GM4型磁通门磁力仪性能检验方法

目前,磁通门磁力仪广泛应用于观测地球磁场相对变化的仪器。相对于应用,仪器的性能测试不为人们所熟悉。本文针对GM4型磁通门磁力仪的噪声特性,频率特性,线性度,温度特性等关键性能指标的测试依据、测试方法及流程给予详细的阐述。     

广西中短期极端温度客观预报方法研究

利用欧洲中心(ECMWF)数值预报产品和常规资料,应用MOS预报方法和多元线性回归技术,研究建立了广西90个站1~7d的最高、最低温度预报方程,试报检验效果较好,预报结果在大多数情况下是可用的或是可参考的,为业务提供了有效的省级客观预报指导产品,对误差特点进行了分析并提出了改进方法。     

Post-depositional modification of NO-3 in snow layers at EastAntarctica and at the headwater of ürumqi River

Acidic species, such as Nitrate, in polar snow and firn layers are “reversibly” deposited, and are sufficiently volatile to undergo significant postdepositional exchange between snow/firn and the atmosphere. Through comparison of the snowpit and snowpack nitrate concentrations from central East Antarctica and the headwater of ürumqi River, we conclude that the nitrate peaks in the uppermost surface snow layers in central Antarctica are not related to an atmospheric signal and must account for post-depositional effects. Such effects, however, are not found in the surface snowpack nitrate profiles from the headwater of ürumqi River. Two reasons may account for the post-depositional difference. At first, nitrate in the polar snow and firn layers appears to be hydrated ion, which can be taken up by the atmosphere, while at the headwater of ürumqi River it seems mainly as mineral ion, which assembles the behavior of aerosol-derived species that are “irreversibly” deposited and do not undergo significant post-depositional exchange with the atmosphere. Secondly, the chemical features of the snow and ice on the Antarctica are mainly determined by wet deposition, to the contrary, dry deposition is more significant at the headwater of lUrumqi River than that on the East Antarctic Plateau.     

青藏高原地面加热场与四川主汛期降水及伏旱关系

分析了高原地面加热场强度距平指数与四川盆地伏旱及主汛期降水的联系。结果表明,高原前期加热强度同四川盆汛期降水和伏旱程度密切相关。把这些关系引入汛期降水预测模型对提高短期气候预测能力有一定积极意义。     

利用海洋温度剖面与海表盐度反演盐度剖面方法研究

为解决海洋中大量观测数据只含有温度剖面而缺乏盐度观测的问题, 基于历史观测的温盐剖面资料, 考虑到盐度卫星数据的发展, 采用回归分析方法, 在孟加拉湾建立了盐度与温度、经纬度、表层盐度的关系, 并对不同反演方法的反演结果进行检验评估。结果发现, 在不引入海表盐度(sea surface salinity, SSS)时, 最佳反演模型是温度、温度的二次项与经纬度确定的回归模型, 而SSS的引入则可以进一步优化反演结果。将反演结果与观测结果进行对比, 显示用反演的盐度剖面计算的比容海面高度误差超过2cm, 而引入SSS后的误差低于1.5cm。SSS的引入能够较为真实地反映海洋盐度场的垂直结构和内部变化特征, 既能够捕捉到对上混合层有重要影响的SSS信号, 又能够反映盐度在跃层上的季节内变化以及盐度障碍层的季节变化。水团分析显示, 与气候态相比, 盐度反演结果可以更好地表征海洋上层水团的变化特征。     

基于GIS技术的三江平原热量资源评价

基于GIS技术,使用黑龙江省气象观测站和农垦、森工系统观测站的气温资料,以及数字高程模型(DEM)资料,运用趋势面分析法和线性内插法得到三江平原栅格化的热量资源数据。分析表明,三江平原纬度和高度因子对各项热量指标分布均有影响,经度因子主要影响年平均气温、4月平均气温、7月平均气温、≥0℃积温和≥10℃积温;佳木斯西部、双鸭山西部、鸡西大部热量资源较丰富,而青黑山、完达山、老爷岭和太平岭等地区热量资源相对较差。分析结果为合理开发利用三江平原热量资源提供了依据。     

