我国主要金矿类型中黄铁矿"电子-空穴心"特征及影响因素

通过对我国主要金矿类型中黄铁矿导电类型的分析表明，黄铁矿“电子。空穴心”与金矿床的成因类型具有密切的联系，华北地台太古代变基性火山岩中的金矿床(绿岩带型)、热水淋滤型(卡林型)金矿床，黄铁矿多为单一的“电子心”型导电。大多数产于中生代岩体中的中深脉状金矿、火山次火山岩中的金矿床，黄铁矿为“电子心”、“空穴心”混合型导电，个别的为单一的“空穴心”导电。黄铁矿的“电子．空穴心”受杂质成分As、Co、Nl在成矿背景中的丰度，进入黄铁矿品格中的替代能力的差异、补偿类质同象现象、成矿时温度以及．f(S2)等多种因素的耦合制约。     

青铜文物腐蚀过程中的次生矿物

产于不同环境不同地方的青铜文物经矿相显微镜观察、电子探针成分分析和X射线衍射研究表明，在青铜文物腐蚀层中观察到次生矿物——赤铜矿、孔雀石、蓝铜矿、白铅矿和锡石。由上述矿物组成的腐蚀层在青铜器表面形成保护层。腐蚀层细分为红色赤铜矿层、绿色碳酸盐矿物层和黄色锡石层组成，其厚度小于1mm。青铜合金在潮湿条件下的腐蚀比在干旱条件下要严重，另外青铜合金是适用于作高放废物地质处置系统中的废物罐的候选材质。     

腾冲热海火山地热区近期水热爆炸的阶段性演化特征

水热爆炸是活动性地热田的典型显示。腾冲热海火山地热区历史上曾发生过强烈的水热爆炸活动，但前期一度沉寂。1993年以来水热爆炸活动再度活跃。在过去十年间，研究区内发生过较大的爆炸喷发事件20余次，且规模越来越大。本文根据对爆炸形成泉点的选出气体化学和氦同位素组成的测试结果，研究了区内近期水热爆炸活动的演化特征。逸出气体化学和氦同位素组成特征指示，区内近期引发水热爆炸活动的气体源区有从浅层、中层向深层发展的趋势；作者认为，区内未来可能发生更大规模的爆炸活动，其危险性应引起高度关注。     

Correcting method of eddy covariance fluxes over non-flat surfaces and its application in ChinaFLUX

Although Eddy Covariance (EC) technique is one of the best methods for estimating the energy and mass exchanges between underlying surface and atmosphere in micrometeorology, errors and uncertainties still exist without necessary corrections. In this paper, we will focus on the effect of coordinate system on the eddy fluxes. Based on the data observed over four sites (one farmland site, one grassland site and two forest sites), the effects of three coordinate system transforming methods (Double Rotation-DR, Triple Rotation-TR and Planar Fit-PF)on the turbulent fluxes are analyzed. It shows that (i) the corrected fluxes are more or less than the uncorrected fluxes, which is related mainly to the sloping degree of surface, wind speed and wind direction; and (ii) pitch angle has a sinusoidal dependence on wind direction, especially in the regular sloping terrain; and (iii) PF method is something like the simplification of TR or DR,and there are not obvious distinctions in correction in sloping grassland and flat farmland, but PF method is not suitable for uneven and irregular forest sites.     

Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).     

广西钦江河口枯季水动力特征及其对冷空气的响应

河口作为陆海相互作用的关键带,是河流入海泥沙及污染物的主要归宿地。钦江作为广西第二大河流,在茅尾海资源开发利用和生态环境保护与修复中发挥着重要作用。为进一步认识钦江河口地区的沉积动力过程,2021年10月27日至12月8日在此展开水动力和水体环境要素的连续观测。现场观测与分析结果表明,观测期间钦江河口潮汐类型为正规全日潮,浅水分潮显著,平均潮差为3.07 m,具有落潮优势;潮流以全日分潮流为主导,平均流速为0.12 m/s,运动形式主要为往复流;余流流向主要为西南方向。钦江河口潮汐和潮流性质较外湾和茅尾海中部海域全日潮特征更显著。枯季期间河口表层沉积物随潮汐运动表现为侵蚀-沉降交替的变化规律,垂向上侵蚀通量大于沉降通量,水平方向上悬沙净向海输运。冷空气过境带来的降雨使得钦江河口水体盐度降低、浊度增大,悬沙浓度及输沙量增加,同时冷空气南下时北风增强引起钦江河口减水效应并使潮差略有增加,水动力强度增大,增加表层沉积物的活动性,从而引起底部沉积物再悬浮强度和频率增加。     

煤层气在煤储层中的扩散及其影响因素

煤层气在煤储层中的扩散是指从煤基质孔隙表面上解吸的煤层气运移到割理系统的主要过程。发生扩散的前提条件是气体浓度差的出现，衡量扩散能力大小的重要参数是扩散系数。前者为由解吸速度、解吸气量和煤层气产量、井孔压力降等因素控制的动态参数，而后者为主要受扩散物质性质、扩散介质特征、扩散系统的温度、压力和孔隙结构形态等因素影响的静态参数。煤层气在煤储层中的扩散量与煤层气浓度差和扩散系数呈正比关系。     

Uncertainty analysis of CO_2 flux components in subtropical evergreen coniferous plantation

We present an uncertainty analysis of ecological process parameters and CO2 flux components (Reco, NEE and gross ecosystem exchange (GEE)) derived from 3 years’ continuous eddy covariance meas-urements of CO2 fluxes at subtropical evergreen coniferous plantation, Qianyanzhou of ChinaFlux. Daily-differencing approach was used to analyze the random error of CO2 fluxes measurements and bootstrapping method was used to quantify the uncertainties of three CO2 flux components. In addition, we evaluated different ...     

火山岩与地形联合约束下海岛土壤稀土元素地球化学空间分布异质性——以广西涠洲岛为例

海岛土壤地球化学特征的研究对于认识海岛表生地质环境有重要意义。本研究以我国最大的第四纪火山海岛——涠洲岛为案例,重点研究亚热带海岛环境下火山岩风化土壤的稀土元素（REE）地球化学特征,并探讨影响其空间分布的关键因素。结果表明,涠洲岛土壤REE总量（ΣREE）自然变化范围较大,介于59.07~575.30 mg/kg,平均值为285.53 mg/kg,高于中国大陆土壤背景值（163.86 mg/kg）,指示火山岩风化海岛具有较高的土壤REE丰度。反距离权重插值法（IDW）分析指示,岛内土壤的REE含量高低变化呈现出以带状和斑块状为主体形态的空间分布不均一性,推断其成因与母质岩石类型和地形位置等因素密切相关。3种不同岩性的成土母岩的ΣREE含量变化序列为：玄武岩（236.66 mg/kg）>火山碎屑岩（215.58 mg/kg）>含生物碎屑海滩沉积物（18.99 mg/kg）,对应的土壤ΣREE含量具有类似变化规律,即玄武岩土壤（307.20 mg/kg）>火山碎屑岩土壤（297.46 mg/kg）>含生物碎屑海滩沉积物土壤（89.73 mg/kg）。该证据指示母岩是控制岛内土壤REE含量变化的首位因素,玄武岩整体上易形成具有较高REE丰度的土壤,火山碎屑岩次之,而含生物碎屑海滩沉积物反之。此外,本研究还发现火山碎屑岩单一岩性区内,发育的土壤REE含量也会随地形地貌差异而出现显著变化,其原因是地形地貌制约了土壤矿物和化学风化程度,海蚀丘陵比海积平原更利于海岛土壤中REE次生富集作用的发生。