab nebula is indeed fading rapidly. The apparent decline is consistent with a rate around  −0.5 (±0.2)  per cent yr⁻¹ at wavelengths near 5000  Å inferred independently from measurements of the optical continuum flux during the same time period.     

Development of a real-time algorithm for detection of solar wind discontinuities

A study is presented of an algorithm, based on the statistical analysis of interplanetary magnetic field data, for the real-time detection of discontinuities in the solar wind. The analysis is based on the application of a sliding or searching algorithm together with a minimum variance treatment. A demonstration is given for a Pioneer data set from 29 August, 1966. This particular data set was chosen because it has been extensively studied (in terms of the fast forward MHD shock wave) by previous groups who utilized the three-dimensional Rankine-Hugoniot shock equations after identifying the shock on a subjective basis. Our procedure differs in that it is perfectly objective because of its searching technique. For this particular data set we identify the original shock with excellent agreement with the earlier studies of its normal vector, as well as an additional shock and tangential discontinuity, neither of which had been identified previously.     

The composition and crystallinity of the near-surface regions of weathered alkali feldspars

Our ability to identify thin non-stoichiometric and amorphous layers beneath mineral surfaces has been tested by undertaking X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) work on alkali feldspars from pH 1 dissolution experiments. The outcomes of this work were used to help interpret XPS and TEM results from alkali feldspars weathered for <10,000 years in soils overlying the Shap Granite (north-west England). The chemistry of effluent solutions indicates that silica-rich layers a few nanometers in thickness formed during the pH 1 experiments. These layers can be successfully identified by XPS and have lower Al/Si, Na/Si, K/Si and Ca/Si values than the outermost ∼9 nm of unweathered controls. Development of Al-Si non-stoichiometry is coupled with loss of crystal structure to produce amorphous layers that are identifiable by TEM where >∼2.5 nm thick, whereas the crystallinity of albite is retained despite leaching of Na to depths of tens to hundreds on nanometers. Integration of XPS data over the outermost 6-9 nm of naturally weathered Shap feldspars shows that they have stoichiometric Al/Si and K/Si ratios, which is consistent with findings of previous TEM work on the same material that they lack amorphous layers. There is some XPS evidence for loss of K from the outermost couple of nanometers of Shap orthoclase, and the possibility of leaching of Na from albite to greater depths cannot be excluded using the XPS or TEM results. This study demonstrates that the leached layer model, as formulated from laboratory experiments, is inapplicable to the weathering of alkali feldspars within acidic soils, which is an essentially stoichiometric reaction.