Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.     

Four-element CODAR beam forming

An HF radar called the Coastal Ocean Dynamics Applications Radar (CODAR) is presently being used in several forms to measure ocean surface parameters. The original version was developed by the National Oceanic and Atmospheric Administration (NOAA) and utilizes a four-element receive array. The array consists of four equally spaced elements arranged on a circle with a radius of 0.2151 wavelengths (at 25.4 MHz). It was designed to measure ocean currents using a direction-finding technique based on an extension to a simple two-element interferometer. The problem of determining the bearing of a radiating source can be readily shown to be equivalent to that incurred in spectral estimation. In an attempt to improve upon the processing of existing data, modern nonlinear spectral estimation techniques are applied in a beam-forming bearing estimation procedure and compared against several direction-finding algorithms. Enhancement of bearing estimators via analysis of the eigenstructure of a spatial correlation matrix is included. Antenna response patterns are calculated and used to investigate properties of direction-finding algorithms. Simulated data are used for a comparison of direction finding and beam forming. The asymmetrical bias of each method is investigated to determine its effect on the error in estimating the angle of arrival of a radar target.     

A note on turbulent perturbations of salinity in a partially mixed estuary

Measurements of salinity perturbations in a partially mixed estuary have been used to evaluate the usefulness of an inductive salinometer and to determine some of the characteristics of the salinity perturbations. The salinometer performed satisfactorily under most conditions. Although internal wave like effects were present, the turbulence fluctuations were dominant. The salinity fluctuations and the turbulent fluxes $\text{sw}$ and $\text{su}$ were found to behave in a manner similar to the density fluctuations in a thermally stratified atmospheric boundary layer and a laboratory open channel flow. A quadrant analysis suggested that the contribution of each quadrant to the turbulent flux changed with Ri. The turbulence parameters ν and c_γ were found to decrease and increase respectively as Ri increases.     

Chronology and evolution of the northern Iceland Plateau

New aeromagnetic data, K-Ar age determinations of dredged marine igneous rocks, as well as other geophysical evidence have shed light on the chronology, nature and evolution of the northern Iceland Plateau. Correspondence between seismic refraction profiles taken on the Jan Mayen Ridge and westward through Jan Mayen Island, suppressed aeromagnetic anomalies, earthquake surface wave studies, and ages of dredged igneous rocks suggest these strata may form an extended region of thickened crust, possibly of Caledonian age, extending westward toward the Kolbeinsey Ridge and northwest to the south wall of the Jan Mayen Fracture Zone.     

About Darcy's law in non-Galilean frame

This paper is aimed towards investigating the filtration law of an incompressible viscous Newtonian fluid through a rigid non-inertial porous medium (e.g. a porous medium placed in a centrifuge basket). The filtration law is obtained by upscaling the flow equations at the pore scale. The upscaling technique is the homogenization method of multiple scale expansions which rigorously gives the macroscopic behaviour and the effective properties without any prerequisite on the form of the macroscopic equations. The derived filtration law is similar to Darcy's law, but the tensor of permeability presents the following remarkable properties: it depends upon the angular velocity of the porous matrix, it verifies Hall–Onsager's relationship and it is a non-symmetric tensor. We thus deduce that, under rotation, an isotropic porous medium leads to a non-isotropic effective permeability. In this paper, we present the results of numerical simulations of the flow through rotating porous media. This allows us to highlight the deviations of the flow due to Coriolis effects at both the microscopic scale (i.e. the pore scale), and the macroscopic scale (i.e. the sample scale). The above results confirm that for an isotropic medium, phenomenological laws already proposed in the literature fails at reproducing three-dimensional Coriolis effects in all types of pores geometry. We show that Coriolis effects may lead to significant variations of the permeability measured during centrifuge tests when the inverse Ekman number Ek⁻¹ is 𝒪(1). These variations are estimated to be less than 5% if Ek⁻¹<0.2, which is the case of classical geotechnical centrifuge tests. We finally conclude by showing that available experimental data from tests carried out in centrifuges are not sufficient to determining the effective tensor of permeability of rotating porous media. Copyright © 2004 John Wiley & Sons, Ltd.