Coulometric TCO2 analyses for marine studies; an introduction

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.     

Arsenic incorporation in a salt marsh ecosystem

Replicate portions of a Delaware salt marsh were enclosed in cylindrical microcosms and exposed to elevated levels of inorganic arsenic (arsenate). All biotic and abiotic components in dosed cylinders rapidly incorporated arsenic. Spartina blades showed the greatest arsenic enrichment, with dosed plants incorporating arsenic concentrations an order of magnitude higher than controls. Spartina detritus and sediments also exhibited greatly elevated arsenic concentrations. Virtually all of the arsenic was incorporated into plant tissue or strongly sorbed to cell surfaces. Thus, elevated arsenic concentrations in estuarine waters will be reflected in living and non-living components of a salt marsh ecosystem, implying that increased arsenic will be available to organisms within the marsh ecosystem.     

Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.     

A note on turbulent perturbations of salinity in a partially mixed estuary

Measurements of salinity perturbations in a partially mixed estuary have been used to evaluate the usefulness of an inductive salinometer and to determine some of the characteristics of the salinity perturbations. The salinometer performed satisfactorily under most conditions. Although internal wave like effects were present, the turbulence fluctuations were dominant. The salinity fluctuations and the turbulent fluxes $\text{sw}$ and $\text{su}$ were found to behave in a manner similar to the density fluctuations in a thermally stratified atmospheric boundary layer and a laboratory open channel flow. A quadrant analysis suggested that the contribution of each quadrant to the turbulent flux changed with Ri. The turbulence parameters ν and c_γ were found to decrease and increase respectively as Ri increases.     

The internal magnetic field of the Sun and peculiarities of the solar activity cycles

The existence of prolonged periods of abnormally low solar activity (such as the Maunder minimum) is explained within the framework of Leighton's model of a solar cycle with a hypothetical internal magnetic field of the Sun taken into account.     

Petrology and origin of amoeboid olivine aggregates in CR chondrites

Abstract— Amoeboid olivine aggregates (AOAs) are irregularly shaped, fine‐grained aggregates of olivine and Ca, Al‐rich minerals and are important primitive components of CR chondrites. The AOAs in CR chondrites contain FeNi metal, and some AOAs contain Mn‐rich forsterite with up to 0.7 MnO and Mn:Fe ratios greater than one. Additionally, AOAs in the CR chondrites do not contain secondary phases (nepheline and fayalitic olivine) that are found in AOAs in some CV chondrites. The AOAs in CR chondrites record a complex petrogenetic history that included nebular gas‐solid condensation, reaction of minerals with the nebular gas, small degrees of melting, and sintering of the assemblage. A condensation origin for the Mn‐rich forsterite is proposed. The Mn‐rich forsterite found in IDPs, unequilibrated ordinary chondrite matrix, and AOAs in CR chondrites may have had a similar origin. A type A calcium, aluminum‐rich inclusion (CAI) with an AOA attached to its Wark‐Lovering rim is also described. This discovery reveals a temporal relationship between AOAs and type A inclusions. Additionally, a thin layer of forsterite is present as part of the Wark‐Lovering rim, revealing the crystallization of olivine at the end stages of Wark‐Lovering rim formation. The Ca, Al‐rich nodules in the AOAs may be petrogenetically related to the Ca, Al‐rich minerals in Wark‐Lovering rims on type A CAIs. AOAs are chondrite components that condensed during the final stage of Wark‐Lovering rim formation but, in general, were temporally, spatially, or kinetically isolated from reacting with the nebula vapor during condensation of the lower temperature minerals that were commonly present as chondrule precursors.     

Chronology and evolution of the northern Iceland Plateau

New aeromagnetic data, K-Ar age determinations of dredged marine igneous rocks, as well as other geophysical evidence have shed light on the chronology, nature and evolution of the northern Iceland Plateau. Correspondence between seismic refraction profiles taken on the Jan Mayen Ridge and westward through Jan Mayen Island, suppressed aeromagnetic anomalies, earthquake surface wave studies, and ages of dredged igneous rocks suggest these strata may form an extended region of thickened crust, possibly of Caledonian age, extending westward toward the Kolbeinsey Ridge and northwest to the south wall of the Jan Mayen Fracture Zone.