雾化进样石墨炉原子吸收光谱法的研究 Ⅰ.直接雾化进样装置及其性能

介绍一种自行设计和加工的直接雾化石墨炉进样装置的结构、工作原理和操作方法。该装置由微机控制与石墨炉加热程序同步工作,可以实现自动控制和自动测量。对雾化进样石墨炉分析的仪器参数和实验条件进行了研究和选择。结果表明,该装置与石墨炉结合具有自动化程度高、重现性好、样品利用率高和分析速度快等特点。     

Fast iterative solution of large undrained soil‐structure interaction problems

In view of rapid developments in iterative solvers, it is timely to re‐examine the merits of using mixed formulation for incompressible problems. This paper presents extensive numerical studies to compare the accuracy of undrained solutions resulting from the standard displacement formulation with a penalty term and the two‐field mixed formulation. The standard displacement and two‐field mixed formulations are solved using both direct and iterative approaches to assess if it is cost‐effective to achieve more accurate solutions. Numerical studies of a simple footing problem show that the mixed formulation is able to solve the incompressible problem ‘exactly’, does not create pressure and stress instabilities, and obviate the need for an ad hoc penalty number. In addition, for large‐scale problems where it is not possible to perform direct solutions entirely within available random access memory, it turns out that the larger system of equations from mixed formulation also can be solved much more efficiently than the smaller system of equations arising from standard formulation by using the symmetric quasi‐minimal residual (SQMR) method with the generalized Jacobi (GJ) preconditioner. Iterative solution by SQMR with GJ preconditioning also is more elegant, faster, and more accurate than the popular Uzawa method. Copyright © 2003 John Wiley & Sons, Ltd.     

暖温带地理景观中土壤硒的分异特征

本文按垂直自然带谱研究了暖温带地理景观中山地草旬土、山地棕壤、山地淋溶褐土和潮土中硒的分异特征。结果表明：（1）硒在土剖面上的分异，除受生物富集的影响外，淋溶和粘人作用强烈地制约着硒在剖面上的迁移；（2）不同机械组分中的硒含量以粘粒中最高，呈明显的粘粒＞细粉粒＞中粉粒＞砂粒序列。因此，成土过程中，不同机械组分以及次生或们生矿物和垂直运动和自然分选作用对土壤硒的地理分异具有非常重要的作用。（3）易于淋溶失的有机态或钙结合的硒对所研究的土壤表层硒的贡献都大于50％。提出淋溶作用是我国低硒带形成的主要外营力。     

Migration and enrichment of trace elements of Lower Palaeozoic carbonate rock strata in Beijing

Analyses of trace elements of the Lower Palaeozoic carbonate rock strata in Beijing show that the contents of As, Hg, F increase from primary carbonate rocks to weathered carbonate rocks and from primary carbonate rocks to the soil coexisting with carbonate rocks, but the distribution regularity of S is not obvious. In the whole weathered stages, the sorption of As is mainly affected by Fe2O3. In soil Fe2O3 is also the main affecting factor of Hg enrichment. The main existing forms of Hg in primary carbonate rocks should simply be physical adsorption, coprecipitation and false isomorphous form between surface of carbonate rock and Hg. In soil the enrichment of F has little relationship with sul-fides and Fe2O3. In primary carbonate rocks, F is mainly absorbed by sulfides and clay minerals, etc. Weathered samples have closer genetic relationships with primary carbonate rocks. This also implies that weathered carbonate rocks have the close existing forms to that of primary carbonate rocks. In primary carbonate rocks FeS2 and FeS are the main forms of S, and sulfides have fixation effect on some heavy metals, whereas in weathered carbonate rocks and soil the fixation effect is weakened.     

