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11.
Familiar since antiquity, and subject in contemporary times to various characterization schemes, the exact nature of solid bitumen is not yet fully known. Bitumens have ‘random polymer-like’ molecular structures, are mobile as highly viscous fluids or were once fluids but have since turned into solids. Solid bitumens consist mainly of large moieties, of polyclyclic aromatic hydrocarbons, occasionally with finely admixed, fine-grained cryptocrystalline graphite. Solid bitumens are distinguished from kerogen, which is the syngenetic and generally finely dispersed particulate organic matter in sedimentary rock that virtually does not migrate following its deposition. Occurrences of solid bitumens are relevant to petroleum exploration as well as the search for, and evaluation of, a variety of metallic mineral deposits. Genesis of bitumen is in many cases linked to the thermal and hydrothermal history of organic matter in sedimentary rock. Apparently bitumen, or more specifically organic acids generated along with bitumen during diagenesis, may alter porosity of reservoir rocks or otherwise prepare the ground for ore deposition. Bitumen is also relatively sensitive to alteration processes, some of which, such as oxidative weathering, water leaching, biodegradation (contact) metamorphism and ionizing radiation may likewise affect its nature. Elemental composition of bitumen commonly reflects the nature of mineral deposits. Is is possible that in petroleum exploration, trace metal abundances of bitumen may eventually allow prediction of crude oil types and volumes anticipated from a given source rock? Beside transition elements, notably Ni and V, highly anomalous concentrations of U, Pt and Au occur in some solid bitumens. During the generation of petroleum from kerogen, the trend in δ13C is toward lighter values. The opposite seems to occur when liquid petroleum is subjected to thermal cracking (and /or related processes) yielding solid bitumen enriched in 13C, and isotopically light methane. In fact, except for deasphalting and possibly some irradiation processes, the result of thermal cracking, oxidation, water leaching, inspissation (drying) and bacterial degradation of crude oil is that lower molecular weight hydrocarbons are removed leaving bitumen residues enriched in aromatic hydrocarbons, heteroatomic compounds (NSO) and 13C. Such phenomena are relevant to bitumen paragenesis in petroleum reservoir rocks, to certain Phanerozoic occurrences of multiple generations of bitumens, and to bitumens in mineral deposits. 相似文献
12.
David A. Williams 《Planetary and Space Science》1992,40(12):1683-1693
We review the present understanding of interstellar CH+. We show that the essential chemistry was correctly identified by Bates and Spitzer in 1951. More recent work has been concerned with defining appropriate venues within which this chemistry can function efficiently. This process had led to a much fuller understanding of the nature of the interstellar medium. 相似文献
13.
14.
The Middle Jurassic Kirkpatrick flood basalts and comagmatic Ferrar intrusions in the Transantarctic Mountains represent
a major pulse of tholeiitic magmatism related to early stages in the breakup of Gondwana. A record of the volcano-tectonic
events leading to formation of this continental flood-basalt province is provided by strata underlying and only slightly predating
the Kirkpatrick lavas. In the central Transantarctic Mountains, the lavas rest on widespread (≥7500 km2) tholeiitic pyroclastic deposits of the Prebble Formation. The Prebble Formation is dominated by lahar deposits and is an
unusual example of a regionally developed basaltic lahar field. Related, partly fault-controlled pyroclastic intrusions cut
underlying strata, and vents are represented by the preserved flanks of two small tephra cones associated with a volcanic
neck. Lahar and air-fall deposits typically contain 50–60% accidental lithic fragments and sand grains derived from underlying
Triassic – Lower Jurassic strata in the upper part of the Beacon Supergroup. Juvenile basaltic ash and fine lapilli consist
of nonvesicular to scoriaceous tachylite, sideromelane, and palagonite, and have characteristics indicating derivation from
hydrovolcanic eruptions. The abundance of accidental debris from underlying Beacon strata points to explosive phreatomagmatic
interaction of basaltic magma with wet sediment and groundwater, which appears to have occurred in particular where rising
magma intersected upper Beacon sand aquifers. Composite clasts in the lahar deposits exhibit complex peperitic textures formed
during fine-scale intermixing of basaltic magma with wet sand and record steps in subsurface fuel-coolant interactions leading
to explosive eruption.
The widespread, sustained phreatomagmatic activity is inferred to have occurred in a groundwater-rich topographic basin linked
to an evolving Jurassic rift zone in the Transantarctic Mountains. Coeval basaltic phreatomagmatic deposits of the Mawson
and Exposure Hill Formations, which underlie exposures of the Kirkpatrick Basalt up to 1500 km to the north along strike in
Victoria Land, appear to represent other parts of a regional, extension-related Middle Jurassic phreatomagmatic province which
developed immediately prior to rapid outpouring of the flood basalts. This is consistent with models which assign an important
role to lithospheric stretching in the generation of flood-basalt provinces.
