二维能量平衡模式中大气温度对二氧化碳增温效应的响应

利用一个考虑了辐射能传输的二维能量平衡气候模式,解析地分析了二氧化碳浓度改变后冰界纬度的变化,得到了冰界纬度随CO2浓度变化的关系以及全球平均温度的变化曲线.结果表明,当CO2浓度由工业革命前的280×10-6增加到700×10-6时,冰界仅后退(北半球向北)几个纬度;当CO2的浓度继续增加时,冰界纬度会加速向极地退缩,直至出现全球无极冰覆盖的现象.同样地,当CO2浓度由280×10-6增加到700×10-6时,全球地表平均温度虽然在增加,但增加的速率很小,并且增加的速率在减小,而当大于700×10-6之后,温度增加的速率会快速增大,温度将加速上升.对不同反照率进行敏感性试验,发现当反照率从0.1到0.32时,结果并没有显著地改变,即结果对反照率的变化并不敏感.这一计算结果表明,在目前的状态下,由CO2引起的增温作用似乎处于变化很小的准饱和状态,即目前气候不会因为CO2浓度的增加而迅速变暖.较为实际的情形可能是大气温度在缓慢增加到一定程度后才会迅速升高.这并不意味着可以忽视CO2的增温效应,因为根据计算结果,这个临界值大概在700×10-6左右,当CO2浓度增加到超过临界值之后,气温会剧烈上升,气候将会处在一个非常温暖的阶段.     

黄河流域地下水资源状况及其生态环境问题

黄河流域是中国重要的生态屏障和经济地带,上中下游面临着不同生态环境问题,水在生态环境问题的形成演化过程中起着重要作用。本文从黄河流域地下水动态特征、地下水资源的数量、质量及开发利用等方面,分析了黄河流域地下水资源及饮水安全状况。黄河流域年度地下水资源量393.55亿m~3,银川平原、河套平原等7处主要平原(盆地)地下水资源量为81.91亿m~3,占比超过20%;黄河流域地下水质量以Ⅰ～Ⅳ类为主,劣质地下水主要受总硬度、硫酸盐、铁、溶解性总固体等天然原生组分影响,砷、氟、硒、碘等原生组分超标是流域部分地区地下水饮水安全的主要威胁;2020年与2019年同期相比,黄河流域地下水位呈上游稳定、中游局部上升、下游下降的态势,主要地下水降落漏斗形态基本稳定。针对黄河源区、宁蒙河套平原等重点区段,分析了存在的主要生态环境问题,提出了全面开展流域水文地质与水资源调查评价,深入开展黄河流域及重点地区水平衡分析等工作建议。     

方解石负载羟基磷灰石复合材料去除水中铀离子的PRB活性介质研究

铀污染地下水分布于世界多国,其危害备受关注。本文基于溶胶-凝胶法制备方解石负载羟基磷灰石复合材料(CLHC),通过静态与动态对比试验,探讨了PRB活性介质对水中铀离子的吸附机理和去除效果。试验结果表明,制备的CLHC表面被羟基磷灰石覆盖,对铀离子具有较强的吸附能力。当U的初浓度为5.0 mg/L、试验周期为2 h、溶液pH值为4、CLHC用量为0.5 g/L时,CLHC可以吸附水中所有的铀离子。CLHC对铀离子的吸附过程可以用Langmuir等温吸附模型、粒子内扩散吸附动力学模型和准二级吸附动力学模型较好地进行描述。石英砂负载羟基磷灰石与CLHC相比,后者具有更强的吸附能力,而且具有更长的使用寿命。CLHC在吸附铀的过程中没有价态变化,其对铀离子的吸附主要为离子交换的化学吸附。本研究的成果可为可渗透反应墙被应用于铀污染地下水修复提供试验依据。     

夏季我国干旱、半干旱区陆面过程能量平衡及其局地大气环流

利用NCEP资料分析得出,夏季我国干旱,半干旱区在整个欧亚大陆上是陆面感热通量最强的地方,与此对应的陆面潜热通量则最弱.陆面所接收的太阳短波辐射主要以感热和长波辐射的能量形式释放.该区降水量很少,降水量的年际变率也很弱;因此,该区的陆面热量通量都显出很弱的年际变率;然而,这些通量的年代际变率信号则比较显著.我国干旱、半干旱区大气环流的热力过程与其陆面过程特征密切相关.该区对流层大气的辐射冷却很强,达-3 K d-1.由于缺乏水汽和上升运动,大尺度凝结加热率、深对流加热率、浅对流加热率都非常弱.因此,600hPa以上的大气以绝热下沉加热来平衡辐射冷却;600hPa以下,陆面感热引起的垂直扩散加热率非常强,多达8 K d-1,它除了平衡辐射冷却以外还制造对流层低层的对流运动,以绝热上升冷却来平衡多余的垂直扩散加热.总之,我国干旱、半干旱区的陆面过程特征决定了该区大气运动的特殊垂直结构,即对流层低层对流上升运动及其上层的下沉运动.我国干旱、半干旱区陆面能量平衡及其局地大气环流的年代际变率,是全球气候系统年代际变率的必然结果.     

