Zircon U–Pb age, trace element and Hf isotope composition of Kongling terrane in the Yangtze Craton: refining the timing of Palaeoproterozoic high-grade metamorphism

U–Pb age, trace element and Hf isotope compositions of zircon were analysed for a metasedimentary rock and two amphibolites from the Kongling terrane in the northern part of the Yangtze Craton. The zircon shows distinct morphological and chemical characteristics. Most zircon in an amphibolite shows oscillatory zoning, high Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, high formation temperature, high trace element contents, clear negative Eu anomaly, as well as HREE-enriched patterns, suggesting that it is igneous. The zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2857 ± 8 Ma, representing the age of the magmatic protolith. The zircon in the other two samples is metamorphic. It has low Th/U ratios, low trace element concentrations, variable HREE contents (33.8 ≥ Lu_N≥2213; 14.7 ≤ Lu_N/Sm_N ≤ 354) and ¹⁷⁶Lu/¹⁷⁷Hf ratios (0.000030–0.001168). The data indicate that the zircon formed in the presence of garnet and under upper amphibolite facies conditions. The metamorphic zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2010 ± 13 Ma. These results combined with previously obtained Palaeoproterozoic metamorphic ages suggest a c. 2.0 Ga Palaeoproterozoic collisional event in the Yangtze Craton, which may result from the assembly of the supercontinent Columbia. The zircon in two samples yields weighted mean two-stage Hf model ( T _DM2) ages of 3217 ± 110 and 2943 ± 50 Ma, respectively, indicating that their protoliths were mainly derived from Archean crust.     

Pressure-induced incipient amorphization of α-quartz and transition to coesite in an eclogite from Antarctica: a first record and some consequences

Monocrystalline quartz inclusions in garnet and omphacite from various eclogite samples from the Lanterman Range (Northern Victoria Land, Antarctica) have been investigated by cathodoluminescence (CL), Raman spectroscopy and imaging, and in situ X‐ray (XR) microdiffraction using the synchrotron. A few inclusions, with a clear‐to‐opalescent lustre, show ‘anomalous’ Raman spectra characterized by weak α‐quartz modes, the broadening of the main α‐quartz peak at 465 cm^?1, and additional vibrations at 480–485, 520–523 and 608 cm^?1. CL and Raman imaging indicate that this ‘anomalous’α‐quartz occurs as relicts within ordinary α‐quartz, and that it was preserved in the internal parts of small quartz inclusions. XR diffraction circular patterns display irregular and broad α‐quartz spots, some of which show an anomalous d‐spacing tightening of ～2%. They also show some very weak, hazy clouds that have d‐spacing compatible with coesite but not with α‐quartz. Raman spectrometry and XR microdiffraction characterize the anomalies with respect to α‐quartz as (i) a pressure‐induced disordering and incipient amorphization, mainly revealed by the 480–485 and 608‐cm^?1 Raman bands, together with (ii) a lattice densification, evidenced by d‐spacing tightening; (iii) the cryptic development of coesite, 520–523 cm^?1 being the main Raman peak of coesite and (iv) Brazil micro‐twinning. This ‘anomalous’α‐quartz represents the first example of pressure‐induced incipient amorphization of a metastable phase in a crustal rock. This issue is really surprising because pressure‐induced amorphization of metastable α‐quartz, observed in impactites and known to occur between 15 and 32 GPa during ultrahigh‐pressure (UHP) experiments at room temperature, is in principle irrelevant under normal geological P–T conditions. A shock (due to a seism?) or a local overpressure at the inclusion scale (due to expansion mismatch between quartz and its host mineral) seem the only geological mechanisms that can produce such incipient amorphization in crustal rocks. This discovery throws new light on the modality of the quartz‐coesite transition and on the pressure regimes (non‐lithostatic v. lithostatic) during high‐pressure/UHP metamorphism. In particular, incipient amorphization of quartz could favour the quartz‐coesite transition, or allow the growth of metastable coesite, as already experimentally observed.     