萨拉乌苏河流域150 ka BP以来的粒度旋回

萨拉乌苏河流域米浪沟湾地层剖面150kaBP以来古流动砂丘砂与河湖相和古土壤在粒度上具有多次显著的粗细韵律交替变化，粒度参数-Mz、σ、Sk、Kg和SC/D亦随之响应为多波动峰谷交替的态势，同时，粒度特征值-φ5、φ16φ、φ25、φ50、φ84、φ9相应地表现为非常有节奏地跳动，据此，将米浪沟湾剖面划分为27个粒度粗细沉积旋回，并认为其是150kaBP以来在东亚冬夏古代季风交替影响下沙漠演变的一个颇为完整的气候-地质过程记录。     

西北五省(区)生态环境综合分区及其建设对策

本文以图像遥感解译为主 ,结合野外实际考察 ,并通过抽样验证完成。在对生态环境界定和赋予内涵的基础上 ,根据区划目的、原则和所选取的指标体系 ,从生态环境分类入手 ,经过从上向下续分和由下向上合并的反复磨合过程、专家集成模拟 ,对西北五省(区 )生态环境做了全面的综合分区研究 ,并针对所存在的生态环境问题 ,提出生态环境保护和建设的对策 ,为西北五省 (区 )实施西部大开发生态环境监测、治理、建设和规划提供科学依据。     

Risk Management for Petroleum Reservoir Production: A Simulation-Based Study of Prediction

We consider numerical solutions of the Darcy and Buckley–Leverett equations for flow in porous media. These solutions depend on a realization of a random field that describes the reservoir permeability. The main content of this paper is to formulate and analyze a probability model for the numerical coarse grid solution error. We explore the extent to which the coarse grid oil production rate is sufficient to predict future oil production rates. We find that very early oil production data is sufficient to reduce the prediction error in oil production by about 30%, relative to the prior probability prediction.     

Methods for extraction of microorganism DNA from glacier surface snow

In order to thoroughly investigate the diversity of glacier microorganisms, four DNA extraction methods with different lysis patterns were tested and two screened methods (the Bosshard-Bano method and the Zhou method) were optimized for the most effective form of the filter membrane (cut vs. uncut), the DNA extraction method, and the precipitation method. The two optimized methods were then compared with the commercial Mo-Bio DNA extraction kit, and the results showed that the kit was generally suitable for extraction of microorganism DNA from glacier surface snow. Procedurally, it was found that a modified Bosshard- Bano method (i.e., cutting the filter membrane into pieces, using a specific lysis pattern [lysozyme (5 mg/mL)-protease K (1 mg/mL)-CTAB (1%)-SDS (1%)], performing the extraction only once by chloroform-isoamyl alcohol (24:1), and conducting DNA precipitation by pure ethanol) was also an effective and less expensive method for extraction of microorganism DNA from glacier surface snow.     

GEOCHRONOLOGICAL LIMITATIONS FOR INTERPRETING THE PALEOCLIMATIC HISTORY OF THE TIBETAN PLATEAU

在当前全球变化背景下,青藏高原冰川急剧退缩严重影响着东亚地区水资源.为了有效地规划水资源,需要对高原气候变化及其机制有深入的理解.尽管在青藏高原及周边地区有大量的古气候记录,但是目前对高原气候的时空变化及其机制仍缺乏深入一致的认识.青藏高原冰川、树轮和石笋记录可以提供过去气候变化的框架,但是这些记录的分布局限于一些特定的地理区域.青藏高原上广泛分布的湖泊沉积物是研究高原气候的时空变化及其机制的优良介质.湖泊沉积物岩芯的年龄控制主要依赖于放射性碳同位素定年,但大多数高原湖泊具有碳库效应,为建立沉积岩芯年代控制需要进行碳库年龄校正所带来的年龄误差目前未有深入研究,这在某种程度上制约了利用湖泊沉积物记录研究高原气候时空变化及其机制.本文比较了目前确定高原湖泊碳库年龄的方法并提出建议采用的方法,汇总目前己发表的高原湖泊碳库年龄,讨论湖泊现代碳库年龄的空间分布及其影响因素,讨论湖泊碳库过去变化及其可能造成的岩芯年代控制误差;以青海湖和班公错两个高原湖泊已发表的记录为例讨论过去碳库年龄变化可能造成对记录完全不同的解释;还讨论了由碳库效应校正而带来的湖泊沉积物岩芯年龄控制误差对青藏高原湖泊记录的末次盛冰期终止年代的空间分布及其对变化机制解释的影响.如果考虑碳库效应的过去变化,目前所观测到的高原气候时空变化及其机制需要重新解释.因此,为了更好地理解青藏高原气候时空变化及其机制,我们需要更多有良好定年、高分辨率和定量化的湖泊记录,本文也建议在解释目前湖泊记录时需要应对年龄控制极大重视.