Adsorption of Copper, Nickel, and Cadmium on Goethite in the Presence of Organic Ligands

Adsorption of copper, cadmium and nickel at low concentrations on goethite was studied in the presence of the simple organic ligands oxalate, salicylate, and pyromellitate. The experimental metal adsorption behavior was compared to calculations with a surface complexation model to evaluate the most important interactions. Oxalate mostly decreased Cu and Ni adsorption at high pH-values by competition between solution and surface complexation but had no effect on Cd adsorption. Cu adsorption in the presence of oxalate below pH 6 could best be described by defining a ternary complex of type A (surface-metal-ligand). Salicylate had only minor effects on metal adsorption. The adsorption of Cu in the presence of salicylate above pH 5 could be explained by a ternary complex of type A. Pyromellitate increased the adsorption of Cu and Cd in the acidic pH-range, likely by formation of ternary surface complexes of type B (surface-ligand-metal).     

利用探地雷达观测分析早春融雪前后沙丘表层土壤含水量的时空分布

积雪融水是古尔班通古特沙漠春季植物发育的重要水源, 快速获取早春沙丘的土壤水分变化具有十分重要的生态学意义. 2010年3、 4月分别使用探地雷达进行了多次测量实验, 结果显示: 1)融雪初期, 沙丘顶部土壤的自由水含量最大, 阳坡次之, 且融雪水在重力作用下沿坡面侧向缓慢流动, 在坡底汇集, 主导了融雪初期乃至整个春季沙丘表层土壤水分的分布格局; 2)融雪后期, 由于阴坡积雪和冻土消融相对滞后, 表层土壤含水量略高于阳坡, 而沙丘顶部由于融雪最早且融雪期间水分转移最多而表面最为干燥; 3)通过与时域反射仪的同步测量结果对比, 探地雷达的测量精度被有效控制在0.03范围内, 且探地雷达提供的连续数据更有利于从细节上把握土壤含水量的变化趋势, 为中小尺度土壤水分的动态研究提供了一种科学、 有效的技术手段.     

The effect of anatase, rutile and sodium titanate on the dissolution of boehmite and gibbsite at 90 °C

Industrial plants that refine bauxite to alumina using the high temperature process have always held the belief that anatase was detrimental to the extraction of boehmite while rutile was not. This study shows that this effect is real and that it is observable at temperatures as low as 90 °C. The extraction of gibbsite is shown to be unaffected which leads us to believe that the kinetics of both the Ti-bearing mineral and the Al-bearing mineral is important in this phenomenon. In addition, it is shown that not only is the presence of anatase an issue in boehmite extraction but so too is the presence of sodium titanate. Rutile was found to have the least impact of the three mineral phases.     

Fe3+纳米胶体颗粒的光吸收边蓝移与溶液中Al/Fe比的关系

合成了n（Al）／n（Fe）和碱化度不同的45个聚合氯化铝铁（PAFC）样品,进行了光谱分析,结果显示光吸收边蓝移或红移以及Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒大小分布与溶液的Al／Fe比和碱化度（B=[OH]／[Al＋Fe]）密切相关。电镜观察和电子衍射分析表明：Al（Ⅲ）的加入使Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒变小、有序度降低是造成PAFE光吸收边蓝移和保持胶体颗粒在亚稳定状态下存在的重要原因。当n（Al）／n（Fe）〉8：2后,PAFC溶液中Fe（Ⅲ）羟基氧化物和Al-Fe共聚体胶体主要以〈10m的纳米颗粒形态存在,对应的光谱能级提高到26000cm^-1以上,且各种曰值下Fe^3＋的光谱能级趋于一致。这表明,在大量Al（Ⅲ）存在条件下,PAFE中Fe3^＋的所处的化学环境相似。点能谱分析显示,n（Al）／n（Fe）=4：6的样品中颗粒物的化学计量比最接近AlOOH,FeOOH,溶液的稳定性最差。