P‐wave transmission across fractures with nonlinear deformational behaviour

Stress wave attenuation across fractured rock masses is a great concern of underground structure safety. When the wave amplitude is large, fractures experience nonlinear deformation during the wave propagation. This paper presents a study on normal transmission of P‐wave across parallel fractures with nonlinear deformational behaviour (static Barton–Bandis model). The results show that the magnitude of transmission coefficient is a function of incident wave amplitude, nondimensional fracture spacing and number of fractures. Two important indices of nondimensional fracture spacing are identified, and they divide the area of nondimensional fracture spacing into three parts (individual fracture area, transition area and small spacing area). In the different areas, the magnitude of transmission coefficient has different trends with nondimensional fracture spacing and number of fractures. In addition, the study reveals that under some circumstances, the magnitude of transmission coefficient increases with increasing number of fractures, and is larger than 1. Copyright © 2006 John Wiley & Sons, Ltd.     

Porphyroblast inclusion-trail orientation data: eppure non son girate*!

Extensive examination of large numbers of spatially orientated thin sections of orientated samples from orogens of all ages around the world has demonstrated that porphyroblasts do not rotate relative to geographical coordinates during highly non-coaxial ductile deformation of the matrix subsequent to their growth. This has been demonstrated for all tectonic environments so far investigated. The work also has provided new insights and data on metamorphic, structural and tectonic processes including: (1) the intimate control of deformation partitioning on metamorphic reactions; (2) solutions to the lack of correlation between lineations that indicate the direction of movement within thrusts and shear zones, and relative plate motion; and (3) a possible technique for determining the direction of relative plate motion that caused orogenesis in ancient orogens.     

Chemical alteration of tephra in the depositional environment: theoretical stability modelling

The study of the chemical stability of vitreous material in aqueous media is well‐established. There has to date been little consideration of the implications of variations in the chemical durability of tephra in Quaternary tephrochronology. Chemical alteration can take the form of cationic leaching from the matrix, or complete destruction of the silica network, either of which could constrain the ability to chemically identify distal tephra. Here we apply established models of vitreous durability to the published chemical analyses of a large number of Icelandic tephras in order to predict their relative durabilities under equivalent conditions. This suggests that some important tephras have relatively poor chemical stability, and that rhyolitic tephras are, in general, more stable than basaltic. We conclude that tephras should be expected to show predictable differential chemical stability in the post‐depositional environment. Copyright © 2003 John Wiley & Sons, Ltd.     

Observations on the ecological importance of salt marshes in the Cumberland Basin,a macrotidal estuary in the Bay of Fundy

The Cumberland Basin, a 118 km² estuary at the head of the Bay of Fundy which has an average tidal range of about 11m, contains large tracts of salt marsh (15% of the area below highest high water). Low marsh (below about 0·9 m above mean high water) is composed almost exclusively of Spartina alterniflora while the vegetation on high marsh is more diverse but dominated by Spartina patens. Because of its higher elevation, high marsh is flooded infrequently for short periods by only extreme high tides. Low marsh is inundated much more frequently by water as much as 4m deep for periods as long as 4 h per tide. Temporal variability in the occurrence of extreme tides influences the flooding frequency of high marsh for any given month and year. Using a modification of Smalley's method, the mean annual net aerial primary production (NAPP) of low and high marsh is estimated to be 272 and 172 g C m^?2, respectively. Vegetation turnover times average 1·0 and 2·0 y for low and high marsh, respectively. Because of abundant tidal energy, much of the low marsh production appears to be exported and distributed widely about the estuary. Since high levels of turbidity suppress phytoplankton production, salt marshes produce approximately half of the carbon fixed photosynthetically in the Cumberland Basin. It is concluded that salt marshes play a major ecological role in the Cumberland Basin.     

