Preliminary observations of oxygen and carbon dioxide of the wintertime Bering Sea marginal ice zone

Wintertime oxygen and pH profiles across the marginal ice zone of the central and southeastern Bering Sea shelf are analyzed and compared with summer data. During the winter, at water depths shallower than 75 m, the water column is homogeneous and near freezing. Between the 75- and 200-m isobaths the structure is essentially two-layered, a cool and fresh upper layer overlying a warmer, more saline bottom layer. The oxygen concentration in the surface mixed layer is higher than the summer values, but the degree of saturation is lower because of the lower temperature in winter. The oxygen degree of saturation in the bottom mixed layer on the shelf in winter are higher than in the surface water in winter and the bottom water in summer.In summer the oxygen and carbon dioxide data show extreme variability governed primarily by biological processes. Winter oxygen and pH data, however, do not scatter as much as the summer data and indicate conservative mixing of several sub-surface water masses. The surface water is undersaturated in both oxygen and carbon dioxide and seems to absorb oxygen, but little carbon dioxide, from the atmosphere.Two stations were occupied in the Aleutian Basin. The homogeneous surface layer has the same oxygen and pH values as in the minimum temperature layer observed in the summer by other investigators at the same location. The result substantiates the hypothesis of early investigators that the summer minimum temperature layer is the remnant local winter water. All winter surface waters sampled are undersaturated with respect to oxygen, suggesting that the input of oxygen through the air-sea exchange does not keep up with the rate of upwelling and cooling, which reduces the degree of oxygen saturation. Surface carbon dioxide is also undersaturated because of cooling. The maximum temperature layer at these two Aleutian Basin stations is warmer, fresher, and contains more oxygen, but less carbon dioxide, than in the summer, suggesting advective input of some nonlocal seawater.     

Upwelling and river runoff as sources of dissolved nitrous oxide to the Alsea estuary,Oregon

Surface waters of Alsea Bay, an unpolluted estuary on the Oregon coast, were analysed for nitrous oxide, nitrate and nitrite on a weekly or biweekly basis during the summer of 1979. The estuary was found to be a variable source of N₂O to the atmosphere. Large and rapid increases in the concentrations of N₂O, NO₃^?, and NO₂^? occurred at the beginning of the sampling period and are attributed to the influx of nutrient-rich upwelling water into the estuary with the tide. The subsequent decline in concentrations of nitrate, nitrite and nitrous oxide over the remainder of the summer is attributed to a decrease in upwelling intensity, a decline in nitrification rates and to assimilatory nitrate reduction. Measurements of nitrous oxide at six stations along the Alsea River were also made in September and October before and after the onset of the rainy season. Samples taken after flood conditions were established were systematically 50% higher than pre-flood samples. The data suggest that soil runoff results in elevated concentrations of N₂O in rivers.     

Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.     

Four-element CODAR beam forming

An HF radar called the Coastal Ocean Dynamics Applications Radar (CODAR) is presently being used in several forms to measure ocean surface parameters. The original version was developed by the National Oceanic and Atmospheric Administration (NOAA) and utilizes a four-element receive array. The array consists of four equally spaced elements arranged on a circle with a radius of 0.2151 wavelengths (at 25.4 MHz). It was designed to measure ocean currents using a direction-finding technique based on an extension to a simple two-element interferometer. The problem of determining the bearing of a radiating source can be readily shown to be equivalent to that incurred in spectral estimation. In an attempt to improve upon the processing of existing data, modern nonlinear spectral estimation techniques are applied in a beam-forming bearing estimation procedure and compared against several direction-finding algorithms. Enhancement of bearing estimators via analysis of the eigenstructure of a spatial correlation matrix is included. Antenna response patterns are calculated and used to investigate properties of direction-finding algorithms. Simulated data are used for a comparison of direction finding and beam forming. The asymmetrical bias of each method is investigated to determine its effect on the error in estimating the angle of arrival of a radar target.     

A note on turbulent perturbations of salinity in a partially mixed estuary

Measurements of salinity perturbations in a partially mixed estuary have been used to evaluate the usefulness of an inductive salinometer and to determine some of the characteristics of the salinity perturbations. The salinometer performed satisfactorily under most conditions. Although internal wave like effects were present, the turbulence fluctuations were dominant. The salinity fluctuations and the turbulent fluxes $\text{sw}$ and $\text{su}$ were found to behave in a manner similar to the density fluctuations in a thermally stratified atmospheric boundary layer and a laboratory open channel flow. A quadrant analysis suggested that the contribution of each quadrant to the turbulent flux changed with Ri. The turbulence parameters ν and c_γ were found to decrease and increase respectively as Ri increases.     

Relationships between Campi Flegrei and Mt. Somma volcanism: evidence from melt inclusions in clinopyroxene phenocrysts from volcanic breccia xenoliths

Summary We present compositions of reheated melt inclusions in clinopyroxene phenocrysts from three mafic xenoliths in Breccia Museo, Campi Flegrei, Italy. Melt inclusion compositions are remarkably different from the compositions of known contemporary Campi Flegrei lavas, being significantly enriched in K₂O and depleted in Na₂O. Some differences are also evident in FeO^* (total Fe as FeO) and TiO₂ contents. The clinopyroxene phenocrysts could not have crystallised from Campi Flegrei magmas. We suggest that they originated from a volcanic system genetically very similar to, and possibly linked with, the >14 ka volcanic system of Mt. Somma, another Campanian volcano ∼ 30 km east from Campi Flegrei, from which Vesuvius subsequently developed. This result indicates a close relationship (or link) between the two volcanic systems which have until now been considered separate. We speculate that the link was established prior to eruption of the Neapolitan Yellow Tuff (NYT) (∼ 12 ka). The xenoliths were derived from a volcanic system older than the host breccias themselves. We suggest that this older volcanism had close similarities with the volcanism of the older products of Mt. Somma (∼25 ka). Received March 20, 2000; accepted November 2, 2000