雾化进样石墨炉原子吸收光谱法的研究 Ⅰ.直接雾化进样装置及其性能

介绍一种自行设计和加工的直接雾化石墨炉进样装置的结构、工作原理和操作方法。该装置由微机控制与石墨炉加热程序同步工作,可以实现自动控制和自动测量。对雾化进样石墨炉分析的仪器参数和实验条件进行了研究和选择。结果表明,该装置与石墨炉结合具有自动化程度高、重现性好、样品利用率高和分析速度快等特点。     

Runoff responses to afforestation in a watershed of the Loess Plateau,China

Afforestation has been suggested as a means of improving soil and water conservation in north‐western China, especially on the Loess Plateau. Understanding of the hydrological responses to afforestation will help us develop sustainable watershed management strategies. A study was conducted during the period of 1956 to 1980 to evaluate runoff responses to afforestation in a watershed on the Loess Plateau with an area of 1·15 km², using a paired watershed approach. Deciduous trees, including locust (locusta L.), apricot (praecox L.) and elm (ulmus L.), were planted on about 80% of a treated watershed, while a natural grassland watershed remained unchanged. It was estimated that cumulative runoff yield in the treated watershed was reduced by 32% as a result of afforestation. A significant trend was also observed that shows annual runoff reduction increases with the age of the trees planted. Reduction in monthly runoff occurred mainly from June to September, which was ascribed to greater rainfall and utilization by trees during this period. Afforestation also resulted in reduction in the volume and peak flow of storm runoff events in the treated watershed with greater reduction in peak flow. Copyright © 2003 John Wiley & Sons, Ltd.     

Modelling the April 15 spectrum of Supernova 1993 J

We present the modeling of the ultraviolet and optical spectra obtained simultaneously on 1993 April 15 with the HST and at Lick Observatory. A Monte Carlo code is employed in the modeling and a comparison is made between models reported by different groups. With an atmosphere similar to the Sun in chemical composition, the observed spectral lines are well reproduced by a power law density structure of index around 20 except the strong H and HeI λ5876 lines which have peculiar absorption profiles. The photospheric velocity is found to be 9500 km/s and the blackbody temperature of the spectrum is 7990 K. For H and HeI λ5876, we suggest a two-component density structure which has a smoother layer located immediately outside the steeply decreasing inner envelope. The power law indices are most probably 20 and 3, respectively, with the transition point at about 13 000 km/s. In addition, this outer smooth layer serves to flatten the far UV spectrum as observed.     

Short-term Climate Characteristics at Ny-(A)lesund over the Arctic Tundra Area

Based on the Germany Koldwey Station's 1994-2003 conventional observation hourly data, this paper conducts a statistical analysis on the short-term climate characteristics for an arctic tundra region (Ny-(A)lesund island) where our first arctic expedition station (Huanghe Station) was located. Affected by the North Atlantic warming current, this area has a humid temperate climate, and the air temperature at Ny-(A)lesund rose above 0 ℃ even during deep winter season during our research period. The wind speed in this area was low and appeared most at southeast direction. We find that the temperature at Ny-(A)lesund rose in the faster rate (0.68 ℃/10 a) than those at the whole Arctic area. Compared with the floating ices where our expedition conducted in the Arctic, Ny-(A)lesund was warmer and more humid and had lower wind speed. Comparison of the near surface air temperature derived by NCEP/NCAR reanalysis to the conventional measurements conducted at the Koldwey site in Ny-(A)lesund area shows a good agreement for winter season and a significant difference for summer season.     

Freshening of the Intermediate Waters in the Northern South China Sea over the PastSix Decades

The properties of salinity in the South China Sea (SCS), a significant marginal sea connecting the Pacific andIndian Oceans, are greatly influenced by the transport of fresh water flux between the two oceans. However, the long-termchanges in the intermediate water in the SCS have not been thoroughly studied due to limited data, particularly in relationto its thermodynamic variations. This study utilized reanalysis data products to identify a 60-year trend of freshening in theintermediate waters of the northern South China Sea (NSCS), accompanied by an expansion of low-salinity water. Thestudy also constructed salinity budget terms, including advection and entrainment processes, and conducted an analysis ofthe salinity budget to understand the impacts of external and internal dynamic processes on the freshening trend of theintermediate water in the NSCS. The analysis revealed that the freshening in the northwest Pacific Ocean and theintensification of intrusion through the Luzon Strait at intermediate levels are the primary drivers of the salinity changes inthe NSCS. Additionally, a weakened trend in the intensity of vertical entrainment also contributes to the freshening in theNSCS. This study offers new insights into the understanding of regional deep sea changes in response to variations in boththermodynamics and oceanic dynamic processes.     

准噶尔盆地中部III 区块原油中25-降藿烷分布特征与成因意义

通过对准噶尔盆地中部Ш区块原油或油砂抽提物的饱和烃气相色谱-质谱分析,研究了原油或油砂抽提物中25-降藿烷的分布规律.结果表明,不同井区或同一口井不同深度(层位)的原油25-降藿烷的相对含量存在比较明显的差别,表明其所遭受的生物降解程度有所差异,沿构造带从南到北,同一油层中原油的生物降解程度增强,比如位于构造北部(构造部位相对较高)的永1井、永3井侏罗系原油25-降藿烷丰度较高,表明生物降解比较明显,而位于南部(构造低部位)的永6井白垩系和侏罗系油层中的原油均无明显的生物降解现象;同一口井随深度增大生物降解作用将弱,如永2井浅部白垩系油层的原油降解较严重,而深部西山窑组的原油降解作用则不明显.根据原油生物降解的特征,结合车-莫古隆起调整对研究区油气成藏的影响,讨论了原油生物降解差异分布的成因机制.     

壳幔混染作用——下扬子区早中生代玄武岩同位素地质特征

下扬子区中生代（231Ma）玄武质火山岩全岩εNd（t）值-8.62～1.92,87Sr/86Sr 值0.7074～0.7179，206Pb/204Pb值为17.786～18.323。岩石中含有前寒武纪捕虏晶锆石。研究表明玄武质岩石可能是由亏损地幔与元古宙地壳岩石混染作用的结果。     

扬子地台钾镁煌斑岩 Nd、Sr、Pb 同位素特征

扬子地台周缘钾镁煌斑岩 Nd、Sr同位素特征介于南非Ⅰ、Ⅱ型金伯利岩和西澳与北美钾镁煌斑岩两种变化趋势之间，不同岩区间同位素组成差异反映地台周边构造性质不同，Pb同位素特征表明晚太古代地幔岩石圈具U亏损特征。     

辽西中生代火山岩岩浆成因——稀土元素配分及同位素定量模式

本文通过对辽西及邻区中生代盆地火山岩稀土元素配分特征的研究及模拟运算，探讨了其岩浆成因及过程。结果显示南北岩区岩浆成因不同，南岩区岩源为MORB地幔和长期富集型幔熔融混合而成，北岩区为MORB和近期亏损型地幔熔融混合而成。