Survival,growth and shell deformities of copper- and cadmium-exposed mussels (Mytilus edulis L.) in brackish water

Mussels, Mytilus edulis L., were exposed to elevated concentrations of copper or cadmium in the laboratory, then placed in cages in the sea (salinity 7‰). One year later maximum lengths of the mussels were measured and shells screened for deformities. Growth was 0·6 cm year^?1 in the control cages and retarded in cages of exposed mussels. A total of 63% of cadmium-exposed and 46% of copper-exposed mussels had shell deformities. In the control cages 26% were deformed while in a natural population only 3% were deformed. The proportion of deformities to growth was inversely related. Low concentrations showed their injuriousness in this long-term test, probably due to the closing of the valves during exposure to high concentrations.     

Numerical prediction of blast‐induced stress wave from large‐scale underground explosion

This paper presents a numerical model for predicting the dynamic response of rock mass subjected to large‐scale underground explosion. The model is calibrated against data obtained from large‐scale field tests. The Hugoniot equation of state for rock mass is adopted to calculate the pressure as a function of mass density. A piecewise linear Drucker–Prager strength criterion including the strain rate effect is employed to model the rock mass behaviour subjected to blast loading. A double scalar damage model accounting for both the compression and tension damage is introduced to simulate the damage zone around the charge chamber caused by blast loading. The model is incorporated into Autodyn3D through its user subroutines. The numerical model is then used to predict the dynamic response of rock mass, in terms of the peak particle velocity (PPV) and peak particle acceleration (PPA) attenuation laws, the damage zone, the particle velocity time histories and their frequency contents for large‐scale underground explosion tests. The computed results are found in good agreement with the field measured data; hence, the proposed model is proven to be adequate for simulating the dynamic response of rock mass subjected to large‐scale underground explosion. Extended numerical analyses indicate that, apart from the charge loading density, the stress wave intensity is also affected, but to a lesser extent, by the charge weight and the charge chamber geometry for large‐scale underground explosions. Copyright © 2004 John Wiley & Sons, Ltd.     

Runoff responses to afforestation in a watershed of the Loess Plateau,China

Afforestation has been suggested as a means of improving soil and water conservation in north‐western China, especially on the Loess Plateau. Understanding of the hydrological responses to afforestation will help us develop sustainable watershed management strategies. A study was conducted during the period of 1956 to 1980 to evaluate runoff responses to afforestation in a watershed on the Loess Plateau with an area of 1·15 km², using a paired watershed approach. Deciduous trees, including locust (locusta L.), apricot (praecox L.) and elm (ulmus L.), were planted on about 80% of a treated watershed, while a natural grassland watershed remained unchanged. It was estimated that cumulative runoff yield in the treated watershed was reduced by 32% as a result of afforestation. A significant trend was also observed that shows annual runoff reduction increases with the age of the trees planted. Reduction in monthly runoff occurred mainly from June to September, which was ascribed to greater rainfall and utilization by trees during this period. Afforestation also resulted in reduction in the volume and peak flow of storm runoff events in the treated watershed with greater reduction in peak flow. Copyright © 2003 John Wiley & Sons, Ltd.     

The Statistical Analysis of Migration of Strong Earthquakes-Taking the North China Region as an Example

The migration of strong earthquakes is an important research topic because the migration phenomena reflect partly the seismic mechanism and involve the prediction of tendency of seismic activity. Research on migration of strong earthquakes has mostly focused on finding the phenomena. Some attempts on getting regularity were comparatively subjective. This paper suggests that there should be indices of migration in earthquake dataset and the indexes should have statistical meaning if there is regularity in the migration of strong earthquakes. In this study, three derivative attributes of migration, i.e., migration orientation, migration distance and migration time interval, were statistically analyzed. Results in the North China region show that the migration of strong earthquakes has statistical meaning. There is a dominant migration orientation (W by S to E by N), a dominant distance (≤100km and on the confines of 300～700km), and a dominant time interval (≤1a and on the confines of 3～4a). The results also show that the migration will differ slightly with different magnitude range or earthquake activity phase.