鄱阳湖流域径流模型

流域径流是鄱阳湖主要来水,建立鄱阳湖流域径流模型对揭示湖泊水量平衡及其受流域自然和人类活动的影响具有重要意义.针对鄱阳湖-流域系统的特点:流域面积大(16.22×104km2)、多条入湖河流、湖滨区坡面入湖径流等,研究了相应的模拟方法,建立了考虑流域土壤属性和土地利用空间变化的鄱阳湖流域分布式径流模型.采用6个水文站1991-2001年的实测河道径流对模型进行了率定和验证.结果显示,模型整体模拟精度较高.其中,赣江、信江和饶河均取得了较好的模拟结果,月效率系数为0.82-0.95;抚河和修水模拟精度略低,为0.65-0.78.模型揭示了研究时段内年平均入湖径流总量为1623×108m3,其中,赣江最多,占47%,其次为信江和抚河,分别占13%和12%,湖滨区坡面入湖径流约占4%,其余24%来自饶河、修水以及其它入湖支流.模型将用于评估流域下垫面或气候变化引起的入湖水量变化,为湖泊水量平衡计算提供依据.     

长沙、株洲、湘潭三市土壤中重金属元素的来源

为追踪长沙、株洲、湘潭3个城市表层土壤中Cd、As、Pb等重金属元素的来源,分析了土壤、基岩、大气干湿沉降、水、悬浮物等介质之间重金属元素的质量平衡和土壤自身重金属元素含量随时间变化的特点。结果显示,除As外,区内基岩中的重金属元素含量低于克拉克值;残积物中Cd相对基岩贫化,As、Pb、Cu、Hg等重金属元素相对基岩的富集小于3倍;大气干湿沉降重金属元素相对土壤富集了数倍至数十倍;湘江水体主要向沿江潮土提供As、Cd物源:近50年内土壤重金属元素有较高的增加速率。不同介质间重金属元素的质量变化特点支持长沙、株洲、湘潭三市土壤重金属元素富集的主要物源为大气沉降,地表水及悬浮物是沿江湖土重金属元素的主要物源,基岩对土壤提供的物源有限的结论。     

137Cs示踪技术在土壤侵蚀估算中的应用研究进展

137Cs示踪技术目前已被广泛用于长期的土壤侵蚀(水蚀)估算。该技术要解决的两个关键问题是土壤137Cs基准值的确定,以及土壤的137Cs损失量与土壤侵蚀量之间的定量模型的建立。对现有的主要的定量模型进行了简述,并提出了各自的局限性。这些模型可分为经验模型和理论模型两大类,其中以理论模型中的质量平衡模型较为成熟,综合考虑了较多的侵蚀因子,如137Cs年沉降分量、土壤颗粒粒径分布差异、地表富集作用、耕作土壤在耕作活动前新沉降137Cs的侵蚀损失等。对现有模型的改进也进行了探讨,并提出了今后的一些研究重点。     

西风爆发时赤道西太平洋的热量平衡：个例分析

The responses of sea surface temperature (SST) in the western equatorial Pacific warm pool to the west erly wind bursts (WWBs) play an important role in the relationship between WWB and ENSO. By using da ta collected from eight buoys of TOGA (Tropical Ocean-Global Atmosphere)-COARE (Coupled Ocean-Atmosphere Response Experiment), the heat balances of the upper ocean in the western equatorial Pacific around 0°. 156°E during two WWB events were calculated according to Stevenson and Niiler＇s (1983) method. In both events, SST increased before and after the WWBs, while decreased within the WWBs. The SST amplitudes approximated to l℃. Although sometimes the horizontal heat advections may become the biggest term in the heat balance, the variation of SST was dominated by the surface heat flux. On the other aspect, some different features of the two events are also revealed. The two cases have different variation of mixed layer depth. The depth of mixed layer is almost double in the first case (35 m to 70 m), which is caused by Ekman convergence, while only 10m increments due to entrainment in the second one. There are also differences in the currents structure. The different variations of thermal and currents struc ture in the mixing layers accounted for the different variation of the heat balance during the two events, es pecially the advection and residue terms. The seasonal variation of SST in this area is also investigated sim ply. The first WWB event happened just during the seasonal transition. So we considered that it is a normal season transition rather than a so-called anomaly. That also suggested that the seasonal distinction of the WWB is worthy of more attention in the researches of its relationship to ENSO.     

Estimation of turbulent sensible heat and momentum fluxes over a heterogeneous urban area using a large aperture scintillometer

The accurate determination of surface-layer turbulent fluxes over urban areas is critical to understanding urban boundary layer (UBL) evolution. In this study, a remote-sensing technique using a large aperture scintillometer (LAS) was investigated to estimate surface-layer turbulent fluxes over a highly heterogeneous urban area. The LAS system, with an optical path length of 2.1 km, was deployed in an urban area characterized by a complicated land-use mix (residential houses, water body, bare ground, etc.). The turbulent sensible heat (Q H) and momentum fluxes (τ) were estimated from the scintillation measurements obtained from the LAS system during the cold season. Three-dimensional LAS footprint modeling was introduced to identify the source areas ("footprint") of the estimated turbulent fluxes. The analysis results showed that the LAS-derived turbulent fluxes for the highly heterogeneous urban area revealed reasonable temporal variation during daytime on clear days, in comparison to the land-surface process-resolving numerical modeling. A series of sensitivity tests indicated that the overall uncertainty in the LAS-derived daytime Q H was within 20%-30% in terms of the influence of input parameters and the non-dimensional similarity function for the temperature structure function parameter, while the estimation errors in τ were less sensitive to the factors of influence, except aerodynamic roughness length. The 3D LAS footprint modeling characterized the source areas of the LAS-derived turbulent fluxes in the heterogeneous urban area, revealing that the representative spatial scales of the LAS system deployed with the 2.1 km optical path distance ranged from 0.2 to 2 km2 (a "micro-α scale"), depending on local meteorological conditions.