量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。     

抗差估计的初值选择

对L1 范估计的平差值和LS估计的平差值作为抗差估计的初值进行了比较 ,指出在 ρ函数是严凸函数时 ,二者无明显的区别。因为LS估计简单且易于计算 ,因此建议用LS估计的平差值作为抗差估计的初值。     

Numerical calculations in the orbital determination of an artificial satellite for a long arc

Numerical methods are usually used for the computation of ephemerides with perturbations for the precise orbital determination of an artificial satellite. But their numerical stability will be encountered in a long arc. In this case the use the improved Encke special perturbation methods has been suggested. The results of this paper show that Encke's method does indeed have a certain effectiveness, but cannot yet completely resolve the numerical stability, and the more efficient method is to use the energy integral or its variational relation to control the growth of the along-track error in general numerical calculations so that the aim of stabilization can be achieved.     

A stepwise method for determining the number of component distributions in a mixture

This paper considers the problem of estimatingm, the number of components in a finite mixture of distributions from a parametric family. A step-up procedure using the bootstrap method is proposed. Some properties of the procedure are illustrated with simulation studies. An example of the method, applied to orientation of beach clasts, is given.     

Notes on Hori Method for Canonical Systems

In this paper a slightly different approach is proposed for the process of determining the functions S _m and H _m ^* of the algorithm of the canonical version of Hori method. This process will be referred to as integration theory of the mth order equation of the method. It will be shown that the ordinary differential equation with an auxiliary parameter t ^* as independent variable, introduced through Hori auxiliary system, can be replaced by a partial differential equation in the time t. In this way, the mth order equation of the algorithm assumes a form very similar to the one of other perturbation methods. In virtue of this new approach of the integration theory for Hori method, Lagrange's variational equations introduced by Sessin are revised. As an example, the Duffing equation is solved through this new approach.     

电测深ρ＿s差值法的应用效果

用电测深研究地电断面、寻找隐伏多金属矿体时，以往采用ρ＿ｓ（或η＿ｓ）等值线断面图进行地质推断解释，因受浅源信号的干扰，效果差。本文提出了采用ρ＿ｓ（或η＿ｓ）差值法，能排除浅源干扰信号，反映出地电断面的相对变化，突出了深部微弱信息，取得了较好的地质解释效果。     

Computerized streamflow measurement using slug injection

Using current meters to estimate flows in fast mountain streams is difficult and inaccurate. The salt dilution method offers an easier and more accurate alternative. The method has been used for many years but is time consuming and messy because of the need to mix chemical solutions and measure chemical concentrations in the field. A computer program has been developed which uses a laptop computer to calculate the mixing length and the mass of salt needed. The program controls the conductivity measurements and calculates the streamflow directly in the field. The development of this program is described and examples are presented of the application of the method in the Rocky Mountains of Alberta and British Columbia.     

A new stereo‐analytical method for determination of removal blocks in discontinuous rock masses

The paper provides a new stereo‐analytical method, which is a combination of the stereographic method and analytical methods, to separate finite removable blocks from the infinite and tapered blocks in discontinuous rock masses. The methodology has applicability to both convex and concave blocks. Application of the methodology is illustrated through examples. Addition of this method to the existing block theory procedures available in the literature improves the capability of block theory in solving practical problems in rock engineering. Copyright © 2003 John Wiley & Sons, Ltd.     

强势语下的无奈——辜鸿铭古籍英译的归化

通过对辜鸿铭所翻译的《中庸》、《论语》进行分析和研究 ,反映出社会背景对中国古典文化经典翻译的不同策略的影响。从而证明辜鸿铭译文的别出心裁出于强势语下的无奈。从翻译理论上揭示归化翻译的历史意义以及译品存在的价值。     

The Asiago Extrasolar Planet Transit Search

RATS is an Italian project devoted to Hot Jupiter search with the transit method. A planet transiting in front of a host star can be mimed by several, and well defined, astrophysical phenomena (Brown, 2003). In order to recognize these false alarms we can utilize a preventive strategy to limit false alarm rates and a spectroscopic follow up to refuse no transit candidates. As preventive strategy it is important to develop an accurate target field selection, with well defined requisites, in order to maximize the solar type star numbers and to minimize the risk of possible astrophysical false alarms.