Received: 28 August 1995 / Accepted: 18 April 1996 相似文献
15.
16.
David J. Dunlop Hironobu Hyodo Todd Knight Alan G. Steele 《Geophysical Journal International》1985,83(3):699-720
Summary. After thermal and alternating field (AF) cleaning, the characteristic high blocking temperature A component of natural remanent magnetization (NRM) of the Tudor gabbro of southern Ontario has a mean direction D = 326°, I =–46° ( k = 132, α95 = 4.8°, N = 8 sites). The corresponding palaeopole, 133°E, 12°N ( dp = 4°, dm = 6°), confirms the palaeopole 137°E, 17°N (α95 = 8.4°) reported earlier by Palmer & Carmichael, based on AF cleaning only. The A NRM has unblocking temperatures > 515–525°C which exceed the estimated 500°C peak temperature reached locally during ∼ 1050 Ma Grenvillian regional metamorphism. The A NRM therefore predates metamorphism and is probably a primary thermoremanence (TRM). The age of the Tudor NRM has previously been taken to be about 675 Ma, but recent 40 Ar/39 Ar dating by Baksi has shown that this is the time of post-metamorphic cooling to 200–250°C. Hornblendes record initial cooling of the intrusion to 590±20°C at 1110 Ma and this is the best estimate of the age of the A remanence. Successful Thellier-type palaeointensity determinations on 11 Tudor samples confirm that the A NRM is a TRM and indicate a palaeofield at this time of 18–27 μT, about 50–70 per cent of the present field intensity at 27° magnetic latitude. The anomalous Tudor A palaeopole, which lies well to the west of both 1000–800 Ma Grenvillian palaeopoles and 1100–1050 Ma poles from Interior Laurentia, is interpreted as recording divergence between Grenvillia and Interior Laurentia just before the Grenvillian orogeny, rather than a post-metamorphic extension of the apparent polar wander path as previously assumed. 相似文献
17.
We present a new Very Large Array (VLA) image of Saturn, made from data taken in October 1998 at a wavelength of λ3.6 cm. The moderate ring opening angle (B≈15°) allows us to explore direct transmission of microwave photons through the A and C rings. We find a strong asymmetry of photons transmitted through the A ring, but not in the C ring, a new diagnostic of wake structure in the ring particles. We also find a weak asymmetry between east and west for the far side of the ansae. To facilitate quantitative comparison between dynamic models of the A ring and radio observations, we extend our Monte Carlo radiative transfer code (described in Dunn et al., 2002, Icarus 160, 132-160) to include idealized wakes. We show the idealized model can reproduce the properties of dynamic simulations in directly transmitted light. We examine the model behavior in directly transmitted and scattered light over a range of physical and geometric wake parameters. Finally, we present a wake model with a plausible set of physical parameters that quantitatively reproduces the observed intensity and asymmetry of the A ring both across the planet and in the ansae. 相似文献
18.
19.
This paper considers the problem of estimatingm, the number of components in a finite mixture of distributions from a parametric family. A step-up procedure using the bootstrap method is proposed. Some properties of the procedure are illustrated with simulation studies. An example of the method, applied to orientation of beach clasts, is given. 相似文献
20.
Andrew J. L. Harris Anna L. Butterworth Richard W. Carlton Ian Downey Peter Miller Pedro Navarro David A. Rothery 《Bulletin of Volcanology》1997,59(1):49-64
Satellite data offer a means of supplementing ground-based monitoring during volcanic eruptions, especially at times or locations
where ground-based monitoring is difficult. Being directly and freely available several times a day, data from the advanced
very high resolution radiometer (AVHRR) offers great potential for near real-time monitoring of all volcanoes across large
(3000×3000 km) areas. Herein we describe techniques to detect and locate activity; estimate lava area, thermal flux, effusion
rates and cumulative volume; and distinguish types of activity. Application is demonstrated using data for active lavas at
Krafla, Etna, Fogo, Cerro Negro and Erebus; a pyroclastic flow at Lascar; and open vent systems at Etna and Stromboli. Automated
near real-time analysis of AVHRR data could be achieved at existing, or cheap to install, receiving stations, offering a supplement
to conventional monitoring methods.
Received: 21 January 1997 / Accepted: 3 April 1997 相似文献